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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

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NASA NTRS1983

Fire resistant films for aircraft applications

Alternative sandwich panel decorative films were investigated as replacements for the polyvinyl fluoride currently used in aircraft interiors. Candidate films were studied for flammability, smoke emission, toxic gas emission, flame spread, and suitability as a printing surface for the decorative acrylic ink system. Several of the candidate films tested were flame modified polyvinyl fluoride, polyvinylidene fluoride, polyimide, polyamide, polysulfone, polyphenylsulfone, polyethersulfone, polybenzimidazole, polycarbonate, polyparabanic acid, polyphosphazene, polyetheretherketon, and polyester. The films were evaluated as pure films only, films silk-screened with an acrylic ink, and films adhered to a phenolic fiberglass substrate. Films which exhibited the highest fire resistant properties included PEEK polyetheretherketon, Aramid polyamide, and ISO-BPE polyester.

Kourtides, D. A.↗

NASA NTRS1983

Evaluation of high temperature structural adhesives for extended service

The preliminary evaluation of crosslinked polyphenyl quinoxaline (X-PPQ), LARC-TPI, ethyl terminated polysulfone (ETPS), and crosslinked polyimide (X-PI) as adhesives is presented. Lap shear strength stability under thermal, combined thermal/humidity, and stressed and unstressed Skydrol exposure was determined. The X-PPQ, LARC-TPI, and X-PI exhibited good adhesive performance at 505K (450 F) after 1000 hours at 505K. These three polymers also performed well after exposure to combined elevated temperature/high humidity, as well as, to Skydrol while under stress. The ETPS exhibited good ambient temperature adhesive properties, but performed poorly under all other exposure conditions, presumably due to inadequate chain extension and crosslinking.

Hill, S. G.↗

NASA NTRS1982

Testing and failure analysis to improve screening techniques for hermetically sealed metallized film capacitors for low energy applications

Effective screening techniques are evaluated for detecting insulation resistance degradation and failure in hermetically sealed metallized film capacitors used in applications where low capacitor voltage and energy levels are common to the circuitry. A special test and monitoring system capable of rapidly scanning all test capacitors and recording faults and/or failures is examined. Tests include temperature cycling and storage as well as low, medium, and high voltage life tests. Polysulfone film capacitors are more heat stable and reliable than polycarbonate film units.

Source record↗

NASA NTRS1983

Fire resistant films for aircraft applications

Kourtides, D. A.↗

NASA NTRS1983

Interlaminar fracture toughness of composites. II - Refinement of the edge delamination test and application to thermoplastics

The mixed mode interlaminar fracture toughness, G(c), is obtained for the two thermoplastic matrices UDEL P1700 polysulfone and ULTEM polyetherimide by means of edge delamination tensile (EDT) tests on unnotched, eleven-ply graphite fiber reinforced composite specimens. A novel method is used to obtain the stiffness parameter employed in the closed form equation for the calculation of G(c), decreasing the number of stiffness measurements required and simplifying the calculations. The G(Ic) values from double cantilever beam (DCB) measurements on composites of the two thermoplastics were similar to each other, but slightly higher than the G(c) data obtained by EDT. Interfacial resin/fiber failures predominated in both the EDT and DCB tests.

Johnston, N. J.↗

NASA NTRS1983

Resin characterization in cured graphite fiber reinforced composites using diffuse reflectance-FTIR

The feasibility of using diffuse reflectance in combination with Fourier transform infrared spectroscopy to obtain information on cured graphite fiber reinforced polymeric matrix resin composites was investigated. Several graphite/epoxy, polysulfone, and polyimide composites exposed to thermal or radiation environments were examined. An experimental polyimide-sulfone adhesive tape was also studied during processing. In each case, significant changes in resin molecular structure was observed due to environmental exposure. These changes in molecular structure were correlated with previously observed changes in material properties providing new insights into material behavior.

Young, P. R.↗

NASA NTRS1985

Long-life high performance fuel cell program

A multihundred kilowatt Regenerative Fuel Cell for use in a space station is envisioned. Three 0.508 sq ft (471.9 cm) active area multicell stacks were assembled and endurance tested. The long term performance stability of the platinum on carbon catalyst configuration suitability of the lightweight graphite electrolyte reservoir plate, the stability of the free standing butyl bonded potassium titanate matrix structure, and the long life potential of a hybrid polysulfone cell edge frame construction were demonstrated. A 18,000 hour demonstration test of multicell stack to a continuous cyclical load profile was conducted. A total of 12,000 cycles was completed, confirming the ability of the alkaline fuel cell to operate to a load profile simulating Regenerative Fuel Cell operation. An orbiter production hydrogen recirculation pump employed in support of the cyclical load profile test completed 13,000 hours of maintenance free operation. Laboratory endurance tests demonstrated the suitability of the butyl bonded potassium matrix, perforated nickel foil electrode substrates, and carbon ribbed substrate anode for use in the alkaline fuel cell. Corrosion testing of materials at 250 F (121.1 C) in 42% wgt. potassium identified ceria, zirconia, strontium titanate, strontium zirconate and lithium cobaltate as candidate matrix materials.

Martin, R. E.↗

NASA NTRS1985

Fracture surface analysis in composite and titanium bonding: Part 1: Titanium bonding

Fractured lap shear Ti 6-4 adherends bonded with polyphenyquinoxaline (PPQ) and polysulfone were analyzed. The effects of adherend pretreatment, stress level, thermal aging, anodizing voltage, and modified adhesive of Ti 6-4 adherend bonded with PPQ on lap shear strength were studied. The effect of adherend pretreatment on lap shear strength was investigated for PS samples. Results of scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) used to study the surface topography and surface composition are also discussed.

Sanderson, K. A.↗

NASA NTRS1985

Polymer matrix and graphite fiber interface study

Hercules AS4 graphite fiber, unsized, or with EPON 828, PVA, or polysulfone sizing, was combined with three different polymer matrices. These included Hercules 3501-6 epoxy, Hercules 4001 bismaleimide, and Hexcel F155 rubber toughened epoxy. Unidirectional composites in all twelve combinations were fabricated and tested in transverse tension and axial compression. Quasi-isotropic laminates were tested in axial tension and compression, flexure, interlaminar shear, and tensile impact. All tests were conducted at both room temperature, dry and elevated temperature, and wet conditions. Single fiber pullout testing was also performed. Extensive scanning electron microphotographs of fracture surfaces are included, along with photographs of single fiber pullout failures. Analytical/experimental correlations are presented, based on the results of a finite element micromechanics analysis. Correlations between matrix type, fiber sizing, hygrothermal environment, and loading mode are presented. Results indicate that the various composite properties were only moderately influenced by the fiber sizings utilized.

Adams, D. F.↗

NASA NTRS1985

Matrix resin development at NASA Langley Research Center

The polymer program at NASA Langley Research Center involves exploratory studies in polymer science. These include the synthesis of novel polymers and their characterization. Polymer synthesis programs involve the development of novel thermoplastics, pseudothermoplastics, and thermosets. Recent investigations have led to the development of more easily processable polyimides, solvent-resistant polysulfones and polyphenylquinoxalines, and tougher high and intermediate-temperature polymers. Characterization efforts have included high-pressure liquid chromatography methodology, the development of toughness tests for fiber-reinforced composites, a study of electrical properties of metal-ion-filled polyimides, and a study of the mutagenicity of aromatic diamines. Also the mechanism of cure/degradation of experimental polymers has been studied by rheology, mechanical behavior, separation techniques and spectroscopy. Some of these programs have involved the degradation crosslinking of alkyl-containing polyimides, the separation and identification of crosslinked phenylquinoxalines, the rheological behavior of hot-melt polyimides, and the elucidation of the cure of norbornene endcapped imides.

St.clair, T. L.↗

NASA NTRS1986

The correlation of low-velocity impact resistance of graphite-fiber-reinforced composites with matrix properties

Summarized are basic studies that were conducted to correlate the impact resistance of graphite-fiber-reinforced composites with polymer matrix properties. Three crosslinked epoxy resins and a linear polysulfone were selected as composite matrices. As a group, these resins possess a significantly large range of mechanical properties. The mechanical properties of the resins and their respective composites were measured. Neat resin specimens and unidirectional and crossply composite specimens were impact tested with an instrumented dropweight tester. Impact resistances of the specimens were assessed on the basis of loading capability, energy absorption, and extent of damage.

Bowles, K. J.↗

NASA NTRS1986

Fracture surface analysis in composite and titanium bonding

Carbon fibers were obtained from several manufacturers. Surface treatments were performed on these fibers by anodization. The surfaces of these fibers were analyzed by X-ray photoelectron spectroscopy and wetting force measurement. The breaking strength of these fibers was measured at 2.5 cm length. It was seen that the surface treatments reduces the strength of the fibers. It was also seen that the Hercules fibers had a higher breaking strength than the Union Carbide fibers. Fiber critical length measurements showed no difference in critical lengths between AS-4 and AU-4 fibers embedded in polysulfone. However, the fiber lengths were much shorter for the surface treated fibers. This effect could be related to increased adhesion between fiber and matrix, or it could be due to the lower breaking strength of the surface treated fiber.

Devilbiss, T. A.↗

NASA NTRS1986

The effects of energetic proton bombardment on polymeric materials: Experimental studies and degradation models

This report describes 3 MeV proton bombardment experiments on several polymeric materials of interest to NASA carried out on the Tandem Van De Graff Accelerator at the California Institute of Technology's Kellogg Radiation Laboratory. Model aromatic and aliphatic polymers such as poly(1-vinyl naphthalene) and poly(methyl methacrylate), as well as polymers for near term space applications such as Kapton, Epoxy and Polysulfone, have been included in this study. Chemical and physical characterization of the damage products have been carried out in order to develop a model of the interaction of these polymers with the incident proton beam. The proton bombardment methodology developed at the Jet Propulsion Laboratory and reported here is part of an ongoing study on the effects of space radiation on polymeric materials. The report is intended to provide an overview of the mechanistic, as well as the technical and experimental, issues involved in such work rather than to serve as an exhaustive description of all the results.

Coulter, D. R.↗

NASA NTRS1985

Correlation of dynamic dielectric measurements with viscosity in polymeric resin systems

Dynamic dielectric analysis has been used to study curing polymer systems and thermoplastics. Measurements have been made over a frequency range of six decades. This wide range of frequencies increases the amount of information which can be obtained. The data are analyzed in terms of the frequency dependence of the specific conductivity sigma and the relaxation time tau, parameters which are characteristic of the cure state of the material and independent of size of the sample. Dynamic dielectric measurements have been correlated with viscosity for the polysulfone thermoplastic UDEL-P1700 and with viscosity and ultrasonic measurements on the DGEBA-type epoxy Epon 828 cured with Agent U. The experimental results suggest that when ionic processes dominate the dielectric response, the intensive property sigma is a good monitor of the resin's viscosity. The results show that the dielectric relaxation time tau can be used to monitor the state of the system and the extent and rate of the reaction.

Kranbuehl, D.↗

NASA NTRS1984

Evaluation of high temperature structural adhesives for extended service

Hendricks, C. L.↗

NASA NTRS1987

Effects of Radiation on Capacitor Dielectrics

Data gathered on key design parameters. Report discusses study of electrical and mechanical properties of irradiated polymer dielectric materials. Data compiled for use by designers of high-energy-density capacitors that operate in presence of ionizing radiation. Study focused on polycarbonates, polyetheretherketones, polymethylpentenes, polyimides (including polyetherimide), polyolefins, polysulfones (including polyethersulfone and polyphenylsulfone), and polyvinylidene fluorides.

Bouquet, F. L.↗

NASA NTRS1987

Baseline tensile tests of composite materials for LDEF (Long Duration Exposure Facility) exposure

Tensile specimens of five graphite fiber reinforced composite materials were tested at room temperature to provide baseline data for similar specimens exposed to the space environment in low-Earth orbit on the NASA Long Duration Exposure Facility. All specimens were 4-ply (+ or - 45 deg)s layups; at least five replicate specimens were tested for each parameter evaluated. Three epoxy-matrix materials and two polysulfone-matrix materials, several fiber volume fractions, and two sizes of specimen were evaluated. Stress-strain and Poisson's ratio-stress curves, ultimate stress, strain at failure, secant modulus at 0.004 strain, inplane shear stress-strain curves, and unidirectional shear modulus at .004 shear strain are presented.

Witte, William G.↗

NASA NTRS1977

Process for crosslinking and extending conjugated diene-containing polymers

A process using a Diels-Alder reaction which increases the molecular weight and/or crosslinks polymers by reacting the polymers with bisunsaturated dienophiles is developed. The polymer comprises at least 75% by weight based on the reaction product, has a molecular weight of at least 5000 and a plurality of conjugated 1,3-diene systems incorporated into the molecular structure. A dienophile reaction with the conjugated 1,3-diene of the polymer is at least 1% by weight based on the reaction product. Examples of the polymer include polyesters, polyamides, polyethers, polysulfones and copolymers. The bisunsaturated dienophiles may include bis-maleimides, bis maleic and bis tumaric esters and amides. This method for expanding the molecular weight chains of the polymers, preferable thermoplastics, is advantageous for processing or fabricating thermoplastics. A low molecular weight thermoplastic is converted to a high molecular weight plastic having improved strength and toughness for use in the completed end use article.

Bell, Vernon L.↗