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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

Fluorine negative ion detachment kinetics

A study of the rate of F(-) detachment by O and H atoms via the reactions F(-) + O yields FO + e and F(-) + H yields FH+ e was undertaken using a drift tube to produce F(-) ions at various drift velocities and therefore different ion temperatures. Preliminary mobility measurements of F(-) ions in Ar were made, indicating that ion temperatures in the 300 K to 5000 K range could be achieved; however due to numerous difficulties experienced in obtaining a reliable F(-) ion source, the study could not be completed.

Burke, R. R.↗
NASA NTRS1976

Electron detachment from negative ions - The effects of isotopic substitution

Absolute total electron-detachment cross sections and relative elastic-scattering cross sections are presented for collisions of H(-) or D(-) with He, Ne, Ar, and N2 for collision energies ranging from about 2 eV up to 100 eV. Special emphasis has been given to the effect of isotopic substitution. It was found that, with the exception of the helium target, the results cannot be in accord with a model using a localized complex potential. On the other hand, the results for H(-) or D(-) with He are in excellent agreement with predictions based on previous (local complex potential) analysis of differential elastic-scattering measurements.

Champion, R. L.↗
NASA NTRS1978

Apparatus for extraction and separation of a preferentially photo-dissociated molecular isotope into positive and negative ions by means of an electric field

Molecules of one and the same isotope were preferentially photodissociated by a laser and an ultraviolet source, or by multiphoton absorption of laser radiation. The resultant ions were confined with a magnetic field, moved in opposite directions by an electric field, extracted from the photodissociation region by means of screening and accelerating grids, and collected in ducts.

Wilhelm, H. E.↗
NASA NTRS1983

Production of negative ions by dissociative electron attachment to SO2

Dissociative electron attachment cross section measurements for the production of O(-), S(-), and SO(-) have been performed utilizing a crossed target SO2 molecule beam-electron beam geometry. The relative flow technique is employed to determine the absolute values of cross sections. The attachment energies corresponding to various cross section maxima are: 4.30 and 7.1 eV for O(-)/SO2; 4.0, 7.5, and 8.9 eV for S(-)/SO2, and 4.7 and 7.5 eV for SO(-)/SO2.

Orient, O. J.↗
NASA NTRS1987

Plasma instability in the presence of negative ions

Ion density fluctuations are studied in a diffusion-controlled argon plasma containing, as a dilutant, two electron-attaching species, carbon dioxide and sulfur hexafluoride. It is found that the system becomes increasingly unstable as the concentration of the electron-attaching species is increased. Nonlinear mode-mode couplings have been identified and the coupling coefficients for these interactions have been computed. Turbulent fluctuations are observed to have pronounced three-dimensionality with distinct axial and azimuthal behaviors. The power spectra of these fluctuations are composed of many discrete modes. The importance of changes in the total discharge pressure is dependent on the electron-attachment cross section of the dilutant species. From these results it is shown that the ionization instability is probably responsible for the observed phenomenon.

Johnson, J. A., III↗
NASA NTRS1987

Propagation of charge-neutral beams in space - Modifications when negative ions are present

Two-dimensional (three velocity component) electrostatic simulations are used to investigate the properties of a charge-neutral beam consisting of H(+), H(-), and electrons which will be used in the Beams on Rockets (BEAR) experiment to be launched in late 1987 or early 1988. For cross-field injection and beam densities much greater than the ambient plasma density, the beam splits into two approximately charge-neutral beams: a H(+)-e(-) beam that propagates down the field lines and a H(+)-H(-) beam that propagates at nearly the initial beam velocity on time scales less than the ion gyroperiod. Because of this splitting, space-charge oscillations are induced in the H(+)-H(-) component, which lead to its breakup. At lower beam densities, particularly when the beam electron density is less than about the density of the ambient plasma, the ambient plasma response reduces the space-charge fields as the beam splits and the space-charge oscillations are suppressed.

Winglee, R. M.↗
NASA NTRS2002

Electronic Absorption Spectra of Neutral Perylene (C20H12), Terrylene (C30H16), and Quaterrylene (C40H20) and their Positive and Negative Ions: Ne Matrix-Isolation Spectroscopy and Time Dependent Density Functional Theory Calculations

We present a full experimental and theoretical study of an interesting series of polycyclic aromatic hydrocarbons, the oligorylenes. The absorption spectra of perylene, terrylene and quaterrylene in neutral, cationic and anionic charge states are obtained by matrix-isolation spectroscopy in Ne. The experimental spectra are dominated by a bright state that red shifts with growing molecular size. Excitation energies and state symmetry assignments are supported by calculations using time dependent density functional theory methods. These calculations also provide new insight into the observed trends in oscillator strength and excitation energy for the bright states: the oscillator strength per unit mass of carbon increases along the series.

Halasinski, Thomas M.↗
NASA NTRS2007

Polarizabilities of the Ps Negative Ion

We have calculated polarizabilities (alpha(sub l), beta(sub 1), gamma(sub l), alpha(sub 2), beta(sub 2), and gamma(sub 2)) of Ps(sup -) by the pseudostate method. These parameters can be used to calculate Rydberg states of Ps(sup -) in the presence of an external electron with high quantum numbers N and L. They are also of importance in a system containing Ps(sup -) bound to a proton [PsH], and also Rydberg states of Ps(sub 2).

Bhatia, A. K.↗
NASA NTRS1989

Nonlinear triggered lightning models for use in finite difference calculations

Two nonlinear triggered lightning models have been developed for use in finite difference calculations. Both are based on three species of air chemistry physics and couple nonlinearly calculated air conductivity to Maxwell's equations. The first model is suitable for use in three-dimensional modeling and has been applied to the analysis of triggered lightning on the NASA F106B Thunderstorm Research Aircraft. The model calculates number densities of positive ions, negative ions, and electrons as a function of time and space through continuity equations, including convective derivative terms. The set of equations is closed by using experimentally determined mobilities, and the mobilities are also used to determine the air conductivity. Results from the model's application to the F106B are shown. The second model is two-dimensional and incorporates an enhanced air chemistry formulation. Momentum conservation equations replace the mobility assumption of the first model. Energy conservation equations for neutrals, heavy ions, and electrons are also used. Energy transfer into molecular vibrational modes is accounted for. The purpose for the enhanced model is to include the effects of temperature into the air breakdown, a necessary step if the model is to simulate more than the very earliest stages of breakdown. Therefore, the model also incorporates a temperature-dependent electron avalanche rate. Results from the model's application to breakdown around a conducting ellipsoid placed in an electric field are shown.

Rudolph, Terence↗