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At least 73 records · Page 4

Fly ash based zeolitic pigments for application in anticorrosive paints

The purpose of this work is to evaluate the utilization of waste fly ash in anticorrosive paints. Zeolite NaY was synthesized from waste fly ash and subsequently modified by exchanging its nominal cation Na{sup +} with Mg{sup 2+} and Ca{sup 2+} ions. The metal ion exchanged zeolite was then used as anticorrosive zeolitic pigments in paints. The prepared zeolite NaY was characterized using X-Ray diffraction technique and Scanning electron microscopy. The size, shape and density of the prepared fly ash based pigments were determined by various techniques. The paints were prepared by using fly ash based zeolitic pigments in epoxy resin and the percentages of pigments used in paints were 2% and 5%. These paints were applied to the mild steel panels and the anticorrosive properties of the pigments were assessed by the electrochemical spectroscopy technique (EIS).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Towards an exact theory of linear absorbance and circular dichroism of pigment-protein complexes: Importance of non-secular contributions

A challenge for the theory of optical spectra of pigment-protein complexes is the equal strength of the pigment-pigment and the pigment-protein couplings. Treating both on an equal footing so far can only be managed by numerically costly approaches. Here, we exploit recent results on a normal mode analysis derived spectral density that revealed the dominance of the diagonal matrix elements of the exciton-vibrational coupling in the exciton state representation. We use a cumulant expansion technique that treats the diagonal parts exactly, includes an infinite summation of the off-diagonal parts in secular and Markov approximations, and provides a systematic perturbative way to include non-secular and non-Markov corrections. The theory is applied to a model dimer and to chlorophyll (Chl) a and Chl b homodimers of the reconstituted water-soluble chlorophyll-binding protein (WSCP) from cauliflower. The model calculations reveal that the non-secular/non-Markov effects redistribute oscillator strength from the strong to the weak exciton transition in absorbance and they diminish the rotational strength of the exciton transitions in circular dichroism. The magnitude of these corrections is in a few percent range of the overall signal, providing a quantitative explanation of the success of time-local convolution-less density matrix theory applied earlier. A close examination of the optical spectra of Chl a and Chl b homodimers in WSCP suggests that the opening angle between Q{sub y} transition dipole moments in Chl b homodimers is larger by about 9{sup ∘} than for Chl a homodimers for which a crystal structure of a related WSCP complex exists. It remains to be investigated whether this change is due to a different mutual geometry of the pigments or due to the different electronic structures of Chl a and Chl b.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Study on the effect of ascorbic acid on the biosynthesis of pigment and citrinin in red yeast rice based on comparative transcriptomics

Pigment is one of the most important metabolites in red yeast rice. However, citrinin may accumulate and cause quality security issues. In the present study, the effect of ascorbic acid (EAA) on the pigment and citrinin was studied, and the metabolic mechanism was discussed using comparative transcriptomics. The introduction of EAA increased the pigment by 58.2% and decreased citrinin by 65.4%. The acid protease activity, DPPH scavenging rate, and total reducing ability also increased by 18.7, 9.0, and 26.7%, respectively. Additionally, a total of 791 differentially expressed genes were identified, and 79 metabolic pathways were annotated, among which carbon metabolism, amino acid metabolism, and fatty acid metabolism were closely related to the biosynthesis of pigment and citrinin. Ethanol dehydrogenase ( M pigC ), oxidoreductase ( M pigE ), reductase ( M pigH ), and monooxygenase ( M pigN ) may be related to the increase of pigment. ctnC and pksCT contributed to the decline of citrinin.

Jiang, Zhilin↗

Seasonal and interannual variability of pigment concentrations across a California Current frontal zone

The seasonal and interannual variability of the latitudinal position of the California Current frontal zone was investigated by examining satellite images of phytoplankton pigment from the coastal-zone color scanner for the periods 1979-1983 and 1986. The pigment concentrations associated with the zonal front were also determined. A general seasonal cycle of pigment concentrations is was established. It was found that variations in the frontal structure are controlled primarily by changes in pigment concentration north of the front. Seasonal variations were found to be minimal south of the front, where pigment concentrations remain low throughout the spring, summer, and fall.

Thomas, A. C.↗

New directions in phthalocyanine pigments

Phthalocyanines have been used as a pigment in coatings and related applications for many years. These pigments are some of the most stable organic pigments known. The phthalo blue and green pigments have been known to be ultraviolet (UV) stable and thermally stable to over 400 C. These phthalocyanines are both a semiconductor and photoconductor, exhibiting catalytic activity and photostabilization capability of polymers. Many metal free and metallic phthalocyanine derivatives have been prepared. Development of the new classes of phthalocyanine pigment could be used as coating on NASA spacecraft material such as glass to decrease the optical degradation from UV light, the outside of the space station modules for UV protection, and coating on solar cells to increase lifetime and efficiency.

Trinh, Diep VO↗

Annual and interannual variations of phytoplankton pigment concentration and upwelling along the Pacific equator

The following variables along the Pacific equator from 145 deg E to 95 deg W were employed: surface layer phytoplankton pigment concentrations derived from Nimbus 7 coastal zone color scanner (CZCS) measurements of ocean color radiances; vertical velocities simulated at the 90-m bottom of the euphotic layer from a wind-driven ocean general circulation model; and nitrate concentrations estimated from model-simulated temperature. The upward flux of nitrate into the euphotic layer was calculated from the simulated vertical motion and nitrate concentration. The CZCS-derived phytoplankton pigment concentration was uniform from 175 deg to 95 deg W. Longitudinal profiles of upwelling, phytoplankton biomass, and 90-m nitrate flux were of different shapes. The small annual cycles of the phytoplankton pigment and nitrate flux were in phase: increased phytoplankton biomass was associated with increased upward nitrate flux, but the phase was not consistent with the annual cycles of the easterly wind or of the upwelling intensity. Variation of phytoplankton pigment concentration was greater during El Nino than during the annual cycle. The substantially reduced phytoplankton pigment concentration observed during El Nino was associated with smaller upward nitrate flux. Phytoplankton biomass during non-El Nino conditions was not related to nitrate flux into the euphotic layer.

Halpern, David↗

Variability in pigment concentration in warm-core rings as determined by coastal zone color scanner satellite imagery from the Mid-Atlantic Bight

A time series of coastal zone color scanner (CZCS) derived chlorophyll (CZCS-chl) and sea surface temperature (SST) satellite imagery was developed for the Mid-Atlantic Bight (MAB). Warm-core rings (WCR) were identified by both the warmer SST signal as well as the low pigment concentrations of their cores. The variation in pigment concentrations and SST observed in satellite imagery over the geographic range and life span of four WCRs is investigated. The hypotheses are that pigment concentration increase during the lifetime of the WCR is a response to processes such as convective overturn, upwelling, edge enhancement due to increased vertical mixing, active convergence, or lateral exchange. Empirical orthogonal function analysis (EOF) is used to investigate the relationship between SST and pigment patterns observed in the presence of a WCR. The first two EOF modes explain more than 80% of the variability observed in all four WCRs and in both (SST and pigment) data sets. The results of this study show that, at the synoptic scales of staellite data, the variability observed in the WCRs is greater at the periphery of the rings. These results show that advective entrainment, rather than processes at ring center (e.g., shoaling of the pycnocline/nutricline in response to frictional decay) or at the periphery due to other processes such as vertical mixing, is the mechanism responsible for the observed variability.

Garcia-Moliner, Graciela↗

Remote Sensing of Phytoplankton Pigments

Pigments, as a vital part of phytoplankton, act as the light harvesters and protectors in the process of photosynthesis. Historically, most of the previous studies have been focused on chlorophyll a, the primary light harvesting pigment. With the advances in technologies, especially High-Performance Liquid Chromatography (HPLC)and satellite ocean color remote sensing, recent studies promote the importance of the accessory pigments within the phytoplankton. In this chapter, we will overview the technology advances in phytoplankton pigment identification, the history of ocean color remote sensing and its application in retrieving phytoplankton pigments, and the existing challenges and opportunities for future studies in this field.

Guoqing Wang↗

The Peak Absorbance Wavelength of Photosynthetic Pigments Around Other Stars From Spectral Optimization

In the search for life on other planets, the presence of photosynthetic surface vegetation may be detectable from the colors of light it reflects, which on the modern Earth is a steep increase in reflectance between the red and near-infrared wavelengths, a “red edge.” This edge-like signature occurs at wavelengths of peak photon absorbance, which are the result of adaptations of the phototroph to their spectral environment. On planets orbiting different stellar types, red edge analogs may occur at other colors than red. Thus, knowing the wavelengths at which photosynthetic organisms preferentially absorb and reflect photons is necessary to detect red edge analogs on other planets. Using a numerical model that predicts the absorbance spectrum of extant photosynthetic pigments on Earth from Marosvolgyi & van Gorkom (2010), we calculate the absorbance spectrum for pigments on an Earth-like planet around F through late M type stars that are adapted for maximal energy production. In this model, cellular energy production is maximized when pigments are tuned to absorb at the wavelength that maximizes energy input from incident photons while minimizing energy losses due to thermal emission and building cellular photosynthetic apparatus. We find that peak photon absorption for photosynthetic organisms around F type stars tends to be in the blue while for G, K, and early M type stars, red or just beyond is preferred. Around the coolest M type stars, these organisms may preferentially absorb in the near-infrared, possibly past 1 micron. These predictions are consistent with previous, qualitative estimates of pigment absorptance. Our predicted absorbance spectra for photosynthetic surface organisms depend on both the stellar type and planetary atmospheric composition, especially atmospheric water vapor concentrations, which alter the availability of surface photons and thus the predicted pigment absorption. By constraining the absorbance spectra of alien, photosynthetic organisms, future observations may be better equipped to detect the weak spectral signal of red edge analogs.

astrobiology↗

Pheomelanin pigment remnants mapped in fossils of an extinct mammal

Recent progress has been made in paleontology with respect to resolving pigmentation in fossil material. Morphological identification of fossilized melanosomes has been one approach, while a second methodology using chemical imaging and spectroscopy has also provided critical information particularly concerning eumelanin (black pigment) residue. In this work we develop the chemical imaging methodology to show that organosulfur-Zn complexes are indicators of pheomelanin (red pigment) in extant and fossil soft tissue and that the mapping of these residual biochemical compounds can be used to restore melanin pigment distribution in a 3 million year old extinct mammal species ( Apodemus atavus ). Synchotron Rapid Scanning X-ray Fluorescence imaging showed that the distributions of Zn and organic S are correlated within this fossil fur just as in pheomelanin-rich modern integument. Moreover, Zn coordination chemistry within this fossil fur is closely comparable to that determined from pheomelanin-rich fur and hair standards. The non-destructive methods presented here provide a protocol for detecting residual pheomelanin in precious specimens.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dissecting pigment architecture of individual photosynthetic antenna complexes in solution

Significance Energy from the sun is captured by the biosphere through photosynthetic antenna proteins, which function by integration of a set of pigments into a protein scaffold. Nature uses relatively similar pigment building blocks to achieve diverse functions, and the organizing principles behind this process are not fully understood. Using a single-molecule microfluidic trap and multiparameter fluorescence spectroscopy, we explore how the photophysical properties of individual pigment sites are modulated by the protein’s oligomerization states, using single proteins of a model antenna from cyanobacteria. Our measurements achieve a bottom-up dissection of the structural-function relation of the model pigment−protein complex with important implications for photosynthetic antenna biophysics.

59 BASIC BIOLOGICAL SCIENCES↗

The Polyketide Synthase Gene pks4 of Trichoderma reesei Provides Pigmentation and Stress Resistance

Species of the fungal genus Trichoderma (Hypocreales, Ascomycota) are well-known for their production of various secondary metabolites. Nonribosomal peptides and polyketides represent a major portion of these products. In a recent phylogenomic investigation of Trichoderma polyketide synthase (PKS)-encoding genes, the pks4 from T. reesei was shown to be an orthologue of pigment-forming PKSs involved in synthesis of aurofusarin and bikaverin in Fusarium spp. In this study, we show that deletion of this gene in T. reesei results in loss of green conidial pigmentation and in pigmentation alteration of teleomorph structures. It also has an impact on conidial cell wall stability and the antagonistic abilities of T. reesei against other fungi, including formation of inhibitory metabolites. In addition, deletion of pks4 significantly influences the expression of other PKS-encoding genes of T. reesei. To our knowledge, this is the first indication that a low-molecular-weight pigment-forming PKS is involved in defense, mechanical stability, and stress resistance in fungi.

Atanasova, Lea↗

A New Method for Production of Titanium Dioxide Pigment - Eliminating CO2 Emission

The objective of this project was to demonstrate the potential of a new process technology to reduce the energy consumption and CO 2 emission from the production of titanium dioxide (TiO 2 ) pigment. TiO 2 is one of the most commonly used minerals in the chemical manufacturing industry. It has been commercially processed as a pigment since the early 1900's, and has a wide variety of domestic and industrial applications. TiO 2 pigment is currently produced primarily by the use of the so called chloride process. A key step of the chloride process relies on high temperature carbo-chlorination of TiO 2 bearing raw materials, hence producing large quantities of CO 2 . The new method uses a chemical/metallurgical sequential extraction methodology to produce pigment grade TiO 2 from high-TiO 2 slag. The specific project objectives were to 1) study and prove the scientific validity of the concept, 2) understand the primary chemical reactions and the efficiency of sequential extraction schemes, 3) determine the properties of TiO 2 produced using the technology, and 4) model the energy consumptions and environmental benefits of the technology.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Vacuum and ultraviolet radiation effects on binders and pigments for spacecraft thermal control coatings

An evaluation of several silicone resin binders and powdered inorganic pigments for potential use in spacecraft thermal-control paint formulations is presented. The pigments were selected on the basis of a hypothesis relating the heat of formation of a compound to the compound's resistance to ultra-radiation-induced degradation. Reflectance measurements were made in situ to determine degradation rates due to ultraviolet radiation. The tested polydimethylsiloxane resins were not significantly affected by long exposures to ultraviolet radiation. All the pigments, which were dispersed in a polydimethylsiloxane resin, were degraded by ultraviolet radiation as determined by an increase of solar absorptance. For the materials evaluated in this study, no evidence was found to indicate that pigments with high heats of formation were resistant to ultraviolet degradation.

Progar, D. J.↗

Phytoplankton pigment concentrations in the Middle Atlantic Bight - Comparison of ship determinations and CZCS estimates

The processing algorithms used for relating the apparent color of the ocean observed with the Coastal-Zone Color Scanner on Nimbus-7 to the concentration of phytoplankton pigments (principally the pigment responsible for photosynthesis, chlorophyll-a) are developed and discussed in detail. These algorithms are applied to the shelf and slope waters of the Middle Atlantic Bight and also to Sargasso Sea waters. In all, four images are examined, and the resulting pigment concentrations are compared to continuous measurements made along ship tracks. The results suggest that over the 0.08-1.5 mg/cu m range, the error in the retrieved pigment concentration is of the order of 30-40% for a variety of atmospheric turbidities. In three direct comparisons between ship-measured and satellite-retrieved values of the water-leaving radiance, the atmospheric correction algorithm retrieved the water-leaving radiance with an average error of about 10%. This atmospheric correction algorithm does not require any surface measurements for its application.

Gordon, H. R.↗

Chlorophyll pigment concentration using spectral curvature algorithms - An evaluation of present and proposed satellite ocean color sensor bands

During the past several years symmetric three-band (460-, 490-, 520-nm) spectral curvature algorithm (SCA) has demonstrated rather accurate determination of chlorophyll pigment concentration using low-altitude airborne ocean color data. It is shown herein that the in-water asymmetric SCA, when applied to certain recently proposed OCI (NOAA-K and SPOT-3) and OCM (ERS-1) satellite ocean color bands, can adequately recover chlorophyll-like pigments. These airborne findings suggest that the proposed new ocean color sensor bands are in general satisfactorily, but not necessarily optimally, positioned to allow space evaluation of the SCA using high-precision atmospherically corrected satellite radiances. The pigment concentration recovery is not as good when existing Coastal Zone Color Scanner bands are used in the SCA. The in-water asymmetric SCA chlorophyll pigment recovery evaluations were performed using (1) airborne laser-induced chlorophyll fluorescence and (2) concurrent passive upwelled radiances. Data from a separate ocean color sensor aboard the aircraft were further used to validate the findings.

Hoge, Frank E.↗

Temperature-plant pigment-optical relations in a recurrent offshore mesoscale eddy near Point Conception, California

The temperature-plant pigment-optical structure of a mesoscale anticyclonic eddy consistently found in shipboard surveys and satellite-sensed data several hundred kilometers southwest of Point Conception, CA, is described on three different time scales (100-day mesoscale, annual, and several-year). The satellite coastal zone color scanner (CZCS) ocean color imagery detected the near-surface chlorophyll structure of the eddy, but in situ optical and plant pigment data suggest that such imagery does not provide a good estimate of the integrated chlorophyll field of the eddy. The temperature and plant pigment boundaries of the eddy, as determined from two-dimensional gradients of advanced very high resolution radiometer (AVHRR) and CZCS imagery, do not coincide spatially. This and in situ temperature, plant pigment, and optical structure provide additional evidence that some eddy systems in the California Current are not isolated vortex systems but rather continuously entrain waters of nonlocal origin laterally into their upper layers. Within the California Current a ratio of AVHRR/CZCS data is useful for separating inshore from oceanic water masses and following their surface entrainment by offshore vortices. The historical 28-year California Cooperative Oceanic Fisheries Investigations data for the Point Conception region of the California Current and remotely sensed data over this region show that the Point Conception eddy is a recurrent feature in the offshore California Current. Moreover, the available data provide evidence that a large number of warm-core mesoscale eddies occur simultaneously in a transition zone between coastal and oceanic regimes, that these features recur at preferred locations within the transition zone, and that this family of eddies should impose a significant offshore boundary condition on the flow of the California Current.

Simpson, James J.↗

Variability of surface pigment concentrations in the South Atlantic Bight

A time sequence of surface pigment images of the South Atlantic Bight (SAB), derived from the Nimbus 7 CZCS for the period between November 1978 and October 1979, was correlated with in situ observations of hydrographic parameters, fresh-water discharge, sea level, coastal winds, and currents in order to couple physical processes and the spatial and temporal variability of the surface pigment fields. A definite seasonal modulation of the surface pigment fields was found, with the concentrations in the Georgia Bight being highest in summer, and those north of Cape Romain highest in winter. This phase difference was found to be the result of variations in wind fields, Gulf Stream-shelf interactions, and fresh-water discharge patterns. At some locations (e.g., near Charleston) the alongshore band of high pigment concentrations increased in width throughout the year; at other locations (near Jacksonville), the alongsore band exhibited a minimum width in the summer and a maximum width in the fall of 1979.

Mcclain, Charles R.↗