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DOE OSTI2022

Metal (Fe, Cu, and As) transformation and association within secondary minerals in neutralized acid mine drainage characterized using X-ray absorption spectroscopy

The formation and transformation of secondary minerals in areas affected by neutralized acid mine drainage (AMD) determine the behavior of toxic elements. To better understand the binding form of toxic elements in the secondary minerals, we focused on the distribution of secondary precipitates and heavy metals in neutralized AMD near a typical Cu-polymetallic deposit located in central Tibet. Compared to background values, the average heavy metal (As, Cu, Co, Cu, Mo, Pb, and Zn) content is higher in sediments close to the neutralized AMD drain. X-ray absorption spectroscopy (XAS) characterization shows the Fe in the suspended particulate matter (SPM) first aggregate as small Fe(III) octahedra clusters and then precipitate as ferrihydrite along the river. The XAS results also show the by-products of neutralization-ferrihydrite and sulfate-are the primary forms of Fe and S in the sediments, respectively. Gypsum retains Cu in the sediments via structural fixation, surface adsorption, and surface coprecipitation. The difference of Cu-O coordination number between the SPM and the sediments reveals the Cu sulfate coprecipitation on the surface of gypsum accompanied by SPM transporting along the river. XAS results confirm that ferrihydrite act as an essential sink for heavy metals, especially As. As (III) mineral in the sediment near the neutralized AMD outfall is dissolved and oxidized to arsenate downstream, which then adsorb to ferrihydrite and/or form As(V)-Fe minerals along the river. Gypsum and ferrihydrite have the potential to release heavy metals with changes in water chemistry, which may pose a threat to the safety of drinking water for downstream residents. These results deepen the understanding of the influence of secondary minerals (especially gypsum and ferrihydrite) on the migration and transformation process of heavy metal pollutants in mine drainage system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2012

In Situ Geochemical Analysis and Age Dating of Rocks Using Laser Ablation-Miniature Mass Spectrometer

A miniaturized instrument for performing chemical and isotopic analysis of rocks has been developed. The rock sample is ablated by a laser and the neutral species produced are analyzed using the JPL-invented miniature mass spectrometer. The direct sampling of neutral ablated material and the simultaneous measurement of all the elemental and isotopic species are the novelties of this method. In this laser ablation-miniature mass spectrometer (LA-MMS) method, the ablated neutral atoms are led into the electron impact ionization source of the MMS, where they are ionized by a 70-eV electron beam. This results in a secondary ion pulse typically 10-100 microsecond wide, compared to the original 5-10-nanosecond laser pulse duration. Ions of different masses are then spatially dispersed along the focal plane of the magnetic sector of the miniature mass spectrometer and measured in parallel by a modified CCD (charge-coupled device) array detector capable of detecting ions directly. Compared to conventional scanning techniques, simultaneous measurement of the ion pulse along the focal plane effectively offers a 100% duty cycle over a wide mass range. LAMMS offers a more quantitative assessment of elemental composition than techniques that detect laser-ionized species produced directly in the ablation process because the latter can be strongly influenced by matrix effects that vary with the structure and geometry of the surface, the laser beam, and the ionization energies of the elements. The measurement of high-precision isotopic ratios and elemental composition of different rock minerals by LAMMS method has been demonstrated. The LA-MMS can be applied for the absolute age determination of rocks. There is no such instrument available presently in a miniaturized version that can be used for NASA space missions. Work is in progress in the laboratory for geochronology of rocks using LA-MMS that is based on K-Ar radiogenic dating technique.

Sinha, Mahadeva P.↗

NASA NTRS1994

The fluorescence-dominated X-ray spectrum of the spiral galaxy NGC 6552

A hard X-ray source with a 2-10 keV flux of approximately 6 x 10(exp -13) ergs/sec/sq cm was detected with ASCA in the north ecliptic pole region. It is identified with the spiral galaxy NGC 6552 at a redshift of z = 0.026, which is optically classified as a Seyfert 2 galaxy. The X-ray spectrum consists of a series of atomic K-emission lines from (nearly-) neutral species of at least seven abundant elements, and a heavily absorbed (N(sub H) approx. = 6 x 10(exp 23)/sq cm) hard continuum. The iron line has an equivalent width as large as approximately 0.9 keV. Our results show that NGC 6552 is an extreme type 2 Seyfert galaxy, in which the fluorescent lines are produced when hard X-rays from a hidden active nucleus are reflected off thick cool matter into our line of sight. The intrinsic 2-10 keV luminosity of the nucleus is estimated to be at least 6 x 10(exp 42) ergs/s.

Fukazawa, Yasushi↗

NASA NTRS1984

Interstellar abundances and depletions inferred from observations of neutral atoms

Data on neutral atomic species are analyzed for the purpose of inferring relative elemental abundances and depletions in diffuse cloud cores, where it is assumed that densities are enhanced in comparison with mean densities over integrated lines of sight. Column densities of neutral atoms are compared to yield relative column densities of singly ionized species, which are assumed dominant in cloud cores. This paper incorporates a survey of literature data on neutral atomic abundances with the result that no systematic enhancement in the depletions of calcium or iron in cloud cores is found, except for zeta Ophiuchi. This may imply that depletions are not influenced by density, but other data argue against this interpretation. It is concluded either that in general all elements are depleted together in dense regions so that their relative abundances remain constant, or that typical diffuse clouds do not have significant cores, but instead are reasonably homogeneous. The data show a probable correlation between cloud-core depletion and hydrogen-molecular fraction, supporting the assumption that overall depletions are a function of density.

Snow, T. P.↗

NASA NTRS2001

ALEXIS Observations of the Monogem Ring Supernova Remnant

The subject grant is for the analysis of ALEXIS observations of the Monogem Ring supernova remnant using the diffuse all-sky maps produced from the ALEXIS all-sky survey. The work is to produce ratio maps of the three energy bands provided by ALEXIS, analyze the ratio data to constrain the intervening neutral hydrogen column density and the temperature and elemental abundances of the X-ray emitting gas, compare the structure to that observed in the ROSAT maps, and incorporate the results into current supenova remnant evolution models. The work outlined above has been significantly delayed since the ALEXIS diffuse all-sky maps took longer to produce than anticipated. Unfortunately, the ALEXIS satellite suffered a failure of the Pegasus launch vehicle which left the satellite in a partially functioning condition. The attitude control system of the spacecraft was unable to operate as planned and this has greatly increased the complexity of the aspect solution. Our colleagues at Los Alamos have made progress in producing these maps and are nearing completion of the final maps. However, the quality of the data have been significantly compromised by the overall lower exposure due to the spacecraft problems and the higher background of the micro-channel plate detectors. We have compared the ALEXIS and ROSAT maps of this region of the sky and there is no obvious signal in the ALEXIS maps of the Monogem Ring. We are now exploring correlation techniques to determine if there is indeed a faint signal in the ALEXIS maps. Although, the project has been a disappointment so far, the data may still provide a valuable lower limit on the neutral hydrogen column density. This is a far cry from our original intentions, but would still be valuable science. Given the large delays in producing the ALEXIS sky maps, this work will continue past the end of the grant period.

Plucinsky, Paul↗

DOE OSTI2023

Measurement of spin-density matrix elements in ρ ( 770 ) production with a linearly polarized photon beam at E γ = 8.2 – 8.8 GeV

The GlueX experiment at Jefferson Lab studies photoproduction of mesons using linearly polarized 8.5GeV photons impinging on a hydrogen target which is contained within a detector with near-complete coverage for charged and neutral particles. We present measurements of spin-density matrix elements for the photoproduction of the vector meson rho(770). The statistical precision achieved exceeds that of previous experiments for polarized photoproduction in this energy range by orders of magnitude. Here we confirm a high degree of s-channel helicity conservation at small squared four-momentum transfer t and are able to extract the t-dependence of natural and unnatural-parity exchange contributions to the production process in detail. We confirm the dominance of natural-parity exchange over the full t range. We also find that helicity amplitudes in which the helicity of the incident photon and the photoproduced rho(770) differ by two units are negligible for -t<0.5GeV 2 /c 2 .

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2025

Dithionite Inhibits Iron(III) (Hydr)oxide Formation during Olivine Dissolution Advancing Simultaneous CO 2 Mineralization and Nickel Recovery

Increasing CO 2 concentration poses significant global challenges, impacting both environmental and human health. As we strive for a carbon-neutral energy technology transition, the demand for critical elements (e.g., nickel and cobalt) continues to increase, while high-grade ores are depleting. Combining CO 2 mineralization with the recovery of critical elements from low-grade ores offers an innovative solution. Olivine, a magnesium-rich ultramafic with trace amounts of critical elements, is a promising mineral; however, its impurities, such as iron (Fe(III)), hinder the dissolution of Ni and Mg from olivine, reducing its carbonation and critical element recovery. Here, to address this challenge, this study examined Ni dissolution from San Carlos olivine at high temperatures and high CO 2 pressure. We found that iron(III) (hydr)oxide layers impeded olivine dissolution; however, with sodium dithionite (Na 2 S 2 O 4 ), a reducing agent, olivine dissolution is significantly improved by preventing iron(III) (hydr)oxide formation. With Na 2 S 2 O 4 , within 24 h, Mg and Ni dissolution from olivine increased 2.85-fold and 2.66-fold, respectively, compared to samples without Na 2 S 2 O 4 . After seven cycles, with solutions replaced every 24 h, 98.9% of the total Mg and 84.6% of the total Ni were recovered. This approach enhances olivine’s CO 2 mineralization and improves the sustainability of critical element supply.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1968

Neutral reactions involving hydrogen and other minor constituents

Neutral reactions involving hydrogen and other minor chemical elements are reviewed

Kaufman, F.↗

NASA NTRS2008

Boundary Layer Receptivity due to Roughness and Freestream Sound for Supersonic Flows over Axisymmetric Cones

The receptivity of supersonic boundary layers due to the interaction of a two-dimensional acoustic wave with a three-dimensional roughness is numerically investigated over a 5-degree sharp tipped straight cone at a free stream Mach number of 3.5 and a high Reynolds number of 10(exp 6)/inch. Both the steady and unsteady solutions are obtained by solving the full Navier-Stokes equations using the fifth-order accurate weighted essentially non-oscillatory (WENO) scheme for spatial discretization and using third-order total-variation-diminishing (TVD) Runge-Kutta scheme for temporal integration. The simulations are performed with different roughness heights and roughness locations. The steady computations with the roughness reveal that the perturbations induced by the roughness remain very close to the wall and do not penetrate to the outer part of the boundary layer. The effects of the roughness persist for about 10 boundary layer thicknesses downstream of each element. The unsteady simulation shows the generation of unstable three-dimensional first mode disturbances within a short distance from the roughness. However, the amplitudes of the instability waves are very small near the neutral point, on the order of 10(exp -4) compared to the free stream disturbances. The receptivity coefficients due to the roughness elements located very close to the tip are one order of magnitude smaller than those due to the roughness elements located closer to the neutral point.

Balakumar, P.↗

NASA NTRS1979

Finite-element numerical modeling of atmospheric turbulent boundary layer

A dynamic turbulent boundary-layer model in the neutral atmosphere is constructed, using a dynamic turbulent equation of the eddy viscosity coefficient for momentum derived from the relationship among the turbulent dissipation rate, the turbulent kinetic energy and the eddy viscosity coefficient, with aid of the turbulent second-order closure scheme. A finite-element technique was used for the numerical integration. In preliminary results, the behavior of the neutral planetary boundary layer agrees well with the available data and with the existing elaborate turbulent models, using a finite-difference scheme. The proposed dynamic formulation of the eddy viscosity coefficient for momentum is particularly attractive and can provide a viable alternative approach to study atmospheric turbulence, diffusion and air pollution.

Lee, H. N.↗

NASA NTRS1972

Neutral buoyancy testing of architectural and environmental concepts of space vehicle design

Design guidelines are presented that are applicable to providing habitability areas and furniture elements for extended periods in a zero gravity environment. This was accomplished by: (1) analyzing the existing habitability crew area requirements, mobility and restraint aids, cross-cultural design, and establishing a man model for zero gravity; (2) designing specific furniture elements, chair and table, and volumes for a stateroom, office, bathroom, galley, and wardroom; and (3) neutral buoyancy testing and evaluation of these areas.

Lenda, J. A.↗

DOE OSTI2025

Spectrophotometric determination of the stability of La hydroxyl complexes at near neutral to alkaline pH from 25 to 75 °C

The hydrolysis of rare earth elements (REE) potentially controls their mobility during fluid-rock interaction in a broad range of pH and temperature conditions. However, there is still a lack of thermodynamic data for modeling accurately the stability of REE hydroxyl complexes in hydrothermal aqueous fluids. Here, in this study, UV–Vis spectrophotometric experiments were conducted from 25 to 75 °C in near-neutral to alkaline NaOH-bearing aqueous solutions with varying lanthanum (La) concentrations (0 to ∼0.23 mmol/kg). The color indicator m-cresol purple was used to determine in situ pH and derive the average OH− ligand number ($\overrightarrow{n}$) and formation constants for the La hydroxyl complexes (LaOH 2+ , La(OH) 2 + , and La(OH) 3 0 ). From 25 to 50 °C, $\overrightarrow{n}$ ranges between ∼1 and 2 at pH from 7.0 to 9.3. At 75 °C, $\overrightarrow{n}$ ranges between ∼1.5 and 3 at pH from 6.3 to 8.8. These results suggest the predominance of LaOH 2+ and La(OH) 2 + complexes from 25 to 50 °C, and an increased predominance of La(OH) 3 0 at 75 °C. The cumulative formation constants (β n °, n = 1 to 3) are derived for the reaction La 3+ + nOH − = La(OH) n 3-n , and fitted between 25 and 250 °C by combining the UV–Vis and literature solubility data. The resulting logβ n ° are expressed as function of temperature (T in Kelvin): logβ 1 ° = −1.786 + 0.0133 T + 1.049·10 3 /T; logβ 2 ° = −5.797 + 0.0267 T + 2.713·10 3 /T; logβ 3 ° = 6.435 + 0.0223 T + 512.7/T. A comparison between these new fits and existing extrapolations using the Helgeson-Kirkham-Flowers equation of state indicates significant differences in the predicted hydrolysis of La. The latter extrapolations should therefore be updated for the hydrolysis of REE.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1985

A computer analysis program for interfacing thermal and structural codes

A software package has been developed to transfer three-dimensional transient thermal information accurately, efficiently, and automatically from a heat transfer analysis code to a structural analysis code. The code is called three-dimensional TRansfer ANalysis Code to Interface Thermal and Structural codes, or 3D TRANCITS. TRANCITS has the capability to couple finite difference and finite element heat transfer analysis codes to linear and nonlinear finite element structural analysis codes. TRANCITS currently supports the output of SINDA and MARC heat transfer codes directly. It will also format the thermal data output directly so that it is compatible with the input requirements of the NASTRAN and MARC structural analysis codes. Other thermal and structural codes can be interfaced using the transfer module with the neutral heat transfer input file and the neutral temperature output file. The transfer module can handle different elemental mesh densities for the heat transfer analysis and the structural analysis.

Thompson, R. L.↗

NASA NTRS1985

A computer analysis program for interfacing thermal and structural codes

Thompson, R. L.↗

NASA NTRS1989

Charge transfer and X-ray emission from supernova remnants

The X-ray line emission excited by charge transfer between neutral hydrogen and the hydrogenic or fully stripped ions of heavy elements has been computed for a grid of nonequilibrium ionization models for supernova remnants. The effects of charge transfer excitation on the X-ray spectra of supernova remnants are discussed. The charge transfer process depends very sensitively upon the abundance of neutral hydrogen behind the shock. Consequently, a careful treatment of the ionization of hydrogen was required. The model line fluxes are compared with those excited by conventional collisional processes involving electrons. Results are presented in the form of contour plots for both the flux excited by charge transfer and the ratio of the charge transfer flux to that associated solely with collisional processes involving electrons. Charge transfer never contributes more than 10 percent of the flux of the strongest electron collisionally excited lines, and its contribution is typically 0.001 to 10 to the -5th for a shock moving into a medium composed of neutral hydrogen.

Wise, Michael W.↗

NASA NTRS2017

Quasi-Static Electric Field Generator

A generator for producing an electric field for with an inspection technology system is provided. The generator provides the required variable magnitude quasi-static electric fields for the "illumination" of objects, areas and volumes to be inspected by the system, and produces human-safe electric fields that are only visible to the system. The generator includes a casing, a driven, non-conducting and triboelectrically neutral rotation shaft mounted therein, an ungrounded electrostatic dipole element which works in the quasi-static range, and a non-conducting support for mounting the dipole element to the shaft. The dipole element has a wireless motor system and a charging system which are wholly contained within the dipole element and the support that uses an electrostatic approach to charge the dipole element.

Generazio, Edward R.↗

NASA NTRS2002

New Atomic Data for Doubly Ionized Iron Group Atoms by High Resolution UV Fourier Transform Spectroscopy

Currently available laboratory spectroscopic data of doubly ionized iron-group element were obtained about 50 years ago using spectrographs of modest dispersion, photographic plates, and eye estimates of intensities. The accuracy of the older wavelength data is about 10 mAngstroms at best, whereas wavelengths are now needed to an accuracy of 1 part in 10(exp 6) to 10(exp 7) (0.2 to 2 mAngstroms at 2000 Angstroms). The Fourier transform (FT) spectroscopy group at Imperial College, London, and collaborators at the Harvard College Observatory have used a unique VUV FT spectrometer in a program focussed on improving knowledge of spectra of many neutral and singly and doubly ionized, astrophysically important, iron group elements. Spectra of Fe II and Fe III have been recorded at UV and VUV wavelengths with signal-to-noise ratios of several hundred for the stronger lines. Wavelengths and energy levels for Fe III are an order of magnitude more accurate than previous work; analysis is close to completion. f-values for Fe II have been published.

Smith, Peter L.↗

NASA NTRS1993

PATSTAGS: PATRAN-To-STAGSC-1 Translator

PATSTAGS computer program translates data from PATRAN finite-element mathematical model into STAGS input records used for engineering analysis. Reads data from PATRAN neutral file and writes STAGS input records into STAGS input file and UPRESS data file. Supports translations of nodal constraints, and of nodal, element, force, and pressure data. Written in FORTRAN 77.

Otte, Neil↗