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All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Exobiology site priorities for Mars Pathfinder

The fact that life developed on the Earth within the first billion years of its history makes it quite plausible that life may have also developed on Mars. If life did develop on Mars, it undoubtedly left behind a fossil record. Such a fossil record is likely to be more accessible than either subsurface environments that may harbor life, or scattered 'oases' that may be present at the surface. Consequently, the post-Viking approach of Mars exobiology has shifted focus to search for evidence of an ancient martian biosphere. This has led to the emergence of a new subdiscipline of paleontology, herein termed 'exopaleontology', which deals with the exploration for fossils on other planets and whose core concepts derive from Earth-based Precambrian paleontology, microbial ecology, and sedimentology. Potential targets on Mars for subaqueous spring deposits, sedimentary cements, and evaporites are ancient terminal lake basins where hydrological systems could have endured for some time under arid conditions. Potential targets for the Mars Pathfinder mission include channeled impact craters and areas of deranged drainage associated with outflows in northwest Arabia and Xanthe Terra, where water may have ponded temporarily to form lakes. The major uncertainty of such targets is their comparatively younger age and the potentially short duration of hydrological activity compared to older paleolake basins found in the southern hemisphere. However, it has been suggested that cycles of catastrophic flooding associated with Tharsis volcanism may have sustained a large body of water, Oceanus Borealis, in the northern plains area until quite late in martian history. Although problematic, the shoreline areas of the proposed northern ocean provide potential targets for a Mars Pathfinder mission aimed at exploring for carbonates or other potentially fossiliferous marine deposits. Carbonates and evaporites possess characteristic spectra signatures in the near-infrared and should be detectable using rover-based spectroscopy and other methods for in situ mineralogical analysis.

Farmer, Jack D.↗
NASA NTRS2014

Evidence for a Noachian-Aged Ephemeral Lake in Gusev Crater, Mars

Gusev crater was selected as the landing site for the Spirit rover because of the likelihood that it contained an ancient lake. Although outcrops rich in Mg-Fe carbonate dubbed Comanche were discovered in the Noachian-aged Columbia Hills, they were inferred to result from volcanic hydrothermal activity. Spirit encountered other mineral and chemical indicators of aqueous activity, but none was recognized as definitive evidence for a former lake in part because none was associated with obvious lacustrine sedimentary deposits. However, water discharge into Martian crater basins like Gusev may have been episodic, producing only small amounts of sediment and shallow ephemeral lakes. Evaporative precipitation from such water bodies has been suggested as a way of producing the Mg- and Fe-rich carbonates found in ALH84001 and carbonates and salts in some nakhlites a hypothesis we examine for the Comanche carbonate.

Ruff, S. W.↗
NASA NTRS1998

Ma'adim Vallis Estuarine Delta in Elysium Basin and Its Relevance as a Landing Site for Exobiology Exploration on Mars

The debouche of Ma'adim Vallis in the Elysium Basin generated a transitional transported sediment structure, which planimetric shape is controlled by the enclosing topography of a deep reentrant gulf of the Basin into the highland. We defined it as an estuarine delta. The location and the importance of this estuarine delta is supported by the theoretical model of graded profile constructed for Ma'adim Vallis, and by two approaches: (i) the reconstruction of Ma'adim Vallis downstream course from Gusev to Elysium Basin, and (ii) the survey of the sediment deposit in the alleged estuary. The longitudinal graded profile of Ma'adim Vallis finds its base-level in the Elysium Basin, at a about 1000 m elevation, which is in agreement with the observed Basin shoreline. This model is supported by observational evidence of flow between the northern rim of Gusev crater, and the Elysium Basin shoreline. This downstream course of Ma'adim Vallis can be divided into three hydrogeologic regions. into three hydrogeologic regions. (a) The first region is a flooded plain (Zephiria Mensae), consisting in chaotic terrain formed by highland rocks, and disintegrated lava of the western flank of Apollinaris. Morphologic indicators of the flood process are: (1) the sediment deposit over the Gusev crater northern rim that reflects the overspilling of the crater-lake water through a 40-km wide gap provided by an ancient impact crater, (2) the tear-drop shaped feature on the northeastern flank of Apollinaris Patera, and (3) the chaotic terrain that suggest the emergence of ground water generated by the seepage of the crater lake through high-permeable broken rampart material. This underground water circulation sustained by the hydrostatic pressure of the crater-lake has likely generated a hydrothermal system in the volcanic environment of Apollinaris Patera. The stratigraphy of the flooded area is identified as Hesperian age, with occurrences of Noachian hilly individual features, and as Amazonian flooded plain and chaotic material, (b) The second region is located on the western flank of Apollinaris Patera. It is surrounded by relics of deep valleys that suggest a former downstream course of Ma'adim Vallis. The geologic setting of this region (Lucus Planum) is interpreted to be an Amazonian formation composed by the middle and lower members of the Medusae Formation., c) The third region corresponds to the convergence of the west and east branches of Ma'adirn Vallis into a deep re-entrant wide gulf that penetrates about 100 km into the highland. This topographic depression is delineated by the 1000 in elevation contour. This gulf has formed an estuarine configuration centered at 3S/190W within the Elysium Basin. This configuration has favored the formation of a estuarine sedimentary delta, because of topographically controlled lateral migration. This estuarine structure is strongly dominated by the incoming supply of Ma'adim Vallis fluvial sediment extracted from Zephiria Mensae and Lucus Planum. The obtuse-angle geometry of the estuary increases the sedimentation rate, which is higher than in the course of the channel. The sediment deposition process is governed by the estuarine water circulation. The inflowing loaded fluvial water enters the estuary as a bottom current, and mixes with the relatively less-loaded water of the receiving basin. When they mixed. the inflowing fluvial material, and the landward basin circulating water generate an accumulation of highly-diversified estuarine deposit stratification. This accumulation of material is mostly centered in the transitional zone of the delta. The sediment trapping efficiency of the estuary is function of the energy balance between the inflowing fluvial water, and the ingoing basin current. The submergence of the delta by the rising of the water-level increases the estuary water-depth, and consequently the sediment entrapment is favored. The locus of sediment accumulation moves landward in the zone of inflowing fluvial water. This results in the rising of the channel base-level, thus in the increase of the length of the longitudinal graded-profile. The sediment deposit facies of the zone A shows a generally smooth surface. The longitudinal deposit is bordered by alluvial terraces that reflect the variations of the channel level. The waning of the Elysium Basin caused the erosion of the Basin estuarine zone by small channels, this episode being characterized by dissected tear-drop shaped mesa-like morphologies in the delta. Our estuarine delta model predicts a lithostratigraphic depositional sequence associated with the water submergence and the transgression of Elysium Basin. The thickness of the estuarine sediment corresponds to the Elysium Basin levels changes relatively to the bed floor of the estuary, The depositional sequence of Ma'adim Vallis are described: (1) a pro-current filled region (A), where fluvial are longitudinally accumulated by the inflowing water, (2) inverse current from Elysium Basin (B), where fluvial and lacustrine sediments are accumulated, and (3) zone of current equilibrium (C), where the sediments are distributed as a shoreline at the boundary of the estuarine delta. The estuary sedimentology dynamics collects and keeps the record of the geologic unit material crossed by Ma'adim Vallis, and those of the lakebed deposit of Elysium Basin. The predicted mixed stratigraphic sequence from fluvial and lacustrine sediment makes this site an exceptional environment to concentrate potential multi-origin biologic records. We envision four possible strategies to explore this sedimentologic record: (1) longitudinal surface and subsurface traverses in region A to investigate outcrop levees, (2) exploration of the mesa walls in region B, (3) deep drilling hole lodging of the sequential deposits in the zones A and B, and (4) surface and subsurface exploration of the shoreline delta. The expected results for each of these strategies are: (1) in the deepest layers of region A are predicted frequent and abundant coarse material, sandy lenses lamination grading downward from sand to cobbles. Volcanic debris from the Noachian crustal Plateau unit material, hydrothermal altered rocks, carbonates, Hesperian and possibly Amazonian volcanic material, from Apollinaris Patera, altered rocks and carbonates from Zephiria Mensae are expected. As a favorable environment for inception of life, possible biological records are expected in transported rock, (2) At the surface, and subsurface (<=100 m), large deposits sandy to silted material from Elysium paleolake basin mixed with fine-grained sediments from Ma'adim Vallis are expected mostly in the upstream part of region B, (3) on the shoreline of the estuarine delta, abundant fine material from Elysium paleolake basin (evaporites, carbonates), mostly Amazonian in age are expected. The Ma'adini estuary is a favorable landing site for all the above mentioned science aspects, and .for its location. The site lies near the equator, which is favorable for the rover solar power supply, and at 1000m elevation, which is a favorable configuration for the descent system braking. Another advantage is the extent of the area of high scientific interest (33,000 sq km), which provides a good ellipse, and potential long study traverses.

Grin, E. A.↗
NASA NTRS1984

Relation of MAGSAT Anomalies to the Main Tectonic Provinces of South America

Comparison of MAGSAT scalar magnetic anomaly data to the main tectonic provinces and boundaries of South America reveals a number of geologic correlations. South America is divisible into a broad platform of Precambrian shields and cratons separated by Phanerozoic basins, grabens and aulacogens to the east, the Phanerozoic Patagonian Platform to the south, and the Mesozoic to Cenozoic Andean Fold Belt and Caribbean Mountain System to the west and north. The continental shields are mainly more magnetic then continental basins and orogenic belts. Cratons, mainly covered by younger sedimentary rocks, are generally associated with magnetic gradients. Most of the anomalies associated with the Patagonian Platform are positive and have higher amplitudes eastward away from the Andean Fold Belt. The northern Andes are coincident with positive magnetic anomalies, whereas the central and southern Andes are associated mainly with negative anomalies.

Lidiak, E. G.↗
NASA NTRS1990

Processing Of Multispectral Data For Identification Of Rocks

Linear discriminant analysis and supervised classification evaluated. Report discusses processing of multispectral remote-sensing imagery to identify kinds of sedimentary rocks by spectral signatures in geological and geographical contexts. Raw image data are spectra of picture elements in images of seven sedimentary rock units exposed on margin of Wind River Basin in Wyoming. Data acquired by Landsat Thematic Mapper (TM), Thermal Infrared Multispectral Scanner (TIMS), and NASA/JPL airborne synthetic-aperture radar (SAR).

Evans, Diane L.↗
NASA NTRSDate not supplied

Overview and Initial Results of DIGMARS: Digging Iceland Geology for Mars Analog Research Science

Preserved in the sedimentary rocks of Mars is a rich record of ancient surface environments and burial diagenesis. Sequences of sandstones and mudstones that indicate sedimentation in deltaic and lacustrine environments have been encountered by the Curiosity rover in Gale crater and likely will be by the Perseverance rover in Jezero crater [1-3]. The compositional variability in these sedimentary rocks points to a complex diagenetic story that bears significantly on the basin history and early martian environment. Because interaction of percolating groundwaters and with unconsolidated sediments is a process commonly observed in lacustrine environments on Earth [4], groundwater has been invoked to develop a sedimentary history for Gale crater [e.g., 5-9]. Unique conceptual models, each with their own implications for the paleoenvironment and hydrologic conditions have been put forward. However, we currently lack a terrestrial reference frame for groundwater-driven diagenesis in a basalt dominated watersheds on Earth. The Digging Iceland Geology for Mars Analog Research Science (DIGMARS) project aims to close this research gap, with the goal of exploring groundwater-sediment interaction from lakes around Iceland. Here, we present the initial results for the 2021 field campaign and the laboratory analysis of aqueous and sediment samples.

M T Thorpe↗
NASA NTRS1988

Multisensor classification of sedimentary rocks

A comparison is made between linear discriminant analysis and supervised classification results based on signatures from the Landsat TM, the Thermal Infrared Multispectral Scanner (TIMS), and airborne SAR, alone and combined into extended spectral signatures for seven sedimentary rock units exposed on the margin of the Wind River Basin, Wyoming. Results from a linear discriminant analysis showed that training-area classification accuracies based on the multisensor data were improved an average of 15 percent over TM alone, 24 percent over TIMS alone, and 46 percent over SAR alone, with similar improvement resulting when supervised multisensor classification maps were compared to supervised, individual sensor classification maps. When training area signatures were used to map spectrally similar materials in an adjacent area, the average classification accuracy improved 19 percent using the multisensor data over TM alone, 2 percent over TIMS alone, and 11 percent over SAR alone. It is concluded that certain sedimentary lithologies may be accurately mapped using a single sensor, but classification of a variety of rock types can be improved using multisensor data sets that are sensitive to different characteristics such as mineralogy and surface roughness.

Evans, Diane↗
NASA NTRS2009

"The Waters of Meridiani" - Further Support for a Fluvial Interpretation of the Ridged, Layered Units

A relatively unknown terrestrial fluvial environment, the mesoscale megafan, provides analogs for various Martian landscapes, including the etched unit (etched unit, Unite E of Arvidson et al., 2003; ridge-forming unit R of Edgett, 2005) of the Sinus Meridiani region on Mars. A global survey of Earth shows that megafans are very large partial cones of dominantly fluvial sediment with radii on the order of hundreds of km, and very low slopes. Responsible fluvial processes are sufficiently different from those of classical arid alluvial fans and deltas that it is useful to class megafans as separate features. The megafan model calls into question two commonly held ideas. 1. Earth examples prove that topographic basins per se are unnecessary for the accumulation of large sedimentary bodies. 2. River channels are by no means restricted to valleys (Meridiani sediments are termed a "valley-ed volume" of Edgett). These perspectives reveal unexpected parallels with features at Meridiani-several channel-like features that are widespread, mostly as ridges inverted by eolian erosion; channel networks covering thousands of sq km, especially on intercrater plains; and regional relationships of sediment bodies situated immediately downstream of highland masses. These all suggest that fluvial explanations are at least part of the Meridiani story.

Wilkinson, Justin↗
NASA NTRS2019

Untangling Source-To-Sink Geochemical Signals in a ~3.5 Ga Martian Lake: Sedimentology and Geochemistry of the Murray Formation

Sedimentary rocks are historical archives of planetary surface processes; their grains, textures, and chemistry integrate the effects of source terrains, paleoclimatic conditions, weathering and transport processes, authigenic mineral precipitation, and diagenesis, which records groundwater chemistry through time. “Source to Sink” basin analysis seeks to constrain the influence of each of these different signals through sedimentary and geochemical analyses. Here, we use Mars Science Laboratory (MSL) Curiosity rover images and geochemical and mineralogical data from a traverse across a portion of the Murray formation—the lowermost unit exposed in the Gale crater central mound—to begin to constrain the aspects of the source to sink system that formed this Martian mudstone between 3.7 and 3.2 Ga.

Siebach, K. L.↗
NASA NTRS1985

The relationship of extensional and compressional tectonics to a Precambrian fracture system in the eastern overthrust belt, USA

The central and southern Appalachians have a long history of interrelated extensional and compressional tectonics. It is proposed that each episode was controlled by a reactivation of a fracture system in the Precambrian basement. Proprietary seismic-reflection profiles show a system of down-to-the-east Precambrian extensional faults. When under renewed extension, these faults produce features such as the western border faults of Mesozoic basins, and when under compression, probably produce tectonic ramps in the overlying sedimentary cover rocks as well as the spatially and genetically related Alleghenian folds. This system, which parallels the Appalachian trend, is cut by a system of cross-strike hinge or scissors faults that have probable strike-slip movements. Reactivation of this cross-strike system appears to have produced lateral ramps that connect decollements at different stratigraphic levels and caused abrupt changes in fold wavelength along strikes. Continued reactivation of this cross-strike system is suggested by east-west border faults and Precambrian highs between Mesozoic basins. The present activity of this system is suggested by the fact that more than 35% of recent earthquakes are coincident with cross-strike faults and lateral ramps.

Pohn, H.↗
NASA NTRS1993

Tectonic controls on rift basin morphology: Evolution of the northern Malawi (Nyasa) rift

Radiometric (K-Ar and Ar-40/Ar-39) age determinations of volcanic and volcaniclastic rocks, combined with structural, gravity, and seismic reflection data, are used to constrain the age of sedimentary strata contained within the seismically and volcanically active northern Malawi (Nyasa) rift and to characterize changes in basin and flank morphologies with time. Faulting and volcanism within the Tukuyu-Karonga basin began at approximately 8.6 Ma, when sediments were deposited in abroad, initially asymmetric lake basin bounded on its northeastern side by a border fault system with minor topographic relief. Extensions, primarily by a slip along the border fault, and subsequent regional isostatic compensation led to the development of a 5-km-deep basin bounded by broad uplifted flanks. Along the low-relief basin margin opposite border fault, younger stratigraphic sequences commonly onlap older wedge-shaped sequences, although their internal geometry is often progradational. Intrabasinal faulting, flankuplift, and basaltic and felsic volcanism from centers at the northern end of the basin became more important at about 2.5 Ma when cross-rift transfer faults developed to link the Tukuyu-Karonga basin to the Rukwa basin. Local uplift and volcanic construction at the northern end of the basin led to a southeastward shift in the basin's depocenter. Sequence boundaries are commonly erosional along this low-relief (hanging wall) margin and conformable in the deep lake basin. The geometry of stratigraphic sequences and the distribution of the erosion indicate that horizontal and vertical crustal movements both across and along the length of the rift basin led to changes in levels of the lake, irrespective of paleoclimatic fluctuations.

Ebinger, C. J.↗
NASA NTRS2006

Widespread Layers in Arabia Terra: Implications for Martian Geologic History

Layered rocks in Arabia Terra have been the focus of several recent papers. Studies have focused on the layers found in crater basins located in the southwest portion of the region. However, Mars Orbiter Camera (MOC) images have identified layered deposits across the region. Terrestrial layered rocks are usually sedimentary, and often deposited in water. Thus extensive layered sequences in Arabia Terra may indicate locations of past, major depositional basins on Mars. Other mechanisms can also create layered rocks, or the appearance of layered rocks, including volcanism (both lava flows and ash falls), wind-blown deposits, and wave-cut terraces at shorelines. By identifying where in the region layers occur, and classifying the layers according to morphology and albedo, past depositional environments may be identified. Arabia Terra is characterized by heavily cratered Noachian plains, as well as a rise from -4000 m in the northwest to 4000 m in the southeast (Mars Orbital Laser Altimeter [MOLA] datum). This slope may have provided a constraint on sediment deposition and thus layer formation. While most of the region is Noachian in age, a significant percentage of the area is identified as Hesperian. Although the history of the Arabia Terra initially seems to be straightforward cratered plains with several younger units atop them analysis of high-resolution imagery may reveal a more complex history.

Venechuk, Elizabeth M.↗
NASA NTRS1992

Does the sedimentology of the Chelmsford formation provide evidence for a meteorite impact origin of the Sudbury structure?

The post-'event' fill of the Paleoproterozoic Sudbury Basin consists of at least 600 m of deep-water mudrocks of the Onwatin Formation, overlain by 850 m of lithic-arkosic muddy sandstones in the Chelmsford Formation. While mudstones of the Onwatin reflect deposition in a deep-water, anoxic setting, there is no clear evidence of local breccias, conglomerates, or sand bodies to support the concept that the basin was protected by the steep walls of an impact crater. Carbonates in the basal, Vermillion Member are of sedimentary exhalitive origin and were not derived from a shallow marine shelf. Turbidites in the Chelmsford Formation show no evidence of centripetal fill as might be expected from a restricted, circular basin. They appear to have been emplaced by predominantly southwesterly flowing turbidity currents, which showed little to no deflection along the depositional axis of an elongate foreland basin that developed in front of the rising Penokean mountain chain. While the presence of minor sandstone-filled fractures in parts of the Chelmsford Formation suggests the presence of north- or south-directed paleoslopes, no evidence is seen to support the existence of subbasins or a central uplift within the Sudbury Basin. While tilt-corrected paleocurrent orientations are ambiguous, due to postdepositional shortening of strata during cleavage development, strain correction of the observations makes little difference to the net, south-southwest-directed paleoflow.

Long, D. G. F.↗
NASA NTRS1979

Discrimination of hydrothermally altered rocks along the Battle Mountain-Eureka, Nevada mineral belt using LANDSAT images

The author has identified the following significant results. Limonitic alteration halos associated with two copper prophyry deposits were successfully mapped at Battle Mountain. Alteration halos from both a hypogene system at Copper Canyon and a supergene system at Copper Basin are recognizable in the composite. Both copper porphyry deposits are located in sedimentary rock units that commonly have ferruginous coatings; yet, in most cases, the hydrothermally derived limonite was distinguishable in the CRC from sedimentary limonite. Large format playback images with pixel sizes from 200 to 400 micron m provided details of spatial resolution and color separation unachievable on enlargements from 70 mm film chips. Details of the alteration halos could be resolved only in the large format images. Two aspects of the alteration halos of the porphyry copper deposits were not mapped on the CRC. The optimum CRC image for the area studied consists of MSS 4/5 as blue, MSS 4/6 as yellow, and MSS 6/7 as magenta using diazo films. The disseminated gold deposits at Gold Acres are not depicted in the CRC image.

Krohn, M. D.↗
NASA NTRS2013

The Origin of Carbon-bearing Volatiles in Surprise Valley Hot Springs in the Great Basin: Carbon Isotope aud Water Chemistry Characterizations

There are numerous hydrothermal fields within the Great Basin of North America, some of which have been exploited for geothermal resources. With methane and other carbon-bearing compounds being observed, in some cases with high concentrations, however, their origins and formation conditions remain unknown. Thus, studying hydrothermal springs in this area provides us an opportunity to expand our knowledge of subsurface (bio)chemical processes that generate organic compounds in hydrothermal systems, and aid in future development and exploration of potential energy resources as well. While isotope measurement has long been used for recognition of their origins, there are several secondary processes that may generate variations in isotopic compositions: oxidation, re-equilibration of methane and other alkanes with CO2, mixing with compounds of other sources, etc. Therefore, in addition to isotopic analysis, other evidence, including water chemistry and rock compositions, are necessary to identify volatile compounds of different sources. Surprise Valley Hot Springs (SVHS, 41º32'N, 120º5'W), located in a typical basin and range province valley in northeastern California, is a terrestrial hydrothermal spring system of the Great Basin. Previous geophysical studies indicated the presence of clay-rich volcanic and sedimentary rocks of Tertiary age beneath the lava flows in late Tertiary and Quaternary. Water and gas samples were collected for a variety of chemical and isotope composition analyses, including in-situ pH, alkalinity, conductivity, oxidation reduction potential (ORP), major and trace elements, and C and H isotope measurements. Fluids issuing from SVHS can be classified as Na-(Cl)-SO4 type, with the major cation and anion being Na+ and SO4 2-, respectively. Thermodynamic calculation using ORP and major element data indicated that sulfate is the most dominant sulfur species, which is consistent with anion analysis results. Aquifer temperatures at depth estimated by both dissolved SiO2 and Na-K-Ca geothermometers are in the range of 125.0 to 135.4 oC, and higher than the values measured at orifices (77.3 to 90.0 oC). CO2 and homologs of straight chain alkanes (C1-C5) were identified in gas samples. Carbon isotope values of alkanes increase with carbon numbers. The 13C fractionation between CO2 and dissolved inorganic carbon suggests they are out of carbon isotope equilibrium. The hypothesis regarding the formation of carbon-bearing compounds in SVHS may involve two processes: 1) Under high heat flow conditions which are caused by regional faulting and crustal extension, original high molecular weight organic compounds (kerogens) in clay-rich rocks decomposed to generate methane and other alkane homologs. 2) The SVHS area is associated with outflow structures, and distant from the heat source. Anaerobic oxidation of methane (AOM) with sulfate at shallow depth (< 90 oC) is suggested as being responsible for the generation of CO2 in SVHS.

Fu, Qi↗
NASA NTRS2013

The Origin of Carbon-bearing Volatiles in Surprise Valley Hot Springs in the Great Basin: Carbon Isotope and Water Chemistry Characterizations

There are numerous hydrothermal fields within the Great Basin of North America, some of which have been exploited for geothermal resources. With methane and other carbon-bearing compounds being observed, in some cases with high concentrations, however, their origins and formation conditions remain unknown. Thus, studying hydrothermal springs in this area provides us an opportunity to expand our knowledge of subsurface (bio)chemical processes that generate organic compounds in hydrothermal systems, and aid in future development and exploration of potential energy resources as well. While isotope measurement has long been used for recognition of their origins, there are several secondary processes that may generate variations in isotopic compositions: oxidation, re-equilibration of methane and other alkanes with CO2, mixing with compounds of other sources, etc. Therefore, in addition to isotopic analysis, other evidence, including water chemistry and rock compositions, are necessary to identify volatile compounds of different sources. Surprise Valley Hot Springs (SVHS, 41 deg 32'N, 120 deg 5'W), located in a typical basin and range province valley in northeastern California, is a terrestrial hydrothermal spring system of the Great Basin. Previous geophysical studies indicated the presence of clay-rich volcanic and sedimentary rocks of Tertiary age beneath the lava flows in late Tertiary and Quaternary. Water and gas samples were collected for a variety of chemical and isotope composition analyses, including in-situ pH, alkalinity, conductivity, oxidation reduction potential (ORP), major and trace elements, and C and H isotope measurements. Fluids issuing from SVHS can be classified as Na-(Cl)-SO4 type, with the major cation and anion being Na+ and SO4(2-), respectively. Thermodynamic calculation using ORP and major element data indicated that sulfate is the most dominant sulfur species, which is consistent with anion analysis results. Aquifer temperatures at depth estimated by both dissolved SiO2 and Na-K-Ca geothermometers are in the range of 125.0 to 135.4 C, and higher than the values measured at orifices (77.3 to 90.0 C). CO2 and homologs of straight chain alkanes (C1-C5) were identified in gas samples. Carbon isotope values of alkanes increase with carbon numbers. The C-13 fractionation between CO2 and dissolved inorganic carbon suggests they are out of carbon isotope equilibrium. The hypothesis regarding the formation of carbon-bearing compounds in SVHS may involve two processes: 1) Under high heat flow conditions which are caused by regional faulting and crustal extension, original high molecular weight organic compounds (kerogens) in clay-rich rocks decomposed to generate methane and other alkane homologs. 2) The SVHS area is associated with outflow structures, and distant from the heat source. Anaerobic oxidation of methane (AOM) with sulfate at shallow depth (< 90 C) is suggested as being responsible for the generation of CO2 in SVHS.

Fu, Qi↗
NASA NTRS1993

A 6,000-year sedimentary molecular record of chemocline excursions in the Black Sea

The Black Sea is the world's largest anoxic basin; it is also a contemporary analogue of the environment in which carbonaceous shales and petroleum source beds formed. Recently, Repeta et al. reported that anoxygenic photosynthesis may be an important component of carbon cycling in the present Black Sea, owing to a shoaling of the chemocline and consequent penetration of the photic zone by anaerobic waters in the past few decades. It has been suggested that this was due to an anthropogenic decrease in freshwater input to the Black Sea, although natural causes were not ruled out. Here we report the distributions of sequestered photosynthetic pigments in eight core samples of sediments from the Black Sea ranging in age from zero to 6,200 years before the present. Our results show that photosynthetic green sulphur bacteria (Chlorobiaceae [correction of Clorobiaceae]) have been active in the Black Sea for substantial periods of time in the past. This finding indicates that the penetration of the photic zone by anaerobic waters is not a recent phenomenon, and suggests that natural causes for shoaling of the chemocline are more likely than anthropogenic ones.

NASA Program Exobiology↗
NASA NTRS2010

Mud Volcanoes as Exploration Targets on Mars

Tens of thousands of high-albedo mounds occur across the southern part of the Acidalia impact basin on Mars. These structures have geologic, physical, mineralogic, and morphologic characteristics consistent with an origin from a sedimentary process similar to terrestrial mud volcanism. The potential for mud volcanism in the Northern Plains of Mars has been recognized for some time, with candidate mud volcanoes reported from Utopia, Isidis, northern Borealis, Scandia, and the Chryse-Acidalia region. We have proposed that the profusion of mounds in Acidalia is a consequence of this basin's unique geologic setting as the depocenter for the tune fraction of sediments delivered by the outflow channels from the highlands.

Allen, Carlton C.↗