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Comparison of Areas in Shadow from Imaging and Altimetry in the North Polar Region of Mercury and Implications for Polar Ice Deposits

Earth-based radar observations and results from the MESSENGER mission have provided strong evidence that permanently shadowed regions near Mercury's poles host deposits of water ice. MESSENGER's complete orbital image and topographic datasets enable Mercury's surface to be observed and modeled under an extensive range of illumination conditions. The shadowed regions of Mercury's north polar region from 65 deg N to 90 deg N were mapped by analyzing Mercury Dual Imaging System (MDIS) images and by modeling illumination with Mercury Laser Altimeter (MLA) topographic data. The two independent methods produced strong agreement in identifying shadowed areas. All large radar-bright deposits, those hosted within impact craters greater than or equal to 6 km in diameter, collocate with regions of shadow identified by both methods. However, only approximately 46% of the persistently shadowed areas determined from images and approximately 43% of the permanently shadowed areas derived from altimetry host radar-bright materials. Some sizable regions of shadow that do not host radar-bright deposits experience thermal conditions similar to those that do. The shadowed craters that lack radar-bright materials show a relation with longitude that is not related to the thermal environment, suggesting that the Earth-based radar observations of these locations may have been limited by viewing geometry, but it is also possible that water ice in these locations is insulated by anomalously thick lag deposits or that these shadowed regions do not host water ice.

MESSENGER↗

A vaporization model for iron/silicate fractionation in the Mercury protoplanet

A study has been carried out on the vaporization of a totally molten silicate magma of chondritic composition heated into the range 2500-3500 K. The motivation for this was to determine the changes in the composition of the mantle that would occur in the Mercury protoplanet should that body have been subjected to the high-temperature phase in the evolution of the primitive solar nebula, but the results are of more general interest. An empirical model based on ideal mixing of complex components was used to describe the nonideal magma. It is found that vaporization of about 70-80 percent of the original amount of silicate from a chondritic planet is required to produce an iron-rich body with a mean uncompressed density equal to that deduced for Mercury. At this point the silicate is depleted in the alkalis, FeO, and SiO2, and enriched in CaO, MgO, Al2O3, and TiO2 relative to chondritic material.

Fegley, Bruce, Jr.↗

Mercury Crustal and Lithospheric Properties from High-resolution Gravity Field Models

We have analyzed all the available tracking data from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) mission to determine high-resolution gravity field models. We have applied a technique based on line-of-sight accelerations that results in models with improved correlations with topography in areas where the spacecraft altitude was low. We have used these models in an analysis of admittance to determine properties of the crust and lithosphere. We focus on four areas where correlations between gravity and topography are high. These locations represent different areas on Mercury: the high-Mg region, the Strindberg crater plus some lobate scarps, heavily cratered terrain, and smooth plains (the northern rise). We find crustal densities around 2600 kg m-3 for the first three areas, and a higher density for the northern rise, indicative of volcanic materials. Elastic thickness is generally low and varies between 11 and 30 km.

Sander Johannes Goossens↗

Waveguides in Thin Film Polymeric Materials

Results on the fabrication of integrated optical components in polymeric materials using photo printing methods will be presented. Optical waveguides were fabricated by spin coating preoxidized silicon wafers with organic dye/polymer solution followed by soft baking. The waveguide modes were studied using prism coupling technique. Propagation losses were measured by collecting light scattered from the trace of a propagation mode by either scanning photodetector or CCD camera. We observed the formation of graded index waveguides in photosensitive polyimides after exposure of UV light from a mercury arc lamp. By using a theoretical model, an index profile was reconstructed which is in agreement with the profile reconstructed by the Wentzel-Kramers-Brillouin calculation technique using a modal spectrum of the waveguides. Proposed mechanism for the formation of the graded index includes photocrosslinking followed by UV curing accompanied with optical absorption increase. We also developed the prototype of a novel single-arm double-mode interferometric sensor based on our waveguides. It demonstrates high sensitivity to the chance of ambient temperature. The device can find possible applications in aeropropulsion control systems.

Sakisov, Sergey↗

Lab Scale Mercury Dissolution Testing

Researchers at the Savannah River National Laboratory were requested by Savannah River Mission Completion to perform laboratory testing and modeling designed to understand why the Defense Waste Processing Facility (DWPF) is not collecting elemental mercury (Hg 0 ) despite long boiling times designed to recover Hg 0 . In response to a Technical Task Request, a Task Technical and Quality Assurance Plan was written and approved to authorize this work.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Defense Waste Processing Facility Nitric-Glycolic Flowsheet Chemical Process Cell Chemistry: Part 2

The conversions of nitrite to nitrate, the destruction of glycolate, and the conversion of glycolate to formate and oxalate were modeled for the Nitric-Glycolic flowsheet using data from Chemical Process Cell (CPC) simulant runs conducted by Savannah River National Laboratory (SRNL) from 2011 to 2016. The goal of this work was to develop empirical correlation models to predict these values from measurable variables from the chemical process so that these quantities could be predicted a-priori from the sludge or simulant composition and measurable processing variables. The need for these predictions arises from the need to predict the REDuction/OXidation (REDOX) state of the glass from the Defense Waste Processing Facility (DWPF) melter. This report summarizes the work on these correlations based on the aforementioned data. Previous work on these correlations was documented in a technical report covering data from 2011-2015. This current report supersedes this previous report. Further refinement of the models as additional data are collected is recommended. The glass REDOX depends on the concentrations of nitrate and manganese (oxidants), and of glycolate, formate, oxalate, carbon, and antifoam (reductants) in the melter feed. The waste sludge contains nitrite, nitrate, manganese (Mn), and oxalate. Virtually all of the nitrite is converted to nitrate or NO+NO 2 +N 2 O gases in the CPC. The portion of the nitrite converted to nitrate increases the amount of nitrate in the sludge. The amount of glycolate in the final melter feed depends on the amount of the glycolic acid feed that is destroyed. Similarly, the amounts of formate and oxalate formed during the decomposition of glycolic acid are required. The material balance on carbon was found to not close in most cases. Generally, there was less carbon at the end of testing compared to the inputs. The most uncertain product variable was glycolate, so material balances were performed where the glycolate concentration was adjusted, usually upward, to close the balance. Correlation versus the original, as-measured, data was generally poor, but correlation against the material balance adjusted values was greatly improved. It was also shown that the correlation of the measured REDOX versus the predicted REDOX was much better when the material balance adjusted glycolate values were used. Three data series were primarily used during the regressions of the data; these series were 1) Sludge Batch 9 NG flowsheet simulant runs NG51-62 (SB9-NG); 2) Scaled Runs + Bounding Hydrogen Runs (SR+BH); and 3) Runs GN43-50 and 57 (43-50,57). The glycolate destruction was found to correlate with acid stoichiometry (AS), percent reducing acid (PRA), and for some data series, headspace to simulant volume ratio (HSV), mercury (Hg), and nitrate. Although glycolate destruction for pairs of data series (e.g., [SB9-NG] and [SR+BH]) were found to depend on HSV, the combination of all three data series was not found to have significant dependence on this variable. The best model for glycolate destruction depended on AS, nitrate, and Hg. This model predicted the product glycolate compositions of the data to within 92-106%. The conversion of glycolate to formate was high when noble metals and Hg were not present, with values up to 100%. When noble metals and Hg were present, this conversion ranged from zero to 7%, and was dependent on AS. Lower AS gave higher conversions to formate. The conversion to oxalate was found to depend on the AS and the initial concentration of nitrite. An alternative fit versus AS and the form of ruthenium (Ru) used is a possible alternative. This fit was somewhat less statistically significant. This second model predicts that more oxalate is formed when Ru-nitrosyl nitrate is used rather than Ru chloride. The conversion of glycolate to oxalate ranged from zero to 6%. The conversion of nitrite to nitrate depended primarily on AS and PRA, with HSV and Hg being significant when these variables were varied. For multiple series of data, nitrite was also needed to SRNL-STI-2017-00172 5HYLVLRQ viL distinguish between data series, and the effect of HSV became insignificant. The best model for nitrite to nitrate conversion depended on AS, PRA, nitrite, and Hg. The 95% confidence intervals on the predicted values of glycolate destruction, glycolate to oxalate conversion, and nitrite to nitrate conversion were used to determine the uncertainty in the predicted REDOX when starting with only the composition of the sludge, AS, and PRA. Using the 95% confidences on an individual value (that is the confidence in getting a particular value for one single test as opposed to what the mean would be for multiple tests), the uncertainty in the predicted REDOX was calculated. The uncertainty in the actual product composition glycolate, oxalate, formate, and nitrate concentrations translated to an uncertainty in the REDOX value of ±0.1,which is approximately the uncertainty claimed in the REDOX model itself.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Magnetism and thermal evolution of the terrestrial planets

The absence in the cases of Venus and Mars of the substantial intrinsic magnetic fields of the earth and Mercury is considered, in light of thermal history calculations which suggest that, while the cores of Mercury and the earth are continuing to freeze, the cores of Venus and Mars may still be completely liquid. It is noted that completely fluid cores, lacking intrinsic heat sources, are not likely to sustain thermal convection for the age of the solar system, but cool to a subadiabatic, conductive state that cannot maintain a dynamo because of the gravitational energy release and the chemically driven convection that accompany inner core growth. The models presented include realistic pressure- and composition-dependent freezing curves for the core, and material parameters are chosen so that correct present-day values of heat outflow, upper mantle temperature and viscosity, and inner core radius, are obtained for the earth.

Stevenson, D. J.↗

Eddy Current Flow Meter Measurements and Modeling Validation

The goal of the eddy current flow meter (ECFM) is to monitor velocities and temperatures of conductive liquid metals. The ECFM can also detect voids in two-phase liquid metal flows. Measurement of these flows can greatly improve the accuracy of the empirical formulas used for fluid dynamics near the reactor core and aid in mapping any non-uniformities in fluid flow such as estimates of temperature and phase. While the eventual goal is to develop the ECFM for the liquid sodium surrounding the Versatile Test Reactor (VTR) core, this report focuses on modeling and experimental validation of ECFM for a moving solid test rod and for liquid mercury in the Target Test Facility (TTF) flow loop to better understand and further develop ECFM measurement capabilities by validating model predictions with benchmark experiments. Eventually the models could be used to design and optimize future ECFMs for specific applications such as monitoring flow within the VTR pool.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Constraining the Thickness of Polar Ice Deposits on Mercury Using the Mercury Laser Altimeter and Small Craters in Permanently Shadowed Regions

Radar-bright deposits at the poles of Mercury are located in permanently shadowed regions, which pro- vide thermally stable environments for hosting and retaining water ice on the surface or in the near sub- surface for geologic timescales. While the areal distribution of these radar-bright deposits is well characterized, their thickness, and thus their total mass and volume, remain poorly constrained. Here we derive thickness estimates for selected water-ice deposits using small, simple craters visible within the permanently shadowed, radar-bright deposits. We examine two endmember scenarios: in Case I, these craters predate the emplacement of the ice, and in Case II, these craters postdate the emplacement of the ice. In Case I, we find the difference between estimated depths of the original unfilled craters and the measured depths of the craters to find the estimated infill of material. The average estimated infilled material for 9 craters assumed to be overlain with water ice is ∼41 +30 −14 m, where 1 −σ standard error of the mean is reported as uncertainty. Reported uncertainties are for statistical errors only. Additional systematic uncertainty may stem from georeferencing the images and topographic datasets, from the radial accuracy of the altimeter measurements, or from assumptions in our models including (1) ice is flat in the bowl- shaped crater and (2) there is negligible ice at the crater rims. In Case II, we derive crater excavation depths to investigate the thickness of the ice layer that may have been penetrated by the impact. While the absence of excavated regolith associated with the small craters observed suggests that impacts generally do not penetrate through the ice deposit, the spatial resolution and complex illumination geometry of images may limit the observations. Therefore, it is not possible to conclude whether the small craters in this study penetrate through the ice deposit, and thus Case II does not provide a constraint on the ice thickness. For Mercury’s polar deposits, we argue that Case I of the small craters predating the emplacement of the ice deposits is more likely, given other geologic evidence that suggests that these ice deposits are relatively young. Using the ice thickness estimates from Case I to calculate the total amount of water ice currently contained in Mercury’s polar deposits results in a value of ∼10 14 –10 15 kg. This is equivalent to ∼100–1000 km 3 ice in volume. This volume of water ice is consistent with delivery via micrometeorite bombardment, Jupiter-family comets, or potentially a single impactor.

Deutsch, Ariel N.↗

Visible-Light-Responsive Photocatalysis: Ag-Doped TiO2 Catalyst Development and Reactor Design Testing

In recent years, the alteration of titanium dioxide to become visible-light-responsive (VLR) has been a major focus in the field of photocatalysis. Currently, bare titanium dioxide requires ultraviolet light for activation due to its band gap energy of 3.2 eV. Hg-vapor fluorescent light sources are used in photocatalytic oxidation (PCO) reactors to provide adequate levels of ultraviolet light for catalyst activation; these mercury-containing lamps, however, hinder the use of this PCO technology in a spaceflight environment due to concerns over crew Hg exposure. VLR-TiO2 would allow for use of ambient visible solar radiation or highly efficient visible wavelength LEDs, both of which would make PCO approaches more efficient, flexible, economical, and safe. Over the past three years, Kennedy Space Center has developed a VLR Ag-doped TiO2 catalyst with a band gap of 2.72 eV and promising photocatalytic activity. Catalyst immobilization techniques, including incorporation of the catalyst into a sorbent material, were examined. Extensive modeling of a reactor test bed mimicking air duct work with throughput similar to that seen on the International Space Station was completed to determine optimal reactor design. A bench-scale reactor with the novel catalyst and high-efficiency blue LEDs was challenged with several common volatile organic compounds (VOCs) found in ISS cabin air to evaluate the system's ability to perform high-throughput trace contaminant removal. The ultimate goal for this testing was to determine if the unit would be useful in pre-heat exchanger operations to lessen condensed VOCs in recovered water thus lowering the burden of VOC removal for water purification systems.

Photocatalysis↗

Mercury ion thruster research, 1978

The effects of 8 cm thruster main and neutralizer cathode operating conditions on cathode orifice plate temperatures were studied. The effects of cathode operating conditions on insert temperature profiles and keeper voltages are presented for three different types of inserts. The bulk of the emission current is generally observed to come from the downstream end of the insert rather than from the cathode orifice plate. Results of a test in which the screen grid plasma sheath of a thruster was probed as the beam current was varied are shown. Grid performance obtained with a grid machined from glass ceramic is discussed. The effects of copper and nitrogen impurities on the sputtering rates of thruster materials are measured experimentally and a model describing the rate of nitrogen chemisorption on materials in either the beam or the discharge chamber is presented. The results of optimization of a radial field thruster design are presented. Performance of this device is shown to be comparable to that of a divergent field thruster and efficient operation with the screen grid biased to floating potential, where its susceptibility to sputter erosion damage is reduced, is demonstrated.

Wilbur, P. J.↗

Processing of thermionic power on an electrically propelled spacecraft

A study to define the power processing equipment required between a thermionic reactor and an array of mercury-ion thrusters for a nuclear electric propulsion system is reported. Observations and recommendations that resulted from this study were: (1) the preferred thermionic-fuel-element source voltages are 23 V or higher; (2) transistor characteristics exert a strong effect on power processor mass; (3) the power processor mass could be considerably reduced should the magnetic materials that exhibit low losses at high frequencies, that have a high Curie point, and that can operate at 15 to 20 kG become avaliable; (4) electrical component packaging on the radiator could reduce the area that is sensitive to meteoroid penetration, thereby reducing the meteoroid shielding mass requirement; (5) an experimental model of the power processor design should be built and tested to verify the efficiencies, masses, and all the automatic operational aspects of the design.

Macie, T. W.↗

The modification stage of basin formation - Conditions of ring formation

The impact cratering process may be divided into three stages, including a short high pressure phase of initial contact between the projectile and target, a longer cratering flow phase during which material is both ejected and displaced to form the transient crater, and a still longer modification phase during which the transient crater is modified into the final observed form. The present investigation is concerned with the nature of the modification stage as constrained by the initial boundary condition which comprises the transient crater and its surroundings, and the final boundary condition which comprises the structure of observed craters and basins. A brief description is provided of an interpretation of basin ring structure based on geophysical, geological, and dimensional analysis of craters and basins on the moon, Mercury, and Mars, on structural observations of terrestrial impact and explosion craters, and on an empirical crater restoration model. A scenario of basin formation is constructed, and relations of this scenario to observed morphology are discussed.

Croft, S. K.↗

The Apollo Sample Suite: 50 Years of Solar System Insight

The Apollo program was undoubtable a crowning achievement in human history. In addition to the obvious cultural significance, scientific results from the Apollo program had a lasting impression on a range of scientific fields, none more so that the effect the samples had on the fields of geology and cosmochemistry. The six Apollo missions collected 382 kg of rock, regolith, and core samples from geologically diverse locations on the Moon. In the nearly 50 years since the first samples were returned, there have been over 3000 different requests for samples, each yielding insights into fields as disparate as biology, medicine, astronomy, engineering, material science, and of course geology. Early studies of the Apollo samples revealed primary insights into the origin and evolution of the Moon, and of the Earth-Moon system, but the results also had implications for bodies throughout the solar system, e.g., defining crater counting rates. Over the decades, continued study of the Apollo samples by new generations of scientists using new instruments have continued to yield significant new discoveries, including the presence of endogenous water in the Moon and the possible presence of a lunar cataclysm, that in turn has contributed to new models of solar system formation and evolution. The Apollo samples have often been used as a proxy for studying other bodies like Mercury or asteroids. The Apollo samples have also directly contributed to the interpretation of remotely sensed data sets, including their use as ground truth for both Clementine and Lunar Prospector global geochemical maps. Despite the Apollo samples being a static collection, recent efforts will ensure that investigators continue to have access to new samples. For example, there was a recent solicitation for study of previously unopened Apollo samples in vacuum-sealed containers, as well as new access to samples stored frozen or in a He atmosphere. Similarly, the use of X-ray computed tomography as part of the curation process is identifying new clasts within polymict breccias that are available for study. Finally, the MoonDB project is putting all previously published lunar geochemical analyses into a searchable database, which should facilitate new investigations.

Zeigler, Ryan↗

Dynamo generation in Mercury

Models of the interior and thermal evolution of Mercury calculated by Siegfried and Solomon (1974) using Lewis' (1972) cosmochemical calculations to constrain the composition are tested for four necessary conditions for MHD dynamo generation. It is shown that dynamo generation requires at least a partially fluid interior, an energy source that drives a flow of core fluid relative to the rigidly rotating planet, a magnetic-field diffusion time in excess of the characteristic fluid-flow time scale, and a fluid flow of sufficient complexity to satisfy Cowling's (1934) theorem. It is concluded that a literal interpretation of Lewis' calculations implies that dynamo generation in Mercury is improbable. Generation would be possible only if the metallic core were contaminated with substantial amounts of radioactive material.

Stevenson, D. J.↗

The non-hydrostatic figures of the terrestrial planets

Solid state creep being exponentially dependent on temperature must dominate the mechanical behavior of the mantles of terrestrial planets beneath their lithospheres. General arguments suggest that the lithospheres of the Moon and Mars are about 200 km thick; the Earth, Venus and Mercury much less. Short wavelength gravity anomalies are explained by the finite strength of the lithosphere: the lunar mascons being an example. The good correlation of the Venus and Mars gravity anomalies with topography up to spherical harmonics of degrees 10-15 is in striking contrast to the lack of correlation between the long wavelength components of the geoid and the continent-ocean distribution or even the plates. Attempts have been made to explain the former correlations by isostatic models but the depths of compensation seem implausible. Low degree harmonics of the gravity fields of the terrestrial planets as is certainly the case in the Earth must arise from the density variations driving solid state convection. In the case of Venus the less dense differentiated materials of the highlands seems to be positioned over the singular points of the convection pattern. Thus the correlated gravity field does not arise from the highlands but from the density difference in the convecting interior. In the Earth lack of correlation seems to arise from the fact that the plates have moved relative to the convection pattern the last 100 M yr.

Runcorn, S. K.↗

NASA Tech Briefs, July 2009

Topics covered include: Dual Cryogenic Capacitive Density Sensor; Hail Monitor Sensor; Miniature Six-Axis Load Sensor for Robotic Fingertip; Improved Blackbody Temperature Sensors for a Vacuum Furnace; Wrap-Around Out-the-Window Sensor Fusion System; Wide-Range Temperature Sensors with High-Level Pulse Train Output; Terminal Descent Sensor Simulation; A Robust Mechanical Sensing System for Unmanned Sea Surface Vehicles; Additive for Low-Temperature Operation of Li-(CF)n Cells; Li/CFx Cells Optimized for Low-Temperature Operation; Number Codes Readable by Magnetic-Field-Response Recorders; Determining Locations by Use of Networks of Passive Beacons; Superconducting Hot-Electron Submillimeter-Wave Detector; Large-Aperture Membrane Active Phased-Array Antennas; Optical Injection Locking of a VCSEL in an OEO; Measuring Multiple Resistances Using Single-Point Excitation; Improved-Bandwidth Transimpedance Amplifier; Inter-Symbol Guard Time for Synchronizing Optical PPM; Novel Materials Containing Single-Wall Carbon Nanotubes Wrapped in Polymer Molecules; Light-Curing Adhesive Repair Tapes; Thin-Film Solid Oxide Fuel Cells; Zinc Alloys for the Fabrication of Semiconductor Devices; Small, Lightweight, Collapsible Glove Box; Radial Halbach Magnetic Bearings; Aerial Deployment and Inflation System for Mars Helium Balloons; Steel Primer Chamber Assemblies for Dual Initiated Pyrovalves; Voice Coil Percussive Mechanism Concept for Hammer Drill; Inherently Ducted Propfans and Bi-Props; Silicon Nanowire Growth at Chosen Positions and Orientations; Detecting Airborne Mercury by Use of Gold Nanowires; Detecting Airborne Mercury by Use of Palladium Chloride; Micro Electron MicroProbe and Sample Analyzer; Nanowire Electron Scattering Spectroscopy; Electron-Spin Filters Would Offer Spin Polarization Greater than 1; Subcritical-Water Extraction of Organics from Solid Matrices; A Model for Predicting Thermoelectric Properties of Bi2Te3; Integrated Miniature Arrays of Optical Biomolecule Detectors; A Software Rejuvenation Framework for Distributed Computing; Kurtosis Approach to Solution of a Nonlinear ICA Problem; Robust Software Architecture for Robots; R4SA for Controlling Robots; Bio-Inspired Neural Model for Learning Dynamic Models; Evolutionary Computing Methods for Spectral Retrieval; Monitoring Disasters by Use of Instrumented Robotic Aircraft; Complexity for Survival of Living Systems; Using Drained Spacecraft Propellant Tanks for Habitation; Connecting Node; and Electrolytes for Low-Temperature Operation of Li-CFx Cells.

Source record↗

Modeling MESSENGER Observations of Calcium in Mercury's Exosphere

The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MESSENGER spacecraft has made the first high-spatial-resolution observations of exospheric calcium at Mercury. We use a Monte Carlo model of the exosphere to track the trajectories of calcium atoms ejected from the surface until they are photoionized, escape from the system, or stick to the surface. This model permits an exploration of exospheric source processes and interactions among neutral atoms, solar radiation, and the planetary surface. The MASCS data have suggested that a persistent, high-energy source of calcium that was enhanced in the dawn, equatorial region of Mercury was active during MESSENGER's three flybys of Mercury and during the first seven orbits for which MASCS obtained data. The total Ca source rate from the surface varied between 1.2x10(exp 23) and 2.6x10(exp 23) Ca atoms/s, if its temperature was 50,000 K. The origin of this high-energy, asymmetric source is unknown, although from this limited data set it does not appear to be consistent with micrometeoroid impact vaporization, ion sputtering, electron-stimulated desorption, or vaporization at dawn of material trapped on the cold nightside.

Messenger↗