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At least 73 records · Page 4

Sensitivity of Multiangle, Multispectral Polarimetric Remote Sensing Over Open Oceans to Water-Leaving Radiance: Analyses of RSP Data Acquired During the MILAGRO Campaign

For remote sensing of aerosol over the ocean, there is a contribution from light scattered underwater. The brightness and spectrum of this light depends on the biomass content of the ocean, such that variations in the color of the ocean can be observed even from space. Rayleigh scattering by pure sea water, and Rayleigh-Gans type scattering by plankton, causes this light to be polarized with a distinctive angular distribution. To study the contribution of this underwater light polarization to multiangle, multispectral observations of polarized reflectance over ocean, we previously developed a hydrosol model for use in underwater light scattering computations that produces realistic variations of the ocean color and the underwater light polarization signature of pure sea water. In this work we review this hydrosol model, include a correction for the spectrum of the particulate scattering coefficient and backscattering efficiency, and discuss its sensitivity to variations in colored dissolved organic matter (CDOM) and in the scattering function of marine particulates. We then apply this model to measurements of total and polarized reflectance that were acquired over open ocean during the MILAGRO field campaign by the airborne Research Scanning Polarimeter (RSP). Analyses show that our hydrosol model faithfully reproduces the water-leaving contributions to RSP reflectance, and that the sensitivity of these contributions to Chlorophyll a concentration [Chl] in the ocean varies with the azimuth, height, and wavelength of observations. We also show that the impact of variations in CDOM on the polarized reflectance observed by the RSP at low altitude is comparable to or much less than the standard error of this reflectance whereas their effects in total reflectance may be substantial (i.e. up to >30%). Finally, we extend our study of polarized reflectance variations with [Chl] and CDOM to include results for simulated spaceborne observations.

Chowdhary, Jacek↗

Compendium of marine luminescence signatures, part 2 (appendix C)

Chlorophyll and Gelbstoff excitation and emission spectra of sea water samples are assembled according to geographic sites from the Atlantic and Gulf coasts, the west coast, and a location north of Hawaii. Data were taken by fluorescent spectrophotometer and include also laboratory algal cultures for comparison with the sea water samples.

Hornig, A. W.↗

Platinum-group elements (PGE) and Rhenium in Marine Sediments across the Cretaceous-Tertiary Boundary: Constraints on Re-PGE Transport in the Marine Environment

The nature of Re-platinum-group element (PGE; Pt, Pd, Ir, Os, Ru) transport in the marine environment was investigated by means of marine sediments at and across the Cretaceous-Tertiary boundary (KTB) at two hemipelagic sites in Europe and two pelagic sites in the North and South Pacific. A traverse across the KTB in the South Pacific pelagic clay core found elevated levels of Re, Pt, Ir, Os, and Ru, each of which is approximately symmetrically distributed over a distance of approx. 1.8 m across the KTB. The Re-PGE abundance patterns are fractionated from chondritic relative abundances: Ru, Pt, Pd, and Re contents are slightly subchondritic relative to Ir, and Os is depleted by approx. 95% relative to chondritic Ir proportions. A similar depletion in Os (approx. 90%) was found in a sample of the pelagic KTB in the North Pacific, but it is enriched in Ru, Pt, Pd, and Re relative to Ir. The two hemipelagic KTB clays have near-chondritic abundance patterns. The approx. 1.8-m-wide Re-PGE peak in the pelagic South Pacific section cannot be reconciled with the fallout of a single impactor, indicating that postdepositional redistribution has occurred. The elemental profiles appear to fit diffusion profiles, although bioturbation could have also played a role. If diffusion had occurred over approx. 65 Ma, the effective diffusivities are approx. 10(exp -13)sq cm/s, much smaller than that of soluble cations in pore waters (approx. 10(exp -5) sq cm/s). The coupling of Re and the PGEs during redistribution indicates that postdepositional processes did not significantly fractionate their relative abundances. If redistribution was caused by diffusion, then the effective diffusivities are the same. Fractionation of Os from Ir during the KTB interval must therefore have occurred during aqueous transport in the marine environment. Distinctly subchondritic Os/Ir ratios throughout the Cenozoic in the South Pacific core further suggest that fractionation of Os from Ir in the marine environment is a general process throughout geologic time because most of the inputs of Os and Ir into the ocean have OsAr ratios greater than or = 1. Mass balance calculations show that Os and Re burial fluxes in pelagic sediments account for only a small fraction of the riverine Os (less than 10%) and Re (less than 0.1%) inputs into the oceans. In contrast, burial of Ir in pelagic sediments is similar to the riverine Ir input, indicating that pelagic sediments are a much larger repository for Ir than for Os and Re. If all of the missing Os and Re is assumed to reside in anoxic sediments in oceanic margins, the calculated burial fluxes in anoxic sediments are similar to observed burial fluxes. However, putting all of the missing Os and Re into estuarine sediments would require high concentrations to balance the riverine input and would also fail to explain the depletion of Os at pelagic KTB sites, where at most approx. 25% of the K-T impactor's Os could have passed through estuaries. If Os is preferentially sequestered in anoxic marine environments, it follows that the OsAr ratio of pelagic sediments should be sensitive to changes in the rates of anoxic sediment deposition. There is thus a clear fractionation of Os and Re from Ir in precipitation out of sea water in pelagic sections. Accordingly, it is inferred here that Re and Os are removed from sea water in anoxic marine depositional regimes.

Lee, Cin-Ty Aeolus↗

A study of marine luminescence signatures, part 1

Fluorescent excitation and emission spectral data on chlorophyll and Gelbstoff in natural sea waters from the Atlantic, Gulf, and Pacific coasts show that algae particulates are totally absorbing over much of the near ultraviolet and visible spectra and act approximately as quantum counters; plant pigments absorb energy and transfer a large portion to chlorophyll where some fraction is emitted as chlorophyll fluorescence. Gelbstoff data do not exhibit quantum counter action because of their low concentration. It is concluded that luminescence data of natural sea waters are useful in monitoring algal and Gelbstoff as well as pollutant concentrations.

Hornig, A. W.↗

Statolith formation in Cnidaria: effects of cadmium on Aurelia statoliths

Statolith formation in Cnidaria was reviewed with an emphasis on Aurelia statoliths. The review provides information on the chemical composition, mechanisms of initiation of mineralization, and effects of environmental factors on Cnidarian statolith formation. Environmental factors discussed included modified sea water ingredients, X-irradiation, clinostat rotation, and petroleum oil ingredients. A detailed account of the effects of cadmium on mineralization and demineralization of Aurelia statoliths is given. Cadmium at dosages of 2 to 4 micromoles significantly reduces statolith numbers in developing ephyrae. At a dosage of 3 micromoles, cadmium accelerates statolith loss in unfed ephyrae studied at 4 and 8 days following ephyrae release from strobilae. Cadmium, therefore, is shown to reduce statolith numbers in developing ephyrae and to cause greater reduction of statolith numbers in unfed ephyrae after 4 and 8 days than occurred in controls. Supplementation of Cd(2+)-containing artificial sea water (ASW) with calcium (3X and 5X ASW calcium content) results in higher numbers of statoliths at day 4 as compared with cadmium-treated ephyrae. At 8 days only the 5X calcium supplemented ASW is effective in enhancing statolith numbers in Cd(2+)-treated ephyrae. These results suggest that cadmium competes in some manner with calcium at the mineralizing sites of Aurelia.

NASA Discipline Number 40-10↗

Some climatological variables for TOGA-COARE domains - 1985-1990

Results are presented of the Tropical Oceans Global Atmosphere-Coupled Ocean Atmosphere Response Experiment (TOGA-COARE) conducted in the western Pacific, with particular attention given to the atmospheric component of the experiment. The climatological variables explored are the mean sea level pressure, precipitable water, sea surface-air temperature difference, zonal wind component at 200 mb and 10 m, vertical motion at 500 mb, and precipitation rates. The paper provides some of the large-scale flow patterns in which other circulation features reside. Results are presented for three of the TOGA-COARE domains bounded by the following: (1) the Upper Air Network, 30 deg N-30 deg S, 90 deg E-70 deg W; (2) the Large-Scale Array, 10 deg N-10 deg S, 140 deg E-180 deg; and (3) the Equatorial Synoptic Array, 5 deg N-5 deg S, 150 deg E-180 deg.

Vincent, Dayton G.↗

An Integrated Examination of AMSR2 Products over Ocean

Integrated processing and analysis are presented for oceanic retrievals of precipitation, sea ice concentration, columnar water vapor and cloud water, sea surface temperature, and near surface wind from the advanced microwave scanning radiometer-2 (AMSR2) sensor. By developing a common algorithmic framework and permitting iterative interaction between historically separate science algorithms, ambiguous and contradictory retrieval results are minimized. The integration also serves to improve each algorithm individually, decreasing reliance on ancillary datasets. Case studies are presented that exemplify both ongoing challenges for these retrievals and potential research uses of such an integrated satellite product. Two cases are presented each for precipitation at high latitudes and marginal sea ice detection, with analysis supplemented by satellite data from CloudSat profiles and Himawari-8 imagery. Detection and retrieval of snowfall remains a challenge, while light rainfall detection can be aided by a variational algorithm. Sea ice concentrations below 20% cause disagreements, but the algorithms otherwise agree well on the sea ice edge. Potential mitigation strategies for ambiguous areas of light rainfall and marginal sea ice are discussed. The analysis demonstrates potential avenues for future algorithm development, but also some physical limitations of remote sensing with the AMSR2 frequencies.

variational methods↗

Photoproduction of carbonyl sulfide in south Pacific Ocean waters as a function of irradiation wavelength

Carbonly sulfide (OCS) photoproduction rates were measured at selected wavelengths of ultraviolet light between 297 and 405 nm in sea water samples from the southern Pacific Ocean. Near-surface and column production rate spectra for natural sunlit waters were calculated using sea-surface sunlight data measured near the austral summer solstice. These plots show that photoproduction rates are at a maximum at 313 nm in tropical waters and at 336 nm in Antarctic waters. Tropical surface and column rates were found to be 68 pM/day and 360 nmol/sq m/day, respectively, and Antarctic surface and column rates were found to be 101 pM/day and 620 nmol/sq m/day, respectively. A high degree of variability was observed between photoproduction rates from different ocean regions, with coastal rates being the highest, suggesting that natural environmental variability is an important factor. Photoproduction rates at 297 nm were found to be constant at individual locations with increasing irradiation time. Relative photoproduction rates from this work are compared to previously measured rates from coastal sea water.

Weiss, Peter S.↗

Ice-Shelf Tidal Flexure and Subglacial Pressure Variations

We develop a model of an ice shelf-ice stream system as a viscoelastic beam partially supported by an elastic foundation. When bed rock near the grounding line acts as a fulcrum, leverage from the ice shelf dropping at low tide can cause significant (approx 1 cm) uplift in the first few kilometers of grounded ice.This uplift and the corresponding depression at high tide lead to basal pressure variations of sufficient magnitude to influence subglacial hydrology.Tidal flexure may thus affect basal lubrication, sediment flow, and till strength, all of which are significant factors in ice-stream dynamics and grounding-line stability. Under certain circumstances, our results suggest the possibility of seawater being drawn into the subglacial water system. The presence of sea water beneath grounded ice would significantly change the radar reflectivity of the grounding zone and complicate the interpretation of grounded versus floating ice based on ice-penetrating radar observations.

tidal↗

Remote measurement of salinity: Repeated measurements over a single flight line near the Mississippi Sound

Experiments to remotely determine sea water salinity from measurements of the sea surface radiometric temperature over the Mississippi Sound were conducted. The line was flown six times at an altitude of 244 meters. The radiometric temperature of the sea surface was measured in two spectral intervals. The specifications of the equipment and the conditions under which the tests were conducted are described. Results of the tests are presented in the form of graphs.

Thomann, G. C.↗

Contributions of the Siberian shelf polynyas to the Arctic Ocean intermediate and deep water

To investigate the role of Siberian Shelf polynyas in water mass formation, and that of Whalers Bay in the cooling of the West Spitsbergen Current, satellite observations from the Nimbus 7 scanning multichannel microwave radiometer are used to determine the size and location of polynyas for November-March, 1978-1982. If salt contributes only to the Arctic Intermediate Water, the results show that the continental shelves can produce 20-60 percent of this water. Alternatively, if the salt contributes only to the deep water of the Eurasian Basin, then without consideration of the mixing of the bottom water with the Greenland and Norwegian Sea water, the contribution from the shelves yields a renewal time of about 100 years. These results imply that there is insufficient water produced in the shelf polynyas to perform all of the roles that have historically been assigned to it.

Martin, Seelye↗

The Dielectric Constant at P-Band for Salinity from 0 to 150 pss

Measurements have been made at P-band (0.707 GHz) to construct a model for the dielectric constant of sea water and extend the model for the dielectric constant to high salinity (50-150 pss). The measurements are part of research to develop a model for the dielectric constant suitable for future wide-bandwidth remote sensing of salinity and for application to water bodies such as the Great Salt Lake with salinity significantly above that found in the open ocean. Measurements have been made at temperatures from 2 to 30 °C and salinity from 0 to 138 pss. The data have been fit to a Debye model for the dielectric constant with a single resonance as has been employed at L-band (1.413 GHz) where remote sensing of salinity is currently done. Comparison with contemporary models developed from data at L-band indicates that the L-band model and new P-band model do well at both frequencies for salinity less than 50 pss but at higher values of salinity the L-band models diverge from the data. The data has also been used to test at high salinity the mathematical relationship between salinity and conductivity which is the basis for the practical salinity scale (pss).

Dielectric Constant↗

Active microwave measurements of artificial sea ice

A 5 m x 15 m outdoor tank of 1.2 m depth was filled with sea water, and polarimetric radar backscatter data were collected at 1.8, 5, and 10 GHz for incidence angles 0 to 60 deg. Observations commenced with open water and continued until 30 cm of sea ice formed. The roughness of the ice surface is important in determining the general backscatter level for first-year ice. Experiments were performed to study the change in backscatter with various roughness scales. Effects of freeze and thaw conditions were also examined. Absolute backscatter levels for new to gray ice are small, except for the large, coherent returns at vertical. The backscatter responses of new, gray, rough grey, and desalinated first-year ice at linear polarization are dissimilar. This is confirmed by examining their polarization signatures.

Onstott, R. G.↗

The Aquarius Salinity Retrieval Algorithm: Early Results

The Aquarius L-band radiometer/scatterometer system is designed to provide monthly salinity maps at 150 km spatial scale to a 0.2 psu accuracy. The sensor was launched on June 10, 2011, aboard the Argentine CONAE SAC-D spacecraft. The L-band radiometers and the scatterometer have been taking science data observations since August 25, 2011. The first part of this presentation gives an overview over the Aquarius salinity retrieval algorithm. The instrument calibration converts Aquarius radiometer counts into antenna temperatures (TA). The salinity retrieval algorithm converts those TA into brightness temperatures (TB) at a flat ocean surface. As a first step, contributions arising from the intrusion of solar, lunar and galactic radiation are subtracted. The antenna pattern correction (APC) removes the effects of cross-polarization contamination and spillover. The Aquarius radiometer measures the 3rd Stokes parameter in addition to vertical (v) and horizontal (h) polarizations, which allows for an easy removal of ionospheric Faraday rotation. The atmospheric absorption at L-band is almost entirely due to O2, which can be calculated based on auxiliary input fields from numerical weather prediction models and then successively removed from the TB. The final step in the TA to TB conversion is the correction for the roughness of the sea surface due to wind. This is based on the radar backscatter measurements by the scatterometer. The TB of the flat ocean surface can now be matched to a salinity value using a surface emission model that is based on a model for the dielectric constant of sea water and an auxiliary field for the sea surface temperature. In the current processing (as of writing this abstract) only v-pol TB are used for this last process and NCEP winds are used for the roughness correction. Before the salinity algorithm can be operationally implemented and its accuracy assessed by comparing versus in situ measurements, an extensive calibration and validation (cal/val) activity needs to be completed. This is necessary in order to tune the inputs to the algorithm and remove biases that arise due to the instrument calibration, foremost the values of the noise diode injection temperatures and the losses that occur in the feedhorns. This is the subject of the second part of our presentation. The basic tool is to analyze the observed difference between the Aquarius measured TA and an expected TA that is computed from a reference salinity field. It is also necessary to derive a relation between the scatterometer backscatter measurements and the radiometer emissivity that is induced by surface winds. In order to do this we collocate Aquarius radiometer and scatterometer measurements with wind speed retrievals from the WindSat and SSMIS F17 microwave radiometers. Both of these satellites fly in orbits that have the same equatorial ascending crossing time (6 pm) as the Aquarius/SAC-D observatory. Rain retrievals from WindSat and SSMIS F 17 can be used to remove Aquarius observations that are rain contaminated. A byproduct of this analysis is a prediction for the wind-induced sea surface emissivity at L-band.

Meissner, Thomas↗

Multifrequency radiometer detection of submarine freshwater sources along the Puerto Rican coastline

The surface area above submarine springs of fresh water exhibit temperatures and salinities lower than the surrounding sea waters. A multifrequency radiometer system which earlier demonstrated an accuracy of 1 degree C and 1 part per thousand in remotely detecting the surface temperature and salinities, respectively, was used to detect submarine freshwater springs. The first mission on February 4, 1978, consisted of overflight measurements over three fourths of the coastal areas around the Island of Puerto Rico. During the second mission on February 6, 1978, special attention was directed to the northwest portion of Puerto Rico where several submarine springs had been reported. The previously reported spring locations correlated well with the locations detected by the radiometers. After separating the surface runoffs such as rivers, lagoons, marshes, and bays, 44 submarine freshwater springs were identified which indicates that the submarine freshwater outflow locations are more numerous around the island than had earlier been estimated. The majority of the submarine springs are located at the northwest and southeast portion of the Puerto Rican coastline. The success of detecting the same submarine springs during both missions at the northwest portion of the island was 39%.

Blume, H.-J. C.↗

Pb isotopes in surficial pelagic sediments from the North Atlantic

The concentration of Pb and its isotopic composition were measured in samples from the surface of sea-water sediments obtained from the northeastern Atlantic, the Sargasso Sea, and the U.S. continental shelf, with the purpose of investigating changes in Pb sources due to the anthropogenic perturbation that took place in modern times. It was found that the anthropogenic Pb input to marine sediments due to the increase of Pb contamination over the ocean during the last century could be identified in all these samples. However, samples from eastern and western Atlantic had very different Pb isotopic profiles, each reflecting the character of anthropogenic Pb emissions from the European and U.S. industries, respectively.

Hamelin, B.↗