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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Performance of and planned improvements to a mountain altitude cosmic ray mass spectrometer

A cosmic ray mass spectrometer with superconducting magnet, wire spark chambers, and time-of-flight scintillation counters has been operated at an altitude of 2750 meters. Various specifications of the spectrometer are presented and the method of event analysis described. Corrections to the data, resolutions and efficiencies of the spark chambers, and momentum resolution are discussed. Recent and planned improvements of the apparatus are indicated.

Jones, J. J.↗
NASA NTRS1991

Superthermal over 36-eV ions observed in the near-tail region of Venus by the Pioneer Venus Orbiter neutral mass spectrometer

The PVO neutral mass spectrometer has measured the over 36-eV ions in the 1300-3700 km altitude range for solar zenith angles greater than 120 deg. The composition is mainly O(+), but He(+), N(+), NO(+), and O2(+) have been identified. The average O(+) flux is about 100,000/sq cm/s, but higher fluxes from 10 to the 6th to 10 to the 8th/sq cm/s are observed about 10 percent of the time. The directions of the apparent O(+) flow in the ecliptic plane show predominantly tailward components with a smaller number of nontailward components. The over 36-eV O(+) escape flux in the ionotail is estimated to be about 100,000/sq cm/s. The O(+) flux data show a factor of 2.5 increase from solar minimum to maximum, implying a photoionization source for these ions. The composition of the superthermal ions in the ionotail suggests that their source is most likely the high-altitude nightside ionosphere. Transport of superthermal O(+) across the terminator to the nightside has been observed.

Kasprzak, W. T.↗
NASA NTRS2000

Miniature micromachined quadrupole mass spectrometer array and method of making the same

The present invention provides a quadrupole mass spectrometer and an ion filter, or pole array, for use in the quadrupole mass spectrometer. The ion filter includes a thin patterned layer including a two-dimensional array of poles forming one or more quadrupoles. The patterned layer design permits the use of very short poles and with a very dense spacing of the poles, so that the ion filter may be made very small. Also provided is a method for making the ion filter and the quadrupole mass spectrometer. The method involves forming the patterned layer of the ion filter in such a way that as the poles of the patterned layer are formed, they have the relative positioning and alignment for use in a final quadrupole mass spectrometer device.

Chutjian, Ara↗
NASA NTRS2001

Miniature micromachined quadrupole mass spectrometer array and method of making the same

The present invention provides a quadrupole mass spectrometer and an ion filter, or pole array, for use in the quadrupole mass spectrometer. The ion filter includes a thin patterned layer including a two-dimensional array of poles forming one or more quadrupoles. The patterned layer design permits the use of very short poles and with a very dense spacing of the poles, so that the ion filter may be made very small. Also provided is a method for making the ion filter and the quadrupole mass spectrometer. The method involves forming the patterned layer of the ion filter in such a way that as the poles of the patterned layer are formed, they have the relative positioning and alignment for use in a final quadrupole mass spectrometer device.

Chutjian, Ara↗
NASA NTRS2002

Miniature micromachined quadrupole mass spectrometer array and method of making the same

The present invention provides a quadrupole mass spectrometer and an ion filter, or pole array, for use in the quadrupole mass spectrometer. The ion filter includes a thin patterned layer including a two-dimensional array of poles forming one or more quadrupoles. The patterned layer design permits the use of very short poles and with a very dense spacing of the poles, so that the ion filter may be made very small. Also provided is a method for making the ion filter and the quadrupole mass spectrometer. The method involves forming the patterned layer of the ion filter in such a way that as the poles of the patterned layer are formed, they have the relative positioning and alignment for use in a final quadrupole mass spectrometer device.

Chutjian, Ara↗
NASA NTRS1989

Measuring Transmission Efficiencies Of Mass Spectrometers

Coincidence counts yield absolute efficiencies. System measures mass-dependent transmission efficiencies of mass spectrometers, using coincidence-counting techniques reminiscent of those used for many years in calibration of detectors for subatomic particles. Coincidences between detected ions and electrons producing them counted during operation of mass spectrometer. Under certain assumptions regarding inelastic scattering of electrons, electron/ion-coincidence count is direct measure of transmission efficiency of spectrometer. When fully developed, system compact, portable, and used routinely to calibrate mass spectrometers.

Srivastava, Santosh K.↗
NASA NTRS2024

The Peregrine Ion Trap Mass Spectrometer (PITMS) Investigation Development and Pre-Flight Planning

The Peregrine Ion Trap Mass Spectrometer (PITMS) is a mass spectrometer instrument that operated during the Astrobotic Peregrine Mission-1 as part of the NASA Commercial Lunar Payload Services (CLPS) initiative. This paper describes the instrument and investigation design, development, and planning conducted by the PITMS team consisting of a successful partnership between NASA Goddard Space Flight Center (GSFC), The Open University (OU), NASA, and ESA. PITMS was designed to measure the abundance and temporal variability of volatile species in the near-surface lunar exosphere from a landed platform on the lunar surface. The PITMS instrument consisted of an ESA-provided Exospheric Mass Spectrometer (EMS; including sensor, electronics, controller, power supply boards) and a GSFC wrapper that provided structural elements, thermal control, and a deployable dust cover. PITMS was designed to operate as a passive sampler, where ambient gases would enter PITMS through an aperture, diffuse around the mass analyzer cavity, become ionized by electron impact and trapped in a radiofrequency field, then sequentially released to a detector to build a mass spectrum. PITMS was capable of measuring species with a massto-charge ratio (m/z) from 10 to 150 Da, with a mass resolution of approximately 0.5 amu. The PITMS science investigation was planned to be operated by GSFC with an international team of scientists. Though the mission did not achieve its lunar landing, information about the PITMS instrument and planning is provided to be able to understand and effectively use data that will be forthcoming from the investigation.

Barbara Cohen↗
NASA NTRS1985

High-performance double-focusing mass spectrometer

Double focusing was first employed when mass spectrometers of a simpler design were not capable any longer to satisfy increasing demands in mass spectroscopy. One of the successful instruments of the 1930's was the mass spectrometer designed by Mattauch and Herzog (1934). The compactness of the Mattauch-Herzog geometry became particularly important in connection with studies involving the employment of rockets, satellites, or space probes. Another advantage of the considered spectrometer is related to the capability of measuring several masses of ions simultaneously. The instrument design was, therefore adopted for some rocket flights to the upper atmosphere, the investigation of the upper atmosphere of Mars, and for studying the upper atmosphere of Venus. Attention is given to laboratory applications involving the instrument in a somewhat enlarged version, and aspects of instrument operation and performance.

Nier, A. O.↗
NASA NTRS2003

A miniature mass spectrometer for hydrazine detection

A Miniature Mass Spectrometer (MMS) with a focal plane (Mattauch-Herzog) geometry has been developed at the Jet Propulsion Laboratory. The MMS has the potential to meet the NASA requirements of 10 parts per billion sensitivity for Hydrazine detection, as well as the requirements for instant response, portability, and low maintenance.

MMS Miniature Mass Spectrometer hydrazine detectio↗
NASA NTRS1997

Design of An Improved Miniature Ion Neutral Mass Spectrometer for NASA Applications

The ion optics of NASA's Ion Neutral Mass Spectrometer (INMS) sensor was simulated with three dimensional models of the open source, the quadrupole deflector, the exit lens system and the quadrupole mass analyzer to design more compact models with lower weight. Comparison of calculated transmission with experimental results shows good agreement. Transmission analyses with varying geometrical parameters and voltages throw light on possible ways of reducing the size of the sensor. Trajectories of ions of mass 1-99 amu were simulated to analyze and optimize transmission. Analysis of open source transmission with varying angle of attack shows that the angular acceptance can be considerably increased by programming the voltages on the ion trap/ collimator. Analysis of transmission sensitivity to voltages and misalignments of the quadrupole deflector rods indicate that increased transmission is possible with a geometrically asymmetrical deflector and a deflector can be designed with much lower sensitivities of transmission. Bringing the disks closer together can decrease the size of the quadrupole deflector and also increase transmission. The exit lens system can be redesigned to be smaller by eliminating at least one electrode entirely without loss of transmission. Ceramic materials were investigated to find suitable candidates for use in the construction of lighter weight mass spectrometer. A high-sensitivity, high-resolution portable gas chromatograph mass spectrometer with a mass range of 2-700 amu has been built and will be commercialized in Phase 3.

Swaminathan, Viji K.↗
NASA NTRS2012

Calibration of the Neutral Mass Spectrometer for the Lunar Atmosphere and Dust Environment Explorer

Science objectives of the LADEE Mission are to (1) determine the composition, and time variability of the tenuous lunar atmosphere and (2) to characterize the dust environment and its variability. These studies will extend the in-situ characterization of the environment that were carried out decades ago with the Apollo missions and a variety of ground based studies. The focused LADEE measurements will enable a more complete understanding of dust and gas sources and sinks. Sources of gas include UV photo-stimulated desorption, sputtering by plasma and micrometeorites, as well as thermal release of species such as argon from the cold service or venting from the lunar interior. Sinks include recondensation on the surface and escape through a variety of mechanisms. The LADEE science payload consists of an Ultraviolet Spectrometer, a Neutral Mass Spectrometer, and a Dust Detector. The LADEE orbit will include multiple passes at or below 50 km altitude and will target repeated sampling at the sunrise terminator where exospheric density will be highest for some thermally released species. The science mission will be implemented in approximately three months to allow measurements to be made over a period of one or more lunations In addition to the science mission NASA will use this mission to demonstrate optical communication technology away from low Earth orbit.

Mahaffy, P. R.↗
NASA NTRS1980

Pioneer Venus Orbiter neutral gas mass spectrometer experiment

The Pioneer Venus Orbiter Neutral Mass Spectrometer (ONMS) is designed to measure the vertical and horizontal density variations of the major neutral constituents in the upper atmosphere of Venus. The mass spectrometer sensor includes a retarding potential ion source, hyperbolic quadrupole rod analyzer, and electron multiplier detector. The supporting electronic system consists of hybrid integrated circuits to reduce weight and power. The ONMS instrument was launched aboard the Pioneer Venus Orbiter on May 20, 1978, and turned on in orbit around Venus on December 4, 1978. It has operated flawlessly for over a Venus year (243 earth days) and has returned data of the composition of the major constituents in the Venus atmosphere between the altitudes of 150 and 350 km.

Niemann, H. B.↗
NASA NTRS1986

Application of an atmospheric pressure sampling mass spectrometer to chlorination reactions

An atmospheric pressure mass spectrometric sampling system, based on a free jet expansion was used to study certain M-Cl-O reactions at high temperatures. The apparatus enables the volatile species from a 1-atm chemical process to be directly identified with a mass spectrometer which operates at approx. 10 to the minus 8th power torr. Studies for both pure metals and alloys are discussed. It is shown that this mass spectrometer system aids in identifying the volatile species, and provides fundamental information on the reaction mechanism.

Jacobson, N. S.↗
NASA NTRS1980

Data acquisition techniques for exploiting the uniqueness of the time-of-flight mass spectrometer: Application to sampling pulsed gas systems

Mass spectra are produced in most mass spectrometers by sweeping some parameter within the instrument as the sampled gases flow into the ion source. It is evident that any fluctuation in the gas during the sweep (mass scan) of the instrument causes the output spectrum to be skewed in its mass peak intensities. The time of flight mass spectrometer (TOFMS) with its fast, repetitive mode of operation produces spectra without skewing or varying instrument parameters and because all ion species are ejected from the ion source simultaneously, the spectra are inherently not skewed despite rapidly changing gas pressure or composition in the source. Methods of exploiting this feature by utilizing fast digital data acquisition systems, such as transient recorders and signal averagers which are commercially available are described. Applications of this technique are presented including TOFMS sampling of vapors produced by both pulsed and continuous laser heating of materials.

Lincoln, K. A.↗
NASA NTRS1994

Shuttle Upper Atmosphere Mass Spectrometer Experimental Flight Results

Calibrated pressure measurements for species with mass-to-charge ratios up to 50 amu/e(-) were obtained trom the shuttle upper atmosphere mass spectrometer experiment during re-entry on the STS-35 mission. The principal experimental objective is to obtain measurements of freestream density in the hypersonic rarefied flow flight regime. Data were collected from 180 to about 87 km. However, data above 115 km were contaminated from a source of gas emanating from pressure transdueers connected in parallel to the mass spectrometer. At lower altitudes, the pressure transducer data are compared to the mass spectrometer total pressure with excellent agreement. Near the orifice entrance, a significant amount of CO2 was generated from chemical reactions. The freestream density in the rarefied flow flight regime is calculated using an orifice pressure coefficient model based upon direct simulation Monte Carlo results. This density, when compared with the 1976 U.S. Standard Atmosphere model, exhibits the wavelike nature seen on previous flights using accelerometry. Selected spectra are presented at higher altitudes (320 km) showing the effects of the ingestion of gases from a forward fuselage fuel dump.

Blanchard, R. C.↗
NASA NTRS1981

The neutral mass spectrometer on Dynamics Explorer B

A neutral gas mass spectrometer has been developed to satisfy the measurement requirements of the Dynamics Explorer mission. The mass spectrometer, a quadrupole, will measure the abundances of neutral species in the region 300-500 km in the earth's atmosphere. These measurements will be used in concert with other simultaneous observations on Dynamics Explorer to study the physical processes involved in the interactions of the magnetosphere-ionosphere-atmosphere system. The instrument, which is similar to that flown on Atmosphere Explorer, employs an electron beam ion source operating in the closed mode and a discrete dynode multiplier as a detector. The mass range is 22 to 50 amu. The abundances of atomic oxygen, molecular nitrogen, helium, argon, and possibly atomic nitrogen will be measured to an accuracy of about + or - 15% over the specified altitude range, with a temporal resolution of one second.

Carignan, G. R.↗