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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Unit operations for gas-liquid mass transfer in reduced gravity environments

Basic scaling rules are derived for converting Earth-based designs of mass transfer equipment into designs for a reduced gravity environment. Three types of gas-liquid mass transfer operations are considered: bubble columns, spray towers, and packed columns. Application of the scaling rules reveals that the height of a bubble column in lunar- and Mars-based operations would be lower than terrestrial designs by factors of 0.64 and 0.79 respectively. The reduced gravity columns would have greater cross-sectional areas, however, by factors of 2.4 and 1.6 for lunar and Martian settings. Similar results were obtained for spray towers. In contract, packed column height was found to be nearly independent of gravity.

Pettit, Donald R.↗
NASA NTRS2022

Ultraviolet Spectropolarimetry Conservative and Nonconservative Mass Transfer in OB Interacting Binaries

The current consensus is that at least half of the OB stars are formed in binary or multiple star systems. The evolution of OB stars is greatly influenced by whether the stars begin as close binaries, and the evolution of the binary systems depend on whether the mass transfer is conservative or nonconservative. FUV/NUV spectropolarimetry is poised to answer the latter question. This paper discusses how the Polstar spectropolarimetry mission can characterize the degree of nonconservative mass transfer that occurs at various stages of binary evolution, from the initial mass reversal to the late Algol phase, and quantify its amount. The proposed instrument combines spectroscopic and polarimetric capabilities, where the spectroscopy can resolve Doppler shifts in UV resonance lines with 10 km/s precision, and polarimetry can resolve linear polarization with 10 −3 precision or better. The spectroscopy will identify absorption by mass streams and other plasmas seen in projection against the stellar disk as a function of orbital phase, as well as scattering from extended splash structures, including jets. The polarimetry tracks the light coming from material not seen against the stellar disk, allowing the geometry of the scattering to be tracked, resolving ambiguities left by the spectroscopy and light-curve information. For example, nonconservative mass streams ejected in the polar direction will produce polarization of the opposite sign from conservative transfer accreting in the orbital plane. Time domain coverage over a range of phases of the binary orbit are well supported by the Polstar observing strategy. Special attention will be given to the epochs of enhanced systemic mass loss that have been identified from IUE observations (pre-mass reversal and tangential gas stream impact). We show how the history of systemic mass and angular momentum loss/gain episodes can be inferred via ensemble evolution through the r–q diagram. Combining the above elements will significantly improve our understanding of the mass transfer process and the amount of mass that can escape from the system, an important channel for changing the final mass and ultimate supernova of a large number of massive stars found in binaries at close enough separation to undergo interaction.

Geraldine J. Peters↗
NASA NTRS1972

Correlation of liquid-film cooling mass transfer data.

An empirical correlation proposed by Gater and Ecuyer (1970) for liquid-film cooling mass transfer, accounting for film roughness and entrainment effects, is extended to include liquid films of arbitrary length. A favorable comparison between the predicted results and the experimental data of Kinney et al. (1952) and Emmons and Warner (1964) shows the utility of the mass transfer correlation for predictions over a wide range of experimental parameters.

Gater, R. A.↗
NASA NTRS1972

Transient mass transfer at the rotating disk electrode.

Transient mass transfer at the rotating disk has been investigated theoretically and experimentally for cathodic reduction of ferricyanide in the redox system ferricyanide-ferrocyanide with potassium hydroxide supporting electrolyte. It has been shown that overpotential-time predictions for the rotating disk are fitted very well for decay (current interruption) but poorly for build-up following switching on of constant current. As an explanation for this behavior, attention is directed to the inadequacy of the assumption that a radially independent concentration profile exists at the disk surface just at the start of galvanostatic current passage.

Nanis, L.↗
NASA NTRS1981

Observations of the gas stream in the mass transfer binary HR 2142 prime 1

The mass transfer binary system HR 2142 was observed at selected phases with the high resolution spectrograph on IUE. The observations were scheduled throughout the interval 0.91 phi 0.00 in order to allow viewing of the light of the primary star through the gas stream as it presents different orientations to the line of sight. Numerous UV lines formed in the gas stream were identified. The strengths and velocity variations displayed by these lines are compared with those observed in the ground based spectral region. As part of a preliminary analysis of the IUE data, column densities and velocities from Si III (4), Si IV (1), and Ti III (1) are used to deduce electron densities in the gas stream as well as its thickness. Possible evidence for stratification in the gas stream is presented.

Peters, G. J.↗
NASA NTRS1999

The Influence of Static and Rotating Magnetic Fields on Heat and Mass Transfer in Silicon Floating Zones

Hear and mass transfer in float-zone processing are strongly influenced by convective flows in the zone. They are caused by buoyancy convection, thermocapillary (Marangoni) convection, or artificial sources such as rotation and radio frequency heating. Flows in conducting melts can be controlled by the use of magnetic fields, either by damping fluid motion with static fields or by generating a def@ned flow with rotating fields. The possibilities of using static and rotating magnetic fields in silicon floating-zone growth have been investigated by experiments in axial static fields up to ST and in transverse rotating magnetic fields up to 7.S mT. Static fields of a few 100 MT already suppress most striations but are detrimental to the radial segregation by introducing a coring effect. A complete suppression of dopant striations caused by time-dependent thermocapillary convection and a reduction of the coring to insignificant values, combined with a shift of the axial segregation profile towards a more diffusion-limited case, is possible with static fields ? 1T. However, under certain conditions the use of high axial magnetic fields can lead to the appearance of a new type of pronounced dopant striations, caused by thermoelec:romagnetic convection. The use of a transverse rotating magnetic field influences the microscopic segregation at quite low inductions, of the order of a few mT. The field shifts time-dependent flows and the resulting striation patterns from a broad range of low frequencies at high amplitudes to a few high frequencies at low amplitudes

Croell, Arne↗
NASA NTRS1999

The Influence of Static and Rotating Magnetic Fields on Heat and Mass Transfer in Silicon Floating Zones

Heat and mass transfer in float-zone processing are strongly influenced by convective flows in the zone. They are caused by buoyancy convection, thermocapillary (Marangoni) convection, or artificial sources such as rotation and radio-frequency heating. Flows in conducting melts can be controlled by the use of magnetic fields, either by damping fluid motion with static fields or by generating a defined flow with rotating fields. The possibilities of using static and rotating magnetic fields in silicon floating-zone growth have been investigated by experiments in axial static fields up to 5 T and in transverse rotating magnetic fields up to 7.5 mT. Static fields of a few 100 mT already suppress most striations but are detrimental to the radial segregation by introducing a coring effect. A complete suppression of dopant striations caused by time-dependent thermocapillary convection and a reduction of the coring to insignificant values, combined with a shift of the axial segregation profile toward a more diffusion-limited case, is possible with static fields greater than or equal to 1 T. However, under certain conditions the use of high axial magnetic fields can lead to the appearance of a new type of pronounced dopant striations, caused by thermoelectromagnetic convection. The use of a transverse rotating magnetic field influences the microscopic segregation at quite low inductions, of the order of a few millitesla. The field shifts time- dependent flows and the resulting striation patterns from a broad range of low frequencies at high amplitudes to a few high frequencies at low amplitudes.

Croll, A.↗
DOE OSTI2025

Process intensification approach to enhancing heat and mass transfer: Radio frequency (RF) assisted drying of paper and board

Conventional multi-cylinder drying of paper and board typically relies on both conductive drying from steam-heated cylinders and convective drying, where heated air flows over the paper web surface. Conduction primarily contributes to heat transfer, while convection is the main driver of mass transfer. However, conventional drying systems are heavily dependent on steam, usually powered by fossil fuels, and are often energy-inefficient with high levels of waste. Additionally, these surface-driven processes result in a lower percentage of energy absorption compared to the energy supplied, leading to significant energy losses. To improve this long-standing process, an experimental system was developed to investigate a process intensification approach involving the integration of Radio Frequency (RF) heating, a volumetric electromagnetic technology, alongside traditional conduction and convection drying methods. This study also emphasizes the use of sensors to continuously monitor key parameters such as moisture content, supply system temperatures, sample temperatures, air flows, and drying rates in real-time. The effect of RF as an auxiliary energy source in localized environments at varying moisture levels was explored to optimize industrial drying systems, quantify potential improvements, and provide insights for future studies. Experimental results from trials combining RF with convection and with the base case alternating conduction-convection drying processes are presented. It is shown that RF is a viable process intensification approach for paper drying improving the drying rate and energy intensity at higher moisture contents. These findings offer valuable insights for process intensification and contribute to the process development, modeling, and simulation of advanced paper drying techniques.

42 ENGINEERING↗
NASA NTRS1979

A new approach to the correlation of boundary layer mass transfer rates with thermal diffusion and/or variable properties

A rational approach to the correlation of boundary layer mass transport rates, applicable to many commonly encountered laminar flow conditions with thermal diffusion and/or variable properties, is outlined. The correlation scheme builds upon already available constant property blowing/suction solutions by introducing appropriate correction factors to account for the additional ('pseudo' blowing and source) effects identified with variable properties and thermal diffusion. Applications of the scheme to the particular laminar boundary layer mass transfer problems considered herein (alkali and transition metal compound vapor transport) indicates satisfactory accuracy up to effective blowing factors equivalent to about one third of the 'blow off' value. As a useful by-product of the variable property correlation, we extend the heat-mass transfer analogy, for a wide range of Lewis numbers, to include variable property effects.

Srivastava, R.↗
DOE OSTI2022

A continuum model for heat and mass transfer in moving-bed reactors for thermochemical energy storage

In this work, a continuum heat and mass transfer model coupling transport phenomena and high-temperature thermochemical reactions is developed for stationary packed-bed and counter-flow moving-bed reactors. After presenting the general modeling framework, we focus on the 2D axisymmetric version of the model for which validation is conducted with experimental results for a packed-bed reactor in the literature for manganese-iron oxide reduction/oxidation and an in-house counter-flow moving-bed reactor for magnesium-manganese oxide reduction up to 1450 °C. Transient simulation results including the local distributions of gas/solid temperatures, oxygen concentration and the extent of reaction, as well as the various energy flow components and energy conversion efficiencies are reported. The results based on the 2D axisymmetric model are also compared with those obtained from a previous 1D model. The comparison shows that capturing the radial variation is critical in reactor modeling and the 2D results demonstrate improved agreement with experiments. Specifically, large temperature variations along the radial direction are observed especially in the reaction zone; this non-uniform radial temperature distribution has a significant effect on the chemical reaction extent due to its strong dependence on temperature; and the overall oxygen concentration at the reactor exit and the predicted system efficiency are slightly lower in the 2D model compared to the 1D model. Finally, the present heat and mass transfer model can provide valuable insights into reactor design, scale-up, and operating conditions selection to maximize system energy storage efficiency.

25 ENERGY STORAGE↗
NASA NTRS1974

Mass transfer in a 1370 C (2500 F) lithium thermal convection loop

Experimental results from a test to evaluate interstitial element mass transfer effects on T-111, ASTAR 811C, and ASTAR 1211C after 5000 hours in flowing lithium at 1370 C (2500 F) are presented. No gross corrosion effects were observed. However, hafnium and nitrogen transfer to cooler regions within the loop were noted. Oxygen was in general removed from test specimens, but there was no evidence to indicate that it was a major factor in the mass transfer process. Carbon and hydrogen transfer were not detected.

Scheuermann, C. M.↗
NASA NTRS1982

Binary stars: Mass transfer and chemical composition

It is noted that mass exchange (and mass loss) within a binary system should produce observable changes in the surface chemical composition of both the mass losing and mass gaining stars as a stellar interior exposed to nucleosyntheses is uncovered. Three topics relating mass exchange and/or mass loss to nucleosynthesis are sketched: the chemical composition of Algol systems; the accretion disk of a cataclysmic variable fed by mass from a dwarf secondary star; and the hypothesis that classical Ba II giants result from mass transfer from a more evolved companion now present as a white dwarf.

Lambert, D. L.↗
DOE OSTI2021

Encapsulation of highly viscous CO 2 capture solvents for enhanced capture kinetics: Modeling investigation of mass transfer mechanisms

The encapsulation of highly viscous liquid-like Nanoparticle Organic Hybrid Materials (NOHMs) inside a gas permeable polymer to form SIPs (Solvent Impregnated Polymers) significantly enhanced the CO 2 capture kinetics of NOHMs, leading to a remarkable 50-fold increase in CO 2 flux compared to the neat NOHMs. To understand the mechanism for enhanced CO 2 mass transfer within these hybrid materials, kinetic modeling of CO 2 uptake into SIPs containing polyethylenimine functionalized NOHMs, denoted NPEI-SIP, was conducted. CO 2 mass transfer into NPEI-SIP films was found to conform, both qualitatively and quantitatively, with a diffusion-controlled moving front model. The diffusion-controlled model was also used to simulate CO 2 uptake within a fixed bed containing polydisperse NPEI-SIP particles, and this model accurately predicted experimentally measured breakthrough curves at 25 °C and 50 °C. The 50-fold increase in gas flux was shown to be a consequence of the very large CO 2 permeability within the polymer–solvent composite. Furthermore, the increase in gas flux is also dependent on the diffusion–reaction regime in which the chemical solvent operates, and the largest improvement will occur when immobilizing solvents, such as NOHMs, which operate in the instantaneous-reaction regime. The CO 2 capacity (~3 mol CO 2 /kg) and saturation time (~5 min) of 430 μm SIP particles were comparable to popular CO 2 chemisorption materials such as amine grafted silicates, in spite of the slow kinetics of NOHM-I-PEI in liquid form (CO 2 saturation time ~24 h for a 1 mm thin film).

36 MATERIALS SCIENCE↗