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At least 73 records · Page 4

Data driven investigation to understand the influence of total solids on biological biogas upgrading

In situ biogas upgrading achieves CO 2 conversion to CH 4 via hydrogenotrophic methanogenesis; however, gas-liquid mass transfer constraints limit the upgrading performance. Recognizing that optimization studies often underrepresent the effects of total solids (TS) and organic loading rate (OLR), this study undertook a holistic, statistics driven assessment of operating conditions for in situ H 2 assisted biogas upgrading, centering the analysis on TS and OLR. A dataset of 31 studies was compiled and comprised 99 observations. A rigorous analytical framework was employed, combining data standardization, fixed- and random-effects (REML) weighted regressions with cluster-robust errors, stratified analyses, and machine learning. Mixed-effects meta regression indicated that TS was the main factor explaining differences of methane fraction (CH 4 %) when considering the between studies heterogeneity. Focusing on a near-stoichiometric subset (H 2 /CO 2 ≈ 4:1), TS remained significant. Stratified results showed a stronger negative relationship between TS and CH 4 % in UASB reactors than in CSTRs, with a negative effect under mesophilic conditions and no significant effect under thermophilic conditions. A Random Forest model corroborated the statistical findings, consistently ranking H 2 /CO 2 ratio, OLR, TS, and hydrogen injection rate (HIR) as the most influential predictors. These findings delineate trends across increasing TS levels, particularly between 1% and 10%, and provide preliminary insights for TS above 15% in in situ biogas upgrading. They further provide insights for the influence of TS by reactor type and temperature, thereby advancing the evidence base for implementing biological CO 2 conversion to CH 4 in practice.

In situ biogas upgrading↗

Impact of Cloud Longwave Scattering on Radiative Fluxes Associated With the Madden-Julian Oscillation in the Indian Ocean and Maritime Continent

Previous studies suggested that cloud longwave radiation contributes to the development and maintenance of the Madden-Julian Oscillation (MJO) and model-based convection is highly sensitive to the radiation scheme. However, currently used radiation schemes do not take cloud longwave scattering into account, resulting in an overestimation of the outgoing longwave radiation (OLR) and an underestimation of the downward longwave flux at the surface. We use combined active and passive satellite cloud property retrievals to quantify the one-layer cloud OLR and heating rate (HR) biases introduced by neglecting cloud longwave scattering in the Indian Ocean and Maritime Continent in the context of MJO, with a focus on its phases 3, 5, and 6. Here, the results show that the satellite-detected one-layer cloud area consists primarily of ice clouds, particularly during the boreal winter in the 4-year study period. An increased ice cloud area fraction of one-layer cloud groups is present up to 5 days before the onset of MJO events. If longwave scattering is neglected, the composite mean OLR overestimation over the one-layer ice cloud area from 5 days before to 4 days after the MJO passage is approximately 3.5 to 5.0 W m –2 . Neglecting longwave scattering also leads to a HR underestimation at cloud base and an overestimation at cloud top, making the base-to-top heating gradient less sharp at the cloud-resolving scale.

54 ENVIRONMENTAL SCIENCES↗

A Refined Understanding of the Ice Cloud Longwave Scattering Effects in Climate Model

Abstract Because longwave (LW) absorption by greenhouse gases and clouds is more significant than the LW scattering effect by clouds, most climate models neglect cloud LW scattering to save computational costs. Ignoring cloud LW scattering directly overestimates outgoing longwave radiation (OLR). This study included ice‐cloud LW scattering treatment in the Exascale Energy Earth System Model (E3SM) version 2 and ran fully‐coupled simulations, prescribed sea surface temperature simulations, and offline radiative transfer calculations to comprehensively assess the impact of ice‐cloud LW scattering on global climate simulation. The instantaneous effect due to ice‐cloud LW scattering reduces the OLR by ∼1 W/m 2 on the global average and 2 W/m 2 on the tropical average. Tropospheric warming and high cloud amount reduction act to partially compensate for such instantaneous OLR reduction caused by the inclusion of LW scattering. When the simulation reaches the equilibrium, the surface warms by 0.66 K on average with respect to the simulation without LW scattering, with the Arctic surface temperature differences more than twice as large as that of the global mean. The impact of including LW scattering on the simulated climate change in response to 4 × CO 2 is also assessed. While including the cloud LW scattering does not significantly modify radiative forcing and total radiative feedback under such a scenario, it results in a 10% more positive cloud feedback.

54 ENVIRONMENTAL SCIENCES↗

Climate variability and atmospheric teleconnection from satellite observed cloud fluctuations

To investigate the low-frequency variability of the large-scale circulation over the tropics and its relationship with different regions of the globe, statistics of cloud fluctuations, as inferred from outgoing longwave radiation (OLR) are used. The data consists of seven years of global OLR in a 2.5 x 2.5-deg grid derived from NOAA polar orbiting satellite observations. The time series of area-averaged monthly deviation from the seven-year mean of OLR over an equatorial Central Pacific region is presented. It is shown that positive and negative deviations reflect local drier and wetter than normal conditions, respectively. Consideration is given to teleconnection based on the Central Pacific variations and to southern oscillation contributions.

Lau, K. M.↗

Global precipitation derived from HIRS2/MSU soundings

Atmospheric and surface soundings for the FGGE obtained by the analysis of HIRS2/MSU sounding data (Susskind et al., 1987) were used, along with a modified version of the radiation code used in the Goddard Laboratory for Atmospheres fourth-order GCM, to compute fields of total outgoing longwave radiation (OLR) for the FGGE year. A reasonable agreement was obtained between the computed OLR values and OLR radiation derived from measurements. Coefficients relating the global difference fields for each month of the FGGE year to precipitation derived from rain-gauge measurements for the FGGE year were derived. The results of this study demonstrate that precipitation is derivable from space on a global scale.

Wu, Man-Li C.↗

Cross correlations between the radiation and atmospheric variables in a general circulation model and satellite data

The classical picture of the influence of midlatitude troughs on cloud patterns is studied in a GCM and in satellite and NMC data, by comparing the cross correlation of the poleward component of the wind and the outgoing longwave radiation (OLR). Over storm tracks, the variance of the OLR is explained by a correlation with the poleward component of the horizontal wind, forced by stronger correlations with the vertical velocity through the cloud and humidity fields. It is found that stratiform clouds have a dominant impact on the model OLR fluctuations, even over much of the tropics.

Charlock, Thomas P.↗

A ten-year monthly data set of outgoing longwave radiation from Nimbus-6 and Nimbus-7 satellites

Monthly mean outgoing longwave radiation (OLR) measurements in the form of global contour maps and coefficients of spherical-harmonic functions for each month of the 10-year period, July 1975 through October 1985, have recently been completed. One data set contains three years (July 1975 to June 1978) of 'continuous' data from the wide field-of-view sensor of the Earth Radiation Budget experiment (ERB) aboard the Nimbus-6 satellite. The other data set contains seven years (November 1978 to October 1985) of 'continuous' data from the ERB experiment aboard the Nimbus-7 satellite. The OLR broadband time series could be used, for example, to study the interannual variability of OLR. An example is given of two El Ninos that occurred in the 10-year timeframe.

Bess, T. Dale↗

Principal modes of intraseasonal variations in atmospheric angular momentum and tropical convection

Five-day National Meteorological Center wind and outgoing longwave radiation (OLR) data are used here to study the seasonal, intraseasonal variation of angular momentum and its relationship with tropical convection. It is found that the zonally averaged u component and the zonally averaged OLR show pronounced periodicities around 30-60 days. The globally averaged zonal wind at 250 mbar exhibits strong seasonal variation in connection with the expansion and contraction of the easterly and westerly belt. At upper levels this is manifested as the poleward and equatorward migration of the subtropical jet streams. Results show that the 30- to 60-day oscillation in 250 mbar zonal mean wind and OLR can be represented by three basic meridional structures: tropical modes, tropical-subtropical modes, and extratropical modes.

Lau, K.-M.↗

Global-scale, intraseasonal fluctuations of diabatic forcing of the atmosphere

Fields of diabatic heating rate estimates (H) for 5-day periods were calculated from the European Center for Medium Weather Forecasts (ECMWF) analyses since 1985 as the residual of the dry thermodynamic equation. Included in these fields are the horizontal and vertical divergences of heat for both mean and eddy statistics. Previous work dealt with 4-day periods, however, with the emphasis in the Global Precipitation Climatology Project (GPCP) for 5-day period totals the change was made to accommodate the GPCP product. H has long been associated with cold tropical cloud-top temperatures as measured by polar orbiting outgoing longwave radiation (OLR) sensors. Correlations between H and OLR fields on three time scales indicate a moderate amount of agreement. For periods less than 90 days, significant negative correlations are found between H and OLR for (1) tropical and NH midlatitude oceanic areas, and (2) for zonal and hemispheric mean values. Positive correlations are seen in NH mean and continental areas of N. Africa, N. America, N. Asia and Antarctica. These latter results reflect seasonal heating and cooling. Comparisons have been made between H as H as calculated from the ECMWF analyses and output from the CCM1 T42 simulations. The CCM1 tends to have a more cellular structure with more heating (precipitation) over land versus that observed (ECMWF) over oceans.

Christy, John R.↗

Observed teleconnection patterns between Nimbus-7 Earth Radiation Budget anomalies and ECMWF 500 mb geopotential heights

Broadband observations from the Nimbus-7 Earth Radiation Budget (ERB) instrument package were used to calculate the outgoing-longwave-radiation (OLR) anomalies as well as the net balance anomalies. The areas of anomalous net balance and OLR were correlated with the ECMWF 500-mb geopotential height anomalies, and many areas of significant correlation were found. Their most interesting teleconnection area was associated with the net balance anomaly near Indonesia, where a series of alternating correlation waves was found similar to the wave pattern reported by Hoskins and Karoly (1981) in their model study of tropical heat sources. The strongest OLR anomaly correlation occurred in central Pacific.

Randel, David L.↗

Spatial variability of outgoing longwave radiation

Spatial distributions of day-to-day variations in the outgoing longwave radiation (OLR) are quantified by examining spatial variations in daily OLR data obtained from the Earth Radiation Budget Experiment scanning radiometer aboard the NOAA-9 meteorological satellite, in the form of daily maps and monthly radiation maps at 2.5 deg latitude-longitude scale. The results show that the variations of OLR during a month are markedly greater in the subtropics than they are in the mid and high altitudes. Results for October 1985 are presented.

Smith, G. L.↗

Comparison of the Highly Reflective Cloud and Outgoing Longwave Radiation datasets for use in estimating tropical deep convection

Two currently existing long-term satellite-derived data sets (the Highly Reflective Cloud (HRC) and the Outgoing Longwave Radiation (OLR) data sets) were compared for the accuracy in estimating tropical deep convection, in terms of their climatological and frequency-dependent characteristics, their consistency in identifying deep tropical convection, and their relationship to local sea surface temperature (SST). The results reveal some important differences between the HRC and OLR data sets in terms of their temporal and spatial scales of variability, their relationships to other geophysical fields, and the logistics of their use. It was found that, for many applications, the HRC data set represents the characteristics of the cloud cluster-scale tropical convection more accurately than the OLR data set.

Waliser, Duane E.↗

Spatial variability of outgoing longwave radiation

Data from the Earth Radiation Budget Experiment scanning radiometer aboard the NOAA-9 operational meteorological satellite are used to investigate the spatial variability of Outgoing Longwave Radiation (OLR). Daily and monthly radiation maps at 2.5 deg latitude-longitude scale are used as a basis for the study. The regions of greatest variability are in the tropics and subtropics. Storm tracks such as the South Pacific convergence zone appear as regions of high OLR variability. Spatial spectra in longitude show two regimes of OLR. At large scales (wavenumbers less than 6), the spatial spectrum is flat. For wavenumbers greater than 10, the spectra decrease as wavenumber to the -3 power. The spatial spectrum of daily anomalies from the mean is a strong function of latitude and season, with interesting features. Correlations of daily anomalies from the monthly mean decrease exponentially in latitude but have a damped-wave structure in longitude. The spatial variability of the daily maps, as measured by degree variance, have 10 times the power at degree 24 than the monthly maps, but at scales between 1 and 10, the degree variance is practically the same for daily as for monthly.

Smith, G. Louis↗

Spectrally Resolved Flux Derived from Collocated AIRS and CERES Observations and its Application in Model Validation: Clear-Sky Over the Tropic Oceans - Part I

Spectrally resolved outgoing IR flux, the integrand of the outgoing longwave radiation (OLR), has its unique value in evaluating model simulations. Here we describe an algorithm of deriving such clear-sky outgoing spectral flux through the whole IR region from the collocated Atmospheric Infrared Sounder (AIRS) and the Clouds & the Earth's Radiant Energy System (CERES) measurements over the tropical oceans. Based on the scene types and corresponding angular distribution models (ADMs) used in the CERES Single Satellite Footprint (SSF) dataset, spectrally-dependent ADMs are developed and used to estimate the spectral flux at each AIRS channel. A multivariate linear prediction scheme is then used to estimate spectral fluxes at frequencies not covered by the AIRS instrument. The whole algorithm is validated using synthetic spectra as well as the CERES OLR measurements. Using the GFDL AM2 model simulation as a case study, the application of the derived clear-sky outgoing spectral flux in model evaluation is illustrated. By comparing the observed and simulated spectral flux in 2004, compensating errors in the simulated OLR from different absorption bands can be revealed, so does the errors from frequencies within a given absorption band. Discrepancies between the simulated and observed spatial distributions and seasonal evolutions of the spectral fluxes at different spectral ranges are further discussed. The methodology described in this study can be applied to other surface types as well as cloudy-sky observations and corresponding model evaluations.

Huang, Xianglei↗

Crucial Role of Thermal Gradients in MMS Fluxgate In-Flight Calibration

To meet the science goals of the Magnetospheric Multiscale (MMS) mission, the Fluxgate Magnetometer (FGM) must measure the ambient magnetic field with an accuracy of 0.1 nT. On a typical MMS orbit, the offsets (or zero levels) of the 3-axis FGM can vary by ~0.5 nT (exclusive of periods in Earth shadow). Previous studies have shown that these variations can be characterized as functions of sensor temperature, TS, and can thus be corrected to within 0.2 nT in the spin plane using in-flight calibration techniques (Bromund, et al., 2016, https://ntrs.nasa.gov/citations/20160014711). In that presentation, we noted two significant observations: A distinct function of TS must be used to characterize offsets during shadow: offsets at a given TScan differ by as much as 2 nT in shadow vs sunlight. Offsets change after maneuvers, without a commensurate change in TS . These changes can be as large as 2 nT. We now note a third, related observation: Offsets increase with proximity to the earth even when TS is constant, resulting in variations of ~0.2 nT at 4-5 Earth radii (RE) These effects are evidence that offsets are a multivariate function of TS and another factor, namely: thermal gradients. Due to the spacecraft spin, the Earth and the Sun each provide a relatively constant thermal input onto one instrument face while the opposite face remains in shadow, thus giving rise to thermal gradients. The thermal gradient depend on the orientation of the spin axis relative to the Earth or Sun. We observe that offsets vary by as much as 0.17 nT/degree as a function of the tilt of the spin axis towards the Sun. Thermal input from the Earth is dominated by Outgoing Longwave Radiation (OLR). Due to the proximity to Earth, the inverse proportion of the distance squared is a significant factor in the thermal gradient attributed to Earth OLR. We find that offsets can be corrected to <0.05 nT accuracy near perigee when accounting for these factors using empirically determined constants of proportionality that account for differences in emissivity of the top and bottom faces of the sensor to OLR (as well as other thermal effects). The changes in offset associated with thermal gradient are of the same order of magnitude as effects that were formerly attributed to sensor temperature alone, and thus both parameters are necessary to characterize the FGM offsets.

Kenneth R Bromund↗

A Rotation Procedure to Improve Seasonally Varying Empirical Orthogonal Function Bases for MJO Indices

Various indices have been defined to characterize the phase and amplitude of the Madden-Julian oscillation (MJO). One widely used index is the Outgoing Longwave Radiation (OLR) based MJO index (OMI), which is calculated using the spatial pattern of 30-96-day eastward-filtered OLR. The EOFs used to calculate the OMI in observations are prone to degeneracy and exhibit oscillations on the order of 10-20 days, despite initial filtering of the OLR. We propose a simple modification to the OMI that involves aligning the EOFs between neighboring days while retaining the spatial pattern described by the EOFs. This rotation method is implemented as a postprocessing procedure of the current OMI calculation and cleanly removes the spurious oscillations and degeneracy issues seen in the standard method. A similar rotation procedure can be implemented in calculations of other MJO indices.

Sarah Weidman↗

Long term performance of pilot methanogenic digester filled with seashell wastes treating slaughterhouse wastes: Biogas production and environmental impact

High ammonia and organic acids contents of decomposed slaughterhouse waste (SHW) often result in the severe inhibition or even failure of the anaerobic digestion (AD). The two-stage AD system can alleviate the ammonia inhibition; however, addition of alkali is often needed to maintain the neutral condition. In this study, seashell wastes containing high percentage of calcium carbonate (CaCO 3 ) were for the first time added in a pilot scale methanogenic digester treating chicken blood waste to retain the microorganisms and provide pH buffers for the substrate. A long-duration performance of this digester was conducted for 400 days under different organic loading rates (OLRs). The results show that methane yields of the digester were 244.8 and 224.9 mL g –1 COD added at OLR of 0.4 and 0.6 g COD L –1 d –1 , respectively, higher than the results of previous studies treating the similar feedstock. An AD system treating blood wastes of a typical poultry slaughterhouse was also proposed for which energy balance and carbon footprint analyses were conducted. The energy production of 0.35 MJ kg –1 blood and carbon emissions reduction of 0.05 kg CO 2 -eq kg –1 blood can be achieved from treating blood waste of the broiler chicken. Finally, this study reveals that using seashell wastes in an AD treating SHW can facilitate the reuse of aquaculture wastes and improve the sustainability of meat industry.

09 BIOMASS FUELS↗

Long-term effects of cycle time and volume exchange ratio on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) production from food waste digestate by Haloferax mediterranei cultivated in sequencing batch reactors for 450 days

Food waste digestate was fed into a sequencing batch reactor (SBR) for Haloferax mediterranei (HM) to produce poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV). This SBR was operated uninterruptedly for 450 days to test its stability, during which the cycle time and volume exchange ratio were varied to understand their impacts on the PHBV fermentation performance under ranged organic loading rates (OLR). Results showed that 1) PHBV productivity was proportional to OLR of food waste digestate; 2) substrate and product inhibitions were two limiting factors constraining substrate utilization and PHBV yields; 3) PHBV titer was dependent on the hydraulic retention time of the SBR while a volume exchange ratio lower than 0.5 is unfavorable due to the product inhibitor accumulation. Furthermore, this study for the first time demonstrated that the long-term stability of food waste-fed PHBV production by HM and revealed that inhibition effects could be barriers in SBR limiting the full-scale application of the technology.

09 BIOMASS FUELS↗