Search NASA⌕ Search

SEARCH · Search NASA

Results for “Nitrogen Dioxide”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 73 records · Page 4

Effective Kitchen Ventilation for Healthy Zero Net Energy Homes with Natural Gas

Past studies indicate that kitchen ventilation that minimally complies with California’s Residential Building Code is inadequate at controlling combustion pollutants from natural gas burners and particulate matter produced during cooking. Effectiveness is further limited by misperceptions that kitchen ventilation is infrequently needed. This project developed the technical basis for updating kitchen ventilation requirements to protect health in new California homes, especially in smaller homes common among low-income renters. Tasks included (1) a field study of ventilation equipment performance and indoor air quality in 23 low-income apartments at four sites; (2) analysis of range hood use related to cooking time and household parameters using data from 54 houses and 17 low-income apartments; (3)a measurement-based study to quantify performance of over-the-range microwave ovens with integrated exhaust fans;and (4) pollutant exposure simulations to inform capture efficiency standards.The field study found operational deficiencies with mechanical ventilation systems in a substantial fraction of low-income apartments that affected performance, resulting in higher exposures to pollutants generated indoors. Using gas cooking burners produced high short-term and weekly time-averaged nitrogen dioxide in apartments.Range hoods were used more frequently with cooking in houses (36percent) than apartments (28percent); use increased with overall cooking frequency in a home and with duration of cooktop but not oven events; actual use was correlated to, but lower than,self-reported use;and use was more frequent in houses when cooking generated any fine particulate matter (PM2.5)or when high PM2.5resulted from cooking in apartments. Performance of over-the-range microwaves with integrated exhaust fans was similar to that of range hoods of comparable price. Simulation analysis found that performance standards need to be updated to ensure that kitchen exhaust ventilation adequately protects for substantial cooking in new California residences.

03 NATURAL GAS↗

Design and Optimization of Structured Multi-Functional Trapping Catalysts for Conversion of Hydrocarbons and NOx from Diesel and Advanced Combustion Engines

Oxides of nitrogen in the form of nitric oxide (NO) and nitrogen dioxide (NO 2 ) commonly referred to as NOx, is one of the two chemical precursors that lead to ground-level ozone, a ubiquitous air pollutant in urban areas. A major source of NOx is generated by equipment and vehicles powered by diesel engines, which have a combustion exhaust that contains NOx in the presence of excess O 2 . Vehicular emission control catalysts are ineffective in eliminating CO, hydrocarbons, and NOx during engine cold-start when exhaust temperatures are below 200°C. The objective of the project was to develop and demonstrate a multi-functional, catalyzed trap that enables vehicles with advanced combustion strategies to meet Tier 3 emissions standards while achieving the 150 °C challenge for sustained co-oxidation of HCs and CO and ≥90% NO trapping and release during warmup. Specifically, the multi-functional Lean HC+NOx (LHCNT) was developed for application in the exhaust aftertreatment of conventional diesel engines and engines having low temperature combustion (LTC) regimes. Activities included the design and synthesis of adsorbents and catalysts, screening and evaluation. Passive NOx absorbers (PNA), hydrocarbon (HC) traps, and oxidation catalysts (OC) were evaluated for use in series or as integrated devices. Predictive tools were developed utilizing the characterization and analysis of these materials, and an emission system was designed and optimized utilizing the catalyst systems. Microkinetic models were developed for the PNA for the simple NO-only feed and complex feed containing CO, H 2 , and model hydrocarbons (ethylene and dodecane). A first-principles, mechanistic-based model of the PNA was developed which utilized molecular-scale estimates (density functional theory) of energy barriers, mechanistic-based kinetics and realistic treatments of the flow and transport processes. Two new oxidation catalysts were developed (PdCu alloy, mixed copper-ceria-cobalt oxide), both of which significantly lessened the detrimental inhibition by CO on hydrocarbon and NO oxidation. A method for lessening the detrimental impact of CO on PNA activity was developed that involves use of an oxidation catalyst upstream of the PNA. The SwRI Ectolab TM burner system was applied to evaluate the baseline PNA material and confirmed performance comparable to the benchflow PNA studies using simulated exhaust. Spatially-resolved mass spectrometry (SpaciMS) was used to measure the transient spatial profiles of reacting species spanning the length of a three-function LHCNT containing PNA, HCT, and OC. The findings from this study provide diesel vehicle and catalyst companies valuable information to develop more cost effective emission control catalysts which helps to expand the use of more fuel efficient diesel power. The fundamental modeling and experimental tools and findings from this project can be applied to catalyst technologies used in the energy and chemical industries. The project led to 14 publications in the peer-reviewed literature with 2 additional currently under review. Finally, the project also led to training of several doctoral students who were placed in research jobs in industry and academia. Specifically, Mugdha Ambast (UH) has joined Cummins, Kevin Gu (UVa) has joined GM, and Abhay Gupta (UH) is to join Caterpillar.

02 PETROLEUM↗

Simulation-Based Analysis of Impacts of Reduced Envelope and Duct Air Leakage on Indoor Air Pollutant Concentrations in Occupied Manufactured Homes

This report presents a simulation-based analysis that estimates the magnitude of indoor air pollutant concentration changes that could result from the proposed energy conservation standards. The analysis was conducted for a 1568 ft 2 , double-wide MH with variations in heating and cooling equipment (either furnace + air conditioner or heat pump) and various types of whole-house mechanical ventilation (continuous exhaust fan or central fan integrated supply), in three locations with varying climate conditions: Chicago IL, Fresno, CA; and Houston TX. The simulations tracked four air pollutants that can reach levels exceeding established safe target levels in homes: acrolein, formaldehyde, fine particulate matter (PM 2.5 ), and nitrogen dioxide (NO 2 ). The simulations considered acrolein and formaldehyde emitted from continuous indoor sources; acrolein, NO 2 and PM 2.5 from cooking; PM 2.5 from dispersed occupant activities; and NO 2 and PM 2.5 from outdoors, using historical data to identify typical levels. The impacts in homes operating or not operating whole-house mechanical ventilation equipment, kitchen and bath exhaust fans, and window opening as ventilation approaches were examined.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

‘Best’ Coal-Fired Power Plant and Cogeneration Case Studies

This National Energy Technology Laboratory (NETL) work was prepared for the Asia-Pacific Economic Cooperation (APEC) Energy Working Group. As many economies are planning for a lower carbon future, the use of inefficient coal-fired power generation remains significant in many parts of the world. In 2018, 45% of power generation in APEC economies came from coal. The transition to a lower carbon future can be aided by employing the most advanced available technologies in existing and future coal-fired power plants. Higher efficiency translates to lower emissions per unit of power produced and also means less carbon to capture once CO 2 capture technologies are fully commercial and widely deployed. In addition to reducing carbon emissions, the most advanced coal plants also have extremely low emissions of other pollutants like sulfur dioxide, nitrogen oxides, mercury and particulate matter. Some of these advanced plants also address regional water constraints by minimizing the use of fresh water.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Design and Optimization of Structured Multi-Functional Trapping Catalysts for Conversion of Hydrocarbons and NOx from Diesel and Advanced Combustion Engines

Oxides of nitrogen in the form of nitric oxide (NO) and nitrogen dioxide (NO 2 ) commonly referred to as NOx, is one of the two chemical precursors that lead to ground-level ozone, a ubiquitous air pollutant in urban areas. A major source of NOx is generated by equipment and vehicles powered by diesel engines, which have a combustion exhaust that contains NOx in the presence of excess O 2 . Vehicular emission control catalysts are ineffective in eliminating CO, hydrocarbons, and NO x during engine cold-start when exhaust temperatures are below 200°C. The objective of the project was to develop and demonstrate a multi-functional, catalyzed trap that enables vehicles with advanced combustion strategies to meet Tier 3 emissions standards while achieving the 150 °C challenge for sustained co-oxidation of HCs and CO and ≥90% NO trapping and release during warmup. Specifically, the multi-functional Lean HC+NOx (LHCNT) was developed for application in the exhaust aftertreatment of conventional diesel engines and engines having low temperature combustion (LTC) regimes. Activities included the design and synthesis of adsorbents and catalysts, screening and evaluation. Passive NOx absorbers (PNA), hydrocarbon (HC) traps, and oxidation catalysts (OC) were evaluated for use in series or as integrated devices. Predictive tools were developed utilizing the characterization and analysis of these materials, and an emission system was designed and optimized utilizing the catalyst systems. Microkinetic models were developed for the PNA for the simple NO-only feed and complex feed containing CO, H 2 , and model hydrocarbons (ethylene and dodecane). A first-principles, mechanistic-based model of the PNA was developed which utilized molecular-scale estimates (density functional theory) of energy barriers, mechanistic-based kinetics and realistic treatments of the flow and transport processes. Two new oxidation catalysts were developed (PdCu alloy, mixed copper-ceria-cobalt oxide), both of which significantly lessened the detrimental inhibition by CO on hydrocarbon and NO oxidation. A method for lessening the detrimental impact of CO on PNA activity was developed that involves use of an oxidation catalyst upstream of the PNA. The SwRI Ectolab TM burner system was applied to evaluate the baseline PNA material and confirmed performance comparable to the benchflow PNA studies using simulated exhaust. Spatially-resolved mass spectrometry (SpaciMS) was used to measure the transient spatial profiles of reacting species spanning the length of a three-function LHCNT containing PNA, HCT, and OC. The findings from this study provide diesel vehicle and catalyst companies valuable information to develop more cost effective emission control catalysts which helps to expand the use of more fuel efficient diesel power. The fundamental modeling and experimental tools and findings from this project can be applied to catalyst technologies used in the energy and chemical industries. The project led to 14 publications in the peer-reviewed literature with 2 additional currently under review. Finally, the project also led to training of several doctoral students who were placed in research jobs in industry and academia. Specifically, Mugdha Ambast (UH) has joined Cummins, Kevin Gu (UVa) has joined GM, and Abhay Gupta (UH) is to join Caterpillar.

42 ENGINEERING↗

Iodine Capture Studies of Silver Mordenite and Novel Alternative Metal Sorbents

Radioiodine is one of the radionuclides of concern when considering reprocessing of used nuclear fuel (UNF). It is expected to be released primarily in the dissolver off-gas (DOG) stream. Sorbents that target I 2 removal from a UNF processing off gas must perform efficiently under elevated temperatures in the presence of water vapor and nitrogen oxide gasses (NOx). Many studies have been conducted that examine the adsorption of iodine species in the presence of NOx gases through reduced silver-exchanged mordenite (Ag 0 Z), a zeolite mineral. This study characterizes the effects of iodine, water vapor, and nitrogen dioxide on the adsorption of I 2 by Ag 0 Z at lower temperatures suitable for comparison with novel Cu- and Bi- bearing sorbents which offer a non-RCRA alternative. When exposed to ‘harsh’ conditions such as I 2 , H 2 O, and NO 2 vapors carried by air, Cu 2 S-polyacrylonitrile (PAN) is more efficient than Ag 0 Z and all other novel sorbents, providing with 11% I capture efficiency. However, under ‘ideal’ conditions in which I 2 is carried by dry air), Ag 0 Z is more efficient than Cu 2 S-PAN and other novel sorbents, providing 74% I capture efficiency. To investigate this result and the overall performance of all sorbents tested, several characterization techniques were employed, including thermal gravimetric analysis, scanning electron microscopy – electron dispersion X-Ray spectroscopy, powder X-ray diffraction, and X-ray photoelectron spectroscopy. These techniques are discussed within this report. This document also includes a design and test plan update from Idaho National Laboratory as the next step in testing the high performing sorbents from thin-bed tests carried out by Oak Ridge National Laboratory.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Low Pressure Oxygen-Assisted Acidic Dissolution of U Metal Foils

Traditional methods of dissolving uranium in nitric acid involve the generation of nitrogen oxide gases (NO x ), which not only are hazardous but also contribute to increased pressure within the dissolver. When uranium metal foils are dissolved in nitric acid, a series of redox reactions occurs, leading to the formation of NO x , such as nitrogen dioxide (NO 2 ) and nitric oxide (NO).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Iodine Capture Studies of Copper- and Bismuth-Based Sorbents

The release of radioiodine, one of several radionuclides of concern when recycling used nuclear fuel (UNF), is an important consideration in the fuel cycle. In this study, two sorbent materials, Cu 0 -polyacrylonitrile (PAN) and Bi 0 -PAN, were tested as solid sorbent candidates for iodine capture. Experiments using a thin bed of sorbent material were exposed to vaporized iodine for over 300 hours (~2 weeks) under varied conditions in a dynamic flow environment. The overall performance was monitored in real-time using thermogravimetric analysis, and the materials were subsequently characterized for surface and bulk analysis using scanning electron microscopy – energy-dispersive spectroscopy (SEM-EDS) and powder x-ray diffraction (pXRD), respectively. Iodine (in the form of I 2 ) is expected to be released primarily in the dissolver off-gas (DOG) stream; therefore, this study demonstrates the effects of elemental iodine (I 2 ), water vapor (H 2 O), and nitrogen dioxide (NO 2 ). When exposed to ‘ideal’ conditions (in which I 2 is carried by dry air), Cu 0 -PAN and Bi 0 -PAN behave differently, with TGA analysis indicating that Cu 0 sorption performance is higher than that of Bi 0 , as evidenced by a larger mass change. Under ‘harsh’ conditions—such as a gaseous feed containing I 2 , H 2 O, and NO 2 vapors carried by air,—iodine capture performance for both Cu 0 - and Bi 0 -PAN are affected. SEM-EDS and pXRD analysis of these materials is discussed herein.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Conceptual Design of a Scaled Voloxidation Apparatus for Testing with Used Nuclear Fuel

This report details the conceptual design overview for Department of Energy (DOE) Level 2 milestone M2FT-25IN030101021 titled “Complete conceptual design of a scaled voloxidation apparatus for testing with used nuclear fuel.” Advanced voloxidation uses high temperature nitrogen dioxide (NO2) gas to oxidize uranium dioxide (UO2) material to triuanium octoxide (U3O8) and ultimately to uranium trioxide (UO3). After consideration of multiple available options and inputs, a rotating advanced voloxidation design was determined to be the best fit for the needs of a full-scale apparatus. The system, which will be deployed in hot cell 4 of the Analytical Research Laboratory (ARL), has been designed to meet the space constraints of the facility while still accommodating at least 100g of used nuclear fuel (UNF). The apparatus consists of three main unit operations, including the gas panel, the custom furnace with reaction vessel, and the liquid scrubber.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Reducing Deferrals by Integrating Health Homes with Weatherization

The U.S. Department of Energy’s Weatherization Assistance Program (WAP) improves energy efficiency and household health for low-income families, yet a substantial number of otherwise eligible homes are deferred from due to health and safety concerns in their homes, including mold, moisture damage, or structural deficiencies. These deferred homes are often occupied by marginalized or otherwise vulnerable residents who may be exposed to elevated indoor air pollutant concentration. Integrating Healthy Homes (HH) interventions with weatherization has been proposed as a strategy to reduce deferrals, address environmental justice concerns, and improve health outcomes. However, limited data on the health and economic implications of such integration exist. This study aimed to assess the potential health benefits and savings-to-investment ratio (SIR) associated with integrating Healthy Homes interventions into weatherization programs for homes typically deferred from WAP services. We collected indoor air pollutant data from homes undergoing health home renovations, including fine particulate matter (PM 2.5 ), nitrogen dioxide (NO 2 ), carbon monoxide (CO), and formaldehyde, with sampling times up to one month. Except for fomaldehyde, which was measured using passive UMEx badges, the other metrics were measured using the airQ Pro indoor air quality monitor.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Understanding Air Quality Changes after Implementation of Mitigation Measures during a Pandemic: A Scoping Review of Literature in the United States

Traffic-related emissions continue to be a significant source of air pollution in the United States (US) and around the globe. Evidence has shown that previous policies implemented to restrict-traffic flows have affected air pollution levels. Thus, mitigation strategies associated with the COVID-19 pandemic that modified population-level mobility patterns provide a unique opportunity to study air pollution change across the US. For instance, to slow the spread of the pandemic, state and local governments started implementing various mitigation actions, including stay-at-home directives, social distancing measures, school closures, and travel restrictions. This scoping review aimed to summarize the existing evidence about how air quality changed through mitigation practices throughout the pandemic in the US. We found 66 articles that fit our inclusion criteria. Generally, the consolidated results revealed that nitrogen dioxide (NO 2 ) and carbon monoxide (CO) decreased across the country. Studies observed mixed directions and magnitudes of change for fine and coarse particulate matter (PM 2.5 , PM 10 ), ozone (O 3 ), and sulfur dioxide (SO2). Few articles tried to explain this notable heterogeneity in air quality changes by associating contextual factors, such as mobility, traffic flow, and demographic factors. However, all studies agreed that the change in air pollution was nonuniform across the US and even varied within a city.

54 ENVIRONMENTAL SCIENCES↗

Methods for the separation of CO2 from a gas stream

Disclosed herein are 2-stage membrane separation methods for capturing CO2 from a feed gas. The methods can employ two selectively permeable membranes, which may be the same or different. The selectively permeable membrane can have a carbon dioxide permeance of from 500 to 3000 GPU at 57° C. and 1 atm feed pressure and a carbon dioxide:nitrogen selectivity of from 10 to 1000 at 57° C. and 1 atm feed pressure. High pressure ratios across the membranes can be achieved by compressing the feed gas to a high pressure, by using vacuum pumps to create a lowered pressure on the permeate side of the membrane, by using a sweep stream, or a combination thereof. When a sweep stream is used, the sweep stream may include a portion of the retentate gas stream obtained from the retentate side of one or more of the membranes used.

Ho, W. S. Winston↗

Ratiometric vapor sensor

A ratiometric vapor sensor is described that includes a first sensor and a second sensor. The first sensor includes a first semiconductor component comprising a vapor-sensitive semiconducting organic compound, while the second sensor includes a second semiconductor component comprising a modified vapor-sensitive semiconducting organic compound including a modifying organic group. The ratiometric vapor sensor can be used to detect the presence of a vapor such as nitrogen dioxide, and determine the concentration of the vapor by comparing the outputs of electrodes connected to the first and second sensor.

47 OTHER INSTRUMENTATION↗

The impact of nitrogen oxides on electrochemical carbon dioxide reduction

The electroreduction of carbon dioxide offers a promising avenue to produce valuable fuels and chemicals using greenhouse gas carbon dioxide as the carbon feedstock. Because industrial carbon dioxide point sources often contain numerous contaminants, such as nitrogen oxides, understanding the potential impact of contaminants on carbon dioxide electrolysis is crucial for practical applications. Herein, we investigate the impact of various nitrogen oxides, including nitric oxide, nitrogen dioxide, and nitrous oxide, on carbon dioxide electroreduction on three model electrocatalysts (i.e., copper, silver, and tin). We demonstrate that the presence of nitrogen oxides (up to 0.83%) in the carbon dioxide feed leads to a considerable Faradaic efficiency loss in carbon dioxide electroreduction, which is caused by the preferential electroreduction of nitrogen oxides over carbon dioxide. The primary products of nitrogen oxides electroreduction include nitrous oxide, nitrogen, hydroxylamine, and ammonia. Despite the loss in Faradaic efficiency, the electrocatalysts exhibit similar carbon dioxide reduction performances once a pure carbon dioxide feed is restored, indicating a negligible long-term impact of nitrogen oxides on the catalytic properties of the model catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Molecular-Scale Considerations of Enhanced Oil Recovery in Shale

With only less than 10% recovery, the primary production of hydrocarbon from shale reservoirs has redefined the energy equation in the world. Similar to conventional reservoirs, Enhanced Oil Recovery (EOR) techniques could be devised to enhance the current recovery factors. However, shale reservoirs possess unique characteristics that significantly affect the fluid properties. Therefore, we are adopting a molecular simulation approach that is well-suited to account for these effects to evaluate the performance of three different gases, methane, carbon dioxide and nitrogen, to recover the hydrocarbons from rough pore surfaces. Our hydrocarbon systems consists of either a single component (decane) or more than one component (decane and pentane). We simulated cases where concurrent and countercurrent displacement is studied. For concurrent displacement (injected fluids displace hydrocarbons towards the production region), we found that nitrogen and methane yielded similar recovery; however nitrogen exhibited a faster breakthrough. On the other hand, carbon dioxide was more effective in extracting the hydrocarbons when sufficient pressure was maintained. For countercurrent displacement (gases are injected and hydrocarbons are produced from the same direction), methane was found to be more effective, followed by carbon dioxide and nitrogen. In all cases, confinement reduced the recovery factor of all gases. This work provides insights to devise strategies to improve the current recovery factors observed in shale reservoirs.

04 OIL SHALES AND TAR SANDS↗

Impact of carbonation on leaching of constituents from a cementitious waste form for treatment of low activity waste at the DOE Hanford site

Carbonation can be a major aging process during disposal of alkaline cementitious waste forms and can impact constituent leaching by changes in material alkalinity, pore structure, and controlling mineral phases. The effect of carbonation on the leaching of major and trace constituents from Cast Stone, a cementitious waste form developed to treat high salt content low activity waste, was studied through a combination of leaching experiments and reactive transport simulations. Diffusive transport of constituents in the waste form was evaluated using reactive transport modeling of diffusion-controlled leaching test results and a geochemical speciation model derived from pH-dependent leaching. Comparisons between Cast Stone materials aged under nitrogen, air, and 2% carbon dioxide in nitrogen showed that carbonation impacts solubility, physical retention and observed diffusivity of major and trace constituents. Carbonation under 2% CO 2 decreased the diffusion-controlled leaching of chromium by two orders of magnitude. Finally, modeling results suggest that carbonation may also decrease solubility of technetium while changes to microstructure by carbonation increases effective diffusivity of constituents in Cast Stone.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

CROCUS Air Quality Data at Northeastern Illinois University Rooftop

This dataset is from the Department of Energy Office of Science funded project, Community Research on Urban and Climate Science (CROCUS) (https://crocus-urban.org/). The AQT (Vaisala AQT530) instrument provides observations on meteorological conditions, including particulate matter (PM2.5, PM10), gas species concentrations (NO, NO2, O3, CO), and environment temperature and moisture. These measurements are critical for understanding air quality. These measurements are useful for understanding changes in aerosol properties, air quality research, and comparing to model experiments especially in urban environments.Datasets are stored in the netCDF data format, and we we encourage users to make use the associated toolkits available from Unidata (https://www.unidata.ucar.edu/software/netcdf/), Project Pythia (https://foundations.projectpythia.org/core/data-formats/netcdf-cf.html), and our “Instrument Cookbooks” (https://crocus-urban.github.io/instrument-cookbooks) for more information on how to process the metadata-rich datasets.

54 ENVIRONMENTAL SCIENCES↗

Electrochemical Conversion of Carbon Dioxide to Alcohols

The vast quantities of fossil fuels used by our society have led to unprecedented atmospheric carbon dioxide levels with widespread climate impacts. Electrochemical conversion of carbon dioxide to valuable fuels and chemicals is a promising technology to utilize carbon dioxide emitted from coal-fired power plants. In this project, the team developed an integrated electrolyzer system that takes the flue gas from the power plant and produce C2/C3 alcohols (i.e., ethanol and n-propanol) through a two-stage electrolysis process. The pretreated carbon dioxide from the flue gas is converted into carbon monoxide by the first stage carbon dioxide electrolysis, followed by the second stage where the produced carbon monoxide is further converted into liquid C2/C3 alcohols with a high selectivity and energy efficiency. Impact and anticipated fate of flue gas contaminants, such as sulfur dioxide and nitrogen oxides, on the proposed technology was also evaluated. Furthermore, a full analysis of economics and life-cycle of the carbon dioxide electrolysis technology for carbon dioxide emissions mitigation from coal-fired power plants was conducted to evaluate the economic feasibility and carbon dioxide mitigation potential of the proposed technology.

20 FOSSIL-FUELED POWER PLANTS↗