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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Formation of Highly Conducting Optically Transparent Films with Multigraphene Structure via Carbonization of Polyimide Langmuir–Blodgett Films

Multigraphene films have been for the first time obtained on the surface of quartz glass via carbonization of polyimide Langmuir–Blodgett films. The Raman spectra of the films show bands G and D and a broad band at 2300–3200 cm{sup –1}, which are characteristic of graphite-like films. The transmission electron microscopy demonstrated that the films are constituted by “stacks” of layers spaced by 0.36 nm. The surface resistance of the 5-nm-thick films was 1.2 ± 0.2 kΩ, and the transmittance was 87% at λ = 550 nm. The transmittance was 97% in the IR part of the spectrum and 70–80% in the UV part.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

New insights on electro-optical response of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) film to humidity

Understanding the relative humidity (RH) response of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is critical for improving the stability of organic electronic devices and developing selective sensors. In this work combined gravimetric sensing, nanoscale surface probing, and mesoscale optoelectronic characterization are used to directly compare the RH dependence of electrical and optical conductivities and unfold connections between the rate of water adsorption and changes in functional properties of PEDOT:PSS film. We report three distinct regimes where changes in electrical conductivity, optical conductivity, and optical bandgap are correlated with the mass of adsorbed water. At low (RH < 25%) and high (RH > 60%) humidity levels dramatic changes in electrical, optical and structural properties occur, while changes are insignificant in mid-RH (25% < RH < 60%) conditions. We associate the three regimes with water adsorption at hydrophilic moieties at low RH, diffusion and swelling throughout the film at mid-RH, and saturation of the film by water at high RH. Optical film thickness increased by 150% as RH was increased from 9% to 80%. Low frequency (1 kHz) impedance increased by ~100% and film capacitance increased by ~30% as RH increased from 9% to 80% due to an increase in the film dielectric constant. Finally, changes in electrical and optical conductivities concomitantly decrease across the full range of RH tested.

36 MATERIALS SCIENCE↗

Optical properties of armchair (7, 7) single walled carbon nanotubes

Full potential linearized augmented plane waves method with the generalized gradient approximation for the exchange-correlation potential was applied to calculate the optical properties of (7, 7) single walled carbon nanotubes. The both x and z directions of the incident photons were applied to estimate optical gaps, dielectric function, electron energy loss spectroscopies, optical conductivity, optical extinction, optical refractive index and optical absorption coefficient. The results predict that dielectric function, ε (ω), is anisotropic since it has higher peaks along z-direction than x-direction. The static optical refractive constant were calculated about 1.4 (z-direction) and 1.1 (x- direction). Moreover, the electron energy loss spectroscopy showed a sharp π electron plasmon peaks at about 6 eV and 5 eV for z and x-directions respectively. The calculated reflection spectra show that directions perpendicular to the tube axis have further optical reflection. Moreover, z-direction indicates higher peaks at absorption spectra in low range energies. Totally, increasing the diameter of armchair carbon nanotubes cause the optical band gap, static optical refractive constant and optical reflectivity to decrease. On the other hand, increasing the diameter cause the optical absorption and the optical conductivity to increase. Moreover, the sharp peaks being illustrated at optical spectrum are related to the 1D structure of CNTs which confirm the accuracy of the calculations.

36 MATERIALS SCIENCE↗

Electrically conductive black optical paint

An electrically conductive flat black paint has been developed for use on the Galileo spacecraft which will orbit Jupiter in the late 1980s. The paint, designed for equipment operating in high-energy radiation fields, has multipurpose functions. Its electrical conductivity keeps differential charging of the spacecraft external surfaces and equipment to a minimum, preventing the buildup of electrostatic fields and arcing. Its flat black aspect minimizes the effects of stray light and unwanted reflectances, when used in optical instruments and on sunshades. Its blackness is suitable, also, for thermal control, when the paint is put on spacecraft surfaces. The paint has good adherence properties, as measured by tape tests, when applied properly to a surface. The electrically conductive paint which was developed has the following characteristics: an electrical resistivity of 5 x 10 to the 7th ohms per square; a visual light total reflectance of approximately 5 percent; an infrared reflectance of 0.13 measured over a spectrum from 10 to the (-5.5) power to 0.001 meter; a solar absorptivity, alpha-s, of 0.93, and a thermal emissivity, epsilon, of 0.87, resulting in an alpha-s/epsilon of 1.07. The formula for making the paint and the process for applying it are described.

Birnbaum, M. M.↗

Optical conductivity-based ultrasensitive mid-infrared biosensing on a hybrid metasurface

Abstract Optical devices are highly attractive for biosensing as they can not only enable quantitative measurements of analytes but also provide information on molecular structures. Unfortunately, typical refractive index-based optical sensors do not have sufficient sensitivity to probe the binding of low-molecular-weight analytes. Non-optical devices such as field-effect transistors can be more sensitive but do not offer some of the significant features of optical devices, particularly molecular fingerprinting. We present optical conductivity-based mid-infrared (mid-IR) biosensors that allow for sensitive and quantitative measurements of low-molecular-weight analytes as well as the enhancement of spectral fingerprints. The sensors employ a hybrid metasurface consisting of monolayer graphene and metallic nano-antennas and combine individual advantages of plasmonic, electronic and spectroscopic approaches. First, the hybrid metasurface sensors can optically detect target molecule-induced carrier doping to graphene, allowing highly sensitive detection of low-molecular-weight analytes despite their small sizes. Second, the resonance shifts caused by changes in graphene optical conductivity is a well-defined function of graphene carrier density, thereby allowing for quantification of the binding of molecules. Third, the sensor performance is highly stable and consistent thanks to its insensitivity to graphene carrier mobility degradation. Finally, the sensors can also act as substrates for surface-enhanced infrared spectroscopy. We demonstrated the measurement of monolayers of sub-nanometer-sized molecules or particles and affinity binding-based quantitative detection of glucose down to 200 pM (36 pg/mL). We also demonstrated enhanced fingerprinting of minute quantities of glucose and polymer molecules.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Conductivity and optical band gaps of polyethylene oxide doped with Li{sub 2}SO{sub 4} salt

The conductivity and optical properties of Li{sub 2}SO{sub 4} doped polyethylene oxide (PEO) films were studied. The polymer electrolyte films are prepared using solution casting technique. The material phase change was confirmed by X-ray diffraction (XRD) technique. Optical absorption study was conducted using UV- Vis. Spectroscopy in the wavelength range 190–1100nm on pure and doped PEO films. The direct and indirect optical band gaps were found decreased from 5.81–4.51eV and 4.84–3.43eV respectively with increasing the Li{sub 2}SO{sub 4}. The conductivity found to increases with increasing the dopant concentration due to strong hopping mechanism at room temperature.

36 MATERIALS SCIENCE↗