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At least 73 records · Page 4

Progress of the NASA/USGS Lunar Regolith Simulant Project

Beginning in 2004 personnel at MSFC began serious efforts to develop a new generation of lunar simulants. The first two products were a replication of the previous JSC-1 simulant under a contract to Orbitec and a major workshop in 2005 on future simulant development. Beginning in 2006 the project refocused its efforts and approached simulant development in a new and more comprehensive manner, examining new approaches in simulant development and ways to more accurately compare simulants to actual lunar materials. This led to a multi-year effort with five major tasks running in parallel. The five tasks are Requirements, Lunar Analysis, Process Development, Feed Stocks, and Standards. Major progress has been made in all five areas. A substantial draft of a formal requirements document now exists and has been largely stable since 2007. It does evolve as specific details of the standards and Lunar Analysis efforts proceed. Lunar Analysis has turned out to be vastly more difficult than anticipated. After great effort to mine existing published and gray literature, the team has realized the necessity of making new measurements of the Apollo samples, an effort that is currently in progress. Process development is substantially ahead of expectations in 2006. It is now practical to synthesize glasses of appropriate composition and purity. It is also possible to make agglutinate particles in significant quantities. A series of minerals commonly found on the Moon has been synthesized. Separation of mineral constituents from starting rock material is also proceeding. Customized grinding and mixing processes have been developed and tested are now being documented. Identification and development of appropriate feedstocks has been both easier and more difficult than anticipated. The Stillwater Mining Company, operating in the Stillwater layered mafic intrusive complex of Montana, has been an amazing resource for the project, but finding adequate sources for some of the components remains a difficult problem. For example the ratio of clino- to ortho-pyroxenes in the Stillwater is not an exact match for lunar materials. One of the sources being examined as an alternative pyroxene source is the Bushveld Complex in South Africa. Standards have been a major success for the project. The Figure of Merit algorithms have been created, tested, and are being considered for an ISO standard. Agreement has been reached in the community about how to make many of the critical measurements. There remains much work to do: (1) driving down the cost of simulants remains a major obstacle; (2) documentation and cost data analysis have not kept up with progress; (3) educating users in the complexity of the lunar regolith and the use of simulants remains a major task. In summary the project has made enormous progress and is successfully placing simulant development and use on a rigorous, scientifically defensible, engineering basis.

Rickman, Doug↗

Development of Leaching Processes for the Recovery of Rare Earth Elements from Acid Mine Drainage Precipitates

Acid mine drainage (AMD) has been a challenge for mine operators to address and has had significant environmental impacts when there is a failure to address it. Fortunately, there is a regulation in the US that requires the treatment of AMD before water can be discharged into the environment. AMD is generated when sulfide minerals are exposed to water and air from mining. The acidic water then leaches metals from the surrounding rock, creating the potential for environmental contamination of this acidic water containing dissolved metals. AMD can contain high concentrations of metals like iron, aluminum, and manganese and also have been shown to contain trace concentrations of critical minerals, including rare earth elements (REEs). This environmental waste stream is now being researched as a potential source for REEs. There is a patented process for processing and extracting REEs from AMD which produces rare earth oxide preconcentrate (REOP) from AMD treatment precipitates and a final stage mixed rare earth oxide (MREO) product. This body of research examines a selective leaching process for each of these products and determines the activation energy associated with the leaching processes. Acid leaching with HCl was examined to selectively leach REEs from REOP while contaminant metals remained in the solid residue. The maximum leaching recovery of the REEs from the REOP was approximately 90% and an activation energy of 6.4 kJ/mol at pH 3.0. Ammonium chloride leaching was examined to selectively remove contaminant metals from a MREO product. The ammonium chloride process successfully leached major contaminant metals in excess of 85% recovery and had a maximum activation energy of 40.0 kJ/mol.

01 COAL, LIGNITE, AND PEAT↗

Current NASA In-Situ Resource Utilization (ISRU) Strategic Vision

Perform development to TRL 5/6 through ground demonstration in relevant environment. Perform component/subscale subsystem flight demonstrations on small/mid-size landers. Assess and characterize water in volatiles in lunar polar shadowed regions and craters. Reduce risk of ISRU for mission critical consumables through Integrated End-to-End Flight Demonstrations (pilot scale). Establish initial Human Mission Scale production capability to promote sustainable operations and as anchor for commercial involvement. Identify and characterize polar region environment and resources/volatiles for Science and future Exploration/Commercial applications. Provide ground-truth physical, mineral, and water/volatile resource characteristic information at multiple locations to provide geological context for science-focused theories of volatile placement and initial mining assessments.Test technologies and processes to reduce risk of future extraction/mining systems. Quantify concentration and lateral/vertical distribution of resources/volatiles. Utilize ISRU capabilities to Extend and Enhance Human Lunar Exploration Missions. Provide oxygen (and fuel) to enable reusable human lunar lander (10+ MT/yr O2)Process carbon-based crew waste/trash into gases and propellants; can reduce logistics while minimizing public perception issues (alternative is conversion to radiation shielding). Scavenge unused propellants and hardware from spent landers. Metal extraction from regolith as feedstock for in situ and in space manufacturing demonstrations. Civil engineering and construction aimed at future outpost/infrastructure build-up. Develop and Demonstrate ISRU for Human Mars Missions. ISRU for propellant production (10-15 MT/yr); Liquefy, store, transfer, and refuel ascent vehicle. Use Moon for operational experience and mission validation for Mars: Pre-deployment & remote activation and operation without crew. Storing and transferring mission consumables Landing crew with empty tanks with ISRU propellants already made and waiting. Support/Promote Commercialization of Space. Large scale polar ice mining (100+ MT/yr water)O2/H2 propulsion for landers/cis-lunar transportation with surface and in space depots. In situ construction and energy expansion at mining and human outpost site(s). ISRU Ground Development. Develop and advance ISRU technologies to enable acquisition of resources and processing into mission consumables. Utilize Multi-center collaboration with a portfolio that includes internal NASA work, external contracts, and collaborative agreements/partnerships. Where appropriate, develop lunar ISRU components and subsystems with a Mars-forward application. Engage industry through public-private partnerships to lay the foundation for long-term lunar and space economic development. Spin-in/spin-out technologies for terrestrial applications and industry (mining, oil & gas, alternative energy, construction). Flight Demonstration Path to Operational ISRU. Utilize small demonstrations with near off-the-shelf hardware to obtain critical information quickly on lunar resources and operations. Demonstrate critical technologies and processes that interact with lunar materials and environments. Perform 'pilot plant' demonstrations at architecture relevant scales and durations to reduce the risk for ISRU-provided products for critical human mission applications.

In-situ Resource Utilization↗

Space Resources Roundtable 2

Contents include following: Developing Technologies for Space Resource Utilization - Concept for a Planetary Engineering Research Institute. Results of a Conceptual Systems Analysis of Systems for 200 m Deep Sampling of the Martian Subsurface. The Role of Near-Earth Asteroids in Long-Term Platinum Supply. Core Drilling for Extra-Terrestrial Mining. Recommendations by the "LSP and Manufacturing" Group to the NSF-NASA Workshop on Autonomous Construction and Manufacturing for Space Electrical Power Systems. Plasma Processing of Lunar and Planetary Materials. Percussive Force Magnitude in Permafrost. Summary of the Issues Regarding the Martian Subsurface Explorer. A Costing Strategy for Manufacturing in Orbit Using Extraterrestrial Resources. Mine Planning for Asteroid Orebodies. Organic-based Dissolution of Silicates: A New Approach to Element Extraction from LunarRegohth. Historic Frontier Processes Active in Future Space-based Mineral Extraction. The Near-Earth Space Surveillance (NIESS) Mission: Discovery, Tracking, and Characterization of Asteroids, Comets, and Artificial Satellites with a microsatellite. Privatized Space Resource Property Ownership. The Fabrication of Silicon Solar Cells on the Moon Using In-Situ Resources. A New Strategy for Exploration Technology Development: The Human Exploration and Development of Space (HEDS) Exploratiori/Commercialization Technology Initiative. Space Resources for Space Tourism. Recovery of Volatiles from the Moon and Associated Issues. Preliminary Analysis of a Small Robot for Martian Regolith Excavation. The Registration of Space-based Property. Continuous Processing with Mars Gases. Drilling and Logging in Space; An Oil-Well Perspective. LORPEX for Power Surges: Drilling, Rock Crushing. An End-To-End Near-Earth Asteroid Resource Exploitation Plan. An Engineering and Cost Model for Human Space Settlement Architectures: Focus on Space Hotels and Moon/Mars Exploration. The Development and Realization of a Silicon-60-based Economy in CisLunar Space. Our Lunar Destiny: Creating a Lunar Economy. Cost-Effective Approaches to Lunar Passenger Transportation. Lunar Mineral Resources: Extraction and Application. Space Resources Development - The Link Between Human Exploration and the Long-term Commercialization of Space. Toward a More Comprehensive Evaluation of Space Information. Development of Metal Casting Molds by Sol-Gel Technology Using Planetary Resources. A New Concept in Planetary Exploration: ISRU with Power Bursts. Bold Space Ventures Require Fervent Public Support. Hot-pressed Iron from Lunar Soil. The Lunar Dust Problem: A Possible Remedy. Considerations on Use of Lunar Regolith in Lunar Constructions. Experimental Study on Water Production by Hydrogen Reduction of Lunar Soil Simulant in a Fixed Bed Reactor.

Ignatiev, A.↗

Biotechnological solutions for critical mineral recovery from unconventional feedstocks

Secure and sustainable metal recovery from unconventional feedstocks is needed to meet the mineral demands of energy, defense, and electronic technologies. Here, we highlight the potential to leverage nature’s ability to extract and differentiate metal ions in biotechnologies that could become the next generation of mining and refining. We describe bulk and trace processes and then discuss the advances and opportunities of two key bioprocesses: microbially mediated solubilization of metal ions from solid matrices (termed ‘bioleaching’) and bio-based separation of solubilized ions via selective adsorption to proteins. Both biotechnologies have advantages such as reduced energy input for leaching low-grade feedstocks and reduced organic solvent demand for separating ions with similar physiochemical properties but require more development for industrial scale recovery from unconventional feedstocks. Innovation in biological science and engineering may bring timely solutions to key challenges toward recovering critical minerals from unconventional feedstocks.

organic↗

Extraterrestrial resources: Implications from terrestrial experience

Terrestrial mining experience indicates that the overwhelming criterion of a potentially economic deposit is its recoverable concentration of the desired mineral or element. Recovery can be based on contrast in physical and/or chemical properties, but processes based on physical properties are typically less expensive. As several processes generally are used in sequence, they have a profound effect on extraction costs. These criteria will also apply to extraterrestrial resources. Although the extreme cost of access to space makes even ordinary materials extremely valuable, this inaccessibility also makes capital and maintenance costs extremely high. The following four development stages will apply, especially with the additional unknowns of an extraterrestrial environment: (1) Exploration for the highest grade of the mineral or element desired (because the extraction plant must be simple, cheap, and rugged to minimize capital and maintenance costs, high grade is extremely important); (2) Laboratory testing of various physical and/or chemical separation techniques on the possible ore to determine if the material can indeed be recovered economically; (3) a pilot plant test, in which a large sample is dug from the deposit to determine excavation rates, power requirements, and equipment wear. (This sample is then run through a pilot mill designed on the basis of the laboratory testing. Pilot plant testing must be carried out at increasing scales, but several trials are generally necessary at each scale before the size of operations can be increased. Moreover, pilot testing is necessary for each new mineral deposit); and (4) Last is the full-scale mine and plant start-up. (New problems invariably occur at this point, but they can be kept to a minimum if the pilot plant tests were realistic). If such a development plan is followed rigorously, major cost overruns, with their potentially disastrous effects on resource developments, can be avoided.

Kuck, David L.↗

Screening Analysis of Terrestrial Enhanced Rock Weathering of Igneous Rocks and Industrial Waste Materials

This poster, presented at the 17th Greenhouse Gas Control Technology Conference, reports on an NETL screening level techno-economic assessment of enhanced weathering (EW). EW is a promising emerging carbon dioxide removal approach that involves harnessing and accelerating the natural weathering process by which atmospheric CO2 passively reacts with exposed alkaline minerals and is removed from the atmosphere. Two primary cases utilizing different sources of alkaline material are considered: (1) utilizing naturally occurring mined igneous rocks, and (2) utilizing industrial waste materials. The analysis highlights that utilizing materials with high weathering potential in suitable locations may result in relatively low levelized cost of captured. NETL is publishing a detailed and transparent report titled “Enhanced Weathering: Techno-Economic and Life Cycle Screening Analysis” that includes more detail on the screening level techno-economic analysis and includes a life cycle analysis.

carbon dioxide removal↗

Interdisciplinary applications and interpretations of ERTS data within the Susquehanna River Basin (resource inventory, land use, and pollution)

The author has identified the following significant results. An interdisciplinary group at Penn State University is analyzing ERTS-1 data. The geographical area of interest is that of the Susquehanna River Basin in Pennsylvania. The objectives of the work have been to ascertain the usefulness of ERTS-1 data in the areas of natural resources and land use inventory, geology and hydrology, and environmental quality. Specific results include a study of land use in the Harrisburg area, discrimination between types of forest resources and vegetation, detection of previously unknown geologic faults and correlation of these with known mineral deposits and ground water, mapping of mine spoils in the anthracite region of eastern Pennsylvania, and mapping of strip mines and acid mine drainage in central Pennsylvania. Both photointerpretive techniques and automatic computer processing methods have been developed and used, separately and in a combined approach.

Mcmurtry, G. J.↗

State-Estimation Algorithm Based on Computer Vision

An algorithm and software to implement the algorithm are being developed as means to estimate the state (that is, the position and velocity) of an autonomous vehicle, relative to a visible nearby target object, to provide guidance for maneuvering the vehicle. In the original intended application, the autonomous vehicle would be a spacecraft and the nearby object would be a small astronomical body (typically, a comet or asteroid) to be explored by the spacecraft. The algorithm could also be used on Earth in analogous applications -- for example, for guiding underwater robots near such objects of interest as sunken ships, mineral deposits, or submerged mines. It is assumed that the robot would be equipped with a vision system that would include one or more electronic cameras, image-digitizing circuitry, and an imagedata- processing computer that would generate feature-recognition data products.

Bayard, David↗

Design criteria for an underground lunar mine

Underground excavation and construction techniques have been well developed terrestrially and provide an attractive option for lunar mining and habitat construction. The lunar mine, processing facilities and habitats could be located beneath the lunar surface in basaltic rock that would protect the crew and equipment from the hazardous surface environment. A terrestrial-like atmosphere would be created within the underground structures allowing more conventional technologies to be utilized. In addition, the basalt would likely contain higher quality mineral deposits than the regolith (lunar soil) since the minerals in the regolith have been degraded by meteorite bombardment. The conditions that would affect the design of an underground lunar mine are described and a lunar rock mass rated to assess its quality using terrestrial rock mass classification systems. Design criteria are established and a construction scenario proposed. Parameters having the greatest effect on stability are identified based on distinct element computer modeling and terrestrial experience.

Siekmeier, John A.↗

Distributed sustainable metals production: opportunities for intensifying separations & alternative feedstocks

Meeting the increased demand for rare earth elements and beyond primary mined ore. Secondary sources like phosphogypsum, coal fly ash, used nuclear fuel, and electronic waste are concentrated sources of critical minerals. One strategy for a resilient supply chain is to decentralize sourcing and hydrometallurgical processing of metals. Rotating packed beds (RPBs) for solid-phase extraction and liquid-liquid extraction are gaining momentum for their ability to increase process throughput by 5-10x the state of the art. In conclusion, this review discusses advances in hydrometallurgical RPB processes and opportunities for implementation in distributed metals production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The brine of the times

New processes directly extract lithium from dilute sources. The accelerating global push to reduce carbon emissions is driving substantial demand for clean energy technologies and the materials on which they depend. Nations are vying for critical minerals, such as lithium, cobalt, and rare earth elements), to produce electric vehicles, energy storage devices, and other low-carbon technologies. Tremendous attention focuses on lithium, which is primarily sourced from either hard rock called spodumene or natural brines—solutions containing lithium and other salts found in continental deposits, for example. However, mining lithium often involves energy-intensive, laborious processes. On pages 1438 and 1444 of this issue, Li et al. and Song et al., respectively, report efficient ways to extract lithium from dilute brine. In conclusion, these advances open up opportunities for sustainable extraction from unexploited dilute brines.

Darling, Seth B.↗

Thermal Characterization and Exhumation of Northwest San Juan Basin Area, NM

The San Juan Basin (SJB), located in southwestern Colorado northwestern New Mexico, containing Paleozoic through middle Cenozoic strata, formed as a partitioned basin approximately 80 Ma in response to the Laramide orogeny. The SJB is a commercially mature, petroleum-producing basin, and currently being explored for CCUS and geothermal resources. Modern heat flow within the SJB is spatially variable with higher geothermal gradients in its northern and eastern portions. The temporal history of the basin thermal history is essential for understanding capacity for carbon storage and geothermal exploration. We present thermochronometric analyses of two surface and two subsurface samples to constrain spatial-temporal thermal evolution of the northwestern San Juan Basin. Apatite (U-Th)/He thermochronometric analyses were conducted on Cliff House and Kirtland Formation outcrops and subsurface samples of the Ojo Alamo and Pictured Cliffs Formations from a DOE funded, CCUS project pilot-well. In addition, vitrinite reflectance data and 1D basin modelling constrain possible time-temperature pathways of the samples in an area where no previous studies have constrained the uplift/exhumation of the Hogback Monocline using thermochronometry. Modeling suggests that elevated subsurface temperatures developed simultaneously with regional late Oligiocene volcanism in the San Juan Volcanic field and timing of maximum burial in the SJB. Late Miocene to Pliocene cooling/exhumation through the apatite (U-Th)/He partial retention zone support stratigraphic evidence of the Colorado Plateau uplift, possibly regional epeirogenic uplift driven by mantle processes.

02 PETROLEUM↗

NEWTS Integrated Dataset (version 2.0)

The National Energy Water Treatment and Speciation (NEWTS) Integrated Dataset v2.0 provides water researchers, community leaders, regulators, and industry stakeholders with a unified and standardized energy-process wastewater chemistry database. This resource is derived from 39 state and federal entities, and scientific publications, and contains more than 700,000 sample records, many of which also provide geospatial information. The dataset includes chemistry data for several different energy-process wastewater types including produced water, other oil and gas wastewaters, mine drainage, coal ash leachate, power plant wastewater, and geothermal fluids. The NEWTS Integrated Dataset was built to support prudent decision-making, characterization of potential critical mineral sources, and modeling of treatment and valorization options. A subset of this novel resource is also featured on the NEWTS State-Level Database Dashboard. Additional data can be found in the NEWTS EDX Group and the NEWTS Federal Database Dashboard.

AMD↗

Combustion detector

A device has been developed for generating a rapid response signal upon the radiation-emitting combustion reaction of certain gases in order to provide a means for the detection and identification of such reaction and concurrently discriminate against spurious signals. This combustion might be the first stage of a coal mine explosion process, and thereby this device could provide a warning of the impending explosion in time to initiate quenching action. This device has the capability of distinguishing between the light emitted from a combustion reaction and the light emitted by miners' lamps, electric lamps, welding sparks or other spurious events so that the quenching mechanism is triggered only when an explosion-initiating combustion occurs.

Trimpi, R. L.↗

Simulation of Helium-3 Extraction from Lunar Ilmenite

Knowledge of the trapping mechanisms and diffusion characteristics of solar-wind implanted isotopes in the minerals of the lunar regolith will enable the optimization of the processes to extract solar wind gases from regolith particles. Extraction parameters include the temperature and duration of extraction, particle size, and gas yield. Diffusion data will increase the efficiency and profitability of future mining ventures. This data will also assist in optimizing the evaluations of various potential mining sites based on remote sensing data. For instance, if magnesian ilmenite (Mg,Fel.,Ti03) is found to retain He better than stoichiometric ilmenite (FeTi03), remote sensing data for Mg could be considered in addition to Ti and maturity data. The context of the currently discussed work is the mining of helium-3 for potential use as a fuel for fusion energy generation. However, the potential resources deposited by the solar wind include hydrogen (and derived water), helium-4, nitrogen and carbon. Implantation experiments such as those performed for helium isotopes in ilmenite are important for the optimized extraction of these additional resources. These experiments can easily be reproduced for most elements or isotopes of interest.

Kuhlman, K. R.↗

Production of Ultrafine, High-purity Ceramic Powders Using the US Bureau of Mines Developed Turbomill

Turbomilling, an innovative grinding technology developed by the U.S. Bureau of Mines in the early 1960's for delaminating filler-grade kaolinitic clays, has been expanded into the areas of particle size reduction, material mixing, and process reaction kinetics. The turbomill, originally called an attrition grinder, has been used for particle size reduction of many minerals, including natural and synthetic mica, pyrophyllite, talc, and marble. In recent years, an all-polymer version of the turbomill has been used to produce ultrafine, high-purity, advanced ceramic powders such as SiC, Si3N4, TiB2, and ZrO2. In addition to particle size reduction, the turbomill has been used to produce intimate mixtures of high surface area powders and whiskers. Raw materials, TiN, AlN, and Al2O3, used to produce a titanium nitride/aluminum oxynitride (TiN/AlON) composite, were mixed in the turbomill, resulting in strength increases over samples prepared by dry ball milling. Using the turbomill as a leach vessel, it was found that 90.4 pct of the copper was extracted from the chalcopyrite during a 4-hour leach test in ferric sulfate versus conventional processing which involves either roasting of the ore for Cu recovery or leaching of the ore for several days.

Hoyer, Jesse L.↗

Multi-functional Sorbent Development for Separation of Critical Minerals and Pollutants

Critical Metals (CMs), including Rare Earth Elements (REEs), aluminum, manganese, cobalt, and others outlined by the U.S. Department of the Interior’s Geological Survey are essential to the national and economic security of the US, and whose supply chain is susceptible to disruption. Because of the negative environmental impacts inherent with the conventional mining and processing of solid ores for CMs, adsorption-based recovery of naturally dissolved species from coal wastewaters is appealing. Acid mine drainage (AMD) remains a relatively untapped source that can be rich in REEs, and especially in Al, Mn, and other CMs. NETL’s Multi-functional Sorbent Technology (MUST) has been developed originally from the functionalized silica sorbents for carbon capture. Ongoing work aims to find AMD sites enriched with either REEs or other CM, and to perform additional field tests at these sites. Overall, our work shows the viability of recovering CMs from AMD and other coal waste streams, using a fixed-bed adsorption system that can also employ a selective elution technique to achieve highly purified metal resources.

Shi, Fan↗