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NASA NTRS2014

Statistical Aspects of North Atlantic Basin Tropical Cyclones During the Weather Satellite Era, 1960-2013

This Technical Publication (TP) is part 2 of a two-part study of the North Atlantic basin tropical cyclones that occurred during the weather satellite era, 1960-2013. In particular, this TP examines the inferred statistical relationships between 25 tropical cyclone parameters and 9 specific climate-related factors, including the (1) Oceanic Niño Index (ONI), (2) Southern Oscillation Index (SOI), (3) Atlantic Multidecadal Oscillation (AMO) index, (4) Quasi-Biennial Oscillation (QBO) index, (5) North Atlantic Oscillation (NAO) index of the Climate Prediction Center (CPC), (6) NAO index of the Climate Research Unit (CRU), (7) Armagh surface air temperature (ASAT), (8) Global Land-Ocean Temperature Index (GLOTI), and (9) Mauna Loa carbon dioxide (CO2) (MLCO2) index. Part 1 of this two-part study examined the statistical aspects of the 25 tropical cyclone parameters (e.g., frequencies, peak wind speed (PWS), accumulated cyclone energy (ACE), etc.) and provided the results of statistical testing (i.e., runs-testing, the t-statistic for independent samples, and Poisson distributions). Also, the study gave predictions for the frequencies of the number of tropical cyclones (NTC), number of hurricanes (NH), number of major hurricanes (NMH), and number of United States land-falling hurricanes (NUSLFH) expected for the 2014 season, based on the statistics of the overall interval 1960-2013, the subinterval 1995-2013, and whether the year 2014 would be either an El Niño year (ENY) or a non-El Niño year (NENY).

Wilson, Robert M.↗
NASA NTRS2014

Interannual Variation in Phytoplankton Class-Specific Primary Production at a Global Scale

We used the NASA Ocean Biogeochemical Model (NOBM) combined with remote sensing data via assimilation to evaluate the contribution of 4 phytoplankton groups to the total primary production. First we assessed the contribution of each phytoplankton groups to the total primary production at a global scale for the period 1998-2011. Globally, diatoms were the group that contributed the most to the total phytoplankton production (50, the equivalent of 20 PgC y-1. Coccolithophores and chlorophytes each contributed to 20 (7 PgC y-1 of the total primary production and cyanobacteria represented about 10 (4 PgC y(sub-1) of the total primary production. Primary production by diatoms was highest in high latitude (45) and in major upwelling systems (Equatorial Pacific and Benguela system). We then assessed interannual variability of this group-specific primary production over the period 1998-2011. Globally the annual relative contribution of each phytoplankton groups to the total primary production varied by maximum 4 (1-2 PgC y-1. We assessed the effects of climate variability on the class-specific primary production using global (i.e. Multivariate El Nio Index, MEI) and regional climate indices (e.g. Southern Annular Mode (SAM), Pacific Decadal Oscillation (PDO) and North Atlantic Oscillation (NAO)). Most interannual variability occurred in the Equatorial Pacific and was associated with climate variability as indicated by significant correlation (p 0.05) between the MEI and the class-specific primary production from all groups except coccolithophores. In the Atlantic, climate variability as indicated by NAO was significantly correlated to the primary production of 2 out of the 4 groups in the North Central Atlantic (diatomscyanobacteria) and in the North Atlantic (chlorophytes and coccolithophores). We found that climate variability as indicated by SAM had only a limited effect on the class-specific primary production in the Southern Ocean. These results provide a modeling and data assimilation perspective to phytoplankton partitioning of primary production and contribute to our understanding of the dynamics of the carbon cycle in the oceans at a global scale.

Chl-a↗
NASA NTRS2013

Interannual Variation in Phytoplankton Primary Production at a Global Scale

We used the NASA Ocean Biogeochemical Model (NOBM) combined with remote sensing data via assimilation to evaluate the contribution of four phytoplankton groups to the total primary production. First, we assessed the contribution of each phytoplankton groups to the total primary production at a global scale for the period 1998-2011. Globally, diatoms contributed the most to the total phytoplankton production ((is)approximately 50%, the equivalent of 20 PgC·y1). Coccolithophores and chlorophytes each contributed approximately 20% ((is) approximately 7 PgC·y1) of the total primary production and cyanobacteria represented about 10% ((is) approximately 4 PgC·y1) of the total primary production. Primary production by diatoms was highest in the high latitudes ((is) greater than 40 deg) and in major upwelling systems (Equatorial Pacific and Benguela system). We then assessed interannual variability of this group-specific primary production over the period 1998-2011. Globally the annual relative contribution of each phytoplankton groups to the total primary production varied by maximum 4% (1-2 PgC·y1). We assessed the effects of climate variability on group-specific primary production using global (i.e., Multivariate El Niño Index, MEI) and "regional" climate indices (e.g., Southern Annular Mode (SAM), Pacific Decadal Oscillation (PDO) and North Atlantic Oscillation (NAO)). Most interannual variability occurred in the Equatorial Pacific and was associated with climate variability as indicated by significant correlation (p (is) less than 0.05) between the MEI and the group-specific primary production from all groups except coccolithophores. In the Atlantic, climate variability as indicated by NAO was significantly correlated to the primary production of 2 out of the 4 groups in the North Central Atlantic (diatoms/cyanobacteria) and in the North Atlantic (chlorophytes and coccolithophores). We found that climate variability as indicated by SAM had only a limited effect on group-specific primary production in the Southern Ocean. These results provide a modeling and data assimilation perspective to phytoplankton partitioning of primary production and contribute to our understanding of the dynamics of the carbon cycle in the oceans at a global scale.

Coccolithophores↗
NASA NTRS2015

The Impact of Trends in the Large Scale Atmospheric Circulation on Mediterranean Surface Turbulent Heat Fluxes

Interannual variations of latent heat fluxes (LHF) and sensible heat fluxes (SHF) over the Mediterranean for the boreal winter season (DJF) show positive trends during 1958-2011. Comparison of correlations between the heat fluxes and the intensity and location of the Azores High (AH), and the NAO and East Atlantic-West Russia (EAWR) teleconnections, along with analysis of composites of surface temperature, humidity and wind fields for different teleconnection states, demonstrates that variations of the AH are found to explain the heat flux changes more successfully than the NAO and the EAWR. Trends in sea level pressure and longitude of the Azores High during DJF show a strengthening, and an eastward shift. DJF Azores High pressure and longitude are shown to co-vary such that variability of the Azores High occurs along an axis defined by lower pressure and westward location at one extreme, and higher pressure and eastward location at the other extreme. The shift of the Azores High from predominance of the low/west state to the high/east state induces trends in Mediterranean Sea surface winds, temperature and moisture. These, combined with sea surface warming trends, produce trends in wintertime Mediterranean Sea sensible and latent heat fluxes.

heat flux↗
NASA NTRS2015

The Impact of Trends in the Large Scale Atmospheric Circulation on Mediterranean Surface Turbulent Heat Fluxes

Interannual variations of latent heat fluxes (LHF) and sensible heat fluxes (SHF) over the Mediterranean for the boreal winter season (DJF) show positive trends during 1958-2011. Using reanalysis and satellite-based products, the variability and trends in the heat fluxes are compared with variations in three atmospheric teleconnection patterns: the North Atlantic Oscillation (NAO), the pressure and position of the Azores High (AH), and the East Atlantic-West Russia teleconnection pattern (EAWR). Comparison of correlations between the heat fluxes and teleconnections, along with analysis of composites of surface temperature, humidity, and wind fields for different teleconnection states, demonstrates that the AH explains the heat flux changes more successfully than NAO and EAWR. Trends in pressure and longitude of the Azores High show a strengthening and an eastward shift. Variations of the Azores High occur along an axis defined by lower pressure and westward location at one extreme and higher pressure and eastward location at the other extreme. The shift of the AH from predominance of the low/west state to the high/east state induces trends in Mediterranean Sea surface winds, temperature, and moisture. These, combined with sea surface warming trends, produce trends in wintertime sensible and latent heat fluxes.

Latent heat↗
NASA NTRS2015

North Atlantic Simulations in Coordinated Ocean-Ice Reference Experiments Phase II (CORE-II) : Inter-Annual to Decadal Variability - Part II

Simulated inter-annual to decadal variability and trends in the North Atlantic for the 1958−2007 period from twenty global ocean - sea-ice coupled models are presented. These simulations are performed as contributions to the second phase of the Coordinated Ocean-ice Reference Experiments (CORE-II). The study is Part II of our companion paper (Danabasoglu et al., 2014) which documented the mean states in the North Atlantic from the same models. A major focus of the present study is the representation of Atlantic meridional overturning circulation (AMOC) variability in the participating models. Relationships between AMOC variability and those of some other related variables, such as subpolar mixed layer depths, the North Atlantic Oscillation (NAO), and the Labrador Sea upper-ocean hydrographic properties, are also investigated. In general, AMOC variability shows three distinct stages. During the first stage that lasts until the mid- to late-1970s, AMOC is relatively steady, remaining lower than its long-term (1958−2007) mean. Thereafter, AMOC intensifies with maximum transports achieved in the mid- to late-1990s. This enhancement is then followed by a weakening trend until the end of our integration period. This sequence of low frequency AMOC variability is consistent with previous studies. Regarding strengthening of AMOC between about the mid-1970s and the mid-1990s, our results support a previously identified variability mechanism where AMOC intensification is connected to increased deep water formation in the subpolar North Atlantic, driven by NAO-related surface fluxes. The simulations tend to show general agreement in their representations of, for example, AMOC, sea surface temperature (SST), and subpolar mixed layer depth variabilities. In particular, the observed variability of the North Atlantic SSTs is captured well by all models. These findings indicate that simulated variability and trends are primarily dictated by the atmospheric datasets which include the influence of ocean dynamics from nature superimposed onto anthropogenic effects. Despite these general agreements, there are many differences among the model solutions, particularly in the spatial structures of variability patterns. For example, the location of the maximum AMOC variability differs among the models between Northern and Southern Hemispheres.

Ocean model comparisons↗
NASA NTRS2018

Winter Precipitation in North America and the Pacific-North America Pattern in GEOS-S2Sv2 Seasonal Hindcast

Reliable prediction of precipitation remains one of the most pivotal and complex challenges in seasonal forecasting. Previous studies show that various large-scale climate modes, such as ENSO, PNA and NAO play significant role in winter precipitation variability over the Northern America. The influences are most pronounced in years of strong indices of such climate modes. This study evaluates model bias, predictability and forecast skills of monthly winter precipitation in GEOS5-S2S 2.0 retrospective forecast from 1981 to 2016, with emphasis on the forecast skill of precipitation over North America during the extreme events of ENSO, PNA and NAO by applying EOF and composite analysis.

Li, Zhao↗
NASA NTRS2018

Southeast Greenland Winter Precipitation Strongly Linked to the Icelandic Low Position

Greenland's largest precipitation flux occurs in its southeast (SE) region during the winter, controlled primarily by easterly winds and frequent cyclogenesis in the North Atlantic. Several studies have attempted to link SE Greenland precipitation to the North Atlantic Oscillation (NAO) but results are inconsistent. This work uses reanalysis, automatic weather station data, and regional climate model output to show that the east-west position of the Icelandic low is a better predictor of SE Greenland precipitation (average correlation of r equals -0.48 in DJF (December January February)) than climate indices such as the NAO (r equals -0.06 in DJF). In years when the Icelandic low is positioned extremely west, moisture transport increases up to approximately 40 percent (or up to 40 kilograms per meter per second) off the SE Greenland coast compared to when the low is in an extreme east position. Furthermore, in years when the Icelandic low is positioned extremely west, storm track density and intensity increase just off the SE coast of Greenland. Thus, the Icelandic low's longitudinal position dominates SE Greenland ice sheet's wintertime precipitation, a positive term in the ice sheet mass balance. Given SE Greenland's importance in the overall ice sheet mass balance, the position of the Icelandic low is therefore important for making projections of future sea level.

Arctic↗
NASA NTRS2018

The Roles of Climate Change and Climate Variability in the 2017 Atlantic Hurricane Season

The 2017 Atlantic hurricane season was extremely active with six major hurricanes, the third most on record. The sea-surface temperatures (SSTs) over the eastern Main Development Region (EMDR), where many tropical cyclones (TCs) developed during active months of August/September, were ~0.96 C above the 1901-2017 average (warmest on record): about ~0.42 C from a long-term upward trend and the rest (~80%) attributed to the Atlantic Meridional Mode (AMM). The contribution to the SST from the North Atlantic Oscillation (NAO) over the EMDR was a weak warming, while that from El Niño-Southern Oscillation (ENSO) was negligible. Nevertheless, ENSO, the NAO, and the AMM all contributed to favorable wind shear conditions, while the AMM also produced enhanced atmospheric instability. Compared with the strong hurricane years of 2005/2010, the ocean heat content (OHC) during 2017 was larger across the tropics, with higher SST anomalies over the EMDR and Caribbean Sea. On the other hand, the dynamical/thermodynamical atmospheric conditions, while favorable for enhanced TC activity, were less prominent than in 2005/2010 across the tropics. The results suggest that unusually warm SST in the EMDR together with the long fetch of the resulting storms in the presence of record-breaking OHC may be key factors in driving the strong TC activity in 2017.

SST↗
NASA NTRS2018

The Role of Atmospheric Teleconnections and Local Forcings in Predicting Greenland Ice Sheet Surface Mass Loss

In recent decades, the Arctic climate has experienced substantial climactic change, including significant decreases in both sea ice extent and Greenland Ice Sheet (GrIS) surface mass balance. These trends are overlain by substantial interannual variability in atmospheric circulation driven by large-scale atmospheric teleconnection patterns. In addition, there is evidence to suggest that the removal of Arctic sea ice can alter local atmospheric circulation through increased air temperature, clouds, and water vapor, which may contribute to increased surface melting on the GrIS. Here, we seek to characterize how these processes are linked to Greenland Ice Sheet surface mass loss and constrain how the representation of these forcings can impact the prediction of meltwater runoff within the NASA Goddard Earth Observing System Model (GEOS) seasonal-to-subseasonal forecasting system (S2S v2.1). To do this, we use a combination of the Modern-Era Retrospective analysis for Research and Applications version 2 (MERRA-2) reanalysis product, retrospective seasonal forecasts from the GEOS S2S v2.1, and independent GEOS simulations. Results from MERRA-2 reanalysis indicate that the negative phase of the North Atlantic Oscillation (NAO) results in warm surface air temperatures and reduced precipitation across Greenland, both of which act to enhance summer ice surface mass losses. When compared with MERRA-2, retrospective forecasts from the GEOS S2S v2.1 system effectively reproduce the pattern of summer GrIS surface mass loss and demonstrate reasonable skill in predicting the magnitude of meltwater runoff at leads of 1 to 3 months. However, during periods with a strong negative NAO, ice sheet surface mass balance is substantially underestimated. This pattern is also associated with an underprediction of the Greenland Blocking Index height and over prediction of sea ice extent, suggesting that both local and non-local forcings may play a role in the reduced prediction skill during these periods. Using both retrospective forecasts and independent simulations, we characterize the relative importance of local and non-local mechanisms in driving summer GrIS

Andrews, Lauren C.↗
NASA NTRS2019

The Roles of Climate Change and Climate Variability in the 2017 Atlantic Hurricane Season

The 2017 Atlantic hurricane season was extremely active with six major hurricanes, the third most on record. The sea-surface temperatures (SSTs) over the eastern Main Development Region (EMDR), where many tropical cyclones (TCs) developed during active months of August/September, were ~0.96°C above the 1901-2017 average (warmest on record): about ~0.42°C from a long-term upward trend and the rest (~80%) attributed to the Atlantic Meridional Mode (AMM). The contribution to the SST from the North Atlantic Oscillation (NAO) over the EMDR was a weak warming, while that from El Nino Southern Oscillation (ENSO) was negligible. Nevertheless, ENSO, the NAO, and the AMM all contributed to favorable wind shear conditions, while the AMM also produced enhanced atmospheric instability. Compared with the strong hurricane years of 2005/2010, the ocean heat content (OHC) during 2017 was larger across the tropics, with higher SST anomalies over the EMDR and Caribbean Sea. On the other hand, the dynamical/thermodynamical atmospheric conditions, while favorable for enhanced TC activity, were less prominent than in 2005/2010 across the tropics. The results suggest that unusually warm SST in the EMDR together with the long fetch of the resulting storms in the presence of record-breaking OHC may be key factors in driving the strong TC activity in 2017.

Lim, Young-Kwon↗
NASA NTRS2019

The Subseasonal Experiment (SubX): A Multi-Model Subseasonal Prediction Experiment

SubX is a multi-model subseasonal prediction experiment designed around operational requirements with the goal of improving subseasonal forecasts. Seven global models have produced seventeen years of retrospective (re-) forecasts and more than a year of weekly real-time forecasts. The re-forecasts and forecasts are archived at the Data Library of the International Research Institute for Climate and Society, Columbia University, providing a comprehensive database for research on subseasonal to seasonal predictability and predictions. The SubX models show skill for temperature and precipitation three weeks ahead of time in specific regions. The SubX multi-model ensemble mean is more skillful than any individual model overall. Skill in simulating the Madden-Julian Oscillation (MJO) and the North Atlantic Oscillation (NAO), two sources of subseasonal predictability, is also evaluated with skillful predictions of the MJO four weeks in advance and of the NAO 2 weeks in advance. SubX is also able to make useful contributions to operational forecast guidance at the Climate Prediction Center. Additionally, SubX provides information on the potential for extreme precipitation associated with tropical cyclones which can help emergency management and aid organizations to plan for disasters. (Capsule Summary) A research to operations project in service of developing better operational subseasonal forecasts.

Precipitation↗
NASA NTRS2020

The role of blocking circulation and emerging open water feedbacks on Greenland cold‐season air temperature variability over the last century

Substantial marine, terrestrial, and atmospheric changes have occurred over the Greenland region during the last century. Several studies have documented record‐levels of Greenland Ice Sheet (GrIS) summer melt extent during the 2000s and 2010s, but relatively little work has been carried out to assess regional climatic changes in other seasons. Here, we focus on the less studied cold‐season (i.e., autumn and winter) climate, tracing the long‐term (1873–2013) variability of Greenland's air temperatures through analyses of coastal observations and model‐derived outlet glacier series and their linkages with North Atlantic sea ice, sea surface temperature (SST), and atmospheric circulation indices. Through a statistical framework, large amounts of west and south Greenland temperature variance (up to r^2~50%) can be explained by the seasonally‐contemporaneous combination of the Greenland Blocking Index (GBI) and the North Atlantic Oscillation (NAO; hereafter the combination of GBI and NAO is termed GBI). Lagged and concomitant regional sea‐ice concentration (SIC) and the Atlantic Multidecadal Oscillation (AMO) seasonal indices account for small amounts of residual air temperature variance (r^2<~10%) relative to the GBI. The correlations between GBI and cold‐season temperatures are predominantly positive and statistically‐significant through time, while regional SIC conditions emerge as a significant covariate from the mid‐20th century through the conclusion of the study period. The inclusion of the cold‐season Pacific Decadal Oscillation (PDO) in multivariate analyses bolsters the air temperature variance explained by the North Atlantic regional predictors, suggesting the remote, background climate state is important to long‐term Greenland temperature variability. These findings imply that large‐scale tropospheric circulation has a strong control on surface temperature over Greenland through dynamic and thermodynamic impacts and stress the importance of understanding the evolving two‐way linkages between the North Atlantic marine and atmospheric environment in order to more accurately predict Greenland seasonal climate variability and change through the 21st century.

air temperatures↗
NASA NTRS2023

Climate Variability and Simultaneous Breadbasket Yield Shocks as Observed in Long-Term Yield Records

That climate variability and change can potentially force multiple simultaneous breadbasket crop yield shocks has been established. But research quantifying the mechanisms behind such simultaneous shocks has been constrained by short records of crop yields. Here we compile a dataset of subnational crop yields in 25 countries dating back to 1900 to study the frequency and trends in multiple breadbasket yield shocks and how large-scale climate anomalies on interannual timescales have affected multiple breadbasket yield shocks over the last century. We find that major simultaneous breadbasket yield shocks have occurred in at least three, four, or five of nine breadbaskets 10.3%, 2.3% and 1.1% of the time for maize and 18.4%, 4.6% and 2.3% of the time for wheat. Furthermore, we find that multiple breadbasket yield shocks decreased in frequency even as those breadbaskets experience increasingly frequent climate-related shocks. For both maize and wheat breadbaskets, there were fewer simultaneous yield shocks during the 1975–2017 time period as compared to 1931–1975. Finally, we find that interannual modes of climate variability - such as the El Niño Southern Oscillation (ENSO), the Indian Ocean Dipole (IOD), and the North Atlantic Oscillation (NAO) - have all affected the relative probability of simultaneous yield shocks in pairs of breadbaskets by up to 20–40% in both maize and wheat breadbaskets. While past literature has focused on the effects of ENSO, we find that at the global scale the NAO affects the overall number of wheat yield shocks most strongly despite only affecting northern hemisphere breadbaskets.

agriculture↗
DOE OSTI2024

Compound Flooding in Halmstad: Common Causes, Interannual Variability and the Effects of Climate Change

Compound flooding was investigated in Halmstad on the Swedish west coast. The highest sea level ever recorded in Sweden was recorded by the Halmstad tide gauge. Moreover, through the city runs Nissan, one of the largest hydropower-producing rivers in southern Sweden. Together these features make the city an interesting location to study compound flooding. Co-variability between different hazards are studied using a unique set of downscaled climate scenario projections produced using state-of-the-art regional atmosphere, ocean and hydrological models. River discharge and sea level annual maxima are found to be correlated with peak strength on interannual time scales. This co-variability is found to derive from a mutual dependence that these hazards have on the North Atlantic Oscillation (NAO). Precipitation also shares this dependence in winter months and acts as a driver, building up the fluvial river hazard, while potentially adding additional pluvial hazard. Trends are also assessed, and it was found that future changes in compound flooding will most likely be driven primarily by mean sea level rise and secondarily by increases in mean river discharge.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2014

Interannual Variation in Phytoplankton Class-specific Primary Production at a Global Scale

Phytoplankton is responsible for over half of the net primary production on earth. The knowledge on the contribution of various phytoplankton groups to the total primary production is still poorly understood. Data from satellite observations suggest that for upwelling regions, photosynthetic rates by microplankton is higher than that of nanoplankton but that when the spatial extent is considered, the production by nanoplankton is comparable or even larger than microplankton. Here, we used the NASA Ocean Biogeochemical Model (NOBM) combined with remote sensing data via assimilation to evaluate the contribution of 4 phytoplankton groups to the total primary production. Globally, diatoms were the group that contributed the most to the total phytoplankton production (approx. 50%) followed by coccolithophores and chlorophytes. Primary production by diatoms was highest in high latitude (>45 deg) and in major upwelling systems (Equatorial Pacific and Benguela system). We assessed the effects of climate variability on the class-specific primary production using global (i.e. Multivariate El Nino Index, MEI) and 'regional' climate indices (e.g. Southern Annular Mode (SAM), Pacific Decadal Oscillation (PDO) and North Atlantic Oscillation (NAO)). Most interannual variability occurred in the Equatorial Pacific and was associated with climate variability. These results provide a modeling and data assimilation perspective to phytoplankton partitioning of primary production and contribute to our understanding of the dynamics of the carbon cycle in the oceans at a global scale.

OBM↗
NASA NTRS2014

Role of Tropical Atlantic SST Variability as a Modulator of El Nino Teleconnections

The present study suggests that the off-equatorial North Atlantic (NATL) SST warming plays a significant role in modulating El Niño teleconnection and its impact on the North Atlantic and European regions. The El Niño events accompanied by NATL SST warming exhibit south-north dipole pattern over the Western Europe to Atlantic, while the ENSO teleconnection pattern without NATL warming exhibits a Rossby wave-like pattern confined over the North Pacific and western Atlantic. Especially, the El Niño events with NATL warming show positive (negative) geopotential-height anomalies over the North Atlantic (Western Europe) which resemble the negative phase of the NAO. Consistently, it is shown using a simple statistical model that NATL SSTA in addition to the tropical Pacific SSTA leads to better prediction on regional climate variation over the North Atlantic and European regions. This role of NATL SST on ENSO teleconnection is also validated and discussed in a long term simulation of coupled global circulation model (CGCM).

Teleconnection↗
DOE OSTI2022

Inhibition of Alkali Metal Reduction of 1-Adamantanol by London Dispersion Effects

Here, a series of alkali metal 1-adamantoxide (OAd 1 ) complexes of formula [M(OAd 1 )(HOAd 1 ) 2 ], where M=Li, Na or K, were synthesised by reduction of 1-adamantanol with excess of the alkali metal. The syntheses indicated that only one out of every three HOAd 1 molecules was reduced. An X-ray diffraction study of the sodium derivative shows that the complex features two unreduced HOAd 1 donors as well as the reduced alkoxide (OAd 1 ), with the Ad 1 fragments clustered together on the same side of the NaO 3 plane, contrary to steric considerations. This is the first example of an alkali metal reduction of an alcohol that is inhibited from completion due to the formation of the [M(OAd 1 )(HOAd 1 ) 2 ] complexes, stabilized by London dispersion effects. NMR spectroscopic studies revealed similar structures for the lithium and potassium derivatives. Computational analyses indicate that decisive London dispersion effects in the molecular structure are a consequence of the many C–H•••H–C interactions between the OAd 1 groups.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗