Vibrational and rotational studies using Q switching of molecular gas lasers.
Vibrational and rotational relaxations in carbon dioxide and nitrous oxide laser systems, using Q- switching techniques
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Vibrational and rotational relaxations in carbon dioxide and nitrous oxide laser systems, using Q- switching techniques
The dust characteristics of a 40 arcmin x 40 arcmin section of the Rho Ophiuchi molecular clouds complex revealed by the IRAS satellite are compared with both molecular line and deep star count data for the region. The data reveal the cloud to be clearly visible at 12 and 25 microns, as well as at 60 and 100 microns. Modeling the infrared emission from the cloud as being due to two populations of dust grains, the short-wavelength emission is found not to reflect the internal structure of the molecular cloud. The 60 micron opacity determined using a single grain emission model correlates reasonably well with (C-13)O column density and visual extinction up to roughly 5 mag. The cloud edges appear to be heated by the interstellar radiation field. The far-infrared luminosity to mass ratio for the region is determined to be 0.9 solar luminosity/solar mass, a value much smaller than the average ratio for the inner Galaxy.
In this paper we describe a powerful method for mapping the distribution of dust through a molecular cloud using data obtained in large-scale, multiwavelength, infrared imaging surveys. This method combines direct measurements of near-infrared color excess and certain techniques of star counting to derive mean extinctions and map the dust column density distribution through a cloud at higher angular resolutions and greater optical depths than those achieved previously by optical star counting. We report the initial results of the application of this method to a dark cloud complex near the cluster IC 5146, where we have performed coordinated, near-infrared, JHK imaging and (13)CO, C(18)O, and CS millimeter-wave, molecular-line surveys of a large portion of the complex. More than 4000 stars were detected in our JHK survey of the cloud. Of these, all but about a dozen appear to be field stars not associated with the cloud. Star count maps at J band show a striking and detailed anticorrelation between the surface density of J-band sources and CO and CS molecular-line emission. We used the (H-K) colors and positions of nearly 1300 sources to directly measure and map the extinction and thus trace the dust column density through the cloud at an effective angular resolution of 1 min .5. We report an interesting correlation between the measured dispersion in our extinction determinations and the extinction. Modeling this relation indicates that effects of small-scale cloud structure dominate the uncertainties in our measurements. Moreover, we demonstrate that such observations can be used to place constraints on the nature of the spatial distribution of extinction on scales smaller than our resolution. In particular, we show that models in which the dust is distributed uniformly or in discrete high-extinction clumps on scales smaller than (1 min .5) are inconsistent with the observations. We have derived extinctions at the same positions and at the same angular resolution (1 min .7) as our molecular-line observations. This enabled a direct comparison of (13)CO, C(18)O, and CS integrated intensities and column densities with A(sub V) for more than 500 positions in the cloud, corresponding to a range in A(sub V) between 0 to 32 mag of extinction. We found the integrated intensities of (13)CO, C(18)O, and CS to be roughly linearly correlated with extinction over different ranges of extinction. However, for all three molecules we find the scatter in the observed relations to be larger than can be accounted for by instrumental error, suggesting that there are large intrinsic variations in the abundances or excitation of the molecules through the cloud. Mean abundances for all the molecules relative to hydrogen were directly derived from the data. The ratio of (13)CO to C(18)O abundances was found to be significantly higher than the terrestrial ratio in regions where extinction is less than 10 mag. In the same region, the dispersion in the abundance ratio is also found to be very large, suggesting that the abundances of one or both molecules are very unstable even at relatively large cloud optical depths. Beyond 10 mag of extinction the abundances of both species appear very stable with their ratio close to the terrestrial value.
We present a number of high-resolution radio images showing evidence for the dynamical interaction of the outflow arising from the IRS 16 complex with the ionized gas associated with the Northern Arm of Sgr A West, and with the northwestern segment of the circumnuclear molecular disk which engulfs the inner few parsecs of the Galactic center. We suggest that the wind disturbs the dynamics of the Northern Arm within 0.1 pc of the center, is responsible for the waviness of the arm at larger distances, and is collimated by Sgr A West and the circumnuclear disk. The waviness is discussed in terms of the Rayleigh-Taylor instability induced by the ram pressure of the wind incident on the surface of the Northern Arm. Another consequence of this interaction is the strong mid-IR polarization of the Northern Arm in the vicinity of the IRS 16 complex which is explained as a result of the ram pressure of the wind compressing the gas and the magnetic field.
Hydrogen is a clean alternative to fossil fuels, emitting only water vapor during combustion. In a future hydrogen economy, large-scale storage will be an important component of the supply chain. Due to its low volumetric density, conventional surface storage methods are inadequate. Underground hydrogen storage (UHS) offers a viable solution, enabling the storage of millions of cubic meters. Among potential geological sites, including salt caverns, aquifers, and depleted gas reservoirs, depleted oil reservoirs show promise. Studying hydrogen interactions with residual oil and reservoir minerals is vital for understanding the properties of hydrogen and the reservoir post-injection. In this work, we employed molecular dynamics simulations to gain molecular-level insights into these interactions. We investigated hydrogen dissolution in oil, adsorption at kaolinite/oil interfaces, the role of CO 2 as a cushion gas, and the influence of kaolinite’s hydrophobicity on H 2 behavior. The main findings include: (1) hydrogen dissolves more in oil than in water, (2) the introduction of CO 2 suppresses hydrogen dissolution in oil and reduces the interfacial tension (IFT) between oil and gas, (3) CO 2 decreases H 2 partitioning near kaolinite surfaces due to its strong affinity for the hydrophilic gibbsite surface of kaolinite, and (4) CO 2 is more effective than H 2 in reducing IFT between kaolinite and the oil–gas mixture. These findings emphasize the effectiveness of CO 2 as a cushion gas and the important role of clay hydrophobicity in UHS, providing insights that are challenging to obtain experimentally.
Results from the first large-scale survey in the CO (J = 1 - 0) line of the Vela-Carina-Centaurus region of the southern Milky Way are reported. The results demonstrate that molecular clouds in the Galaxy are largely confined to the spiral arms and that CO is therefore an extremely good tracer of the large-scale structure of the system. The Carina arm is the dominant feature in the data. Its abrupt tangent at l of roughly 280 deg and characteristic loop in the (l, v) diagram are unmistakable evidence for CO spiral structure. When the emission is integrated over velocity and latitude, the height of the step seen in the tangent direction indicate that the arm-interarm contrast is at least 13:1.
Titan's northern spring equinox occurred in August 2009. General Circulation Models (e.g. Lebonnois et al., 2012) predict strong modifications of the global circulation in this period, with formation of two circulation cells instead of the pole-to-pole cell that occurred during northern winter. This winter single cell, which had its descending branch at the north pole, was at the origin of the enrichment of molecular abundances and high stratopause temperatures observed by Cassini/CIRS at high northern latitudes (e.g. Achterberg et al., 2011, Coustenis et al., 2010, Teanby et al., 2008, Vinatier et al., 2010). The predicted dynamical seasonal variations after the equinox have strong impact on the spatial distributions of trace gas, temperature and aerosol abundances. We will present here an analysis of CIRS limb-geometry datasets acquired in 2010 and 2011 that we used to monitor the seasonal evolution of the vertical profiles of temperature, molecular (C2H2, C2H6, HCN, ..) and aerosol abundances.
The distribution of the atomic and ionized hydrogen along the inner spiral arms of M51 are compared. As is the case in M83, the location of both these phases of the interstellar medium with respect to the major dust lanes suggests that molecular hydrogen is dissociated on kpc scales in active star-forming regions, and that this dissociation process may strongly affect the observed morphology of atomic hydrogen in spiral arms.
The present study includes 65 spiral galaxies selected from the Five College Radio Astronomy Observatory (FCRAO) Extragalactic CO Survey for which the major axis distributions of CO emission and 1.49 GHz radio continuum emission are well determined. The radial distribution of the CO emission has been measured with the FCRAO at positions along the major axis that are spaced by one half power beam width (HPBW) (45 seconds). The radial profile of the 1.49 GHz radio continuum emission was constructed by determining the radio emission at the location of the CO measurements from the 1.49 GHz maps of Condon (1987). Large, greater than a factor of ten, radially decreasing gradients in the star formation efficiency are observed for a small percentage, approx. 10 percent, of the spirals in this sample. The majority of spirals, however, are associated with small gradients in the star formation efficiency that do not systematically increase or decrease with radius. That the star formation efficiency does not systematically decrease with radius tends to argue against a global dynamical mechanism, such as a spiral density wave, for being the dominant mechanism triggering disk star formation for the majority of spirals in this sample. The results tend to support the view that the star formation in spiral disks is dominated by a local process that depends more on the molecular cloud properties than the dynamical structure of a galaxy.
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The Taurus dark cloud complex is a collection of many individual clouds scattered across approximately 50 pc. Within one of these, Heiles Cloud 2, is the dense condensation TMC 1. TMC 1 is one of the few sources in which some of the long carbon chain molecules are found. The present investigation is concerned with a mapping of the density structure in a narrow ridge of the TMC 1 structure. It is shown that the HC3N emission from the J = 5 to 4, J = 9 to 8, and J = 12 to 11 transitions is well matched by a narrow ridge of material at a single density of 50,000-100,000 per cu cm. There is evidence that the HC3N fractional abundance is variable along the ridge. Evidence is also found for the presence of subcondensations within this ridge from maps at individual velocities.
The J = 1 - 0 transition of (C-13)O over a 3 sq deg region in Heiles Cloud 2 has been mapped using the Five College Radio Astronomy Observatory 14 m telescope. The complete map contains 3600 individual spectra of which 2400 were sampled with 1 arcmin spacing. The map suggests that the structure of Heiles Cloud 2 is dominated by a quasi-equilibrium rotating ring similar to those found in numerical calculations of the gravitational collapse of a rotating cloud. Within this ring, several dense condensations have been identified and partially mapped in C(O-18). These subcondensations, among which is the dense filament TMC-1, probably result from the instability of the ring to fragmentation and have masses on the order of the jeans mass. Thus, they are marginally unstable to further collapse and may be the precursors of fragments that will eventually form stars.
A comparison of COS-B gamma-ray observations of the large complex of interstellar clouds in Orion and Monoceros with the Columbia CO and Berkeley H I surveys of this region reveals a good correlation between gamma-ray emission and total gas distribution. The observed gamma-ray emission is explainable in terms of interactions of cosmic rays that are uniformly distributed in this region with the interstellar gas. The correlation is used as the basis of a calibration of the ratio between H2 column density and the integrated CO line intensity; the value of (2.6 + or - 1.2) X 10 to the 20th mol/sq cm K km s thereby obtained is consistent with the value derived from a similar analysis for the inner galaxy.
The present study is concerned with the development of a computational model for the description of the vibrational energy exchange in flowing gas mixtures, taking into account a given number of energy levels for each vibrational degree of freedom. It is possible to select an arbitrary number of energy levels. The presented model uses values in the range from 10 to approximately 40. The distribution of energy with respect to these levels can differ from the equilibrium distribution. The kinetic model developed can be employed for arbitrary gaseous mixtures with an arbitrary number of vibrational degrees of freedom for each type of gas. The application of the model to CO2-H2ON2-O2-He mixtures is discussed. The obtained relations can be utilized in a study of the suitability of radiation-related transitional processes, involving the CO2 molecule, for laser applications. It is found that the computational results provided by the model agree very well with experimental data obtained for a CO2 laser. Possibilities for the activation of a 16-micron and 14-micron laser are considered.
The Owens Valley Millimeter Wave Interferometer has been used to map the 2.6-mm CO emission in the ultraluminous infrared galaxy Arp 220. Approximately 70 percent of the CO emission from the galaxy originates from an unresolved region less than 4 arcsec x 6 arcsec in size (corresponding to 1500 pc diameter) centered on the near-infrared nucleus. The mass of gas within this region is 10 to the 10th solar mass, which is about 30 times greater than that in an equivalent area of the Galaxy. This concentration could result in efficient star formation via cloud-cloud collisions and provide a significant accretion flow onto a compact, central object.
The NASA 64-m and CSIRO 64-m antennas at Tidbinbilla and Parkes, respectively, have been used to observe the star-forming region associated with HH46 and HH47 in the Bok globule known as ESO 210-6A or Sa III. The (1,1), (2,2), and (3,3) transitions of ammonia were observed at the position of the infrared point source, which is the star energizing this complex. Ammonia was not detected at other nearby locations in the globule. The ammonia emission is attributed to a circumstellar toroid or disk with a gas temperature of 17 + or - 2 K, a density of 7 + or - 20,000/cu cm, a size of 6000-7500 Au, and a mass of 0.09-0.14 solar masses, assuming an ammonia abundance of 10 to the -7th. Such a low disk mass may imply more than mere confinement as the mechanism for achieving high collimation observed in the outflow from this region.
The emission from the Galactic center at 2.72 mm from (C-13)O has been surveyed, and the results are reported. Data from 488 spectra taken in the region of l between -2.0 deg and +2.0 deg and b between -0.467 deg and +0.467 deg, and with a spectral resolution of 2.7 km/s over the V(LSR) range of -300 km/s to +300 km/s, are presented in eight l-v diagrams and in 123 maps in the plane of the sky. An averaged l-v diagram shows that virtually all of the (C-13)O emission falls within a roughly symmetrical parallelogram in l-v space; the center of symmetry is near l = +0.25 deg, V(LSR) = +30 km/s. A map of the integrated (C-13)O is presented which is very similar to maps of the far-IR continuum in which Sgr A, B2, C, and D are prominent. Maps of the emission at absolute value of V(LSR) above 100 km/s show that most of the high-velocity gas is tilted out of the Galactic plane by 7 deg; the nuclear disk appears to be inclined to the line of sight by about 85 deg.
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