Three-Dimensional Spirals of Conjugated Block Copolymers Driven by Screw Dislocation
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The dendron-shaped macromolecules AB n crystallize into well-ordered pyramid-like structures from mixed solvents, which is on the contrary to spherical motifs with curved structures in bulk.
Summary Starch and protein are important components of food, the mixed system formed between them (complexes, gels, mixtures, etc.) can improve the physical and chemical properties of starch and protein, and its potential application in the food industry has also attracted widespread attention. In this study, indica rice flour and soybean 7S protein (β‐Conglycinin) were used as the experimental materials to explore the effect of soybean 7S protein addition on the quality and digestibility of rice noodles. Aims to develop rice noodles with high protein and low GI, so that people can take care of their health while satisfying their appetites. The results showed that with the increase of soybean 7S protein addition, the starch digestibility decreased, resulting in the estimated glycaemic index (eGI) and glycaemic load (GL) decreasing. However, the cooking loss rate and breakage rate of rice noodles gradually increased, the water absorption first increased and then decreased, and the taste of rice noodles is acceptable when the 7S protein addition amount is within 9%. The interaction between starch and soybean 7S protein was mediated by weak interactions such as hydrogen bonds and hydrophobic forces indicated by Fourier transform infrared spectroscopy (FTIR) and X‐ray diffraction (XRD).
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During the first phase of this project, small and large Strangpresse extruders were assessed at Oak Ridge National Laboratory’s Manufacturing Demonstration Facility (MDF). This phase resulted in Strangpresse exclusively licensing some of ORNL’s previously developed extruder technology for high-volume thermoplastic additive manufacturing (AM). Phase II of this project will focus on further development and optimization of Strangpresse extruders for increased efficiency and increased throughput. The objective of this project is to develop a new extruder with a higher output and less energy usage than current AM thermoplastic extruders and to develop and evaluate a new tamper mechanism for increasing Z-strength resulting in an advanced and optimized extruder and tamper system.
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This project has demonstrated the key components and engineering principles to support a residential scale (1 to 2 kWe) recuperated Brayton cycle generator based upon a screw compressor and screw expander. This technical work is a continuation of the previously awarded ‘GENSETS’ program. The product goal has been to achieve a 40% fuel-to-electric LHV efficiency, an 80% overall CHP efficiency, emissions qualified to the California Air Resources Board standards, and at noise levels of 55 dB or less at 1 meter. Further, the product must operate with 8,000 hour service intervals and achieve a mean-time to overhaul of 90,000 hours. Lastly, and possibly most importantly, the product must meet demanding cost targets, exhibiting a factory cost well below $1,500/kWe. After extensive aerodynamic studies under the ‘GENSETS’ program, Brayton concluded that miniature turbomachinery could not achieve an efficiency consistent with the product’s system performance goal. Given compressor and turbine efficiency targets in the range of 78 to 81%, Brayton turned to the rotary screw machines. While the justification for a screw compressor over a conventional centrifugal compressor is well supported by industry experience, the high temperature expander represented the core technology advancement. To meet the extremely high efficiency goals, an all-ceramic rotary screw expander hot section was developed and has now been tested in the laboratory. This first-of-its-kind ceramic screw expander prototype was able to demonstrate aerodynamic efficiency in line with predictions. The test article was successfully run to full stress conditions so has also validated the mechanical design of such a unit. This has opened new avenues for the commercialization of high efficiency, small scale power generation. Interest in the technology has sparked several requests for alternate uses, an invitation to present at a screw machine conference, and continued interest from parties looking to develop a product in the spirit of the original ‘GENSETS’ goals.
Global interest for using terrestrial biomass as an energy source has been increasing recently due to potentially significant socio-economic and environmental benefits relative to fossil energy. Thermochemical biomass processes converting biomass to fuels are relatively well developed, e.g. for direct combustion, gasification, and pyrolysis. However, critical problems often arise when attempting to feed biomass into commercial-scale reactors continuously and without interruption. Biomass particles, whether derived from woody or agricultural feedstock, vary greatly in size, shape, density, and moisture content. High cohesiveness, low bulk density, and poor material flow characteristics often prevent continuous feeding due to bridging, rat-hole formation, blockage, and seal failures. Among all different types of feeders utilized to feed biomass into reactors, screw feeding has received significant attention in recent years. Screw feeders are fuel-specific and require careful design to be reliable, efficient, and economical, especially for reactors operating at elevated pressures. In order to mimic the flow properties of compressed biomass inside a compression-screw feeder, rheological properties of three types of compressed lignocellulosic biomass were investigated using a co-rotating twin screw microcompounder. Experiments were conducted to find the impact of moisture content, particle size and type, and screw speed on rheological properties of forest residual particles as well as sawdust. Increasing moisture from 10 to 50% reduced the apparent viscosity of the compressed biomass. Also, higher screw speeds (10 to 90 rpm) led to a lower relative viscosity. At elevated screw speeds, significant temperature differences were measured between the initial and final states, which should be accounted for in equipment design and operation.
The interaction of xylan, an abundant plant polysaccharide, with cellulose microfibrils is essential for secondary cell wall strength. A deeper understanding of these interactions is crucial both to improve our understanding of plant cell wall architecture and to design alternate strategies to overcome cellulose recalcitrance for the production of biofuels and sustainable biomaterials. Naturally occurring acetate or glucuronic acid substitutions on xylan have been shown to influence xylan-cellulose interactions. In this work, we use unrestrained molecular dynamics simulations to determine the interactions with the (110) hydrophilic face of cellulose fibers of four different xylans. In the absence of cellulose, all xylans, independent of the substitution pattern, adopt a highly flexible threefold helical screw conformation. However, when xylan is spatially close to a cellulose surface 1,2 linked acetyl xylans (2AcX) adopt rigid twofold helical screw conformations. The 2AcX conformations are primarily stabilized by interactions between the acetylated oxygen and the glycosidic linkage with C-O6 of cellulose. In contrast, the glycosidic oxygens and acetyl decorations for 1,3 linked acetyl groups (3AcX) are oriented away from the cellulose surface and the 3AcX xylans maintain threefold helical screw conformations on the cellulose surface. Our results show that evenly spaced chemical functionalization (with acetyl groups) and the position of substitution (1,2) on xylan backbone play key roles in tuning the xylan-cellulose interactions to stabilize the twofold helical screw conformations of xylan on the cellulose surface. A comparison with previous experimental findings further suggests that 1,2 substitutions induce twofold helical screw conformations of xylan on the cellulose surface irrespective of the chemical nature of the substituent, while 1,3 substitutions primarily bind lignin in threefold helical screw conformations rather than cellulose in plant cell walls.
Transport of milled solid biomass can be problematic in biomass conversion processes due to the material’s high cohesiveness, low bulk density, and poor flowability. Here, the goal is to investigate the flow behavior of compressed biomass under conditions similar to compression-screw feeders. To mimic the flow of woody biomass inside a compression-screw feeder, two lignocellulosic biomass feedstocks were fed to a co-rotating twin-screw microcompounder. Force and screw speed from the microcompounder were correlated to viscosity in a traditional rheometer, where low-density polyethylene served as a control. The deformation of compressed biomass in a lab-scale compounder is strongly dependent on screw speed and moisture content. Shear stress in woody biomass decreased with the shear rate, indicating negative plastic viscosity. Moreover, viscosity decreased one order of magnitude as screw speed increased from 10 to 90 rpm. Increasing moisture from 10 to 50% reduced the viscosity of the compressed biomass by 60%.
Refractory multi-principal element alloys (RMPEAs) combine a chemically disordered lattice with a structurally ordered, single‐phase body‐centered cubic (bcc) crystal structure. Chemical fluctuations in these alloys give rise to significant energy barriers that impede dislocation motion. In this study, we use phase field dislocation dynamics to examine how spatial temperature fluctuations compete with randomness in energy barriers to affect the motion of long screw dislocations in three equi-atomic MoNbTa‐based RMPEAs: MoNbTa, MoNbTaW, and MoNbTaVW. Over a wide range of homologous temperatures (T h ≈ 0–0.6), we determined a screw dislocation ‘flow stress’ as the minimum applied stress to sustain continuous motion over a long excursion distance within a fixed timeframe. All three RMPEAs exhibit temperature dependent flow stress with three characteristic glide regimes: at low homologous temperatures, flow stress drops sharply, and screw glide remains planar and rectilinear; at intermediate homologous temperatures, the flow stress levels off as glide becomes planar but wavy; and at high homologous temperatures, flow stress plateaus as screws exhibit nonplanar, three‐dimensional motion. Glide kinetics and transition temperatures are controlled by the chemically induced fluctuations in the energy landscape. The rectilinear to wavy transition temperature is controlled by statistically weakest local barriers in the glide plane, whereas the wavy to 3D transition temperature is governed by statistically strongest local barriers. At low and intermediate homologous temperatures, the relative spread in energy barriers governs glide behavior by controlling the local kinetics of kink pair formation and kink pinning. At high homologous temperatures, the average barrier height governs the glide behavior by controlling the number of out-of-plane excursions during 3D glide. These findings reveal how random chemical fluctuations determine screw‐driven plasticity in RMPEAs, providing critical insight for the design of high temperature structural alloys.
Cross-slip is a thermally activated process by which screw dislocation changes its glide plane to another slip plane sharing the same Burgers vector. The rate at which this process happens is determined by a Boltzmann type expression that is a function of the screw segment length and the stress acting on the dislocation. In continuum dislocation dynamics (CDD), the information regarding the length of the screw dislocation segment and local stress state on dislocations are lost due to the coarse-grained representation of the density. Here, in this work, a data driven approach to characterize the lost information by analyzing the discrete dislocation configurations is proposed to enable cross-slip modeling in the CDD framework in terms of the coarse-grained dislocation density and stress fields. The analysis showed that the screw segment length follows an exponential distribution, and the stress fluctuations, defined as the difference between the stress on the dislocations and the mean field stress in CDD, follows a Lorentzian distribution. A novel approach for cross slip implementation in CDD employing the screw segment length and stress fluctuation statistics was proposed and rigorously tested by comparing the CDD cross-slip rates with discrete dislocation dynamics (DDD) rates. This approach has been applied in conjunction with three cross-slip models used in DDD simulations differing mainly in the functional form of cross slip activation energy. It was found that different cross-slip activation energy formulations yielded different cross-slip rates, yet the effect on mechanical stress-strain response and dislocation density evolution was minimal for the [001] type loading.