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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Nonequilibrium vibrational population measurements in an expanding flow using spontaneous Raman scattering

Vibrational relaxation of nitrogen in a 2D nozzle flow is studied using spontaneous Raman scattering. An electric arc driven shock tube operating as a reflected shock tunnel produces stagnation conditions of 5600 K and 100 atm. A 248 nm KrF laser pulse is focused into the nozzle to produce spatially resolved spontaneous Raman spectra. Vibrational population distributions are derived from the spectra for the states v = 0 to v = 8. The experimental results are compared with two theoretical models: the Landau-Teller relaxation model and a numerical solution of the master equations using transition rates derived from SSH theory. The Landau-Teller correction factor has been measured at 1.0 - 1.5.

Sharma, Surendra P.↗
NASA NTRS1982

Evaluation of turbulence induced noise in coherent anti-Stokes Raman scattering

The effect of turbulence in a transonic wind tunnel on coherent anti-Stokes Raman scattering is considered. The driving pump and Stokes waves are taken to be coaxially propagating Gaussian beam waves which are focused on the Raman active medium through the turbulent boundary layer of the flow tube. The random index of refraction variations in the layer are modeled as phase perturbations of the driving waves which cause a reduction of the mean on-axis field and an increase in the mean diameter of the beams. Effective Gaussian beam parameters are developed and the radiated anti-Stokes power calculated as a function of the phase screen parameters. A significant reduction in signal strength occurs for realistic estimates of the phase screen parameter appropriate to a confined transonic flow. A method for estimating the signal degradation which could be applied to other experimental situations is presented.

Elliott, R. A.↗
NASA NTRS1973

Raman scattering applied to gas mixing in the successive channel flow of two gases

The Raman scattering technique has been applied to investigate the effects of fluid undercutting in a simulation of the fluid-piston concept for wind-tunnel design. Measurements of the structure of the driver-driven gas interface and of the effect of undercutting on test duration were performed. Tests were conducted over a Froude number range of 0.0021 to 0.526 at driver-to-driven gas density ratios of 1.103 and 1.573. The effects of inlet design, test-channel inclination angle, and pretest pressurization were also examined. The results are compared with shadowgraph and pressure measurements to illustrate the characteristics of the Raman technique and to explain the discrepancy between the shadowgraph and pressure results.

Hillard, M. E., Jr.↗
NASA NTRS2006

First Results from the OMI Rotational Raman Scattering Cloud Pressure Algorithm

We have developed an algorithm to retrieve scattering cloud pressures and other cloud properties with the Aura Ozone Monitoring Instrument (OMI). The scattering cloud pressure is retrieved using the effects of rotational Raman scattering (RRS). It is defined as the pressure of a Lambertian surface that would produce the observed amount of RRS consistent with the derived reflectivity of that surface. The independent pixel approximation is used in conjunction with the Lambertian-equivalent reflectivity model to provide an effective radiative cloud fraction and scattering pressure in the presence of broken or thin cloud. The derived cloud pressures will enable accurate retrievals of trace gas mixing ratios, including ozone, in the troposphere within and above clouds. We describe details of the algorithm that will be used for the first release of these products. We compare our scattering cloud pressures with cloud-top pressures and other cloud properties from the Aqua Moderate-Resolution Imaging Spectroradiometer (MODIS) instrument. OMI and MODIS are part of the so-called A-train satellites flying in formation within 30 min of each other. Differences between OMI and MODIS are expected because the MODIS observations in the thermal infrared are more sensitive to the cloud top whereas the backscattered photons in the ultraviolet can penetrate deeper into clouds. Radiative transfer calculations are consistent with the observed differences. The OMI cloud pressures are shown to be correlated with the cirrus reflectance. This relationship indicates that OMI can probe through thin or moderately thick cirrus to lower lying water clouds.

Joiner, Joanna↗
NASA NTRS1990

Single pulse vibrational Raman scattering by a broadband KrF excimer laser in a hydrogen-air flame

Spontaneous vibrational Raman scattering (VRS) is produced by a broadband excimer laser at 248 nm (KrF) in a H2-air flame, and VRS spectra are recorded for lean, stoichiometric, and rich flames. Except at very lean flame conditions, laser-induced fluorescence (LIF) processes interfere with VRS Stokes lines from H2, H2O, and O2. No interference is found for the N2 Stokes and N2 anti-Stokes lines. In a stoichiometric H2/air flame, single-pulse measurements of N2 concentration and temperature (by the VRS Stokes to anti-Stokes ratio) have a relative standard deviation of 7.7 and 10 percent, respectively. These single pulse measurement errors compare well with photon statistics calculations using measured Raman cross sections.

Pitz, Robert W.↗
NASA NTRS1983

Spatially and spectrally resolved multipoint coherent anti-Stokes Raman scattering from N2 and O2 flows

Single-shot spectrally resolved broadband rotational coherent anti-Stokes Raman scattering (CARS) from multiple points along a line intersecting a flow has been observed for N2 and O2. A large-angle phase-matching configuration was used to achieve spatial resolution of 0.1 mm x 0.1 mm x 0.1 mm for each of 20 points in the interaction volume. Single-shot multipoint CARS of N2 at different temperatures and of several species in a coflowing jet was observed.

Snow, J. B.↗
NASA NTRS2002

Flow Visualization of Density in a Cryogenic Wind Tunnel Using Planar Rayleigh and Raman Scattering

Using a pulsed Nd:YAG laser (532 nm) and a gated, intensified charge-coupled device, planar Rayleigh and Raman scattering techniques have been used to visualize the unseeded Mach 0.2 flow density in a 0.3-meter transonic cryogenic wind tunnel. Detection limits are determined for density measurements by using both unseeded Rayleigh and Raman (N2 vibrational) methods. Seeding with CO2 improved the Rayleigh flow visualization at temperatures below 150 K. The seeded Rayleigh version was used to demonstrate the observation of transient flow features in a separated boundary layer region, which was excited with an oscillatory jet. Finally, a significant degradation of the laser light sheet, in this cryogenic facility, is discussed.

Herring, Gregory C.↗
NASA NTRS1985

Raman scattering from phonons and magnons in magnetic semiconductors, MnTe

Comparisons are made between theoretical and experimental data on laser Raman scattering by phonons and two-magnons in antiferromagnetic and paramagnetic phases of MnTe. The study was performed specifically to characterize the magnetic exchange coupling constants of the Mn ions in the samples. Crystal MnTe samples were bombarded with an Ar ion laser beam to obtain spectrometer and photon counter data. One E(2g) phonon with a room temperature energy of 178/cm and a two-magnon peak of 360/cm were observed in the Raman spectrum. A spin wave dispersion relation is presented for the spectrum. Finally, a Monte Carlo technique was used to calculate the two-magnon joint density of states that best fits the experimental data.

Mobasser, S. R.↗
NASA NTRS1973

Absolute intensity and polarization of rotational Raman scattering from N2, O2, and CO2

An experimental examination of the absolute intensity, polarization, and relative line intensities of rotational Raman scattering (RRS) from N2, O2, and CO2 is reported. The absolute scattering intensity for N2 is characterized by its differential cross section for backscattering of incident light at 647.1 nm, which is calculated from basic measured values. The ratio of the corresponding cross section for O2 to that for N2 is 2.50 plus or minus 5 percent. The intensity recent for N2, O2, and CO2 are shown to compare favorably to values calculated from recent measurements of the depolarization of Rayleigh scattering plus RRS. Measured depolarizations of various RRS lines agree to within a few percent with the theoretical value of 3/4. Detailed error analyses are presented for intensity and depolarization measurements. Finally, extensive RRS spectra at nominal gas temperatures of 23 C, 75 C, and 125 C are presented and shown to compare favorably to theoretical predictions.

Penney, C. M.↗
NASA NTRS2003

Dual-Pump Coherent Anti-Stokes Raman Scattering Temperature and CO2 Concentration Measurements

Measurements of temperature and CO2 concentration using dual-pump coherent anti-Stokes Raman scattering, (CARS) are described. The measurements were performed in laboratory flames,in a room-temperature gas cell, and on an engine test stand at the U.S. Air Force Research Laboratory, Wright-Patterson Air Force Base. A modeless dye laser, a single-mode Nd:YAG laser, and an unintensified back-illuminated charge-coupled device digital camera were used for these measurements. The CARS measurements were performed on a single-laser-shot basis. The standard deviations of the temperatures and CO2 mole fractions determined from single-shot dual-pump CARS spectra in steady laminar propane/air flames were approximately 2 and 10% of the mean values of approximately 2000 K and 0.10, respectively. The precision and accuracy of single-shot temperature measurements obtained from the nitrogen part of the dual-pump CARS system were investigated in detail in near-adiabatic hydrogen/air/CO2 flames. The precision of the CARS temperature measurements was found to be comparable to the best results reported in the literature for conventional two-laser, single-pump CARS. The application of dual-pump CARS for single-shot measurements in a swirl-stabilized combustor fueled with JP-8 was also demonstrated.

Lucht, Robert P.↗
NASA NTRS2008

Measurement of Off-Body Velocity, Pressure, and Temperature in an Unseeded Supersonic Air Vortex by Stimulated Raman Scattering

A noninvasive optical method is used to make time-averaged (30 sec) off-body measurements in a supersonic airflow. Seeding of tracer particles is not required. One spatial component of velocity, static pressure, and static temperature are measured with stimulated Raman scattering. The three flow parameters are determined simultaneously from a common sample volume (0.3 by 0.3 by 15 mm) using concurrent measurements of the forward and backward scattered line shapes of a N2 vibrational Raman transition. The capability of this technique is illustrated with laboratory and large-scale wind tunnel testing that demonstrate 5-10% measurement uncertainties. Because the spatial resolution of the present work was improved to 1.5 cm (compared to 20 cm in previous work), it was possible to demonstrate a modest one-dimensional profiling of cross-flow velocity, pressure, and translational temperature through the low-density core of a stream-wise vortex (delta-wing model at Mach 2.8 in NASA Langley's Unitary Plan Wind Tunnel).

Herring, Gregory C.↗
NASA NTRS2004

Quantitative Analysis of Spectral Interference of Spontaneous Raman Scattering in High-Pressure Fuel-Rich H2-Air Combustion

We present a theoretical study of the spectral interferences in the spontaneous Raman scattering spectra of major combustion products in 30-atm fuel-rich hydrogen-air flames. An effective methodology is introduced to choose an appropriate line-shape model for simulating Raman spectra in high-pressure combustion environments. The Voigt profile with the additive approximation assumption was found to provide a reasonable model of the spectral line shape for the present analysis. The rotational/vibrational Raman spectra of H2, N2, and H2O were calculated using an anharmonic-oscillator model using the latest collisional broadening coefficients. The calculated spectra were validated with data obtained in a 10-atm fuel-rich H2-air flame and showed excellent agreement. Our quantitative spectral analysis for equivalence ratios ranging from 1.5 to 5.0 revealed substantial amounts of spectral cross-talk between the rotational H2 lines and the N2 O-/Q-branch; and between the vibrational H2O(0,3) line and the vibrational H2O spectrum. We also address the temperature dependence of the spectral cross-talk and extend our analysis to include a cross-talk compensation technique that removes the nterference arising from the H2 Raman spectra onto the N2, or H2O spectra.

Kojima, Jun↗
NASA NTRS1992

Raman scattering measurements in flames using a tunable KrF excimer laser

A narrow-band tunable KrF excimer laser is used as a spontaneous vibrational Raman scattering source to demonstrate that single-pulse concentration and temperature measurements, with only minimal fluorescence interference, are possible for all major species (O2, N2, H2O, and H2) at all stoichiometries (fuel-lean to fuel rich) of H2-air flames. Photon-statistics-limited precisions in these instantaneous and spatially resolved single-pulse measurements are typically 5 percent, which are based on the relative standard deviations of single-pulse probability distributions. In addition to the single-pulse N2 Stokes/anti-Stokes ratio temperature measurement technique, a time-averaged temperature measurement technique is presented that matches the N2 Stokes Raman spectrum to theoretical spectra by using a single intermediate state frequency to account for near-resonance enhancement. Raman flame spectra in CH4-air flames are presented that have good signal-to-noise characteristics and show promise for single-pulse UV Raman measurements in hydrocarbon flames.

Wehrmeyer, Joseph A.↗
NASA NTRS1995

Raman scattering characterization of space solar cell structures

A contactless method for the determination of the free-carrier density and the composition distribution across the thickness of 3-5 multi-layer solar cell structures, using the Raman scattering method, is developed. The method includes a step analysis of Raman spectra from optical phonons and phonon-plasmon modes of different layers. The method provides simultaneous measurements of the element composition and the thickness of the structure's layers together with the free-carrier density. The results of measurements of the free-carrier density composition distributions of the liquid phase epitaxy grown AlGaAs/GaAs and GaSb solar cell structures are presented and discussed.

Mintairov, Alexander M.↗
NASA NTRS1990

Stimulated Raman scattering seeded by a fibre continuum

A broadband continuum generated in a germanosilicate optical fiber has been used as a coherent seed to initiate stimulated Raman scattering in gases. The technique used is described. The results show a fivefold increase in conversion efficiency and a similar reduction in the requisite pump power.

Selker, M. D.↗