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At least 73 records · Page 4

Fe 3+ /Fe T ratios of amphiboles determined by high spatial resolution single-crystal synchrotron Mössbauer spectroscopy

The Fe 3+ /Fe T ratios (Fe 3+ /[Fe 2+ +Fe 3+ ]) in minerals can be used to understand their crystallization and post-crystallization conditions. However, as natural minerals are often zoned and contain inclusions, bulk techniques, e.g., wet chemistry, may not provide accurate Fe 3+ /Fe T values for a single phase of interest. We determined Fe 3+ /Fe T ratios of amphiboles in different crystallographic orientations by single-crystal synchrotron Mössbauer spectroscopy (SMS) in energy and time domain modes from four volcanic localities (Long Valley Caldera, Mount St. Helens, Lassen Volcanic Center, U.S.A., and Mt. Pinatubo, Philippines). The high spatial resolution (as low as 12 × 12 μm spot size) and standard-free nature of SMS allow the detection of intra-grain compositional heterogeneities in Fe 3+ /Fe T with relatively low uncertainties. Here, we combine SMS with major element compositions, water contents, and hydrogen isotope compositions to document the Fe 3+ /Fe T ratios as a function of mineral composition and post-crystallization dehydrogenation. Spectra were fitted with up to five distinct sites: ferrous iron on M(1), M(2), M(3), and ferric iron on M(2) and M(3), consistent with X-ray diffraction studies on single crystals of amphibole. The Fe 3+ /Fe T ratios range from 0.14 ± 0.03 (Long Valley Caldera), 0.51 to 0.63 ± 0.02 (representing intra-grain heterogeneities, Mount St. Helens) to 0.86 ± 0.03 (Lassen Volcanic Center). The latter grain experienced post-crystallization dehydrogenation, shown by its low water content (0.6 ± 0.05 wt%) and its elevated hydrogen isotope composition (δD = +25 ± 3‰ relative to SMOW). The Fe 3+ /Fe T ratios of 0.62 ± 0.01 and 0.20 ± 0.01 of two Mt. Pinatubo grains correlate with high-Al 2 O 3 cores and low-Al 2 O 3 rims and smaller phenocrysts in the sample, respectively. This study shows that SMS is capable of distinguishing two different domains with dissimilar Fe 3+ /Fe T values formed under different crystallization conditions, demonstrating that SMS in combination with major element, water, and hydrogen isotope compositions allows the interpretation of amphibole Fe 3+ /Fe T ratios in the context of crystallization and post-crystallization processes.

47 OTHER INSTRUMENTATION↗

High-pressure electrical conductivity and elasticity of iron-bearing δ-AlOOH

Abstract The electrical conductivity and elasticity of deep hydrous phases are essential to constraining water distribution, as well as deciphering the origins of conductivity anomalies in the lower mantle. To uncover the impact of iron-bearing δ-AlOOH on the geophysical properties of the lower mantle, we carried out synchrotron X-ray diffraction and electrical conductivity measurements on δ-(Al0.52Fe0.48)OOH and (Al0.95Fe0.05)OOH in diamond-anvil cells at pressures up to 75 GPa at room temperature. A sharp volume reduction of ~6.5% was observed in δ-(Al0.52Fe0.48)OOH across the spin transition at 40.8–43.3 GPa, where its electrical conductivity increases steadily without abrupt changes. The electrical conductivity of δ-(Al0.52Fe0.48)OOH is greater than that of pure δ-AlOOH at high pressure, suggesting that both small polaron and proton conduction mechanisms dominate in iron-bearing δ-AlOOH. Furthermore, the high-pressure electrical conductivity profiles are comparable between δ-(Al0.95Fe0.05)OOH and δ-(Al0.52Fe0.48)OOH, indicating that high-iron content only marginally influences the conductivity of iron-bearing δ-AlOOH. Notably, the electrical conductivity of iron-bearing δ-AlOOH along the North Philippine geotherm is greater than the average 1D electrical conductivity profile in the mantle (Ohta et al. 2010a). This result suggests that δ-(Al,Fe)OOH is a promising candidate to account for high conductivity in some subducting slabs.

Geochemistry & Geophysics↗

Effectiveness of Electric Vehicle Policies and Implications for Pakistan

This report explores evidence from several key countries regarding the impacts to electric vehicle (EV) market penetration from financial incentives, road access policies, EV mandates, fuel taxes, discounted electricity rates, charging infrastructure, and government investment in the domestic automotive industry. It reviews EV promotional policies in countries that have demonstrated success deploying EVs, focusing on Norway, China, the United States, India, and Korea. It also provides anecdotal examples from select ASEAN countries trying to promote domestic auto industry EV activity, such as Thailand, Indonesia, Philippines, and Vietnam. It provides applicability to policy efforts for growing the EV industry in Pakistan.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

CLimate Impact: Determining Etiology thRough pAthways (CLDERA)

Climate impacts have broad economic, health, political, and national security ramifications. Societally relevant impacts are typically farther downstream, are the product of multiple interacting processes, and can arise over small regions and timeframes because their sources are short-term and localized. Short-term forcings (as can be seen in volcanic eruptions, climatic tipping points (e.g., the collapse of rainforests or the disappearance of sea ice), or in increasingly plausible climate interventions) fundamentally possess low signal-to-noise and could benefit from accounting for the multiple conditional processes through which a downstream impact arises. Under the Grand Challenge LDRD CLDERA (CLimate impacts: Discovering Etiology thRough pAthways), we have developed tools to enable downstream impact attribution from geographically and temporally localized source forcings in the climate. CLDERA developed methods that can distinguish how a localized source drives the climate system to respond with particular impacts. The how is embodied in pathways – the spatio-temporally evolving chain of physical processes that connects a source to a series of increasingly distant impacts. Novel analytic methods in pursuit of downstream impact attribution were developed and demonstrated on simulations and observations of the 1991 eruption of Mt. Pinatubo in the Philippines. As described within this report we have • developed stratospheric expertise and aerosol modeling capabilities in E3SM, • created original methods to detect and model pathways from source-to-impact, and • advanced climate attribution through novel methods, cases, and approaches. Further, CLDERA developed a tiered verification process consisting of controlled datasets to prototype, verify, and refine the original method development. CLDERA increased Sandia’s footprint in the climate analytics community and developed new climate collaborations whilst also creating a cadre of climate analysts at Sandia. The products from CLDERA have been extensive with a total of 9 journal articles published, 12 articles submitted and under review, and an additional 8 articles in preparation. We have produced 1750 simulated years and developed 9 code-bases. This report details these accomplishments and serves as a summary of the work completed during the CLDERA Grand Challenge.

54 ENVIRONMENTAL SCIENCES↗

Enhancing Power Resilience for Remote Communities: A Comprehensive Renewable Energy Solution for Itbayat Island

The island of Itbayat, Philippines, faces significant challenges in maintaining a reliable and resilient power supply due to its current reliance on a vulnerable power distribution system managed by a local electric cooperative. The existing infrastructure, which includes diesel generators and a radial network configuration with some above-ground lines, is highly susceptible to frequent typhoons and adverse weather conditions. These factors, combined with inadequate staffing and high operational costs, result in frequent power outages that disrupt daily life and hinder economic development. This white paper proposes a comprehensive solution to enhance the resilience and reliability of Itbayat's power system by integrating renewable energy sources, specifically solar photovoltaic (PV) systems, battery storage, and a microgrid controller. The proposed solution aims to reduce dependency on diesel fuel, optimize energy use, and provide a sustainable and robust power supply for the island. Key components of the solution include: 1. Solar PV Installation: Deploying solar PV panels to harness abundant solar energy, reducing reliance on diesel fuel. 2. Battery Storage Systems: Installing battery storage to store excess solar energy and ensure a continuous power supply during low solar generation periods. 3. Microgrid Controller: Implementing a microgrid controller to manage and optimize the integration of solar PV, battery storage, and existing diesel generators. The proposed solution addresses several critical issues, including system vulnerability, generator dependency, and operational inefficiencies. By adopting this innovative approach, Itbayat Island can achieve a more resilient, efficient, and sustainable energy infrastructure, ensuring a stable power supply for its residents and enhancing overall energy security.

14 SOLAR ENERGY↗

Warm-phase microphysical evolution in large-eddy simulations of tropical cumulus congestus: evaluating drop size distribution evolution using polarimetry retrievals, in situ measurements, and a thermal-based framework

Owing to uncertainties in convective microphysics processes, improving parameterizations in Earth system models (ESMs) can benefit from observationally constrained cases suitable for scaling between cloud-resolving models and ESMs. We propose a benchmark large-eddy simulation (LES) cumulus congestus case study from the NASA Cloud, Aerosol, and Monsoon Processes Philippines Experiment (CAMP 2 Ex) for evaluating and improving ESMs in single-column model (SCM) mode. We seek observational constraints using novel polarimetric retrievals and in situ cloud microphysics measurements. Simulations using bulk and bin microphysics initialized with observed aerosol profiles are compared to cloud-top retrievals of cloud droplet effective radius (R eff ), effective variance (ν eff ), and number concentration (N d ) from the airborne Research Scanning Polarimeter (RSP). Both schemes reproduce characteristics of cloud-top N d and R eff that increase and decrease with altitude, respectively. Cloud-top N d is low-biased relative to RSP retrievals in both schemes, potentially due to limitations in both simulations and retrieval assumptions. Cloud-top R eff is low-biased in the bulk scheme but reasonably reproduced by the bin scheme. Profiles of N d and R eff are sensitive to the collision–coalescence process and the vertical variation in aerosol size distribution. Comparison of simulated and in situ droplet size distributions (DSDs) shows that, to first order, integrated moments are always sensitive to sizes < ~ 30 µm and can also be sensitive to larger sizes if the DSDs are sufficiently broad, with implications for the assumed maximum observed size retrieved by the RSP. The bin scheme captures the observed extended tail of the DSD, while the bulk scheme is unable to due to parametric constraints. Differences in expected relationships between in situ measurements of cloud cores and cloud-top retrievals by RSP demonstrate difficulty in constraining well the case presented herein. Finally, a thermal-tracking framework demonstrates that the dilution of N d throughout a thermal's lifetime is heavily determined by collision–coalescence and the height-varying aerosol distribution and that, in the absence of these, the impact of entrainment on diluting N d is largely offset by secondary activation. Implications for evaluating warm-phase convective microphysics schemes in ESMs and translating results for use on global, space-based polarimetry platforms are discussed.

Stanford, McKenna Wallace [Columbia Univ., New Yor↗

The equatorial electrojet satellite and surface comparison

The OGO 4 and 6 (POGO) magnetic field results for the equatorial electrojet indicate that while the present models are approximately correct, the possibility of a westward component must be incorporated. The scatter diagrams of POGO amplitudes and surface data show a correlation. The ratios between the amplitudes estimated from surface data and those at 400 km altitude are as follows: India 5 to 8, East Africa (Addis Ababa) 4, Central Africa 3, West Africa (Nigeria) 3, South America (Huancayo) 5, and Philippines 5. The variation in the ratio is due to the conductivity structure of the earth in various zones.

Cain, J. C.↗

Engineering analysis of ERTS data for southeast Asian agriculture

The present program focuses on rice because of its importance world-wide as a food. Specifically, the focus is on rice fields in the Philippines. Two primary program objectives are: (1) to establish the feasibility of extracting from ERTS imagery the areas where rice is grown, and (2) to determine those measurements on the imagery which enable the assessment of crop condition. Achieving these objectives with procedures which can be cost-effective can lead the way toward yield prediction, irrigation system management, and similar functions which are known to be important needs in Southeast Asia.

Heydt, H. L.↗

A model of convergent plate margins based on the recent tectonics of Shikoku, Japan

A viscoelastic finite element plate tectonic model is applied to displacement data for the island of Shikoku, Japan. The flow properties and geometry of the upper portions of the earth are assumed known from geophysical evidence, and the loading characteristics are determined from the model. The nature of the forces acting on the Philippine Sea plate, particularly in the vicinity of the Nankai trough, is determined. Seismic displacement data related to the 1946 Nankaido earthquake are modeled in terms of a thick elastic plate overlying a fluidlike substratum. The sequence of preseismic and seismic displacements can be explained in terms of two independent processes operating on elastic lithospheric plates: a strain accumulation process caused by vertical downward forces acting on or within the lithosphere in the vicinity of the trench, and a strain release process caused by plate failure along a preexisting zone on weakness. This is a restatement of Reid's elastic rebound theory in terms of elastic lithospheric plates.

Bischke, R. E.↗

Utilization of LANDSAT imagery for mapping vegetation on the millionth scale

A series of test sites were examined to determine if the information content of the LANDSAT imagery that may be obtained of these sites is sufficient to permit their mapping according to the vegetation classification system recently published by Unesco. These sites include examples from the humid tropics, arid and semi-arid subtropics and temperature zones: Western Highlands of Papua New Guinea, Mindoro Island in the Philippines, Great Smoky Mountains of the southeastern United States, East Tennessee Valley, interior of Western Australia, northeastern Uganda, and south-central Kansas. The results of the experiment were presented in the form of vegetation maps and annotated images which serve to illustrate the detectability of various formations. It was concluded that, for the test sites examined, the formations of the Unesco vegetation classification can be satisfactorily distinguished on LANDSAT MSS images, especially when used as color composites and judiciously chosen as to season.

Williams, D. L.↗

Engineering analysis of LANDSAT 1 data for Southeast Asian agriculture

The author has identified the following significant results. LANDSAT spatial resolution was estimated to be adequate, but barely so, for the purpose of detailed assessment of rice or site status. This was due to the spatially fine grain, heterogenous nature of most rice areas. Use of two spectral bands of digital data (MSS 5 and MSS 6 or 7) appeared to be adequate for site recognition and gross site status assessment. Spectral/temporal signatures were found to be more powerful than spectra signatures alone and virtually essential for most analyses of rice growth and rice sites in the Philippine environment. Two band, two date signatures were estimated to be adequate for most purposes, although good results were achieved using one band two- or four-date signatures. A radiometric resolution of 64 levels in each band was found adequate for the analyses of LANDSAT digital data for site recognition and gross site or rice growth assessment.

Mcnair, A. J.↗

Applications of LANDSAT data to the integrated economic development of Mindoro, Phillipines

LANDSAT data is seen as providing essential up-to-date resource information for the planning process. LANDSAT data of Mindoro Island in the Philippines was processed to provide thematic maps showing patterns of agriculture, forest cover, terrain, wetlands and water turbidity. A hybrid approach using both supervised and unsupervised classification techniques resulted in 30 different scene classes which were subsequently color-coded and mapped at a scale of 1:250,000. In addition, intensive image analysis is being carried out in evaluating the images. The images, maps, and aerial statistics are being used to provide data to seven technical departments in planning the economic development of Mindoro. Multispectral aircraft imagery was collected to compliment the application of LANDSAT data and validate the classification results.

Wagner, T. W.↗

The behavior of a convergent plate boundary - Crustal deformation in the South Kanto district, Japan

The northwesternmost part of the Sagami trough, a part of the Philippine Sea-Eurasian plate boundary, was ruptured during the great South Kanto earthquake in 1923. Very extensive and frequent geodetic measurements of crustal deformation have been made in the South Kanto district since the 1890's, and these constitute the most complete data set on crustal movements in the world. These data were reanalyzed and interpreted and according to our interpretation indicate the following sequence of events. The coseismic movements were due to oblique thrust and right lateral slip of about 8 m on a fault outcropping at the base of the Sagami trough. This was followed by postseismic deformation resulting from reversed afterslip of 20-60 cm that occurred at an exponentially decaying rate in time. The interseismic deformation is produced by steady subduction at a rate of about 1.8 cm/yr. During subduction the top 10-15 km of the plate boundary is apparently locked, while deeper parts slip aseismically at an irregular rate. No significant precursory deformation was observed. The recurrence time for 1923 type earthquakes is 200-300 years. The Boso and Miura peninsulas are broken into a series of fault-bound blocks that move semi-independently of the surrounding region. The subduction zone itself, where it is exposed on land, is shown to be a wide zone encompassing several faults that are active at different times.

Scholz, C. H.↗

Typhoon June /1975/ viewed by a scanning microwave spectrometer

Data were collected by the scanning microwave spectrometer onboard Nimbus 6 during the June 1975 typhoon in the Philippine Sea. The spectrometer was equipped with channels centered on 22.23 GHz (a water vapor band), 31.65 GHz (a transmittance window), and 52.85, 53.85, and 55.45 GHz (an oxygen band). Temperature maps, derived from oxygen band measurements, showed that the typhoon eye had a single peak varying in amplitude with time. Water line and window measurements were used to develop a coordinate system having mutually orthogonal atmospheric variables of column water-vapor content and cloud liquid-water content. Vapor measurements showed a maximum around the intensifying typhoon with a more developed structure during typhoon development. Values were extrapolated for surface wind speed and cloud liquid water vapor content by assuming the troposphere to be saturated with respect to the water vapor in the typhoon. Comparisons with infrared cloud imagery and aircraft flight data show different time variations, attributed to poor typhoon-eye resolution in the microwave images.

Rosenkranz, P. W.↗

Gravity anomaly and geoid undulation results in local areas from GEOS-3 altimeter data

The adjusted GEOS-3 altimeter data, taken as averages within a data frame, have been used to construct free air anomaly and geoid undulation profiles and maps in areas of geophysical interest. Profiles were constructed across the Philippine Trench (at a latitude of 6 deg) and across the Bonin Trench (at a latitude of 28 deg). In the latter case an anomaly variation of 443 mgals in 143 km was derived from the altimeter data. These variations agreed reasonably with terrestrial estimates, considering the predicted point accuracy was about + or - 27 mgals. An area over the Patton Sea mounts was also investigated with the altimeter anomaly field agreeing well with the terrestrial data except for the point directly over the top of the sea mount. It is concluded that the GEOS-3 altimeter data is valuable not only for determining 5 deg and 1 deg x 1 deg mean anomalies, but also can be used to describe more local anomaly variations.

Rapp, R. H.↗

Applications of SLAR in nuclear power plant siting: A case history

Over 10,000 square km of side-looking airborne radar (SLAR) imagery was obtained and analyzed for the siting of the first nuclear power plant in the Republic of the Philippines. The imagery was obtained using the Motorola APS/AN-94D (X-band) real aperture system as part of an overall remote sensing program to site and evaluate potential site regions. Analysis of SLAR images, in conjunction with LANDSAT, color, black and white, and thermal infrared images, provided basic information on structure, relative geochronology, stratigraphy, geomorphology, and ground water, which facilitated field operations and data synthesis.

Siegal, B. S.↗

Landsat analysis of tropical forest succession employing a terrain model

Landsat multispectral scanner (MSS) data have yielded a dual classification of rain forest and shadow in an analysis of a semi-deciduous forest on Mindonoro Island, Philippines. Both a spatial terrain model, using a fifth side polynomial trend surface analysis for quantitatively estimating the general spatial variation in the data set, and a spectral terrain model, based on the MSS data, have been set up. A discriminant analysis, using both sets of data, has suggested that shadowing effects may be due primarily to local variations in the spectral regions and can therefore be compensated for through the decomposition of the spatial variation in both elevation and MSS data.

Barringer, T. H.↗