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At least 73 records · Page 4

A Novel Resilience-Oriented Cellular Grid Formation Approach for Distribution Systems with Behind-the-Meter Distributed Energy Resources

This paper presents a resilience-oriented cellular grid formation approach to achieve scalable and reconfigurable community microgrid operations for distribution systems with behind-the-meter distributed energy resources. A set of interconnected solar photovoltaics, energy storage systems, and load is termed as a cell, implying a subset of the grid that can operate independently using its own resources. Cells are identified such that each cell inherently has sufficient energy resources to black start and can provide a certain level of backup power for its load under the loss of utility power supply. The proposed cell formation approach builds on a unique self-organizing map-based method (SomRes) to quantify a system's resilience. Using SomRes and a non-dominated sorting-based genetic algorithm (NSGA-II), a fast and efficient cell formation algorithm is developed to identify cells in a distribution system that are resilient against extreme events. The efficacy of the proposed approach is demonstrated on a numerical model of a real distribution feeder in Colorado, United States.

distributed energy resource↗

Chronology of ungrouped achondrites Northwest Africa 11119 and 7325/8486: implications for early evolution of a heterogeneous crust on a differentiated planetesimal

The chronology of ungrouped achondrites provides key insights into the timeline of igneous activity in the early Solar System. Two ungrouped achondrites – Northwest Africa (NWA) 11119 (andesite-dacite) and NWA 8486 and its pair NWA 7325 (olivine gabbro) – are the focus of this study, where their chronologies are investigated using multiple high-resolution techniques. Here we report the lead-lead (207Pb-206Pb) and manganese-chromium (53Mn-53Cr) systematics of NWA 11119, as well as the 207Pb-206Pb systematics of NWA 8486 alongside aluminum-magnesium (26Al-26Mg) systematics for NWA 7325. The U-corrected 207Pb-206Pb ages of NWA 11119 and the combined ages of NWA 7325/8486 are 4566.4 ± 0.8 Ma and 4563.8 ± 1.9 Ma, respectively. Additionally, we report the 53Mn-53Cr age of NWA 11119 to be 4564.4 ± 2.5 Ma and the 26Al-26Mg age of NWA 7325/8486 to be 4563.1 ± 0.3 Ma. The formation of NWA 11119 requires partial melting of a (likely chondritic) source reservoir leading to eruption of Si rich, alkali depleted magmas, while NWA 7325/8486 likely formed from a chemically fractionated reservoir with superchondritic Al/Mg. The clear geochemical and isotopic similarities of these achondrites, combined with the chronology reported here, is suggestive of formation of these two ungrouped achondrites on a common parent body which likely formed in the inner Solar System and experienced early differentiation under reducing conditions. If these achondrites did share a parent body, it would suggest that primary asteroids in the early Solar System commonly produced mineralogically and geochemically heterogeneous crusts. While mineralogical and geochemical heterogeneity is known to exist in the (mostly mafic) crust of asteroid Vesta, our findings show that even more significant crustal heterogeneity (representing felsic and mafic compositions) may exist on other asteroids.

Cartwright, Julia [University of Leicester, UK]↗

pvlib iotools—Open-source Python functions for seamless access to solar irradiance data

Access to accurate solar resource data is critical for numerous applications, including estimating the yield of solar energy systems, developing radiation models, and validating irradiance datasets. However, lack of standardization in data formats and access interfaces across providers constitutes a major barrier to entry for new users. pvlib python’s iotools subpackage aims to solve this issue by providing standardized Python functions for reading local files and retrieving data from external providers. All functions follow a uniform pattern and return convenient data outputs, allowing users to seamlessly switch between data providers and explore alternative datasets. The pvlib package is community-developed on GitHub: https://github.com/pvlib/pvlib-python. As of pvlib python version 0.9.5, the iotools subpackage supports 12 different datasets, including ground measurement, reanalysis, and satellite-derived irradiance data. The supported ground measurement networks include the Baseline Surface Radiation Network (BSRN), NREL MIDC, SRML, SOLRAD, SURFRAD, and the US Climate Reference Network (CRN). Additionally, satellite-derived and reanalysis irradiance data from the following sources are supported: PVGIS (SARAH & ERA5), NSRDB PSM3, and CAMS Radiation Service (including McClear clear-sky irradiance).

14 SOLAR ENERGY↗

Improved reproducibility of metal halide perovskite solar cells via automated gas quenching

Achieving reproducible perovskite solar cell fabrication is crucial for making it a scalable technology. We demonstrate an automated gas quenching system to improve perovskite solar cell reproducibility at the lab-scale. We use in situ photoluminescence to monitor the perovskite film formation as a function of the atmosphere in the glove box and find that antisolvent quenching is more sensitive to lingering precursor solvents than the gas quenching method. We observe a better reproducibility with gas quenching than with antisolvent quenching because it maintains a more consistent atmosphere in the glove box. The automated gas quenching process leads to high performing devices that are reproducible both batch to batch and researcher to researcher. The insights into gas quenching film formation as a function of solvent atmosphere and quench velocity will help inform future studies on large scale fabrication systems.

14 SOLAR ENERGY↗

Rethinking the Price Formation Problem–Part 1: Participant Incentives under Uncertainty

Operators of organized wholesale electricity markets attempt to form prices in such a way that the private incentives of market participants are consistent with a socially optimal commitment and dispatch schedule. In the U.S. context, several competing price formation schemes have been proposed to address the non-convex production cost functions characteristic of most generation technologies. Here, this paper considers how the design and analysis of price formation policies for non-convex markets are affected by the uncertainty inherent in electricity demand and supply. We argue that by excluding uncertainty, the analytical framework underlying existing policies mischaracterizes the incentives of market participants, leading to inefficient price formation and poor incentives for flexibility. We establish favorable theoretical properties of a new construct, ex ante convex hull pricing , and demonstrate the difference between this idealized benchmark and existing methods on a large-scale test system. Given increased operational uncertainty with a transition to wind and solar generation, distortions caused by poor incentives for flexibility are likely to grow without improved price formation in organized wholesale markets.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Identification of the weak-to-strong transition in Alfvénic turbulence from space plasma

Abstract Plasma turbulence is a ubiquitous dynamical process that transfers energy across many spatial and temporal scales in astrophysical and space plasma systems. Although the theory of anisotropic magnetohydrodynamic (MHD) turbulence has successfully described natural phenomena, its core prediction of an Alfvénic transition from weak to strong MHD turbulence when energy cascades from large to small scales has not been observationally confirmed. Here we report evidence for the Alfvénic weak-to-strong transition in small-amplitude, turbulent MHD fluctuations in Earth’s magnetosheath using data from four Cluster spacecraft. Our observations demonstrate the universal existence of strong turbulence accompanied by weak turbulent fluctuations on large scales. Moreover, we find that the nonlinear interactions of MHD turbulence are crucial to the energy cascade, as they broaden the cascade directions and fluctuating frequencies. The observed connection between weak and strong MHD turbulence systems may be present in many astrophysical environments, such as star formation, energetic particle transport, turbulent dynamos, and solar corona or solar wind heating.

79 ASTRONOMY AND ASTROPHYSICS↗

Identification of the weak-to-strong transition in Alfvénic turbulence from space plasma

Plasma turbulence is a ubiquitous dynamical process that transfers energy across many spatial and temporal scales in astrophysical and space plasma systems. Although the theory of anisotropic magnetohydrodynamic (MHD) turbulence has successfully described natural phenomena, its core prediction of an Alfvénic transition from weak to strong MHD turbulence when energy cascades from large to small scales has not been observationally confirmed. Here we report evidence for the Alfvénic weak-to-strong transition in small-amplitude, turbulent MHD fluctuations in Earth’s magnetosheath using data from four Cluster spacecraft. Our observations demonstrate the universal existence of strong turbulence accompanied by weak turbulent fluctuations on large scales. Moreover, we find that the nonlinear interactions of MHD turbulence are crucial to the energy cascade, as they broaden the cascade directions and fluctuating frequencies. The observed connection between weak and strong MHD turbulence systems may be present in many astrophysical environments, such as star formation, energetic particle transport, turbulent dynamos, and solar corona or solar wind heating.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Analysis of 0.1-Hz Var Oscillations in Solar Photovoltaic Power Plants

Oscillations with very low frequency at 0.1 Hz, have been observed in voltage and var in practical solar photovoltaic (PV) systems when power exporting ramps up to a certain level. Here, this letter provides an explanation on the formation of 0.1-Hz oscillations and identifies three critical factors that lead to the oscillations: communication delay between the plant-level control and the inverter-level control, high volt/var sensitivity at a high power exporting level, and the volt-var feedback system consisting of the plant control, inverter control and the grid impact. Furthermore, a critical feature of the 0.1-Hz oscillation is also explained: why oscillations appear only in voltage and var, but not in real power.

14 SOLAR ENERGY↗

Formate as an Energy Source to Allow Sugar Fermentation with No Net CO2 Generation: Integration of Electrochemistry with Fermentation

This poster summarizes at a high-level the scope of various groups' work on Formate as an Energy Source to Allow Sugar Fermentation with No Net CO2 Generation: Integration of Electrochemistry with Fermentation. The goals of this research are to develop and demonstrate an integrated process that electrochemically generates formate from CO2 and use the formate as an energy source for the fermentation of sugars to fatty acid methyl esters (FAME) without net CO2 generation wherein formate provides reducing equivalents for sugar fermentation and a chemical looping reactor system takes advantage of intermittent low-cost electricity from wind and solar resources.

BIOMASS FUELS,INORGANIC, ORGANIC, PHYSICAL, AND AN↗

Growth of Jupiter: Formation in disks of gas and solids and evolution to the present epoch

The formation of Jupiter is modeled via core-nucleated accretion, and the planet's evolution is simulated up to the present epoch. Throughout the phases when the planet acquires most of its heavy-element content, the calculation of solids' accretion accounts for interactions with an evolving disk of planetesimals. The phase of growth from an embryo of a few hundred kilometers in radius until the time when the accretion of gas overtakes solids' accretion was presented by D'Angelo et al., and the same numerical methods are applied here. Those calculations followed the formation for about 4 × 10 5 years, until the epoch when the heavy-element and hydrogen/helium masses were $M_Z ≈ 7.3$ and $M_{XY} ≈ 0.15$ Earth's masses ($M_⊕$), respectively, and $\dot {M} _{XY} ≈ $$\dot {M}_Z$. In this work, the calculation is continued through the phase when $M_{XY}$ grows to equal $M_Z$ , at which age, about 2.4 × 10 6 years, the total mass of the planet is $M_p ≈ 20 M_⊕$. About 9 × 10 5 years later, $M_p$ is approximately $60 M_⊕$ and $M_Z ≈ 16 M_⊕$, three-quarters of which are delivered by planetesimals larger than 10 km in radius. Around this epoch, the contraction of the envelope dictates gas accretion rates a few times 10 –3 $M_⊕$ per year, initiating the regime of disk-limited accretion, whereby the planet can accrete all the gas provided by the disk, and its evolution is therefore tied to disk's evolution. Growth is continued by constructing simplified models of protosolar accretion disks that evolve through viscous diffusion, winds, and accretion on the planet. Jupiter's formation ends after ≈ 3.4–4.2 Myr, depending on the applied disk viscosity parameter, when nebula gas disperses. The young Jupiter is 4.5–5.5 times as voluminous as it is presently and thousands of times as luminous, ~10 –5 $L_⊙$. The heavy-element mass is ≈ 20 $M_⊕$. The evolution proceeds through the cooling and contraction phase, in isolation except for solar irradiation. After 4570 Myr, the age of the solar system, radius and luminosity of the planet are within 10$\%$ of current values, accounting also for uncertainties in the power absorbed from the Sun. During formation, and soon thereafter, the planet exhibits features, e.g., luminosity and effective temperature, that may probe aspects of the latter stages of formation, if observable. These possibly distinctive features, however, seem to disappear within a few tens of Myr.

79 ASTRONOMY AND ASTROPHYSICS↗

Optimizing molecular light absorption in the strong coupling regime for solar energy harvesting

The strong coupling of optical absorbers (e.g., molecules or semiconductors) to confined photonic modes fundamentally alters the physical properties of the coupled system via the formation of hybrid light-matter states. One potential application of strong light-matter coupling relies on exploiting it to localize light-induced charge excitation processes to small volumes of material. Applications that would benefit from this localization include thin-film photovoltaics, photodetection, photocatalysis, and others, where the overall performance depends on the ability of a material to amplify light absorption (i.e., the formation of electron-hole pairs) within specific locations in space. This contribution investigates how strong light-matter coupling affects light absorption rates in molecular absorbers coupled to photonic nanostructures. Here, our results show that the molecular light absorption efficiencies are highest in configurations where the strongly coupled molecules interact directly with the incoming photon flux. We also identify a nonlinear dependence in the molecular absorption as a function of concentration, unique to the strongly coupled systems. Based on these results, we propose design principles for engineering nanostructured systems that allow for high efficiencies of charge carrier localization into strongly coupled absorbers.

14 SOLAR ENERGY↗

Demonstrating SolarPILOT’s Python API Through Heliostat Optimal Aimpoint Strategy Use Case

SolarPILOT is a software package that generates solar field layouts and characterizes the optical performance of concentrating solar power (CSP) tower systems. SolarPILOT was developed by the National Renewable Energy Laboratory (NREL) as a stand-alone desktop application but has also been incorporated into NREL’s1 System Advisor Model (SAM) in a simplified format. Prior means for user interaction with SolarPILOT have included the application’s graphical interface, the SAM routines with limited configurability, and through a built-in scripting language called “LK.” This paper presents a new, full-featured, Python-based application programmable interface (API) for SolarPILOT, which we hereafter refer to as CoPylot. CoPylot provides access to all SolarPILOT’s capabilities to generate and characterize power tower CSP systems seamlessly through Python. Supported capabilities include (i) creating and destroying a model instance with message reporting tools; (ii) accessing and setting any SolarPILOT variable including custom land boundaries for field layouts; (iii) programmatically managing receiver and heliostat objects with varied attributes for systems with multiple receiver or heliostat types; (iv) generating, assigning, and modifying solar field layouts including the ability to set individual heliostat locations, aimpoints, soiling rates, and reflectivity levels; (v) simulating solar field performance; (vi) returning detailed results describing performance of individual heliostats, the aggregate field, and receiver flux distribution; and, (vii) exporting Python-based model instances to multiple file formats. CoPylot enables Python users to perform detailed CSP tower analysis utilizing either the Hermite expansion technique (analytical) or the SolTrace ray-tracing engine. In addition to CoPylot’s functionality, Python users have access to the over 100,000 open-source libraries to develop, analyze, optimize, and visualize power tower CSP research. This enables CSP researchers to perform analysis that was previously not possible through SolarPILOT’s existing interfaces. This paper discusses the capabilities of CoPylot and presents a use case wherein we demonstrate optimal solar field aiming strategies.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Bayesian constraints on the origin and geology of exoplanetary material using a population of externally polluted white dwarfs

ABSTRACT White dwarfs that have accreted planetary bodies are a powerful probe of the bulk composition of exoplanetary material. In this paper, we present a Bayesian model to explain the abundances observed in the atmospheres of 202 DZ white dwarfs by considering the heating, geochemical differentiation, and collisional processes experienced by the planetary bodies accreted, as well as gravitational sinking. The majority (>60 per cent) of systems are consistent with the accretion of primitive material. We attribute the small spread in refractory abundances observed to a similar spread in the initial planet-forming material, as seen in the compositions of nearby stars. A range in Na abundances in the pollutant material is attributed to a range in formation temperatures from below 1000 K to higher than 1400 K, suggesting that pollutant material arrives in white dwarf atmospheres from a variety of radial locations. We also find that Solar System-like differentiation is common place in exoplanetary systems. Extreme siderophile (Fe, Ni, or Cr) abundances in eight systems require the accretion of a core-rich fragment of a larger differentiated body to at least a 3σ significance, whilst one system shows evidence that it accreted a crust-rich fragment. In systems where the abundances suggest that accretion has finished (13/202), the total mass accreted can be calculated. The 13 systems are estimated to have accreted masses ranging from the mass of the Moon to half that of Vesta. Our analysis suggests that accretion continues for 11 Myrs on average.

79 ASTRONOMY AND ASTROPHYSICS↗

Semiconductor nanocrystal photocatalysis for the production of solar fuels

Colloidal semiconducting nanocrystals (NCs) are powerful elements of a photocatalytic system useful for enabling a variety of chemical transformations owing to their strong light-absorbing properties and high degree of size-, shape-, and composition-tunability. Key to their utility is our understanding of the photoinduced charge transfer processes required for these photochemical transformations. This Perspective will focus on the implementation of semiconductor NCs for photochemical fuel formation. Three general system designs for photocatalytic proton reduction using semiconductor NCs will be reviewed: metal–semiconductor heterostructures, NC photosensitizers with molecular catalysts, and hydrogenase-based systems. Additionally, other relevant reactions toward solar fuel targets, such as CO 2 and N 2 reductions with NCs, will also be highlighted. Illustrating the versatile roles that NCs can play in light-driven chemical reactions, advances made toward NC-catalyzed organic transformations will be discussed. Finally, we will share a few concluding thoughts and perspectives on the future of the field, with a focus on goals toward improving and implementing NC-based technologies for solar fuel development.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Comparison of the earliest NC and CC planetesimals: Evidence from ungrouped iron meteorites

Isotope anomalies in meteorites reveal a fundamental dichotomy between Non-Carbonaceous- (NC) and Carbonaceous-type (CC) planetary bodies. Until now, this dichotomy is established for the major meteorite groups, representing about 36 distinct parent bodies. Ungrouped meteorites represent an even larger number of additional parent bodies, but whether they conform to the overall NC-CC dichotomy is unknown. Here, the genetics and chronology of 26 ungrouped iron meteorites are considered through nucleosynthetic Mo and radiogenic W isotopic compositions. Secondary cosmic ray-induced modifications of these isotope compositions are corrected using Pt isotope measurements on the same samples. We find that all of the ungrouped irons have Mo isotope anomalies within the range of the major meteorite groups and confirm the NC-CC dichotomy for Mo, where NC and CC meteorites define two distinct, subparallel s-process mixing lines. All ungrouped NC irons fall on the NC-line, which is now precisely defined for 41 distinct parent bodies. The ungrouped CC irons show scatter around the CC-line indicative of small r-process Mo heterogeneities among these samples. These r-process Mo isotope variations correlate with O isotope anomalies, most likely reflecting mixing of CI chondrite-like matrix, chondrule precursors, and Ca-Al-rich inclusions. This implies that CC iron meteorite parent bodies accreted the same nebular components as the later-formed carbonaceous chondrites. The Hf-W model ages of core formation for the ungrouped irons overlap with those of the iron meteorite groups from each reservoir and reveal a narrow age peak at ∼3.3 Ma after Ca-Al-rich inclusions for the CC irons. By contrast, the NC irons display more variable ages, including younger ages indicative of impact-induced melting events, which seem absent among the CC irons. This is attributed to the more fragile and porous nature of the CC bodies, making impact-induced melting on their surfaces difficult. The chemical characteristics of all iron meteorites together reveal slightly more oxidizing conditions during core formation for CC compared to NC irons. More strikingly, strong depletions in moderately volatile elements, typical of many iron meteorite parent bodies, predominantly occur among CC irons, for reasons that remain unclear at present.

Chondrite components↗

Machine learning the electric field response of condensed phase systems using perturbed neural network potentials

Abstract The interaction of condensed phase systems with external electric fields is of major importance in a myriad of processes in nature and technology, ranging from the field-directed motion of cells (galvanotaxis), to geochemistry and the formation of ice phases on planets, to field-directed chemical catalysis and energy storage and conversion systems including supercapacitors, batteries and solar cells. Molecular simulation in the presence of electric fields would give important atomistic insight into these processes but applications of the most accurate methods such as ab-initio molecular dynamics (AIMD) are limited in scope by their computational expense. Here we introduce Perturbed Neural Network Potential Molecular Dynamics (PNNP MD) to push back the accessible time and length scales of such simulations. We demonstrate that important dielectric properties of liquid water including the field-induced relaxation dynamics, the dielectric constant and the field-dependent IR spectrum can be machine learned up to surprisingly high field strengths of about 0.2 V Å −1 without loss in accuracy when compared to ab-initio molecular dynamics. This is remarkable because, in contrast to most previous approaches, the two neural networks on which PNNP MD is based are exclusively trained on molecular configurations sampled from zero-field MD simulations, demonstrating that the networks not only interpolate but also reliably extrapolate the field response. PNNP MD is based on rigorous theory yet it is simple, general, modular, and systematically improvable allowing us to obtain atomistic insight into the interaction of a wide range of condensed phase systems with external electric fields.

Science & Technology - Other Topics↗

Initial Conditions of Planet Formation: Time Constraints from Small Bodies and the Lifetime of Reservoirs in the Solar Protoplanetary Disk

This review explores the timescales of the initial phase of planet formation, from nebular dust (CAIs and chondrules) to planetesimal accretion and differentiation, using evidence from meteorite research. Aluminium-Mg systematics of CAIs indicate either an extended period of CAI formation (∼0.3 Ma) or an initial 26 Al heterogeneity, with evidence supporting a homogeneous 26 Al abundance in the protoplanetary disk. Thermal and aqueous alteration on the parent body can disturb the U-Pb and Al-Mg chronometers in chondrules. Focusing on relatively robust isochron data from plagioclase of pristine (types ≤3.05) chondrites indicates a shift in chondrule formation locations, moving from the inner to the outer disk over time. Ages of basaltic achondrites show that silicate differentiation on small bodies was well underway within the first few million years (Ma) of our solar system. Their age record, however, reveals inconsistencies between different chronometers, partly caused by (i) secondary disturbances due to thermal metamorphism, aqueous alteration, or impacts, (ii) the presence of xenolithic minerals, and (iii) potentially variable initial 26 Al abundances due to disturbances at the mineral scale. Nucleosynthetic isotope data indicate that parent bodies of iron and stony meteorites formed in two distinct regions within the protoplanetary disk: the inner, non-carbonaceous (NC) and the outer, carbonaceous (CC) region. Based on Hf-W chronometry it has been demonstrated that NC and CC parent bodies of magmatic iron meteorites segregated their cores within ∼1–3 Ma after CAI formation, implying that parent body accretion occurred within <1 Ma in both reservoirs. Combining accretion ages with nucleosynthetic data further reveals that, at first order, NC and CC reservoirs in the solar protoplanetary disk were established within 1 Ma and existed over several Ma with limited exchange between them. In the CR chondrite accretion region of the disk, planetary bodies formed over at least 3 Ma, while in most other regions, formation spanned at least 1 Ma, with minimal changes in nucleosynthetic isotope compositions. Aerodynamical size sorting of dust likely introduced or amplified some of these variations.

26Al distribution↗

Origin of Plutonium-244 in the Early Solar System

We investigate the origin in the early Solar System of the short-lived radionuclide 244 Pu (with a half life of 80 Myr) produced by the rapid (r) neutron-capture process. We consider two large sets of r-process nucleosynthesis models and analyse if the origin of 244 Pu in the ESS is consistent with that of the other r and slow (s) neutron-capture process radioactive nuclei. Uncertainties on the r-process models come from both the nuclear physics input and the astrophysical site. The former strongly affects the ratios of isotopes of close mass ( 129 I/ 127 I, 244 Pu/ 238 U, and 247 Pu/ 235 U). The 129 I/ 247 Cm ratio, instead, which involves isotopes of a very different mass, is much more variable than those listed above and is more affected by the physics of the astrophysical site. We consider possible scenarios for the evolution of the abundances of these radioactive nuclei in the galactic interstellar medium and verify under which scenarios and conditions solutions can be found for the origin of 244 Pu that are consistent with the origin of the other isotopes. Solutions are generally found for all the possible different regimes controlled by the interval (δ) between additions from the source to the parcel of interstellar medium gas that ended up in the Solar System, relative to decay timescales. If r-process ejecta in interstellar medium are mixed within a relatively small area (leading to a long δ), we derive that the last event that explains the 129 I and 247 Cm abundances in the early Solar System can also account for the abundance of 244 Pu. Due to its longer half life, however, 244 Pu may have originated from a few events instead of one only. If r-process ejecta in interstellar medium are mixed within a relatively large area (leading to a short δ), we derive that the time elapsed from the formation of the molecular cloud to the formation of the Sun was 9-16 Myr.

79 ASTRONOMY AND ASTROPHYSICS↗