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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Species Separation and Hydrogen Streaming upon Shock Release from Polystyrene under Inertial Confinement Fusion Conditions

Shock release from inertial confinement fusion (ICF) shells poses a great challenge to single-fluid hydrodynamic equations, especially for describing materials composed of different ion species. This has been evidenced by a recent experiment [Haberberger et al., Phys. Rev. Lett. 123, 235001 (2019)], in which low-density plasmas ( 10 19 to 10 20 cm – 3 ) are measured to move far ahead of what radiation-hydrodynamic simulations predict. To understand such experimental observations, in this work we have performed large-scale nonequilibrium molecular-dynamics simulations of shock release in polystyrene (CH) at experimental conditions. These simulations revealed that upon shock releasing from the back surface of a CH foil, hydrogen can stream out of the bulk of the foil due to its mass being lighter than carbon. This released hydrogen, exhibiting a much broader velocity distribution than carbon, forms low-density plasmas moving in nearly constant velocities ahead of the in-flight shell, which is in quantitative agreement with the experimental measurements. Such kinetic effect of species separation is currently missing in single-fluid radiation-hydrodynamics codes for ICF simulations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Atmospheric pressure plasma functionalization of polystyrene

Atmospheric pressure plasma jets (APPJs) are used to improve the adhesive and hydrophilic properties of commodity hydrocarbon polymers such as polypropylene, polyethylene, and polystyrene (PS). These improvements largely result from adding oxygen functional groups to the surface. PS functionalization is of interest to produce high value biocompatible well-plates and dishes, which require precise control over surface properties. In this paper, we discuss results from a computational investigation of APPJ functionalization of PS surfaces using He/O 2 /H 2 O gas mixtures. A newly developed surface reaction mechanism for functionalization of PS upon exposure to these plasmas is discussed. A global plasma model operated in plug-flow mode was used to predict plasma-produced species fluxes onto the PS surface. A surface site balance model was used to predict oxygen-functionalization of the PS following exposure to the plasma and ambient air. We found that O-occupancy on the surface strongly correlates with the O-atom flux to the PS, with alcohol groups and cross-linked products making the largest contributors to total oxygen fraction. Free radical sites, such as alkoxy and peroxy, are quickly consumed in the post-plasma exposure to air through passivation and cross-linking. O-atom fluences approaching 10 17 cm -2 saturate the O-occupancy on the PS surface, creating functionality that is not particularly sensitive to moderate changes in operating conditions.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Solid-state laser refrigeration of core-shell polystyrene microspheres

Microlaser designs based on the coupling of whispering gallery modes (WGMs) with the upconversion processes which take place within lanthanide-doped nanoparticles (UCNPs) have been demonstrated and shown to have many valuable qualities, such as high Q factors and low lasing thresholds. One obstacle that these microlaser designs still face is the challenges caused by photothermal heating of the gain medium, which could be solved through the design of a radiation balanced microlaser. In this work, WGM microresonators composed of 5 µm diameter polystyrene spheres are fabricated with a layer of Yb3+-doped NaYF4 UCNPs in order to test if the anti-Stokes cooling properties of the UCNPs can cool the microresonator and its environment under laser irradiation. We find via calibrated mean fluorescence spectroscopy that the UCNPs can cool their local environment by as much as 23 °C and significantly reduce the heating of the aqueous environment surrounding the microresonator, showing promise for inclusion in a design for a radiation balanced microlaser.

whispering gallery modes, optical refrigeration, m↗
DOE OSTI2023

Explicit solvent machine-learned coarse-grained model of sodium polystyrene sulfonate to capture polymer structure and dynamics

In this article, strongly charged polyelectrolytes (PEs) demonstrate complex solution behavior as a function of chain length, concentrations, and ionic strength. The viscosity behavior is important to understand and is a core quantity for many applications, but aspects remain a challenge. Molecular dynamics simulations using implicit solvent coarse-grained (CG) models successfully reproduce structure, but are often inappropriate for calculating viscosities. To address the need for CG models which reproduce viscoelastic properties of one of the most studied PEs, sodium polystyrene sulfonate (NaPSS), we report our recent efforts in using Bayesian optimization to develop CG models of NaPSS which capture both polymer structure and dynamics in aqueous solutions with explicit solvent. We demonstrate that our explicit solvent CG NaPSS model with the ML-BOP water model [Chan et al. Nat Commun 10, 379 (2019)] quantitatively reproduces NaPSS chain statistics and solution structure. The new explicit solvent CG model is benchmarked against diffusivities from atomistic simulations and experimental specific viscosities for short chains. We also show that our Bayesian-optimized CG model is transferable to larger chain lengths across a range of concentrations. Overall, this work provides a machine-learned model to probe the structural, dynamic, and rheological properties of polyelectrolytes such as NaPSS and aids in the design of novel, strongly charged polymers with tunable structural and viscoelastic properties

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS1967

Method accurately measures mean particle diameters of monodisperse polystyrene latexes

Photomicrographic method determines mean particle diameters of monodisperse polystyrene latexes. Many diameters are measured simultaneously by measuring row lengths of particles in a triangular array at a glass-oil interface. The method provides size standards for electronic particle counters and prevents distortions, softening, and flattening.

Kubitschek, H. E.↗
NASA NTRS1967

Polystyrene cryostat facilitates testing tensile specimens under liquid nitrogen

Lightweight cryostat made of expanded polystyrene reduces eccentricity in a tensile system being tested under liquid nitrogen. The cryostat is attached directly to the tensile system by a special seal, reducing misalignment effects due to cryostat weight, and facilitates viewing and loading of the specimens.

Shogan, R. P.↗
NASA NTRS1975

A flame-resistant modified polystyrene

Several modified polystyrenes have been developed that are self-extinguishing in air. Information is included in report that also describes molding and fabrication properties, toxicology, and thermal behavior of the polymers.

Karle, D. W.↗
NASA NTRS1983

Fluorescence from polystyrene - Photochemical processes in polymeric systems, 7

Results are presented for measurements of the fluorescence spectra of polystyrene in dilute solution and in pure solid films. It is determined that a major potential source of experimental error is the concurrent photooxidative degradation in air which may obscure fluorescence emission from monomeric sites in solid films at 25 C. The fluorescence spectra of oriented films are evaluated in terms of the monomer to excimer fluorescence intensity ratio and the excimer 'red shift'. The monomer to excimer fluorescence intensity ratio is determined to be significantly higher in fluid solution than in solid film.

Gupta, M. C.↗
NASA NTRS1983

Evaluation of the Separability of Monodisperse Polystyrene Latex Microspheres in a Continuous Flow Electrophoresis System

The continuous flow electrophoresis system makes electrophoresis possible in a free flowing film of aqueous electrolyte medium. The sample is introduced at one end of the chamber and is subjected to a lateral dc field. This process separates the sample into fractions since each component has a distinctive electrophoric mobility. Evaluations were made of sample conductivity and buffer conductivity as they affect sample band spread and separation using the Continuous Particle Electrophoresis (CPE) system. Samples were prepared from mixtures of 5 percent and 1 percent polystyrene latex (PSL) microspheres which were .4, .56 and .7 microns in diameter. These were prepared in electrolyte media 1x and 3x the conductivity of the curtain buffer, approximately 150 and 450 micro mhos/cm. Samples with matched conductivities produced greater resolution and less band spread than those with 3x the conductivity of the curtain buffer.

Williams, G., Jr.↗
NASA NTRS1983

Theoretical study of the freezing of polystyrene sphere suspensions

A theoretical study of melting in aqueous suspensions of polystyrene spheres is presented. The Helmholtz free energies of the liquid and solid phase of the suspensions are calculated as functions of sphere number density and electrolyte concentrations. The results tend to show that the freezing curve of such suspensions is that of a conventional classical liquid with repulsive short-range interactions. The interactions can be treated satisfactorily within a slightly modified Debye-Hueckel approximation. The modifications include size correction and a correction for nonlinear screening. The results are confirmed by analogous calculations for the solid phase, and for the line along which liquid and solid free energies are equal.

Shih, W.-H.↗
NASA NTRS1984

Theoretical study of miscibility and glass-forming trends in mixtures of polystyrene spheres

A theoretical study of glass-forming trends and miscibility in mixtures of polystyrene spheres (polyballs) of different diameters, suspended in an aqueous solution, is presented. The polyballs are assumed to be charged and to interact via a Debye-Hueckel screened Coulomb potential. The Helmholtz free energy is calculated from a variational principle based on the Gibbs-Bogoliubov inequality, in which a mixture of hard spheres of different diameters is chosen as the reference system. It is found that when the charges of the two types of polyballs are sufficiently different, the variationally determined ratio of hard-sphere diameters differs substantially, leading to packing difficulties characteristic of glass formation. The experimentally observed range of glass formation corresponds to a ratio of hard-sphere diameters of 0.8 or less. Calculations of the free energy as a function of concentration indicate that the liquid polyball mixture is stable against the phase separation, even for widely different polyball charges.

Shih, W.-H.↗
NASA NTRS1985

Polyvinyl alcohol coating of polystyrene inertial confinement fusion targets

An inertial confinement fusion (ICF) target made of polystyrene is first levitated in an acoustic field. The surface of the target is then etched using an appropriate solution (e.g., cyclohexane) to enhance the wetting characteristics. A specially prepared polyvinyl alcohol solution is atomized using an acoustic atomizer and deposited on the surface of the target. The solution is air dried to form a thin coating (2 microns) on the target (outside diameter of about 350-850 microns). Thicker coatings are obtained by repeated applications of the coating solutions. Preliminary results indicate that uniform coatings may be achievable on the targets with a background surface smoothness in the order of 1000 A.

Annamalai, P.↗
NASA NTRS1985

Seeding subsonic, transonic and supersonic flows with 0.5 micron polystyrene spheres

Polystyrene latex particles have been successfully used as laser velocimetry seed material for flows in the Ames High Reynolds Channels (HR) 1 and 2, the pilot channel, and the one-foot low speed tunnel. These facilities provide test flows with Mach numbers from 0.1 to 3.0 and test section sizes from 4 inches by 6 inches to 18 inches by 24 inches. Tunnel mass flow in the HR-2 channel can approach 1000 lb/sec. The latex particles have the following favorable characteristics: size of 0.35 to 0.55 microns diameter; spherical shape; specific gravity of 1.05; excellent flow trackability; low toxicity; and low cost. they have the disadvantage of being packaged as an aqueous suspension which must be diluted and introduced into the test flow as an atomized mist. This must occur sufficiently far upstream of the test section to minimize flow disturbances and permit the liquid mist to evaporate before reaching the model. Several techniques which have been developed to accomplish satisfactory seeding will be described.

Seegmiller, H. L.↗
NASA NTRS1986

Polystyrene latex separations by continuous flow electrophoresis on the Space Shuttle

The seventh mission of the Space Shuttle carried two NASA experiments in the McDonnell Douglas Astronautics Corporation continuous flow electrophoresis system. The objectives were to test the operation of continuous flow electrophoresis in a reduced gravity environment using stable particles with established electrokinetic properties and specifically to evaluate the influence of the electrical properties of the sample constituents on the resolution of the continuous flow electrophoretic device. Polystrene latex microspheres dispersed in a solution with three times the electrical conductivity of the curtain buffer separated with a significantly larger band spread compared to the second experiment under matched conductivity conditions. It is proposed that the sample of higher electrical conductivity distorted the electric field near the sample stream so that the polystyrene latex particles migrated toward the chamber walls where electroosmosis retarded and spread the sample.

Snyder, R. S.↗