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Genesis Silicon Carbide Concentrator Target 60003 Preliminary Ellipsometry Mapping Results

The Genesis concentrator was custom designed to focus solar wind ions primarily for terrestrial isotopic analysis of O-17/O-16 and O-18/O-16 to +/-1%, N-15/N-14 to +/-1%, and secondarily to conduct elemental and isotopic analysis of Li, Be, and B. The circular 6.2 cm diameter concentrator target holder was comprised of four quadrants of highly pure semiconductor materials that included one amorphous diamond-like carbon, one C-13 diamond, and two silicon carbide (SiC). The amorphous diamond-like carbon quadrant was fractured upon impact at Utah Test and Training Range (UTTR), but the remaining three quadrants survived fully intact and all four quadrants hold an important collection of solar wind. The quadrants were removed from the target holder at NASA Johnso n Space Center Genesis Curation Laboratory in April 2005, and have been housed in stainless steel containers under continual nitrogen purge since time of disintegration. In preparation for allocation of a silicon carbide target for oxygen isotope analyses at UCLA, the two SiC targets were photographed for preliminary inspection of macro particle contamination from the hard non-nominal landing as well as characterized by spectroscopic ellipsometry to evaluate thin film contamination. This report is focused on Genesis SiC target sample number 60003.

Calaway, M. J.↗

Jet Propulsion Laboratory: Annual Report 2004

Once or twice in an age, a year comes along that the historians proclaim as an Annus Mirabilis - a year of wonders. For the Jet Propulsion Laboratory, 2004 was just that sort of time. From beginning to end, it was a nonstop experience of wondrous events in space. Imagine that two robot rovers embark on cross-country rambles across Mars, scrutinizing rocks for signs of past water on the now-arid world. A flagship spacecraft brakes into orbit at Saturn to begin longterm surveillance of the ringed world, preparing to drop a sophisticated probe to the surface of its haze-shrouded largest moon. Another craft makes the closest-ever pass by the nucleus of a comet, collecting sample particles as it goes. Two new space telescopes peer into the depths of the universe far beyond our solar system, viewing stars, nebulas and galaxies in invisible light beyond the spectrum our eyes can see. A pair of instruments is lofted on a NASA Earth-orbiting satellite to monitor air quality and the protective layer of ozone blanketing our home planet. A small probe brings samples of the solar wind to Earth for in-depth study. While JPL was absorbed with all of these ventures on other worlds, NASA and the White House unveiled an ambitious new plan of space exploration. The Vision for Space Exploration announced in January foresees a program of robotic and astronaut missions leading to a human return to the Moon by 2020, and eventual crewed expeditions to Mars. The vision also calls for more robotic missions to the moons of the outer planets; spaceborne observatories that will search for Earth-like planets around other stars and explore the formation and evolution of the universe; and continued study of our home planet. In order to accomplish all of this, NASA must perfect many as-yet-uninvented technologies and space transportation capabilities. JPL has a great deal to bring to this vision. Robotic exploration of Mars will lead the way for missions that will carry women and men to the red planet. Our engineers and scientists are formulating spacecraft that could use nuclear power to enable exploration missions of the future. And even now we are designing formations of space telescopes that will capture family portraits of the planets around neighboring stars. Those are only some of the ways that the Laboratory is contributing to NASA's broader goals. During 2004, JPL made a distinctive contribution to agencywide initiatives in areas such as safety, NASA transformation, the agency's Internet portal and NASA's Explorer Schools programs. Years like 2004 pose a special challenge for us. It would be easy to say that this was a once-in-a-decade high point of mission activities, but I believe that this would miss an opportunity. We are fortunate to have many space projects in the works that have the promise of being just as exhilarating as the great mission successes that we celebrated this year. The challenge and opportunity for us now is to make every year like this one.

National Aeronautics and Space Administration (NAS↗

Advances in Astromaterials Curation: Supporting Future Sample Return Missions

NASA's Astromaterials, curated at the Johnson Space Center in Houston, are the most extensive, best-documented, and leastcontaminated extraterrestrial samples that are provided to the worldwide research community. These samples include lunar samples from the Apollo missions, meteorites collected over nearly 40 years of expeditions to Antarctica (providing samples of dozens of asteroid bodies, the Moon, and Mars), Genesis solar wind samples, cosmic dust collected by NASA's high altitude airplanes, Comet Wild 2 and interstellar dust samples from the Stardust mission, and asteroid samples from JAXA's Hayabusa mission. A full account of NASA's curation efforts for these collections is provided by Allen, et al [1]. On average, we annually allocate about 1500 individual samples from NASA's astromaterials collections to hundreds of researchers from around the world, including graduate students and post-doctoral scientists; our allocation rate has roughly doubled over the past 10 years. The curation protocols developed for the lunar samples returned from the Apollo missions remain relevant and are adapted to new and future missions. Several lessons from the Apollo missions, including the need for early involvement of curation scientists in mission planning [1], have been applied to all subsequent sample return campaigns. From the 2013 National Academy of Sciences report [2]: "Curation is the critical interface between sample return missions and laboratory research. Proper curation has maintained the scientific integrity and utility of the Apollo, Antarctic meteorite, and cosmic dust collections for decades. Each of these collections continues to yield important new science. In the past decade, new state-of-the-art curatorial facilities for the Genesis and Stardust missions were key to the scientific breakthroughs provided by these missions." The results speak for themselves: research on NASA's astromaterials result in hundreds of papers annually, yield fundamental discoveries about the evolution of the solar system (e.g. [3] and references contained therein), and serve the global scientific community as ground truth for current and planned missions such as NASA's Dawn mission to Vesta and Ceres, and the future OSIRIS REx mission to asteroid Bennu [1,3]

Evans, C. A.↗

Technology Development and Advanced Planning for Curation of Returned Mars Samples

NASA Johnson Space Center (JSC) curates extraterrestrial samples, providing the international science community with lunar rock and soil returned by the Apollo astronauts, meteorites collected in Antarctica, cosmic dust collected in the stratosphere, and hardware exposed to the space environment. Curation comprises initial characterization of new samples, preparation and allocation of samples for research, and clean, secure long-term storage. The foundations of this effort are the specialized cleanrooms (class 10 to 10,000) for each of the four types of materials, the supporting facilities, and the people, many of whom have been doing detailed work in clean environments for decades. JSC is also preparing to curate the next generation of extraterrestrial samples. These include samples collected from the solar wind, a comet, and an asteroid. Early planning and R\&D are underway to support post-mission sample handling and curation of samples returned from Mars. One of the strong scientific reasons for returning samples from Mars is to search for evidence of current or past life in the samples. Because of the remote possibility that the samples may contain life forms that are hazardous to the terrestrial biosphere, the National Research Council has recommended that all samples returned from Mars be kept under strict biological containment until tests show that they can safely be released to other laboratories. It is possible that Mars samples may contain only scarce or subtle traces of life or prebiotic chemistry that could readily be overwhelmed by terrestrial contamination . Thus, the facilities used to contain, process, and analyze samples from Mars must have a combination of high-level biocontainment and organic / inorganic chemical cleanliness that is unprecedented. JSC has been conducting feasibility studies and developing designs for a sample receiving facility that would offer biocontainment at least the equivalent of current maximum containment BSL-4 (BioSafety Level 4) laboratories, while simultaneously maintaining cleanliness levels equaling those of state-of-the-art cleanrooms. Unique requirements for the processing of Mars samples have inspired a program to develop handling techniques that are much more precise and reliable than the approach (currently used for lunar samples) of employing gloved human hands in nitrogen-filled gloveboxes. Individual samples from Mars are expected to be much smaller than lunar samples, the total mass of samples returned by each mission being 0.5- 1 kg, compared with many tens of kg of lunar samples returned by each of the six Apollo missions. Smaller samples require much more of the processing to be done under microscopic observation. In addition, the requirements for cleanliness and high-level containment would be difficult to satisfy while using traditional gloveboxes. JSC has constructed a laboratory to test concepts and technologies important to future sample curation. The Advanced Curation Laboratory includes a new-generation glovebox equipped with a robotic arm to evaluate the usability of robotic and teleoperated systems to perform curatorial tasks. The laboratory also contains equipment for precision cleaning and the measurement of trace organic contamination.

Lindstrom, David J.↗

Characterization of Particle and Heat Losses from a High-Temperature Particle Receiver (2 nd Ed)

High - temperature particle receivers are being pursued to enable next - generation concentrating solar thermal power (CSP) systems that can achieve higher temperatures (> 700 C) to enable more efficient power cycles, lower overall system costs, and emerging CSP - based process - heat applications. The objective of this work was to develop characterization methods to quantify the particle and heat losses from the open aperture of the particle receiver. Novel camera - based imaging methods were developed and applied to both laboratory - scale and larger 1 MW t on - sun tests at the National Solar Thermal Test Facility in Albuquerque, New Mexico. Validation of the imaging methods was performed using gravimetric and calorimetric methods. In addition, conventional particle - sampling methods using volumetric particle - air samplers were applied to the on - sun tests to compare particle emission rates with regulatory standards for worker safety and pollution. Novel particle sampling methods using 3 - D printed tipping buckets and tethered balloons were also developed and applied to the on - sun particle - receiver tests. Finally, models were developed to simulate the impact of particle size and wind on particle emissions and concentrations as a function of location. Results showed that particle emissions and concentrations were well below regulatory standards for worker safety and pollution. In addition, estimated particle temperatures and advective heat losses from the camera - based imaging methods correlated well with measured values during the on - sun tests.

14 SOLAR ENERGY↗

Light Isotopes and Trace Organics Analysis of Mars Samples with Mass Spectrometry

Precision measurement of light isotopes in Mars surface minerals and comparison of this isotopic composition with atmospheric gas and other, well-mixed reservoirs such as surface dust are necessary to understand the history of atmospheric evolution from a possibly warmer and wetter Martian surface to the present state. Atmospheric sources and sinks that set these ratios are volcanism, solar wind sputtering, photochemical processes, and weathering. Measurement of a range of trace organic species with a particular focus on species such as amino acids that are the building blocks of terrestrial life are likewise important to address the questions of prebiotic and present or past biological activity on Mars. The workshop topics "isotopic mineralogy" and "biology and pre-biotic chemistry" will be addressed from the point of view of the capabilities and limitations of insitu mass spectrometry (MS) techniques such as thermally evolved gas analysis (TEGA) and gas chromatography (GC) surface experiments using MS, in both cases, as a final chemical and isotopic composition detector. Insitu experiments using straightforward adaptations of existing space proven hardware can provide a substantial improvement in the precision and accuracy of our present knowledge of isotopic composition both in molecular and atomic species in the atmosphere and those chemically bound in rocks and soils. Likewise, detection of trace organic species with greatly improved sensitivity from the Viking GCMS experiment is possible using gas enrichment techniques. The limits to precision and accuracy of presently feasible insitu techniques compared to laboratory analysis of returned samples will be explored. The insitu techniques are sufficiently powerful that they can provide a high fidelity method of screening samples obtained from a diverse set of surface locations such as the subsurface or the interior of rocks for selection of those that are the most interesting for return to Earth.

Mahaffy, P.↗

The composition and origin of the C, P, and D asteroids - Water as a tracer of thermal evolution in the outer belt

A telescopic and laboratory investigation of water distribution among low albedo asteroids in the outer belt, using the 3-micron reflectance absorption of molecular H2O and structural OH ions (coincident with the 3-micron spectral signature of meteorite and asteroid hydrated silicates) shows that 66 percent of the C-class asteroids in the sample have hydrated silicate surfaces. In conjunction with the apparently anhydrous P and D surfaces, this pronounced hydration difference between C-class asteroids and the more distant P and D classes points to an original outer belt asteroid composition of anhydrous silicates, water ice, and complex organic material. Early solar-wind induction heating of protoasteroids, declining in intensity with distance from the sun, is conjectured to have produced the observed diminution of hydrated silicate abundance.

Jones, Thomas D.↗

Characterization of Particle and Heat Losses from a High-Temperature Particle Receiver

High-temperature particle receivers are being pursued to enable next-generation concentrating solar thermal power (CSP) systems that can achieve higher temperatures (> 700 °C) to enable more efficient power cycles, lower overall system costs, and emerging CSP-based process-heat applications. The objective of this work was to develop characterization methods to quantify the particle and heat losses from the open aperture of the particle receiver. Novel camera- based imaging methods were developed and applied to both laboratory-scale and larger 1 MW t on-sun tests at the National Solar Thermal Test Facility in Albuquerque, New Mexico. Validation of the imaging methods was performed using gravimetric and calorimetric methods. In addition, conventional particle-sampling methods using volumetric particle-air samplers were applied to the on-sun tests to compare particle emission rates with regulatory standards for worker safety and pollution. Novel particle sampling methods using 3-D printed tipping buckets and tethered balloons were also developed and applied to the on-sun particle-receiver tests. Finally, models were developed to simulate the impact of particle size and wind on particle emissions and concentrations as a function of location. Results showed that particle emissions and concentrations were well below regulatory standards for worker safety and pollution. In addition, estimated particle temperatures and advective heat losses from the camera-based imaging methods correlated well with measured values during the on-sun tests.

14 SOLAR ENERGY↗

The JOCR program

Observational data on large-scale plasma structures in comets is of value in (1) analyzing the interaction between the solar wind and comets, (2) using comets as solar wind probes, and (3) using comets as an astrophysical plasma laboratory with the CO+ plasma serving as tracers of the magnetic field. To obtain this data, the Joint Observatory for Cometary Research was built on South Baldy in the Magdalena Mountains west of Socorro, New Mexico, at an altitude of 10,615 feet. The telescope is a 14" f/2 Schmidt camera which records an 80 deg x 10 deg field onto 4 x 5 inch plates. The camera is designed for fixed focus operation, i.e., within design limits, the focus is not a function of temperature. A vacuum platen system allows the use of film for color photography. Sample observations of comets Kohoutek, West, Kobayashi-Berger-Milon and Bradfield are interpreted.

Brandt, J. C.↗

Understanding the Activation and Solution Properties of Lunar Dust for Future Lunar Habitation

The decision to return humans to the moon by 2020 makes it imperative to understand the effects of lunar dust on human and mechanical systems.( Bush 2004; Gaier 2005; Mendell 2005) During the Apollo missions, dust was found to cause numerous problems for various instruments and systems. Additionally, the dust may have caused health issues for some of the astronauts.(Gaier 2005; Rowe 2007) It is necessary, therefore, for studies to be carried out in a variety of disciplines in order to mitigate the effects of the dust as completely as possible. Due to the lack of an atmosphere, there is nothing to protect the lunar soil from ultraviolet radiation, solar wind, and meteorite impacts. These processes could all serve to "activate" the soil, or produce reactive surface species. In order to understand the possible toxic effects of the reactive dust, it is necessary to "reactivate" the dust, as samples returned during the Apollo missions were exposed to the atmosphere of the Earth. We have used grinding and exposure to UV radiation in order to mimic some of the processes occurring on the lunar surface. To monitor the reactivity of the dust, we have measured the ability of the dust to produce hydroxyl radicals in solution. These radicals have been measured using a novel fluorescent technique developed in our laboratory,(Wallace et al. 2008) as well as using electron paramagnetic resonance (EPR).

Wallace, William T.↗

Proceedings of the 40th Lunar and Planetary Science Conference

The 40th Lunar and Planetary Science Conference included sessions on: Phoenix: Exploration of the Martian Arctic; Origin and Early Evolution of the Moon; Comet Wild 2: Mineralogy and More; Astrobiology: Meteorites, Microbes, Hydrous Habitats, and Irradiated Ices; Phoenix: Soil, Chemistry, and Habitability; Planetary Differentiation; Presolar Grains: Structures and Origins; SPECIAL SESSION: Venus Atmosphere: Venus Express and Future Missions; Mars Polar Caps: Past and Present; SPECIAL SESSION: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1, Part I; 5 Early Nebula Processes and Models; SPECIAL SESSION: Icy Satellites of Jupiter and Saturn: Cosmic Gymnasts; Mars: Ground Ice and Climate Change; SPECIAL SESSION: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1, Part II; Chondrite Parent-Body Processes; SPECIAL SESSION: Icy Satellites of Jupiter and Saturn: Salubrious Surfaces; SNC Meteorites; Ancient Martian Crust: Primary Mineralogy and Aqueous Alteration; SPECIAL SESSION: Messenger at Mercury: A Global Perspective on the Innermost Planet; CAIs and Chondrules: Records of Early Solar System Processes; Small Bodies: Shapes of Things to Come; Sulfur on Mars: Rocks, Soils, and Cycling Processes; Mercury: Evolution and Tectonics; Venus Geology, Volcanism, Tectonics, and Resurfacing; Asteroid-Meteorite Connections; Impacts I: Models and Experiments; Solar Wind and Genesis: Measurements and Interpretation; Mars: Aqueous Processes; Magmatic Volatiles and Eruptive Conditions of Lunar Basalts; Comparative Planetology; Interstellar Matter: Origins and Relationships; Impacts II: Craters and Ejecta Mars: Tectonics and Dynamics; Mars Analogs I: Geological; Exploring the Diversity of Lunar Lithologies with Sample Analyses and Remote Sensing; Chondrite Accretion and Early History; Science Instruments for the Mars Science Lander; . Martian Gullies: Morphology and Origins; Mars: Dunes, Dust, and Wind; Mars: Volcanism; Early Solar System Chronology; Seek Out and Explore: Upcoming and Future Missions; Mars: Early History and Impact Processes; Mars Analogs II: Chemical and Spectral; Achondrites and their Parent Bodies; and Planning for Future Exploration of the Moon The poster sessions were: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1; LRO and LCROSS; Geophysical Analysis of the Lunar Surface and Interior; Remote Observation and Geologic Mapping of the Lunar Surface; Lunar Spectroscopy; Venus Geology, Geophysics, Mapping, and Sampling; Planetary Differentiation; Bunburra and Buzzard Coulee: Recent Meteorite Falls; Meteorites: Terrestrial History; CAIs and Chondrules: Records of Early Solar System Processes; Volatile and Organic Compounds in Chondrites; Crashing Chondrites: Impact, Shock, and Melting; Ureilite Studies; Petrology and Mineralogy of the SNC Meteorites; Martian Meteorites; Phoenix Landing Site: Perchlorate and Other Tasty Treats; Mars Polar Atmospheres and Climate Modeling; Mars Polar Investigations; Mars Near-Surface Ice; Mars: A Volatile-Rich Planet; Mars: Geochemistry and Alteration Processes; Martian Phyllosilicates: Identification, Formation, and Alteration; Astrobiology; Instrument Concepts, Systems, and Probes for Investigating Rocks and Regolith; Seeing is Believing: UV, VIS, IR, X- and Gamma-Ray Camera and Spectrometer Instruments; Up Close and Personal: In Situ Analysis with Laser-Induced Breakdown Spectroscopy and Mass Spectrometry; Jupiter and Inscrutable Io; Tantalizing Titan; Enigmatic Enceladus and Intriguing Iapetus; Icy Satellites: Cryptic Craters; Icy Satellites: Gelid Geology/Geophysics; Icy Satellites: Cool Chemistry and Spectacular Spectroscopy; Asteroids and Comets; Comet Wild 2: Mineralogy and More; Hypervelocity Impacts: Stardust Models, LDEF, and ISPE; Presolar Grains; Early Nebular Processes: Models and Isotopes; Solar Wind and Genesis: Measurements and Interpretation; Education and Public Outreach; Mercury; Pursuing Lunar Exploration; Sources and Eruptionf Lunar Basalts; Chemical and Physical Properties of the Lunar Regolith; Lunar Dust and Transient Surface Phenomena; Lunar Databases and Data Restoration; Meteoritic Samples of the Moon; Chondrites, Their Clasts, and Alteration; Achondrites: Primitive and Not So Primitive; Iron Meteorites; Meteorite Methodology; Antarctic Micrometeorites; HEDs and Vesta; Dust Formation and Transformation; Interstellar Organic Matter; Early Solar System Chronology; Comparative Planetology; Impacts I: Models and Experiments; Impacts II: Craters and Ejecta; Mars: Volcanism; Mars: Tectonics and Dynamics; Martian Stratigraphy: Understanding the Geologic History of Mars Through the Sedimentary Rock Record; Mars: Valleys and Valley Networks; Mars: Aqueous Processes in Valles Marineris and the Southern Highlands; Mars: Aqueous Geomorphology; Martian Gullies: Morphology and Origins; Mars: Dunes, Dust, and Wind; Mars: Remote Sensing; Mars: Geologic Mapping, Photogrammetry, and Cratering; Martian Mineralogy: Constraints from Missions and Laboratory Investigations; Mars Analogs: Chemical and Physical; Mars Analogs: Sulfates and Sulfides; Missions: Approaches, Architectures, Analogs, and Actualities; Not Just Skin Deep: Electron Microscopy, Heat Flow, Radar, and Seismology Instruments and Planetary Data Systems, Techniques, and Interpretation.

Source record↗

Catalog of solar wind events identified from observations by ISTP spacecraft

The ISTP Science Planning and Operations Facility (SPOF), in collaboration with ISTP investigators, is developing a catalog of solar wind events and features. The catalog is primarily based on plasma and magnetic field observations from the WIND and IMP-8 spacecraft. Interplanetary events that may trigger magnetospheric activity are included as well as features of interest for using the solar wind as a plasma laboratory. Catalog coverage begins on September 8, 1992, the start of ISTP science data collection. The catalog is based on Key Parameter data sets (preliminary summary data at approximately 1 min time resolution produced quickly for survey purposes) and as such has limited citability in formal scientific work. Its primary intent is to serve as a reference for identifying candidate periods for further study, such as may be the focus of coordinated data analysis efforts during ISTP and/or IACG Science Campaigns. To facilitate access by members of the ISTP and wider space physics communities, the catalog will be available on the World Wide Web. The contents of the catalog will be described, and samples of catalog information will be presented.

Peredo, M.↗

Pieces of Other Worlds - Extraterrestrial Samples for Education and Public Outreach

During the Year of the Solar System spacecraft from NASA and our international partners will encounter two comets; orbit the asteroid Vesta, continue to explore Mars with rovers, and launch robotic explorers to the Moon and Mars. We have pieces of all these worlds in our laboratories, and their continued study provides incredibly valuable "ground truth" to complement space exploration missions. Extensive information about these unique materials, as well as actual lunar samples and meteorites, are available for display and education. The Johnson Space Center (JSC) has the unique responsibility to curate NASA's extraterrestrial samples from past and future missions. Curation includes documentation, preservation, preparation, and distribution of samples for research, education, and public outreach. At the current time JSC curates six types of extraterrestrial samples: (1) Moon rocks and soils collected by the Apollo astronauts (2) Meteorites collected on US expeditions to Antarctica (including rocks from the Moon, Mars, and many asteroids including Vesta) (3) "Cosmic dust" (asteroid and comet particles) collected by high-altitude aircraft (4) Solar wind atoms collected by the Genesis spacecraft (5) Comet particles collected by the Stardust spacecraft (6) Interstellar dust particles collected by the Stardust spacecraft These rocks, soils, dust particles, and atoms continue to be studied intensively by scientists around the world. Descriptions of the samples, research results, thousands of photographs, and information on how to request research samples are on the JSC Curation website: http://curator.jsc.nasa.gov/ NASA provides a limited number of Moon rock samples for either short-term or long-term displays at museums, planetariums, expositions, and professional events that are open to the public. The JSC Public Affairs Office handles requests for such display samples. Requestors should apply in writing to Mr. Louis Parker, JSC Exhibits Manager. Mr. Parker will advise successful applicants regarding provisions for receipt, display, and return of the samples. All loans will be preceded by a signed loan agreement executed between NASA and the requestor's organization. Email address: louis.a.parker@nasa.gov Sets of twelve thin sections of Apollo lunar samples and sets of twelve thin sections of meteorites are available for short-term loan from JSC Curation. The thin sections are designed for use in college and university courses where petrographic microscopes are available for viewing. Requestors should contact the Ms. Mary Luckey, Education Sample Curator. Email address: mary.k.luckey@nasa.gov

Allen, Carlton C.↗

Coordinated Analysis of an Experimentally Space Weathered Carbonaceous Chondrite

The surfaces of airless bodies experience solar wind irradiation and micrometeorite impacts, a process collectively known as space weathering. These mechanisms alter the chemical composition, microstructure, and optical properties of surface materials and considerable work has been done to understand this phenomenon in lunar and ordinary chondritic materials. However, ongoing sample return missions Hayabusa2 to asteroid Ryugu and OSIRIS-REx to asteroid Bennu have prompted the need to study the effects of space weathering on hydrated, organic-rich materials, especially in the context of early results. Understanding space weathering of these samples is critical for properly interpreting remote sensing data during asteroid encounters, for sample site selection, and for the eventual study of returned samples. We can better understand space weathering of carbonaceous materials by simulating these processes in the laboratory. Recent experiments have shown that the changes in spectral characteristics of carbonaceous chondrites are not consistent among experiments, suggesting additional work is needed before these results can inform our understanding of spectral variations on asteroidal surfaces. Similarly, substantial work remains to characterize the chemical and microstructural effects of these processes in order to correlate these features with spectral changes. Here, we build on our previous work, presenting new results of the pulsed laser irradiation of the Murchison (CM2) meteorite to simulate micrometeorite impacts and the progressive space weathering of carbonaceous surfaces.

Thompson, M. S.↗

Clean is not Sterile: A Planetary Science and Planetary Protection Perspective on Cleanroom Microbiology at NASA

The Astromaterials Acquisition and Curation Office at NASA is responsible for the curation of extraterrestrial samples from NASA’s past and future sample return missions. Our office curates samples from the moon, meteorites, comets, asteroids, cosmic dust and solar wind particles. All these samples are kept in cleanrooms to limit particulate and trace metal contamination, but none of these cleanrooms are specifically designed to control microbial contamination. During the early Apollo missions NASA scientists were very concerned with protecting the Earth from potential microbial contamination from the moon and with protecting the lunar samples from terrestrial microbes. NASA developed specialized equipment and clean rooms to keep these collections pristine. However, as we learned more about the lunar environment our concerns about microbial contamination lessened. Today none of the existing collections have microbial contamination requirements because they are not considered susceptible to microbial alteration under curation conditions (e.g. solar wind samples, and lunar samples) or have already been contaminated by terrestrial biology (meteorites collected in Antarctica). However, NASA’s OSIRIS-REx mission will land in 2023 with samples from a carbon rich asteroid that will be susceptible to microbial alteration. The Perseverance rover on Mars will begin to collect and cache samples that will be returned to Earth as soon as 2031. Martian samples may contain signs of extraterrestrial life and will have to be treated like the early Apollo samples. Martian samples will be isolated to protect the Earth, and must also be protected from terrestrial contamination. I will present microbial monitoring data from existing NASA cleanrooms and discuss how NASA is planning to use techniques from the pharmaceutical industry and academia to design new laboratories and equipment that will protect astromaterials and the earth from unwanted microbial contamination. I will also discuss a project to sample the external microbiome of the International Space Station. Results from this research will be used to design facilities for use on Mars that limit the amount of contamination associated with crewed missions.

Aaron B Regberg↗

Cleaning Genesis Mission Payload for Flight with Ultra-Pure Water and Assembly in ISO Class 4 Environment

Genesis mission to capture and return to Earth solar wind samples had very stringent contamination control requirements in order to distinguish the solar atoms from terrestrial ones. Genesis mission goals were to measure solar composition for most of the periodic table, so great care was taken to avoid particulate contamination. Since the number 1 and 2 science goals were to determine the oxygen and nitrogen isotopic composition, organic contamination was minimized by tightly controlling offgassing. The total amount of solar material captured in two years is about 400 micrograms spread across one sq m. The contamination limit requirement for each of C, N, and O was <1015 atoms/sq cm. For carbon, this is equivalent to 10 ng/cm2. Extreme vigilance was used in pre-paring Genesis collectors and cleaning hardware for flight. Surface contamination on polished silicon wafers, measured in Genesis laboratory is approximately 10 ng/sq cm.

Allton, Judith H.↗

In Situ Measurement of Atmospheric Krypton and Xenon on Mars with Mars Science Laboratory

Mars Science Laboratorys Sample Analysis at Mars (SAM) investigation has measured all of the stable isotopes of the heavy noble gases krypton and xenon in the martian atmosphere, in situ, from the Curiosity Rover at Gale Crater, Mars. Previous knowledge of martian atmospheric krypton and xenon isotope ratios has been based upon a combination of the Viking missions krypton and xenon detections and measurements of noble gas isotope ratios in martian meteorites. However, the meteorite measurements reveal an impure mixture of atmospheric, mantle, and spallation contributions. The xenon and krypton isotopic measurements reported here include the complete set of stable isotopes, unmeasured by Viking. The new results generally agree with Mars meteorite measurements but also provide a unique opportunity to identify various non-atmospheric heavy noble gas components in the meteorites. Kr isotopic measurements define a solar-like atmospheric composition, but deviating from the solar wind pattern at 80Kr and 82Kr in a manner consistent with contributions originating from neutron capture in Br. The Xe measurements suggest an intriguing possibility that isotopes lighter than 132Xe have been enriched to varying degrees by spallation and neutron capture products degassed to the atmosphere from the regolith, and a model is constructed to explore this possibility. Such a spallation component, however, is not apparent in atmospheric Xe trapped in the glassy phases of martian meteorites.

Conrad, P. G.↗

Volatile Analysis by Pyrolysis of Regolith (Vapor) on the Moon using Mass Spectrometry

The identification of lunar resources such as water is a fundamental component of the the NASA Vision for Space Exploration. The Lunar Prospector mission detected high concentrations of hydrogen at the lunar poles that may indicate the presence of water or other volatiles in the lunar regolith [1]. One explanation for the presence of enhanced hydrogen in permanently shadowed crater regions is long term trapping of water-ice delivered by comets, asteroids, and other meteoritic material that have bombarded the Moon over the last 4 billion years [2]. It is also possible that the hydrogen signal at the lunar poles is due to hydrogen implanted by the solar wind which is delayed from diffusing out of the regolith by the cold temperatures [3]. Previous measurements of the lunar atmosphere by the LACE experiment on Apollo 17, suggested the presence of cold trapped vola'tiles that were expelled by solar heating [4]. In situ composition and isotopic analyses of the lunar regolith will be required to establish the abundance, origin, and distribution of water-ice and other volatiles at the lunar poles. Volatile Analysis by Pyrolysis of Regolith (VAPoR) on the Moon using mass spectrometry is one technique that should be considered. The VAPoR pyrolysis-mass spectrometer (pyr-MS) instrument concept study was selected for funding in 2007 by the NASA Lunar Sortie Science Opportunities (LSSO) Program. VAPoR is a miniature version of the Sample Analysis at Mars (SAM) instrument suite currently being developed at NASA Goddard for the 2009 Mars Science Laboratory mission (Fig. 1).

Glavin, D. P.↗