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At least 73 records · Page 4

The Mineralogical Record of Oxygen Fugacity Variation and Alteration in Northwest Africa 8159: Evidence for Interaction Between a Mantle Derived Martian Basalt and a Crustal Component(s)

A prominent geochemical feature of basaltic magmatism on Mars is the large range in initial Sr isotopic ratios (approx. 0.702 - 0.724) and initial epsilon-Nd values (approx. -10 to greater than +50). Within this range, the shergottites fall into three discreet subgroups. These subgroups have distinct bulk rock REE patterns, mineral chemistries (i.e. phosphate REE patterns, Ni, Co, V in olivine), oxygen fugacity of crystallization, and stable isotopes, such as O. In contrast, nakhlites and chassignites have depleted epsilon-Nd values (greater than or equal to +15), have REE patterns that are light REE enriched, and appear to have crystallized near the FMQ buffer. The characteristics of these various martian basalts have been linked to different reservoirs in the martian crust and mantle, and their interactions during the petrogenesis of these magmas. These observations pose interesting interpretive challenges to our understanding of the conditions of the martian mantle (e.g. oxygen fugacity) and the interaction of mantle derived magmas with the martian crust and surface. Martian meteorite NWA 8159 is a unique fine-grained augite basalt derived from a highly depleted mantle source as reflected in its initial epsilon-Nd value, contains a pronounced light REE depleted pattern, and crystallized presumably under very oxidizing conditions. Although considerably older than both shergottites and nahklites, it has been petrogenetically linked to both styles of martian magmatism. These unique characteristics of NWA 8159 may provide an additional perspective for deciphering the petrogenesis of martian basalts and the nature of the crust of Mars.

Shearer, Charles K.↗

Aiding in the Efforts of Bioregenerative Life Support for the Future Residents of Mars and Long-Duration Space Flights Plant Growth in Amended Martian Regolith Simulant

Currently, the goal of plant growth research at KSC (Kennedy Space Center) is to provide a sustainable source of healthy food on long-duration space flights so astronauts and future residents of Mars can get the nutrition they need and produce food, recycle the atmosphere, and aid in recycling water. The sustainable production of food will aid in the efforts of closed life support. Plants have a vital application for bioregenerative life support as demands for food and oxygen can be provided through photosynthesis, while the carbon dioxide from human respiration is removed. In order for a growing medium to provide for plant growth, it needs to provide support, oxygen, ions, and liquid to the plant. This summer research determines how amended Martian regolith simulant acts as a growing medium for plants through looking at the structural properties of each amendment. Mars is covered with regolith which is crushed volcanic rock that is composed of a high amount of perchlorate salts. The composition of Martian soil is such that it is roughly basaltic and consists of sulfur, nitrates, and oxychlorine species. Martian regolith simulants have been generated to further analyze plant growth and aim to replicate features of the reference sample. The JSC (Johnson Space Center) Mars-1A regolith simulant resembles Martian regolith at the Viking I landing site. The objectives of the research this summer at Kennedy Space Center are to devise a plant growth in amended JSC Mars-1A Martian regolith simulant and perform crop studies to assess the performance of full duration crop growth in amended Martian regolith simulant. This research will provide a deeper understanding of how the combination of soil amendments to Martian regolith has a synergistic effect on improving crop production The plant growth experiment will be completed with three treatments each containing inorganic and organic soil amendments.

Onsay, Daphne↗

Chalcophile Element Constraints on the Sulfur Content of the Martian Mantle

The sulfur content of the Martian mantle is critical to understanding volcanic volatiles supplied to the surface of Mars and possibly climate. In the absence of Martian mantle rocks, sulfur content of the mantle has been inferred from S contents of Martian meteorites or from sedimentary sulfate abundances. Estimates of the sulfur content of the Martian mantle vary from 390-2,000 ppm, all of which are higher than that of the terrestrial mantle (~250 ppm;). Residual sulfide in the Martian mantle controls the distribution of chalcophile elements during partial melting. In this study, we report new analyses of Martian meteorites, and use the incompatible behavior of As, Tl and Pb to infer the sulfide mode of the Martian mantle using a different set of assumptions than those of prior studies.

Yang, S.↗

Scroll Pump Dust Tolerance Test for Martian Atomospheric Acquisition

The ability to generate oxygen on the Martian surface will be essential to establishing a human presence on Mars. Flow generating devices such as pumps, compressors, and blowers will be essential components in Martian atmospheric acquisition and processing systems that need to work reliably during the mission duration. A concern with the reliability of the system is its ability to continue to perform nominally when Martian dust, if it bypasses the inlet filter, enters into the system. A series of tests were conducted to simulate the ingesting of Martian dust on a small scroll pump, similar to the one used on the MOXIE payload, during its pumping operation. The inlet of the pump was connected to a large volume closed-loop pipe system, known as the Mars Atmospheric Flow Loop, containing pure CO2 gas at a Martian pressure of 7 Torr. A length of stainless steel tubing was extended from the inlet port of scroll pump, which was mounted outside the flow loop, to the inside volume of the flow loop using a feed-through compression fitting. A steady low-speed flow was generated inside the flow loop to continuously disperse and transport the dust toward the inlet tubing. JSC-Mars 1 Martian simulant was used to challenge the pump. The pump performance parameters such as flow rate, pump speed, pressures and temperature were monitored during these tests. Samples of the dust entering the pump inlet were taken prior to exposure tests, using an inline filter element to determine the rate of dust ingestion into the internal components of the pump. After two tests with exposure times of the order of 60 minutes, the data indicated that small changes in pump performance took place under high rates of dust exposure.

scroll pump↗

Scroll Pump Dust Tolerance Test for Martian Atmospheric Acquisition

The ability to generate oxygen on the Martian surface will be essential to establishing a human presence on Mars. Flow generating devices such as pumps, compressors, and blowers will be crucial components in Martian atmospheric acquisition and processing systems that need to work reliably during the mission duration. A concern with the reliability of the system is its ability to continue to perform nominally when Martian dust, if it bypasses the inlet filter, enters into the system. A series of tests were conducted to simulate the ingestion of Martian dust on a small scroll pump, similar to the one used on the MOXIE payload. The inlet of the pump was connected to a large volume closed-loop pipe system, known as the Mars Atmospheric Flow Loop, containing pure CO2 gas at a Martian pressure of 7 Torr. A length of stainless steel tubing was extended from the inlet port of scroll pump, which was mounted outside the flow loop, to the inside volume of the flow loop using a feed-through compression fitting. A steady low-speed flow was generated inside the flow loop to continuously disperse and transport the dust toward the inlet tubing. JSC-Mars 1 Martian simulant was used to challenge the pump. Pump performance parameters such as flow rate, pump speed, pressure and temperature were monitored during these tests. Samples of the dust entering the pump inlet were taken prior to the exposure tests, using an inline filter element to determine the rate of dust ingestion into the internal components of the pump. After two tests with exposure times of one hour, the data indicated that small changes in pump performance took place under high rates of dust exposure.

Martian Atmospheric↗

Martian crater depth/diameter relationships - Comparison with the moon and Mercury

New Martian topographic data from Mariner 9 ultraviolet spectrometer (UVS) profiles provide depth data for 139 Martian craters of all degrees of degradation, between the diameters of 15 and 201 km. The population of Martian craters, including morphologically fresh examples, is shallower than both lunar and Mercurian fresh crater populations. Because the surface gravities of Mercury and Mars are identical within 5%, these differences in fresh crater depths suggest that factors other than gravity may play important roles in determining initial crater depths (e.g., differences in impact velocity, substrate variations, and Martian atmospheric effects during the crater-forming event). Degraded Martian craters are, on the average, no shallower than lunar pre-Imbrian craters of similar sizes. If the early bombardment of Mars was as significant a degradational agent as it was on the moon, then major levels of crater degradation and crater shallowing on Mars were associated with this mechanism. Continued eolian infilling, although locally significant, may be a less significant cause of morphometric degradation of large old Martian craters.

Cintala, M. J.↗

Comparison between infrared Martian disk spectra and optical properties of terrestrial analogs

Medium spectral resolution (20 kaysers) infrared measurements of the Martian disk made between 2900 and 5600 kaysers from the NASA Lear Airborne Observatory have been successfully compared with predictions derived from a model of the Martian soil and atmosphere. Modeling of the Martian atmosphere permitted the extraction of Martian soil reflectance in the CO2 bands centered at 3657 kaysers. Three Martian soil analogs previously considered acceptable - limonite, montmorillonite, and basalt - were analyzed to determine the optical complex indices of refraction in the same range as the airborne observations, for mathematical modeling. A characteristic surface particle size approximately 1 to 3 microns diameter is indicated. It is concluded that the Martian soil surface near-infrared optical properties are consistent with a soil composition similar to montmorillonite or limonite, mixed with a basalt.

Egan, W. G.↗

Volatile/mobile trace elements in meteoritic, non-lunar basalts: Guides to Martian sample contents

A variety of genetic processes on or in extraterrestrial objects can be examined by study of volatile/mobile trace elements. Doubtless, considerable efforts will be expended on determining these elements in returned Martian samples. The purpose is to estimate levels of such elements expected to be present in returned Martian samples. Some ideas about Martian genesis were already advanced from the volatile/mobile element contents in SNC meteorites, assuming that Mars was their parent body. Even is Mars and the SNC meteorite parent body are identical, compositional ranges for returned Martian samples should exceed those of SNC meteorites. It is expected, therefore, that Martian samples returned from locations other than Polar regions will have indigenous volatile/mobile element contents within howardite-diogenite ranges. Elements with strong lithophile tendences may be more abundant, as they are in many lunar samples. Most of these elements should be at ppb levels except for Co, Ga, Zn, and Rb, which should lie at ppm levels. If Martian volcanism was accompanied by fumarolic emanations, it should be reflected in occasional huge enrichments of mobile trance elements, as in lunar meteorite Y 791197. During collection and transport Earthward, samples must be contained under conditions appropriate to ppb concentrations. Materials must be used that will not cause contamination which occurred during the Apollo program, where indium from seals contaminated many samples.

Lipschutz, M. E.↗

On the weathering of Martian igneous rocks

Besides the young crystallization age, one of the first arguments for the martian origin of shergottite, nakhlite, and chassignite (SNC) meteorites came from the chemical similarity of the meteorite Shergotty and the martian soil as measured by Viking XRF analyses. In the meantime, the discovery of trapped rare gas and nitrogen components with element and isotope ratios closely matching the highly characteristic ratios of the Mars atmosphere in the shock glasses of shergottite EETA79001 was further striking evidence that the SNC's are martian surface rocks. The martian soil composition as derived from the Viking mission, with its extremely high S and Cl concentrations, was interpreted as weathering products of mafic igneous rocks. The low SiO2 content and the low abundance of K and other trace elements in the martian soils point to a mafic crust with a considerably smaller degree of fractionation compared to the terrestrial crust. However, the chemical evolution of the martian regolith and soil in respect to surface reaction with the planetary atmosphere or hydrosphere is poorly understood. A critical point in this respect is that the geochemical evidence as derived from the SNC meteorites suggests that Mars is a very dry planet that should have lost almost all its initially large water inventory during its accretion.

Dreibus, G.↗

An attempt to comprehend Martian weathering conditions through the analysis of terrestrial palagonite samples

Spectroscopic observations of the Martian surface in the invisible to near infrared (0.4-1.0 micron), coupled with measurements made by Viking, have shown that the surface is composed of a mixture of fine-grained weathered and nonweathered minerals. The majority of the weathered components are thought to be materials like smectite clays, scapolite, or palagonite. Until materials are returned for analysis there are two possible ways of proceeding with an investigation of Martian surface processes: (1) the study of weathering products in meteorites that have a Martian origin (SNC's), and (2) the analysis of certain terrestrial weathering products as analogs to the material found in SNC's, or predicted to be present on the Martian surface. We describe some preliminary measurements of the carbon chemistry of terrestrial palagonite samples that exhibit spectroscopic similarities with the Martian surface. The data should aid the understanding of weathering in SNC's and comparisons between terrestrial palagonites and the Martian surface.

Douglas, C.↗

Implications of noble gases in a recently recognized Martian meteorite (ALH84001) for the degassing history of Mars

For terrestrial planets, atmospheric compositions are not static, but evolve with time, in part due to degassing of the interior. Unfortunately, the evolution is slow enough that it is usually not observable on human timescales, or even on the timescales of rocks that preserve samples of Earth's ancient atmosphere. Preliminary results on a recently recognized Martian meteorite, ALH84001, indicate that it is a very old rock, and has a relatively high noble gas content suggestive of atmospheric incorporation, but with an isotopic composition slightly inconsistent with currently known Martian reservoirs. Hence, this rock may provide a sample of ancient Martian atmosphere, which can be used to test models of volatile evolution (in particular, degassing) on Mars. ALH84001 is a cumulate orthopyroxenite. Although originally classified as a diogenite, its oxygen isotopes, and several chemical and petrographic features, strong suggest that it is, like the SNC meteorites, Martian. A Sm-Nd crystallization age of 4.5 Ga has been reported. The meteorite is rich in noble gases, compared to most SNC's. In many respects the noble gases are typical of SNC meteorites. However, there are some subtle differences. In particular, the Xe isotopes in SNC meteorites can be explained as a mixture of Martian atmospheric Xe (as represented by glass in EETA 79001), the Xe in the dunite Chassigny (usually assumed to be representative of the Martian interior, and with lower (129)Xe/(132)Xe, (134)Xe/(132)Xe and (136)Xe/(132)Xe ratios), and later additions from known processes like fission, spallation and terrestrial contamination. The isotopic composition of ALH84001 is inconsistent (at greater than 2-3 sigma) with any mixture of those components. Even if no accumulation of fission Xe during the age of the rock is assumed, there is too little (136)Xe and (134)Xe for the amount of (129)Xe measured.

Swindle, T. D.↗

Martian carbonates in ALH 84001: Textural, elemental, and stable isotopic compositional evidence on their formation

Martian orthopyroxenite ALH 84001 is unusual compared to other martian meteorites in its abundance of Mg-Fe-Ca carbonites. Becasue textural evidence indicates that these carbonates are undoubtedly of martian origin, we have undertaken stable isotopic studies to elucidate their origin by evaluating whether they represent primordial martian C that was outgassing from the mantle of Mars, or volatile additions to the ALH 84001 protolith that equilibrated with the martian atmosphere. If precipitation occurred in a closed system then the isotopic results are compatible with the observed chemical zonation. A unique temperature of formation can be calculated using the difference in C-13 and O-18 between the Fe and Mg carbonates, assuming that precipitation occurred at a constant temperature. Precipitation of approximately one-half of the CO2 reservoir at 320 C can account for the observed values, with the original CO2 reservoir having a delta C-13 of approximately 45% and delta O-18 of approximately 22%. If carbonate precipitated in equilibrium with a large isotopically homogeneous CO2 reservoir (open system), isotopic differences must be attributed to a change in temperature of at least several hundreds of degrees. This temperature change is compatible with a calculated range of temperatures based on carbonate geothermometry. Clearly, carbonate in ALH 84001 is in delta O-18 disequilibrium with orthopyroxene groundmass. Most likely, the carbonate precipitated from a fluid that equilibrated with the martian atmosphere. The deposits or fluids in equilibrium with these deposits were remobilized in the crust producing the carbonate in ALH 84001. This observation establishes a link for the first time between the atmospheric and lithospheric C and O pools that reside on Mars.

Romanek, C. S.↗

Shergottite Impact Melt Glasses Contain Soil from Martian Uplands

Martian meteorite (shergottite) impact melt glasses that contain high concentrations of martian atmospheric noble gases and show significant variations in Sr-87/Sr-86 isotopic ratios are likely to contain Martian surface fines mixed with coarser regolith materials. The mixed soil constituents were molten due to shock at the time of meteoroid impact near the Martian surface and the molten glass got incorporated into the voids and cracks in some shergottite meteorites. Earlier, Rao et al. found large enrichments of sulfur (sulfate) during an electron-microprobe study of several impact melt glass veins and pods in EET79001,LithC thin sections. As sulfur is very abundant in Martian soil, these S excesses were attributed to the mixing of a soil component containing aqueously altered secondary minerals with the LithC precursor materials prior to impact melt generation. Recently, we studied additional impact melt glasses in two basaltic shergottites, Zagami and Shergotty using procedures similar to those described by Rao et al. Significant S enrichments in Zagami and Shergotty impact melt glass veins similar to the EET79001, LithC glasses were found. In addition, we noticed the depletion of the mafic component accompanied by the enrichment of felsic component in these impact melt glass veins relative to the bulk host rock in the shergottites. To explain these observations, we present a model based on comminution of basaltic rocks due to meteroid bombardment on martian regolith and mechanical fractionation leading to enrichment of felsics and depletion of mafics in the fine grained dust which is locally mobilized as a result of saltation and deflation due to the pervasive aeolian activity on Mars.

Rao, M. N.↗

Shergottite Impact Melt Glasses Contain Soil from Martian Uplands

Martian meteorite (shergottite) impact melt glasses that contain high concentrations of martian atmospheric noble gases and show significant variations in Sr-87/Sr-86 isotopic ratios are likely to contain Martian surface fines mixed with coarser regolith materials. The mixed soil constituents were molten due to shock at the time of meteoroid impact near the Martian surface and the molten glass got incorporated into the voids and cracks in some shergottite meteorites. Earlier, Rao et al. found large enrichments of sulfur (sulfate) during an electron-microprobe study of several impact melt glass veins and pods in EET79001,LithC thin sections. As sulfur is very abundant in Martian soil, these S excesses were attributed to the mixing of a soil component containing aqueously altered secondary minerals with the LithC precursor materials prior to impact melt generation. Recently, we studied additional impact melt glasses in two basaltic shergottites, Zagami and Shergotty using procedures similar to those described. Significant S enrichments in Zagami and Shergotty impact melt glass veins similar to the EET79001, LithC glasses were found. In addition, we noticed the depletion of the mafic component accompanied by the enrichment of felsic component in these impact melt glass veins relative to the bulk host rock in the shergottites. To explain these observations, we present a model based on comminution of basaltic rocks due to meteoroid bombardment on martian regolith and mechanical fractionation leading to enrichment of felsics and depletion of mafics in the fine grained dust which is locally mobilized as a result of saltation and deflation due to the pervasive aeolian activity on Mars.

Rao, M. N.↗

Considerations Concerning the Development and Testing of In-situ Materials for Martian Exploration

Natural Martian surface materials are evaluated for their potential use as radiation shields for manned Mars missions. The modified radiation fluences behind various kinds of Martian rocks and regolith are determined by solving the Boltzmann equation using NASA Langley s HZETRN code along with the 1977 Solar Minimum galactic cosmic ray environmental model. To make structural shielding composite materials from constituents of the Mars atmosphere and from Martian regolith for Martian surface habitats, schemes for synthesizing polyimide from the Mars atmosphere and for processing Martian regolith/polyimide composites are proposed. Theoretical predictions of the shielding properties of these composites are computed to assess their shielding effectiveness. Adding high-performance polymer binders to Martian regolith to enhance structural properties enhances the shielding properties of these composites because of the added hydrogenous constituents. Laboratory testing of regolith simulant/polyimide composites is planned to validate this prediction.

Kim, M.-H. Y.↗

Two Successive Martian Years on the Orbit: Similarities and Differences of CO2 Seasonal Cycle from HEND/ODYSSEY Data

The three years of Mars Odyssey successful work on the martian orbit provide a lot of new information about peculiarities of long term variations of CO2 seasonal cycle. To start such analysis we have used observations of neutron albedo of Mars obtained by High Energy Neutron detector (HEND) mounted onboard Mars Odyssey spacecraft. The high latitude northern and southern regions of Mars are affected by global redistribution of atmospheric CO2 which resulted in 25% of atmospheric mass condensed on martian surface of these regions during winter period of time. The seasonal deposit is formed starting from 60N/60S latitudes and achieve its maximal thickness about 1 m at latitudes close to martian poles. Changes of CO2 deposit thickness is the reason for significant variations of neutron flux above martian poles from summer to winter seasons because CO2 frost effectively hides upper water rich surface layers from the orbit observations in neutrons and gamma-rays. This effect was used to estimate column density of CO2 deposit at different latitudes on North and South of Mars and reconstruct multidimensional model of CO2 deposit showing how snow depth varies as function of latitude, longitude and time. In this presentation we tried to make a next step in our study of martian seasonal CO2 cycle and look for similarities and differences between two successive martian years.

Litvak, M. L.↗

Refining Martian Ages and Understanding Geological Processes From Cratering Statistics

Senior Scientist William K. Hartman presents his final report on Mars Data Analysis Program grant number NAG5-12217: The third year of the three-year program was recently completed in mid-2005. The program has been extremely productive in research and data analysis regarding Mars, especially using Mars Global Surveyor and Mars Odyssey imagery. In the 2005 alone, three papers have already been published, to which this work contributed.1) Hartmann, W. K. 200.5. Martian cratering 8. Isochron refinement and the history of Martian geologic activity Icarus 174, 294-320. This paper is a summary of my entire program of establishing Martian chronology through counts of Martian impact craters. 2) Arfstrom, John, and W. K. Hartmann 2005. Martian flow features, moraine-like rieges, and gullies: Terrestrial analogs and interrelationships. Icarus 174,32 1-335. This paper makes pioneering connections between Martian glacier-like features and terrestrial glacial features. 3) Hartmann, W.K., D. Winterhalter, and J. Geiss. 2005 Chronology and Physical Evolution of Planet Mars. In The Solar System and Beyond: Ten Years of ISSI (Bern: International Space Science Institute). This is a summary of work conducted at the International Space Science Institute with an international team, emphasizing our publication of a conference volume about Mars, edited by Hartmann and published in 2001.

Hartmann, William K.↗

Noble Gas Analysis for Mars Robotic Missions: Evaluating K-Ar Age Dating for Mars Rock Analogs and Martian Shergottites

The purpose of this noble gas investigation was to evaluate the possibility of measuring noble gases in martian rocks and air by future robotic missions such as the Mars Science Laboratory (MSL). The MSL mission has, as part of its payload, the Sample Analysis at Mars (SAM) instrument, which consists of a pyrolysis oven integrated with a GCMS. The MSL SAM instrument has the capability to measure noble gas compositions of martian rocks and atmosphere. Here we suggest the possibility of K-Ar age dating based on noble gas release of martian rocks by conducting laboratory simulation experiments on terrestrial basalts and martian meteorites. We provide requirements for the SAM instrument to obtain adequate noble gas abundances and compositions within the current SAM instrumental operating conditions, especially, a power limit that prevents heating the furnace above approx.1100 C. In addition, Martian meteorite analyses from NASA-JSC will be used as ground truth to evaluate the feasibility of robotic experiments to constrain the ages of martian surface rocks.

Park, J.↗