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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Tuning the Solvation Structure in Aqueous Zinc Batteries to Maximize Zn-Ion Intercalation and Optimize Dendrite-Free Zinc Plating

Aqueous zinc batteries are recognized to suffer from H + /Zn 2+ coinsertion in the cathode, but few approaches have been reported to suppress deleterious H + intercalation. We realize this goal by tuning the solvation structure, using LiV 2 (PO 4 ) 3 (LVP) as a model cathode. Phase conversion of LVP induced by H + intercalation is observed in 4 m Zn(OTf) 2 , whereas dominant Zn 2+ insertion is confirmed in a ZnCl 2 water-in-salt electrolyte (WiSE). This disparity is ascribed to the complete absence of free water and a strong Zn 2+ –H 2 O interaction in the latter that interrupts the H 2 O hydrogen bonding network, thus suppressing H + intercalation. On the basis of this strategy, a novel PEG-based hybrid electrolyte is designed to replace the corrosive ZnCl2 WiSE. This system exhibits an optimized Zn 2+ solvation sheath with a similar low free water content, showing not only much better suppression of H + intercalation but also highly reversible Zn plating/stripping with a CE of ~99.7% over 150 cycles.

25 ENERGY STORAGE↗
NASA NTRS1972

Theoretical study of corrugated plates: Shear stiffness of a trapezoidally corrugated plate with discrete attachments to a rigid flange at the ends of the corrugations

Analysis and numerical results are presented for the elastic shear stiffness of a corrugated shear web with a certain type of discrete attachments at the ends of the trough lines of the corrugations, namely point attachments to a rigid flange which interferes with the deformations of the end cross sections by preventing downward movement but permitting upward (lifting off) movement. The analysis is based on certain assumed modes of deformation of the cross sections in conjunction with the method of minimum total potential energy and the calculus of variations in order to obtain equations for the manner in which the assumed modes of deformation vary along the length of the corrugation. The numerical results are restricted to the case of equal-width crests and troughs but otherwise apply to a wide variety of geometries. They are in the form of graphs which give the overall shear stiffness as a fraction of the overall shear stiffness that could be obtained by having continuous attachment at the ends of the corrugations.

Hsiao, C.↗
NASA NTRS1989

The interpretation of crustal dynamics data in terms of plate motions and regional deformation near plate boundaries

A particularly detailed set of observations in the vicinity of an intraplate, thrust earthquake (M 7.4) in Argentina, indicate a cyclic pattern of deformation very similar to that reported previously for interplate earthquakes. This deformation cycle, which may be characteristic of many seismically active areas, consists of: (1) steady strain accumulation, possibly punctuated by strain reversals; (2) coseismic strain release; (3) a period of continued strain release due to afterslip (persisting for perhaps a year or so); and (4) rapid postseismic strain accumulation which decreases exponentially and grades into steady strain accumulation. Deformation associated with three earthquakes in the U.S. (1940, M7.1 Imperial Valley California; 1964, M8.4 Alaska; 1959, M7.5 Hebgen Lake, Montana) are interpreted in light of this general earthquake cycle and are used to investigate the mechanics of strain release for these events. These examples indicate that large postseismic movements can occur for strike-slip, thrust, and normal fault events, and both viscoelastic relaxation and postseismic after-slip must be incorporated in models of earthquake related deformation. The mechanics of the strain release process revealed by these examples has implications for estimating earthquake repeat times from geodetic observations near active faults.

Solomon, Sean C.↗
NASA NTRS1990

Crustal dynamics project: The interpretation of crustal dynamics data in terms of plate motions and regional deformation near plate boundaries

The focus of the research was in two broad areas: (1) the nature and dynamics of time-dependent deformation and stress along major seismic zones, and (2) the nature of long-wavelength oceanic geoid anomalies in terms of lateral variations in upper mantle temperature and composition. The principal findings are described in the appendices.

Solomon, Sean C.↗
NASA NTRS1991

The interpretation of crustal dynamics data in terms of plate motions and regional deformation near plate boundaries

The focus of the research was in two broad areas: (1) the nature and dynamics of time dependent deformation and stress along major seismic zones; and (2) the nature of long wavelength oceanic geoid anomalies in terms of lateral variations in upper mantle temperature and composition. The principle findings of the research are described in the accompanying appendices. The first two and the fourth appendices are reprints of papers recently submitted for publication, and the third is the abstract of a recently completed thesis supported by this project.

Soloman, Sean C.↗
NASA NTRS1991

The interpretation of crustal dynamics data in terms of plate motions and regional deformation near plate boundaries

The focus was in two broad areas during the most recent 6-month period: (1) the nature and dynamics of time dependent deformation and stress along major seismic zones; and (2) the nature of long-wavelength oceanic geoid anomalies in terms of lateral variations in upper mantle temperature and composition. The principle findings are described in the accompanying appendices.

Soloman, Sean C.↗
NASA NTRS1993

A note on the distortion of a flat-plate boundary layer by free-stream vorticity normal to the plate

The purpose of this note is to construct a local solution that eliminates a residual velocity discontinuity in the inviscid portion of a solution obtained in a recent paper by Goldstein, Leib and Cowley (1992). This result is of importance because it shows that the solution obtained in that paper is entirely non-singular outside the viscous wall boundary layer and that any singularity in the problem will have to arise in the usual way through a breakdown in the viscous boundary layer.

Goldstein, M. E.↗
NASA NTRS1999

Receptivity of Flat-Plate Boundary Layer in a Non-Uniform Free Stream (Vorticity Normal to the Plate)

Experimental and theoretical studies of low speed leading edge boundary layer receptivity to free-stream vorticity produced by upstream wires normal to the leading edge are discussed. Data include parametric variations in leading edge configuration and details of the incident disturbance field including single and multiple wakes. The induced disturbance amplitude increases with increases in the leading edge diameter and wake interactions. Measurements agree with the theory of M. E. Goldstein.

Kogan, M. N.↗
NASA NTRS1986

Plate motion controls on back-arc spreading

The motions of the subducting and the overriding plates influence the spatial and temporal distribution of back-arc spreading. Cenozoic plate motions in hot spot-fixed and no-net-rotation reference frames were studied with attention to correlations between changes in motion and episodes of back-arc spreading in the western Pacific. The results suggest that major back-arc opening occurs when both the overriding plate retreats from the trench in an absolute sense and the subducting plate undergoes a significant speed-up. Neither phenomenon alone is sufficient to initiate spreading. Three major plate velocity increases can be identified in the Cenozoic: (1) the Pacific plate 5-9 Ma; (2) the Indian plate at 27 Ma; and (3) the Pacific plate at 43 Ma, due to its shift from northerly to more westerly motion. At the present time, the Indian and Philippine are the only overriding plates that are retreating from their Pacific trenches and back-arc spreading occurs only on these two retreating plates. Although the Indian plate has been retreating for at least 25 Ma, back-arc spreading began only following the Pacific plate speed-up 5-9 Ma. Earlier, during the Indian plate speed-up, no overriding plates were retreating strongly and no back-arc spreading epsiodes are preserved from this time. For the earliest Pacific plate shift at 43 Ma, the Eurasian plate was not advancing, thus creating the only favorable plate kinematic conditions in the Cenozoic for back-arc basin formation in this region. It is unclear whether extension in the Japan Sea is a result of these conditions.

Fein, J. B.↗