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At least 73 records · Page 4

Methane Hydrate Formation in Thick Sandstones by Free Gas Flow

We show with a two-dimensional multiphase flow and multicomponent transport model that free gas flow is a viable mechanism to form concentrated methane hydrate in meter-scale, dipping sandstones far above the base of the hydrate stability zone (BHSZ). In this model, gas preferentially flows updip along the top of sandstone due to buoyancy. This drives hydrate formation, increasing the local salinity to the stability limit and developing three-phase (gas, liquid, and hydrate) equilibrium above the BHSZ. With time, the gas and the hydrate solidification front (HSF) advance together updip. Behind the HSF, hydrate continues to form as the elevated salinity diffuses away. High hydrate saturations reduce the sediment permeability significantly. As a result, as the gas and HSF move updip, they are also pushed perpendicularly from the top to the base of the sandstone. The hydrate system ultimately self-seals itself due to reduced permeability across the entire thickness of the sandstone. Gas starts to retreat downdip and accumulates below the BHSZ. With this model high hydrate saturations form far above the BHSZ at high methane supply rates while hydrate is concentrated at the BHSZ or no hydrate forms at low methane supply rates. This study provides further insights into hydrate formation by free gas flow, which can be used to design the best strategies for economic and environmental production of methane from hydrate reservoirs.

58 GEOSCIENCES↗

High-Resolution Computed Tomography Dataset of Mount Simon Sandstone

The Illinois Basin is a critical structure for subsurface energy related activities and their implementation in the United States. The Mount Simon Sandstone has been identified as a storage target for permanent and transient storage of fluids in the basin. Known for its exceptional thickness, depth, porosity, and sealing properties of overlying formations, this saline reservoir is crucial for long-term subsurface energy efforts. We present an extensive Computed Tomography (CT) dataset on a high porosity and permeability zone in the lower Mount Simon Sandstone available on the Energy Data eXchange® (EDX). This publicly accessible database comprises over 500 GB of high-resolution CT scans of six core samples, with resolutions ranging from 14.8 µm to 0.7 µm per pixel. The scans include both dry sandstone samples and those saturated with multiple fluids, allowing for comparative analyses across different conditions and resolutions. Coarser scans capture the bedding structure of the sandstone, while finer resolutions reveal detailed pore infill and throat characteristics. Metadata on location, depth, and saturation state enhance usability, enabling quick identification and cross-sample comparisons. By providing a robust resource for research and collaboration, the database contributes to domestic energy advancement by supporting continued progress in the use of the subsurface for energy solutions.

characterization↗

Hydrogen, Methane, Brine Flow Behavior, and Saturation in Sandstone Cores During H 2 and CH 4 Injection and Displacement

Large-scale underground hydrogen storage (UHS) is a critical component in the emerging hydrogen economy. Knowledge of multiphase flow behavior involving hydrogen in storage reservoir formations is crucial to characterizing hydrogen transport properties and essential for the deliverability and storage operations of UHS. There are still many gaps in fully understanding hydrogen–methane–brine multiphase phase flow that require further investigation. In this work, H 2 and CH 4 were injected through brine-saturated sandstone cores using a tri-axial core holder system fitted with flow rate meters and pressure transducers, while the effluent gas concentrations were analyzed using an online micro gas chromatograph. Brine displacement, permeability, and gas breakthrough curves were measured. We studied the flow behavior of hydrogen and methane in sandstone cores through testing brine displacement by gas injection and comparing the hydrogen displacement of methane with the methane displacement of hydrogen. We also tested the differences between horizontal and vertical flow in brine displacement. The results showed that brine displacement was more efficient in a core with higher permeability and porosity, resulting in a higher initial gas saturation. A higher gas injection rate brought about faster gas breakthrough measured by pore volume and sharper concentration curves. Hydrogen did not exhibit abnormal flow in the sandstone when the flow was horizontal and downward vertical. Gas overriding was observed in brine displacements when the flow was horizontal, with hydrogen showing this behavior more profoundly compared to methane. Downward vertical gas injection induced higher efficiency brine displacement compared to horizontal displacement and resulted in a higher initial gas saturation in the sandstone cores. These findings address critical knowledge gaps regarding gas flow patterns and displacement behaviors during hydrogen injection and recovery phases in UHS facilities using methane as the cushion gas. The insights from this research offer valuable guidance for optimizing UHS systems, ensuring operational efficiency, and advancing sustainable energy solutions in alignment with decarbonization goals.

08 HYDROGEN↗

Utilization of the St. Peter Sandstone in the Illinois Basin for CO2 Sequestration

This project is part of a larger project co-funded by the United States Department of Energy (US DOE) under cooperative agreement DE-FE0002068 from 12/08/2009 through 9/31/2014. The study is to evaluate the potential of formations within the Cambro-Ordovician strata above the Mt. Simon Sandstone as potential targets for carbon dioxide (CO2) sequestration in the Illinois and Michigan Basins. This report evaluates the potential injectivity of the Ordovician St. Peter Sandstone. The evaluation of this formation was accomplished using wireline data, core data, pressure data, and seismic data acquired through funding in this project as well as existing data from two additional, separately funded projects: the US DOE funded Illinois Basin – Decatur Project (IBDP) being conducted by the Midwest Geological Sequestration Consortium (MGSC) in Macon County, Illinois, and the Illinois Industrial Carbon Capture and Sequestration (ICCS) Project funded through the American Recovery and Reinvestment Act (ARRA), which received a phase two award from DOE. This study addresses the question of whether or not the St. Peter Sandstone may serve as a suitable target for CO2 sequestration at locations within the Illinois Basin where it lies at greater depths (below the underground source of drinking water (USDW)) than at the IBDP site. The work performed included numerous improvements to the existing St. Peter reservoir model created in 2010. Model size and spatial resolution were increased resulting in a 3 fold increase in the number of model cells. Seismic data was utilized to inform spatial porosity distribution and an extensive core database was used to develop porosity-permeability relationships. The analysis involved a Base Model representative of the St. Peter at “in-situ” conditions, followed by the creation of two hypothetical models at in-situ + 1,000 feet (ft.) (300 m) and in-situ + 2,000 ft. (600 m) depths through systematic depthdependent adjustment of the Base Model parameters. Properties for the depth shifted models were based on porosity versus depth relationship extracted from the core database followed by application of the porosity-permeability relationship. Each of the three resulting models were used as input to dynamic simulations with the single well injection target of 3.2 million tons per annum (MTPA) for 30 years using an appropriate fracture gradient based bottom hole pressure limit for each injection level. Modeling results are presented in terms of well bottomhole pressure (BHP), injection rate profiles, and three-dimensional (3D) saturation and differential pressure volumes at selected simulation times. Results suggest that the target CO2 injection rate of 3.2 MTPA may be achieved in the St. Peter Sandstone at in-situ conditions and at the in-situ +1,000 ft. (300 m) depth using a single injector well. In the latter case the target injection rate is achieved after a ramp up period which is caused by multi-phase flow effects and thus subject to increased modeling uncertainty. Results confirm that the target rate may not be achieved at the in-situ +2,000 ft. (600 m) level even with multiple wells. These new modeling results for the in-situ case are more optimistic than previous modeling results. This difference is attributed to the difference in methods and data used to develop model permeability distributions. Recommendations for further work include restriction of modeling activity to the in-situ +1,000 ft. (300 m) and shallower depth interval, sensitivity and uncertainty analysis, and refinement of porosity and permeability estimates through depth and area selective querying of the available core database. It is also suggested that further modeling efforts include scope for evaluating project performance in terms of metrics directly related to the Environmental Protection Agency (EPA) Class VI permit requirements for the area of review (AoR) definition and post injection site closure monitoring.

Will, Robert↗

Mechanism of formation of wiggly compaction bands in porous sandstone: 2. Numerical simulation using discrete element method

Wiggly compaction bands in porous aeolian s andstone vary from chevron shape to wavy shape to nearly straight. In some outcrops these variations occur along a single band. Here, a bonded close-packed discrete element model is used to investigate what mechanical properties control the formation of wiggly compaction bands (CBs). To simulate the volumetric yielding failure of porous sandstone, a discrete element shrinks when the force state of one of its bonds reaches the yielding cap defined by the failure force and the aspect ratio (k) of the yielding ellipse. A Matlab code “MatDEM 3D ” has been developed on the basis of this enhanced discrete element method. Mechanical parameters of elements are chosen according to the elastic properties and the strengths of porous sandstone. In numerical simulations, the failure angle between the band segment and maximum principle stress decreases from 90° to approximately 45° as k increases from 0.5 to 2, and compaction bands vary from straight to chevron shape. With increasing strain, subsequent compaction occurs inside or beside compacted elements, which leads to further compaction and thickening of bands. The simulations indicate that a greater yielding stress promotes chevron CBs, and a greater cement strength promotes straight CBs. Combined with the microscopic analysis introduced in the companion paper, we conclude that the shape of wiggly CBs is controlled by the mechanical properties of sandstone, including the aspect ratio of the yielding ellipse, the cri tical yielding stress, and the cement strength, w hich are d etermined primarily by petrophysical attributes, e.g., grain sorting, porosity, and cementation.

58 GEOSCIENCES↗

Investigation on porosity and permeability change of Mount Simon sandstone (Knox County, IN, USA) under geological CO 2 sequestration conditions: a numerical simulation approach

In this paper, a numerical model was developed to simulate reactive transport with porosity and permeability change of Mount Simon sandstone (samples from Knox County, IN) after 180 days of exposure to CO 2 -saturated brine under CO 2 sequestration conditions. The model predicted formation of a high-porosity zone adjacent to the surface of the sample in contact with bulk brine, and a lower porosity zone just beyond that high-porosity zone along the path from sample/bulk brine interface to sample core. The formation of the high porosity zone was attributed to dissolution of quartz and muscovite/illite, while the formation of the lower porosity zone adjacent to the aforementioned high porosity zone was attributed to precipitation of kaolinite and feldspar. The model predicted a 40% permeability increase for the Knox sandstone sample after 180 days of exposure to CO 2 -saturated brine, which was consistent with laboratory-measured permeability results. Model-predicted solution chemistry results were also found to be consistent with laboratory-measured solution chemistry data. Finally, initial porosity, initial feldspar content and the exponent n value (determined by pore structure and tortuosity) used in permeability calculations were three important factors affecting permeability evolution of sandstone samples under CO 2 sequestration conditions.

54 ENVIRONMENTAL SCIENCES↗

CO 2 -SCREEN tool: Application to the oriskany sandstone to estimate prospective CO 2 storage resource

Here, the ability to accurately predict the CO 2 storage resource in saline formations is important to make high-level, energy-related government policy and business decisions. CO 2 -SCREEN (Storage prospeCtive Resource Estimation Excel aNalysis) is a tool developed by the United States Department of Energy – National Energy Technology Laboratory (US-DOE-NETL) to screen saline formations for prospective CO 2 storage resources. CO 2 -SCREEN uses DOE methods and equations to serve as a consistent mechanism for calculating prospective CO 2 storage resources. CO 2 -SCREEN is comprised of two files: an Excel file used for inputs and outputs and a GoldSim Player file used to run Monte Carlo simulations. CO 2 -SCREEN requires input of physical geologic parameters (i.e. thickness, porosity) as well as efficiency factor ranges (i.e. net-to-gross thickness) to calculate a mass storage estimate. An application of CO 2 -SCREEN is demonstrated here using well log data from the Oriskany Sandstone portion in Pennsylvania. The Oriskany Sandstone is divided into 20 km x 20 km grid cells in which 151 cells contain well log data. CO 2 -SCREEN calculates prospective CO 2 storage resource for each grid cell based on the well log data and uses lithology and depositional environment information for efficiency factor ranges. The Oriskany Sandstone CO 2 storage resource estimate for Pennsylvania, calculated by CO 2 -SCREEN, ranges from 0.07 to 1.28 gigatons (Gt) with a P 50 value of 0.32 Gt. This resource assessment analysis is done to demonstrate the use of CO 2 -SCREEN and results are comparable to previous studies which encourages the application of CO 2 -SCREEN to other saline formations and warrants exploring the expansion of this tool to assess the CO 2 storage resource in other formations such as shale and depleted oil and gas reservoirs.

03 NATURAL GAS↗

Experimental investigation on oil migration and accumulation in tight sandstones

Here, this study presents an experimental investigation to simulate and analyze the physical processes of oil migration and accumulation with 19 tight sandstone cores. Characteristic curves of oil migration were obtained by using the experimental results. It shows that the curve variations were mainly influenced by two factors: the permeability of the core and the viscosity of the injected oil. Based on the experimental results, we introduced three important parameters to quantitatively characterize and determine the processes of oil migration and accumulation in tight sandstones. The apparent permeability was introduced to describe the level of oil migration during experiments. The minimum migration pressure gradient (MMPG) and the terminal oil saturation were proposed to evaluate the features of the beginning and final stages of the migration, respectively. The relationships between MMPG, terminal oil saturation and mobility were analyzed, all showed strong linear relationships in the double logarithmic coordinate system. Furthermore, a prediction map of tight oil accumulation was plotted according to the measured oil saturation data, which could be used for estimating the scale and size of oil accumulation in tight reservoirs. Lastly, the concepts and results in this study provide valuable insight for understanding and quantitatively analyzing the processes of oil migration and accumulation in tight sandstones.

58 GEOSCIENCES↗

Impact of exposure to brine/CO 2 on the mechanical and transport properties of the Mt. Simon Sandstone

When sandstone rocks are exposed to CO 2 -saturated brine, their transport and mechanical properties can, potentially, change due to chemical reactions as a result of such exposure. This paper investigates changes in the flow-through characteristics, porosity, and the mechanical properties of Mt. Simon Sandstone samples caused by such exposure to brine/CO 2 . A core, extracted from the Mt. Simon formation, was first characterized for its porosity and relevant transport properties, and it was then aged for over 500 hr in CO 2 -saturated brine at formation-relevant pressure, temperature, and confining stress conditions. The deformation of the sample was measured in situ during aging via strain gauges attached to the core's surface. Following the aging experiment, the sample's porosity and transport properties were again analyzed. Our experiments show that both the porosity and permeability of the Mt. Simon sandstone sample increase due to exposure to brine/CO 2 , with the impact on permeability being more significant. The deformation measurements employing strain gauges indicate a weakening of the core material. Analysis of the composition of the brine at the conclusion of the testing reveals changes, specifically, an increase in the concentration of several of the cations. These changes are indicative of mineral/clay dissolution, consistent with the porosity, permeability, and strain gauge measurements.

58 GEOSCIENCES↗

Nuclear magnetic resonance and molecular simulation study of H 2 and CH 4 adsorption onto shale and sandstone for hydrogen geological storage

Understanding pure H 2 and H 2 /CH 4 adsorption and diffusion in earth materials is one vital step toward a successful and safe H 2 storage in depleted gas reservoirs. Despite recent research efforts such understanding is far from complete. In this work we first use Nuclear Magnetic Resonance (NMR) experiments to study the NMR response of injected H 2 into Duvernay shale and Berea sandstone samples, representing materials in confining and storage zones. Then we use molecular simulations to investigate H 2 /CH 4 competitive adsorption and diffusion in kerogen, a common component of shale. Our results indicate that in shale there are two H 2 populations, i.e., free H 2 and adsorbed H 2 , that yield very distinct NMR responses. However, only free gas presents in sandstone that yields a H 2 NMR response similar to that of bulk H 2 . About 10 % of injected H 2 can be lost due to adsorption/desorption hysteresis in shale, and no H 2 loss (no hysteresis) is observed in sandstone. Here, our molecular simulation results support our NMR results that there are two H 2 populations in nanoporous materials (kerogen). The simulation results also indicate that CH 4 outcompetes H 2 in adsorption onto kerogen, due to stronger CH 4 -kerogen interactions than H 2 -kerogen interactions. Nevertheless, in a depleted gas reservoir with low CH 4 gas pressure, about ~30 % of residual CH 4 can be desorbed upon H 2 injection. The simulation results also predict that H 2 diffusion in porous kerogen is about one order of magnitude higher than that of CH 4 and CO 2 . This work provides an understanding of H 2 /CH 4 behaviors in deleted gas reservoirs upon H 2 injection and predictions of H 2 loss and CH 4 desorption in H 2 storage.

08 HYDROGEN↗

Stress and Strain Heterogeneity and Persistence in Uniaxially‐ and Triaxially‐Loaded Sandstone

Two critical questions in brittle rock mechanics are how rocks developed localized strains and to what extent internal stress heterogeneity controls this localization and subsequent macroscopic failure. Definitive answers have not yet been found, but would provide insight into rock fracture mechanics as relevant to hydrocarbon extraction and sequestration. Here, we use synchrotron X‐ray tomography (XRT) and 3D X‐ray diffraction (3DXRD) during uniaxial and triaxial tests on Nugget and Bentheimer sandstones to examine strain and stress localization prior to mechanical failure. 3DXRD was used to measure intra‐granular lattice strains which were used to compute elastic stress tensors of each grain. Digital volume correlation (DVC) was applied to XRT images to determine the strain field in the sample. Both samples featured marked spatial heterogeneity, localization, and temporal persistence of elevated stresses and strains during their mechanical deformation toward failure. Both samples featured a majority of grains with at least one principal stress component that was tensile, a signature of the influence of heterogeneity on stress transmission. Measurements further revealed that compressive stress orientations and statistics evolved in a similar manner to those of inter‐particle forces in loose granular materials, with triaxially‐compressed rock exhibiting enhanced grain stress heterogeneity compared to uniaxially‐compressed rock. Our results complement recent work by others who employed XRT and scanning 3DXRD to study triaxially‐compressed sandstone, but extend those results to uniaxial compression, sandstones of varied porosity, and grain stress measurements throughout the 3D full extent of the samples rather than in a single layer examined with scanning 3DXRD.

58 GEOSCIENCES↗

Origin and heterogeneity of pore sizes in the Mount Simon Sandstone and Eau Claire Formation: Implications for multiphase fluid flow

The Mount Simon Sandstone and Eau Claire Formation represent a principal reservoir - caprock system for wastewater disposal, geologic CO 2 storage, and compressed air energy storage (CAES) in the Midwestern United States. Of primary concern to site performance is heterogeneity in flow properties that could lead to non-ideal injectivity and distribution of injected fluids (e.g., poor sweep efficiency). Using core samples from the Dallas Center Structure, Iowa, we investigate pore structure that governs flow properties of major lithofacies of these formations. Methods include gas porosimetry and permeametry, mercury intrusion porosimetry, thin section petrography, and X-ray diffraction. The lithofacies exhibit highly variable intra- and inter-informational distributions of pore throat and body sizes. Based on pore-throat size, samples fall into four distinct groups. Micropore-throat dominated samples are from the Eau Claire Formation, whereas the macropore-, mesopore-, and uniform-dominated samples are from the Mount Simon Sandstone. Complex paragenesis governs the high degree of pore and pore-throat size heterogeneity, due to an interplay of precipitation, non-uniform compaction, and later dissolution of cements. Furthermore, the cement dissolution event probably accounts for much of the current porosity in the unit. The unusually heterogeneous nature of the pore networks in the Mount Simon Sandstone indicates that there is a greater-than-normal opportunity for reservoir capillary trapping of non-wetting fluids — as quantified by CO 2 and air column heights — which should be taken into account when assessing the potential of the reservoir-caprock system for CO 2 storage and CAES.

58 GEOSCIENCES↗

Interpreting pre-vegetation landscape dynamics: The Cambrian Lower Mount Simon Sandstone, Illinois, U.S.A.

ABSTRACT The Cambrian Mount Simon Sandstone has been the subject of extensive study and multiple industrial-scale carbon storage demonstrations at Decatur, Illinois, USA. The development of a reliable paleoenvironmental model is critical to successful large-scale carbon dioxide (CO2) storage, but is complicated by the need to interpret pre-vegetation sedimentation processes. The present study presents a paleoenvironmental model of the Lower Mount Simon Sandstone, based on analysis of primary sedimentary structures in two cores and four complete high-resolution resistivity logs (FMI). The Lower Mount Simon Sandstone represents a vertical “drying-up” sequence composed of three associated depositional units: a north–south oriented coastal system at the base, an eastward-directed fluvial unit in the middle, and a westward-directed eolian system at the top that recycled medium- and fine-grained sand in the basin. Quantitative analysis of fluvial cross-strata indicates that the perennial river system was shallow (c. 1 m deep) with relatively narrow channel belts (c. 1 km). Adjacent sandy eolian-floodplain deposits contain abundant thin, crinkly planar laminae that are enriched in fines and are interpreted as cementation surfaces, likely of biological origin. Deflation lags and wind-ripple strata are commonly interbedded with the crinkly strata, suggesting that the recurrence of erosion and deposition that controlled sedimentary preservation on the floodplain were dominated by eolian transport, re-wetting, and (bio-) cementation. Such a prominent role of exposure to the wind, basin-scale sediment recycling, and eolian removal of fine-grained sediment would have ceased to exist for most climates after the development of vegetation on land, yet, may well be key to understanding the environmental context for early life on Earth.

Geology↗

An Evaluation of the Carbon Sequestration Potential of the Cambro-Ordovician Strata of the Illinois and Michigan Basins. Part 1. Evaluation of Phase 2 CO 2 Injection Testing in the Deep Saline Gunter Sandstone Reservoir (Cambro-Ordovician Knox Group), Marvin Blan No. 1 Hancock County, Kentucky Part 2. Time-lapse Three-Dimensional Vertical Seismic Profile (3D-VSP) of Sequestration Target Interval with Injected Fluids

Part 1 of this report focuses on results of the western Kentucky carbon storage test, and provides a basis for evaluating injection and storage of supercritical CO 2 in Cambro-Ordovician carbonate reservoirs throughout the U.S. Midcontinent. This test demonstrated that the Cambro- Ordovician Knox Group, including the Beekmantown Dolomite, Gunter Sandstone, and Copper Ridge Dolomite in stratigraphic succession from shallowest to deepest, had reservoir properties suitable for supercritical CO 2 storage in a deep saline reservoir hosted in carbonate rocks, and that strata with properties sufficient for long-term confinement of supercritical CO 2 were present in the deep subsurface. Injection testing with brine and CO 2 was completed in two phases. The first phase, a joint project by the Kentucky Geological Survey and the Western Kentucky Carbon Storage Foundation, drilled the Marvin Blan No. 1 carbon storage research well and tested the entire Knox Group section in the open borehole – including the Beekmantown Dolomite, Gunter Sandstone, and Copper Ridge Dolomite – at 1152–2255 m, below casing cemented at 1116 m. During Phase 1 injection testing, most of the 297 tonnes of supercritical CO 2 was displaced into porous and permeable sections of the lowermost Beekmantown below 1463 m and Gunter. The wellbore was then temporarily abandoned with a retrievable bridge plug in casing at 1105 m and two downhole pressure-temperature monitoring gauges below the bridge plug pending subsequent testing. Pressure and temperature data were recorded every minute for slightly more than a year, providing a unique record of subsurface reservoir conditions in the Knox. In contrast, Phase 2 testing, this study, tested a mechanically-isolated dolomitic-sandstone interval in the Gunter.

54 ENVIRONMENTAL SCIENCES↗

CO 2 Injectivity, Storage Capacity, Plume Size, and Reservoir and Seal Integrity of the Ordovician St. Peter Sandstone and the Cambrian Potosi Formation in the Illnois Basin

The Cambro-Ordovician strata of the Illinois and Michigan Basins underlie most of the states of Illinois, Indiana, Kentucky, and Michigan. This interval also extends through much of the Midwest of the United States and, for some areas, may be the only available target for geological sequestration of CO 2 . We evaluated the Cambro-Ordovician strata above the basal Mt. Simon Sandstone reservoir for sequestration potential. The two targets were the Cambrian carbonate intervals in the Knox and the Ordovician St. Peter Sandstone. The evaluation of these two formations was accomplished using wireline data, core data, pressure data, and seismic data from the USDOE-funded Illinois Basin Decatur Project being conducted by the Midwest Geological Sequestration Consortium in Macon County, Illinois. Interpretations were completed using log analysis software, a reservoir flow simulator, and a finite element solver that determines rock stress and strain changes resulting from the pressure increase associated with CO 2 injection. Results of this research suggest that both the St. Peter Sandstone and the Potosi Dolomite (a formation of the Knox) reservoirs may be capable of storing up to 2 million tonnes of CO 2 per year for a 20-year period. Reservoir simulation results for the St. Peter indicate good injectivity and a relatively small CO 2 plume. While a single St. Peter well is not likely to achieve the targeted injection rate of 2 million tonnes/year, results of this study indicate that development with three or four appropriately spaced wells may be sufficient. Reservoir simulation of the Potosi suggest that much of the CO 2 flows into and through relatively thin, high permeability intervals, resulting in a large plume diameter compared with the St. Peter.

54 ENVIRONMENTAL SCIENCES↗

Multi-Scale 3D Imaging for Machine Learning Property Upscaling: Mt. Simon Sandstone Case Study

Petrographic properties of principal target reservoirs for carbon sequestration, such as the Mt. Simon Sandstone, are relevant to broad interest groups. The Mt. Simon Sandstone is a deep, saline, regionally extensive Cambrian sandstone, overlain by low permeability sealing formations, making it one of the viable geologic carbon storage reservoirs in the Midwestern US. Its thickness (exceeding 2400 ft in some localities), depth, and lateral extent, combined with high porosity and permeability make it a high-priority target of multiple ongoing geologic carbon sequestration efforts in the United States of America. The National Energy Technology Laboratory in Morgantown, West Virginia, has been engaged in characterization efforts of the Mt. Simon for over a decade, with a strong focus on Computed Tomographic data acquisition. Data generated during this period has been hitherto not accessible to the public. This archival effort focused on preservation of historical CT data and associated metadata, and facilitating their accessibility, culminating with the publication of the entire dataset on NETL’s Energy Data eXchange (EDX) and the associated Gill et. al (2024) paper.

Gill, Magdalena K.↗

Control of Cement Timing, Mineralogy, and Texture on Hydro-chemo-mechanical Coupling from CO2 Injection into Sandstone: A Synthesis

Carbon capture, utilization, and storage (CCUS) has been widely applied to enhance oil recovery (CO2-EOR). A thorough investigation of the impact of injecting CO2 into a heterogeneous reservoir is critical to understanding the overall reservoir robustness and storage performance. We conducted fifteen flow-through tests on Morrow B sandstone that allowed for chemical reactions between a CO2-rich brackish solution and the sandstones, and four creep/flow-through tests that simultaneously allowed for chemical reactions and stress monitoring. From fluid chemistry and X-ray computed tomography, we found that the dissolution of disseminated cements and the precipitation of iron-rich clays did not significantly affect the permeability and geomechanical properties. Minor changes in mechanical properties from Brazilian and creep tests indicated that the matrix structure was well-supported by early diagenetic quartz overgrowth cement and the reservoir’s compaction history at deep burial depths. However, one sample experienced a dissolution of poikilotopic calcite, leading to a permeability increase and significant tensile strength degradation due to pore opening, which overcame the effect of the early diagenetic cements. We concluded that the Morrow B sandstone reservoir is robust for CO2 injection. Most importantly, cement timing, the abundance and texture of reactive minerals, and the reservoir’s burial history are critical in predicting reservoir robustness and storage capacity for CO2 injection.

Wu, Zhidi (ORCID:0000000338869492)↗

Discordant K-Ar and Young Exposure Dates for the Windjana Sandstone, Kimberley, Gale Crater, Mars

K-Ar and noble gas surface exposure age measurements were carried out on the Windjana sandstone, Kimberley region, Gale Crater, Mars, by using the Sample Analysis at Mars instrument on the Curiosity rover. The sandstone is unusually rich in sanidine, as determined by CheMin X-ray diffraction, contributing to the high K2O concentration of 3.09 +/- 0.20 wt % measured by Alpha-Particle X-ray Spectrometer analysis. A sandstone aliquot heated to approximately 915 C yielded a K-Ar age of 627 +/- 50 Ma. Reheating this aliquot yielded no additional Ar. A second aliquot heated in the same way yielded a much higher K-Ar age of 1710 +/- 110 Ma. These data suggest incomplete Ar extraction from a rock with a K-Ar age older than 1710 Ma. Incomplete extraction at approximately 900 C is not surprising for a rock with a large fraction of K carried by Ar-retentive K-feldspar. Likely, variability in the exact temperature achieved by the sample from run to run, uncertainties in sample mass estimation, and possible mineral fractionation during transport and storage prior to analysis may contribute to these discrepant data. Cosmic ray exposure ages from He-3 and Ne-21 in the two aliquots are minimum values given the possibility of incomplete extraction. However, the general similarity between the He-3 (57 +/- 49 and 18 +/- 32 Ma, mean 30 Ma) and Ne-21 (2 +/- 32 and 83 +/- 24 Ma, mean 54 Ma) exposure ages provides no evidence for underextraction. The implied erosion rate at the Kimberley location is similar to that reported at the nearby Yellowknife Bay outcrop.

K-Ar↗