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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Regional Application of an Ecosystem Production Model for Studies of Biogeochemistry in the...

The degree to which primary production, soil carbon, and trace gas fluxes in tropical forests of the Amazon are limited by moisture availability and other environmental factors was examined using an ecosystem modeling application for the country of Brazil. A regional geographic information system (GIS) serves as the data source of climate drivers, satellite images, land cover, and soil properties for input to the NASA Ames-CASA (Carnegie-Ames-Stanford Approach) model over a 8-km grid resolution. Simulation results supports the hypothesis that net primary production (NPP) is limited by cloud interception of solar radiation over the humid northwestern portion of the region. Peak annual rates for NPP of nearly 1.4 kg C m-2yr -1are localized in the seasonally dry eastern Amazon in areas that we assume are primarily deep-rooted evergreen forest cover. Regional effects of forest conversion on NPP and soil carbon content are indicated in the model results, especially in seasonally dry areas. Comparison of model flux predictions along selected eco-climatic transects reveal moisture, soil, and land use controls on gradients of ecosystem production and soil trace gas emissions (CO2, N2O, and NO). These results are used to formulate a series of research hypotheses for testing in the next phase of regional modeling, which includes recalibration of the light-use efficiency term in CASA using field measurements of NPP, and refinements of vegetation index and soil property (texture and potential rooting depth) maps for the region.

Potter, C. S.↗
NASA NTRS1994

Effect of lightning on the concentration of odd nitrogen species in the lower stratosphere: An update

Revised model estimates of the effect of lightning on the lower stratospheric NOy are presented. Several changes in the Atmospheric and Environmental Research Incorporated model were made since the last evaluation of the impact of lightning. Improvements were made in the model circulation and location of tropopause in the tropics, which is now calculated from the National Meteorological Center temperature data. Changes in model circulation reduced the mass flux from the troposphere to the tropical stratosphere. The calculated mass fluxes are found to agree better with some recent estimates. The circulation changes also reduced the advective mass flux from the tropical lower stratosphere to the midlatitudes. The change in circulation and the change in the tropopause height lead to increases in the calculated concentration of N2O, O3 and NOy in the tropical lower stratosphere. The effect of lightning is to increase the calculated concentration of NOy around 64 mbar by a factor of 2, compared to a factor of 10 enhancement in the previous calculations. Comparison with the Stratosphere Troposphere Exchange Project 1987 data indicates that the inclusion of a lightning source brings the model results in closer agreement with the observations.

Kotamarthi, V. R.↗
NASA NTRS1981

Solar UV variability - Effects on stratospheric ozone, trace constituents and thermal structure

The effect of long-term (11-year solar cycle) solar UV variability on stratospheric chemical and thermal structure has been studied using a time-dependent one-dimensional model. Previous studies have suggested substantial variations in local and total ozone, and in stratospheric thermal structure from solar minimum to solar maximum. It is shown that significant variations also occur in some of the trace constituents. Members of the HOx family and N2O exhibit the largest variations, and these changes, if detected, may provide additional means of verifying the presence of solar UV variability and its effects. Some of the species show large phase differences with the assumed solar flux variation. The role of chemical and transport time constants on the time variations of the trace species is examined. Comparisons with reported ozone and temperature data show reasonable agreement for the period 1960 to 1972.

Natarajan, M.↗
DOE OSTI2022

AmeriFlux FLUXNET-1F US-ARM ARM Southern Great Plains site- Lamont

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-ARM ARM Southern Great Plains site- Lamont. This is the FLUXNET version of the carbon flux data for the site US-ARM ARM Southern Great Plains site- Lamont produced by applying the standard ONEFlux (1F) software. Site Description - Central facility tower crop field (winter wheat, corn, soy, alfalfa). The site also has continuous measurements of precise mixing ratios of CO2, CH4, CO, N2O, and isotopic ratio of 13CO2. In addition to 4 m system, there are sonic anemometers at 25 m and 60 m.

Biraud, Sebastien↗
NASA NTRS1992

A model of nitrous oxide evolution from soil driven by rainfall events. I - Model structure and sensitivity. II - Model applications

Simulations of N2O and CO2 emissions from soils were conducted with a rain-event driven, process-oriented model (DNDC) of nitrogen and carbon cycling processes in soils. The magnitude and trends of simulated N2O (or N2O + N2) and CO2 emissions were consistent with the results obtained in field experiments. The successful simulation of these emissions from the range of soil types examined demonstrates that the DNDC will be a useful tool for the study of linkages among climate, soil-atmosphere interactions, land use, and trace gas fluxes.

Changsheng, LI↗
NASA NTRS1979

Actinometric measurements and theoretical calculations of j/O3/, the rate of photolysis of ozone to O/1D/

The paper presents an experimental technique which measures j/O3-O(1-D)/, the rate of solar photolysis of ozone to singlet oxygen atoms. It is shown that a flow actinometer carries dilute O3 in N2O into direct sunlight where the O(1D) formed reacts with N2O to form NO which chemiluminescence detects, with a time resolution of about one minute. Measurements indicate a photolysis rate of 1.2 (+ or - .2) x 10 to the -5/s for a cloudless sky, 45 deg zenith angle, 0.345 cm ozone column and zero albedo. Finally, ground level results compare with theoretical calculations based on the UV actinic flux as a function of ozone column and solar zenith angle.

Dickerson, R. R.↗
NASA NTRS1986

A dynamically based transport parameterization for one-dimensional photochemical models of the stratosphere

The net vertical tracer flux in the stratosphere is due primarily to advection by the global-scale mean meridional circulation, not to diffusion by turbulent eddies. Using a simple model of this circulation, it is shown that the net flux can be approximated by a flux-gradient relationship in which the vertical 'eddy transport' coefficient is proportional to the square of the diabatic heating rate and inversely proportional to the rate at which meridional tracer gradients are destroyed by horizontal eddy mixing and chemical damping. Thus the transport coefficient will differ for tracers with differing chemical lifetimes. Profiles computed for various source gases (CH4 N2O, CF2Cl2, and CFCl3) show that this parameterization provides an improvement over conventional formulations that utilize a single transport coefficient for all species.

Holton, J. R.↗
NASA NTRS1991

Elements of radiative interactions in gaseous systems

Basic formulations, analyses, and numerical procedures are presented to study radiative interactions in gray as well as nongray gases under different physical and flow conditions. After preliminary fluid-dynamical considerations, essential governing equations for radiative transport are presented that are applicable under local and nonlocal thermodynamic equilibrium conditions. Auxiliary relations for relaxation times and spectral absorption model are also provided. For specific applications, several simple gaseous systems are analyzed. The first system considered consists of a gas bounded by two parallel plates having the same temperature. For this system, both vibrational nonequilibrium effects and radiation conduction interactions are studied. The second system consists of fully developed laminar flow and heat transfer in a parallel plate duct under the boundary condition of a uniform surface heat flux. For this system, effects of gray surface emittance are studied. With the single exception of a circular geometry, the third system is identical to the second system. Here, the influence of nongray walls is also studied, and a correlation between the parallel plates and circular tube results is presented. The particular gases selected are CO, CO2, H2O, CH4, N2O, NH3, OH, and NO. The temperature and pressure range considered are 300 to 2000 K, and 0.1 to 100 atmosphere, respectively. Illustrative results obtained for different cases are discussed and some specific conclusions are provided.

Tiwari, Surendra N.↗
DOE OSTI2022

Stable isotopes of carbon dioxide (CO2), dissolved inorganic carbon (DIC), water and concentrations of greenhouse gases in a mountainous watershed (Crested Butte, Colorado)

Temperature and precipitation variability in response to climate change affects water cycling of watersheds and can potentially impact water quality, water availability, elemental and molecular fluxes, and biogeochemical processes. Here we report the measurements of light stable isotopes and greenhouse gases analysis to a large multidisciplinary project addressing watershed function. Water hydrogen (H) and oxygen (O) stable isotopes of snow and water saturated soil were measured to constrain source contributions to groundwater and streamflow. In an effort to better constrain existing nitrogen and carbon cycling models in high-altitude ecosystems, carbon dioxide (CO2), nitrous oxide (N2O), methane (CH4) greenhouse gases concentrations and stable isotope signatures of CO2, dissolved inorganic carbon (DIC), and water were measured. This dataset includes one CSV file and one Excel file containing data including stable isotopes of carbon dioxide (CO2), dissolved inorganic carbon (DIC), water and concentrations of greenhouse gases. The CSV and Excel files contain the same information/data but have included both versions for accessibility.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2010

Radiation Chemistry in Ammonia-Water Ices

We studied the effects of 100 keV proton irradiation on films of ammonia-water mixtures between 20 and 120 K. Irradiation destroys ammonia, leading to the formation and trapping of H2, N2 NO, and N2O, the formation of cavities containing radiolytic gases, and ejection of molecules by sputtering. Using infrared spectroscopy, we show that at all temperatures the destruction of ammonia is substantial, but at higher temperatures (120 K), it is nearly complete (approximately 97% destroyed) after a fluence of 10(exp 16) ions per square centimeter. Using mass spectroscopy and microbalance gravimetry, we measure the sputtering yield of our sample and the main components of the sputtered flux. We find that the sputtering yield depends on fluence. At low temperatures, the yield is very low initially and increases quadratically with fluence, while at 120 K the yield is constant and higher initially. The increase in the sputtering yield with fluence is explained by the formation and trapping of the ammonia decay products, N2 and H2 which are seen to be ejected from the ice at all temperatures.

Loeffler, M. J.↗
NASA NTRS1976

Effect of water vapor on the destruction of ozone in the stratosphere perturbed by ClX or NOx pollutants

Results are presented for a self-consistent one-dimensional coupled flow calculation for Ox, NOx, HOx, ClX, H2O, H2, CH4, H2O2, and N2O densities between 10 and 120 km. The results agree well with observations for the normal midlatitude atmosphere over this altitude range. ClX, NOx, and H2O are varied independently in the model considered. It is shown that the effect of depletion of ozone by ClX is to remove ozone preferentially above 30 km and to lower the altitude of maximum ozone density. This leads to enhanced solar heating of the lower stratosphere and tropopause and suggests the possibility of an increased flux of water into the stratosphere. Increasing water vapor in the stratosphere greatly enhances the rate of destruction of O3 by ClX and also causes an increase in the rate of destruction of O3 in the NOx-perturbed atmosphere.

Liu, S. C.↗
NASA NTRS1993

Experimental investigation of nozzle/plume aerodynamics at hypersonic speeds

Work continued on the improvement of 16-Inch Shock Tunnel. This comprised studies of ways of improving driver gas ignition, an improved driver gas mixing system, an axial translation system for the driver tube, improved diaphragm materials (carbon steel vs. stainless steel), a copper liner for the part of the driven tube near the nozzle, the use of a buffer gas between the driver and driven gases, the use of N2O in the driven tube, the use of a converging driven tube, operation of the facility as a non-reflected shock tunnel and expansion tube, operation with heated hydrogen or helium driver gas, the use of detonations in the driver and the construction of an enlarged test section. Maintenance and developmental work continued on the scramjet combustor continued. New software which greatly speeds up data analysis has been written and brought on line. In particular, software which provides very rapid generation of model surface heat flux profiles has been brought on line. A considerable amount of theoretical work was performed in connection with upgrading the 16 Inch Shock Tunnel Facility. A one-dimensional Godunov code for very high velocities and any equation of state is intended to add viscous effects in studying the operation of the Shock Tunnel and also of two-stage light gas guns.

Bogdanoff, David W.↗
NASA NTRS2001

A Thermal Infrared Radiation Parameterization for Atmospheric Studies

This technical memorandum documents the longwave radiation parameterization developed at the Climate and Radiation Branch, NASA Goddard Space Flight Center, for a wide variety of weather and climate applications. Based on the 1996-version of the Air Force Geophysical Laboratory HITRAN data, the parameterization includes the absorption due to major gaseous absorption (water vapor, CO2, O3) and most of the minor trace gases (N2O, CH4, CFCs), as well as clouds and aerosols. The thermal infrared spectrum is divided into nine bands. To achieve a high degree of accuracy and speed, various approaches of computing the transmission function are applied to different spectral bands and gases. The gaseous transmission function is computed either using the k-distribution method or the table look-up method. To include the effect of scattering due to clouds and aerosols, the optical thickness is scaled by the single-scattering albedo and asymmetry factor. The parameterization can accurately compute fluxes to within 1% of the high spectral-resolution line-by-line calculations. The cooling rate can be accurately computed in the region extending from the surface to the 0.01-hPa level.

Chou, Ming-Dah↗
NASA NTRS1994

On the apparent velocity of integrated sunlight. 2: 1983-1992 and comparisons with magnetograms

We report additional results in our program to monitor the wavelength stability of lines in the 2.3 micrometer spectrum of integrated sunlight. We use the McMath Fourier transform spectrometer (FTS) of the National Solar Observatory to monitor 16 delta V = 2 lines of (12)C(16)O, as well as five atomic lines. Wavenumber calibration is achieved using a low-pressure N2O absorption cell and checked against terrestrial atmospheric lines. Imperfect optical integration of the solar disk remains the principal source of error, but this error has been reduced by improved FTS/telescope collimation and observing procedures. The present results include data from an additional 13 quarterly observing runs since 1985. We continue to find that the apparent velocity of integrated sunlight is variable, in the sense of having a greater reshift at solar maximum. This is supported by the temporal dependence of the integrated light velocity, and by the presence of a correlation between velocity and the disk-averaged magnetic flux derived from Kitt Peak magnetograms. The indicated peak-to-peak apparent velocity amplitude over a solar cycle is approximately the same as the velocity amplitude of the Sun's motion about the solar system barycenter. This represents about half the amplitude which we inferred in Paper I (Deming et al. 1987), but the present result has a much greater statistical significance. Our results have implications for those investigations which search for the Doppler signatures of planetary-mass companions to solar-type stars. We contrast our results to the recent finding by McMillan et al. 1993 that solar absorption lines in the violet spectral region are wavelength-stable over the solar cycle.

Deming, Drake↗
NASA NTRS2004

[CO2 Budget and Atmospheric Rectification (COBRA) Over North America]

The purpose of the CO2 Budget and Rectification Airborne (COBRA) study was to assess terrestrial sources and sinks of carbon dioxide using an air-borne study. The study was designed to address the measurement gap between plot-scale direct flux measurements and background hemispheric-scale constraints and to refine techniques for measuring terrestrial fluxes at regional to continental scales. The initial funded effort (reported on here) was to involve two air-borne campaigns over North America, one in summer and one in winter. Measurements for COBRA (given the acronym C02BAR in the initial proposal) were conducted from the University of North Dakota Citation 11, a twin-engine jet aircraft capable of profiling from the surface to 12 km and cruising for up to 4 hours and 175m/s. Onboard instrumentation measured concentrations of CO2, CO, and H2O, and meteorological parameters at high rates. In addition, two separate flask sampling systems collected discrete samples for laboratory analysis of CO2,CO, CH4, N2O, SF6, H2, 13CO2, C18O16O,O2/N2, and Ar/N2. The project involved a collaboration between a number of institutions, including (but not limited to) Harvard, NOAA-CMDL, the University of North Dakota, and Scripps.

Source record↗
DOE OSTI2023

Changes in soil pore structure generated by the root systems of maize , sorghum and switchgrass affect in situ N 2 O emissions and bacterial denitrification

Due to the heterogeneous nature of soil pore structure, processes such as nitrification and denitrification can occur simultaneously at microscopic levels, making prediction of small-scale nitrous oxide (N 2 O) emissions in the field notoriously difficult. We assessed N 2 O+N 2 emissions from soils under maize (Zea mays L.), switchgrass (Panicum virgatum L.), and energy sorghum (Sorghum bicolor L.), three potential bioenergy crops in order to identify the importance of different N 2 O sources to microsite production, and relate N 2 O source differences to crop-associated differences in pore structure formation. The combination of isotopic surveys of N 2 O in the field during one growing season and X-ray computed tomography (CT) enabled us to link results from isotopic mappings to soil structural properties. Further, our methodology allowed us to evaluate the potential for in situ N 2 O suppression by biological nitrification inhibition (BNI) in energy sorghum. Our results demonstrated that the fraction of N 2 O originating from bacterial denitrification and reduction of N 2 O to N 2 is largely determined by the volume of particulate organic matter occluded within the soil matrix and the anaerobic soil volume. Bacterial denitrification was greater in switchgrass than in the annual crops, related to changes in pore structure caused by the coarse root system. This led to high N-loses through N 2 emissions in the switchgrass system throughout the season a novel finding given the lack of data in the literature for total denitrification. Isotopic mapping indicated no differences in N 2 O-fluxes or their source processes between maize and energy sorghum that could be associated with the release of BNI by the investigated sorghum variety. The results of this research show how differences in soil pore structures among cropping systems can determine both N 2 O production via denitrification and total denitrification N losses in situ.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

The Modeled Seasonal Cycles of Surface N 2 O Fluxes and Atmospheric N 2 O

Nitrous oxide (N 2 O) is a greenhouse gas and stratospheric ozone-depleting substance with large and growing anthropogenic emissions. Previous studies identified the influx of N 2 O-depleted air from the stratosphere to partly cause the seasonality in tropospheric N 2 O (aN 2 O), but other contributions remain unclear. Here, we combine surface fluxes from eight land and four ocean models from phase 2 of the Nitrogen/N 2 O Model Intercomparison Project with tropospheric transport modeling to simulate aN 2 O at eight remote air sampling sites for modern and pre-industrial periods. Models show general agreement on the seasonal phasing of zonal-average N 2 O fluxes for most sites, but seasonal peak-to-peak amplitudes differ several-fold across models. The modeled seasonal amplitude of surface aN 2 O ranges from 0.25 to 0.80 ppb (interquartile ranges 21%–52% of median) for land, 0.14–0.25 ppb (17%–68%) for ocean, and 0.28–0.77 ppb (23%–52%) for combined flux contributions. The observed seasonal amplitude ranges from 0.34 to 1.08 ppb for these sites. The stratospheric contributions to aN 2 O, inferred by the difference between the surface-troposphere model and observations, show 16%–126% larger amplitudes and minima delayed by ~1 month compared to Northern Hemisphere site observations. Land fluxes and their seasonal amplitude have increased since the pre-industrial era and are projected to grow further under anthropogenic activities. Our results demonstrate the increasing importance of land fluxes for aN 2 O seasonality. Considering the large model spread, in situ aN 2 O observations and atmospheric transport-chemistry models will provide opportunities for constraining terrestrial and oceanic biosphere models, critical for projecting carbon-nitrogen cycles under ongoing global warming.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Denitrification and the challenge of scaling microsite knowledge to the globe

Here, our knowledge of microbial processes—who is responsible for what, the rates at which they occur, and the substrates consumed and products produced—is imperfect for many if not most taxa, but even less is known about how microsite processes scale to the ecosystem and thence the globe. In both natural and managed environments, scaling links fundamental knowledge to application and also allows for global assessments of the importance of microbial processes. But rarely is scaling straightforward: More often than not, process rates in situ are distributed in a highly skewed fashion, under the influence of multiple interacting controls, and thus often difficult to sample, quantify, and predict. To date, quantitative models of many important processes fail to capture daily, seasonal, and annual fluxes with the precision needed to effect meaningful management outcomes. Nitrogen cycle processes are a case in point, and denitrification is a prime example. Statistical models based on machine learning can improve predictability and identify the best environmental predictors but are—by themselves—insufficient for revealing process-level knowledge gaps or predicting outcomes under novel environmental conditions. Hybrid models that incorporate well-calibrated process models as predictors for machine learning algorithms can provide both improved understanding and more reliable forecasts under environmental conditions not yet experienced. Incorporating trait-based models into such efforts promises to improve predictions and understanding still further, but much more development is needed.

59 BASIC BIOLOGICAL SCIENCES↗