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Adaptive Site Management Strategies for the Hanford Central Plateau Groundwater

Adaptive site management (ASM) is a systematic and iterative management approach that can be used to expedite the remediation of large and/or complex sites. ASM is defined as a formal and systematic project or site management approach centered on rigorous site planning and a firm understanding of site conditions and uncertainties, using science and technology to routinely re-evaluate and prioritize site remedial actions and characterization activities. The goal of the approach is to create a framework of structured and continuous planning, implementation, and assessment processes that accommodates new information and changing site conditions to develop effective and efficient cleanup approaches that achieves the required outcome(s) while optimizing costs, cleanup timeframe, and performance. Central to ASM is an evolving conceptual site model (CSM). Over time, incremental reductions in uncertainty associated with the CSM will occur, while supporting continued progress toward site cleanup and closure through remedy optimization and evaluation. ASM has the potential to expedite cleanup for the Central Plateau area at Hanford through a planned and systematic approach for reducing uncertainty with targeted characterization activities, while continuing remediation activities that advance cleanup for key risk-driving contaminants. A core component of cleanup within the Central Plateau is the 200 West Pump-and-Treat (P&T) system. Even with an active P&T remedy, uncertainty exists with respect to plume distributions, total mass in the aquifer, and currently known continuing sources. Additional uncertainty is associated with multiple contaminant source locations in the vadose zone, which have the potential to create new groundwater plumes in the absence of any source control measures, although not all contaminant fluxes to groundwater will result in contaminant concentrations above cleanup levels. Collectively, these uncertainties need to be addressed in the CSM to support effective and efficient site progress toward cleanup goal(s). Other nontechnical factors that may warrant an ASM approach at the Hanford Central Plateau are associated with the formation of operable units (OUs) used to manage cleanup. With the exception of the 200-ZP-1 OU, the three remaining groundwater OUs only have interim action records of decision. Nine vadose zone source area OUs are also in the early stages of the remedial investigation and feasibility study process, with pending characterization and technology identification activities. A set of proposed site objectives for the Central Plateau are provided in this document as an initial consideration/example and basis for discussion for ASM implementation. These example site objectives were selected with the goal of maintaining protectiveness at the Columbia River through confinement of contaminant plumes within an administratively controlled area below existing surface waste sites and waste disposal facilities. Although site decision makers and regulators need to provide concurrence, these site objectives are used in this document to describe the elements of an ASM approach, including selection of interim objectives and a long-term adaptive management plan. Interim objectives are also defined to yield measurable incremental progress toward the overall site goals. This document identifies initial technical considerations for developing an ASM framework for the Central Plateau cleanup decisions. These considerations are intended to facilitate more specific decisions, such as objectives, near- and long-term actions, and performance metrics, to develop an overall approach that maintains protectiveness but recognizes the uncertainty, long timeframe, and technical challenges that need to be considered in selecting, implementing, and managing remediation at the Hanford Central Plateau.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Formation of Residual Gases from Source Materials in Closed Crystal Growth Systems

Different, non-constituent cases are present in crystal growth systems and may affect processes like growth rate in PVT or voids formation and detached solidification in melt growth systems. The presence of the gas may be detrimental or advantageous depending on its amount and composition, and on the process in question. The presence of the cases, their amount and composition, can be caused and changed by diffusion through and desorption from the growth container material. We have investigated these phenomena for silica glass ampoules. We also found, that residual cases can be generated by the source materials: even very high purity commercial elements and compounds may contain trace amounts of impurities, particularly oxides. The oxides may have low volatilities themselves but their reaction with other species, particularly carbon and hydrogen, may produce volatile compounds like water or carbon oxides. The amount of the gas and its composition is dependent on the original purity of the material (oxide contaminants) and the heat treatment of the source prior to sealing. In many cases. particularly at temperatures below about 900 C and in well-outgassed ampoules, this mechanism dominates. The problem is of a particular importance in sealed systems where the amount and composition of the gas cannot be directly controlled. Therefore, a reasonable knowledge and understanding of the origin, composition, magnitude, and change with time of gases present in sealed ampoules may be important for a meaningful control and interpretation of crystal growth processes. We have investigated this phenomenon in more details for a number of elements and compounds, primarily for II-VI and IV-VI materials. Different source pre-treatment and annealing procedures were applied, and subsequent consecutive annealings and measurements were done to determine the origin and development of the gas in the systems.

Palosz, W.↗

Catalyst Substrates Remove Contaminants, Produce Fuel

A spacecraft is the ultimate tight building. We don t want any leaks, and there is very little fresh air coming in, says Jay Perry, an aerospace engineer at Marshall Space Flight Center. As a result, there is a huge potential for a buildup of contaminants from a host of sources. Inside a spacecraft, contaminants can be introduced from the materials that make spacecraft components, electronics boxes, or activities by the crew such as food preparation or cleaning. Humans also generate contaminants by breathing and through the body s natural metabolic processes. As part of the sophisticated Environmental Control and Life Support System on the International Space Station (ISS), a trace contaminant control system removes carbon dioxide and other impurities from the cabin atmosphere. To maintain healthy levels, the system uses adsorbent media to filter chemical contaminant molecules and a high-temperature catalytic oxidizer to change the chemical structure of the contaminants to something more benign, usually carbon dioxide and water. In the 1990s, while researching air quality control technology for extended spaceflight travel, Perry and others at Marshall were looking for a regenerable process for the continuous removal of carbon dioxide and trace chemical contaminants on long-duration manned space flights. At the time, the existing technology used on U.S. spacecraft could only be used once, which meant that a spacecraft had to carry additional spare parts for use in case the first one was depleted, or the spacecraft would have to return to Earth to exchange the components.

Source record↗

On orbit surfacing of thermal control surfaces

Substrates to be contaminated and contamination source were prepared. Additional information on paint spray method apparatus was obtained. Silver teflon second surface mirror samples and S 13 GLO paint samples were mounted, photographed under the microscope and measured to establish baseline data. Atomic oxygen cleaning and spray painting are being considered. Electrostatic powder and plasma spray coating systems appear to have serious drawbacks.

Racette, G. W.↗

Fiber optics for advanced aircraft

The increased use of composites makes the digital control more susceptible to electromagnetic effects. In order to provide the protection to the digital control additional shielding will be required as well as protective circuitry for the electronics. This results in increased weight and reduced reliability. The advantages that fiber optic technology provides for advanced aircraft applications is recognized. The use of optical signals to carry information between the aircraft and the control module provides immunity from contamination by electromagnetic sources as well as other important benefits such as reduced weight and volume resulting from the elimination of the shielding and the replacement of metal conductors with low weight glass fibers. In 1975 NASA began work to develop passive optical sensors for use with fiber optics in aircraft control systems. The problem now is to choose the best optical sensor concepts and evaluate them for use. In 1985 NASA and DOD entered into a joint program, Fiber Optic Control System Integration (FOCSI), to look at optical technology specifically for use in advanced aircraft systems. The results of this program are discussed. The conclusion of the study indicated that the use of fiber optic technology in advanced aircraft systems is feasible and desirable. The study pointed to a lack of available sensors from vendors capable of operating in the adverse environments of advanced aircraft.

Baumbick, Robert J.↗

Fiber optics for advanced aircraft

The increased use of composites makes the digital control more susceptible to electromagnetic effects. In order to provide the protection to the digital control additional shielding will be required as well as protective circuitry for the electronics. This results in increased weight and reduced reliability. The advantages that fiber optic technology provides for advanced aircraft applications is recognized. The use of optical signals to carry information between the aircraft and the control module provides immunity from contamination by electromagnetic sources as well as other important benefits such as reduced weight and volume resulting from the elimination of the shielding and the replacement of metal conductors with low weight glass fibers. In 1975 NASA began work to develop passive optical sensors for use with fiber optics in aircraft control systems. The problem now is to choose the best optical sensor concepts and evaluate them for use. In 1985 NASA and DOD entered into a joint program, Fiber Optic Control System Integration (FOCSI), to look at optical technology specifically for use in advanced aircraft systems. The results of this program are discussed. The conclusion of the study indicated that the use of fiber optic technology in advanced aircraft systems is feasible and desirable. The study pointed to a lack of available sensors from vendors capable of operating in the adverse environments of advanced aircraft.

Baumbick, Robert J.↗

NASA's International Space Station: A Testbed for Planetary Protection Protocol Development

Wherever humans go, they inevitably carry along the critters that live in and on them. Conventional wisdom has long held that it is unlikely those critters could survive the space environment, but in 2007 some microscopic aquatic animals called Tardigrades survived exposure to space and in 2008 Cyanobacteria lived for 548 days outside the ISS. Unlike the Mars rovers that were cleaned once and sent on their way, crew members will provide a constantly regenerating contaminant source. Are we prepared to certify that we can meet forward contamination protocols as we search for life at new destinations? What about the organisms we might reasonably expect a crewed spacecraft to leak or vent? Do we even know what they are? How long might our tiny hitch-hikers survive in close proximity to a warm spacecraft that periodically leaks/vents water or oxygen and how might they mutate with long-duration exposure? How will these contaminants migrate from their source in conditions encountered in space or on other planetary surfaces? This project aims to answer some of these questions by bringing together key stakeholder communities to develop a human forward contamination test, analysis, and integration plan. A system engineering approach to identify the experiments, analysis, and modeling needed to develop the contamination control protocols required will be used as a roadmap to integrate the many different parts of this problem - from launch to landing, living, and working on another planetary surface.

Bell, M. S.↗

Nasa's International Space Station: A Testbed for Planetary Protection Protocol Development

Wherever humans go, they inevitably carry along the critters that live in and on them. Conventional wisdom has long held that it is unlikely those critters could survive the space environment, but in 2007 some microscopic aquatic animals called Tardigrades survived exposure to space and in 2008 Cyanobacteria lived for 548 days outside the ISS. Unlike the Mars rovers that were cleaned once and sent on their way, crew members will provide a constantly regenerating contaminant source. Are we prepared to certify that we can meet forward contamination protocols as we search for life at new destinations? What about the organisms we might reasonably expect a crewed spacecraft to leak or vent? Do we even know what they are? How long might our tiny hitch-hikers survive in close proximity to a warm spacecraft that periodically leaks/vents water or oxygen and how might they mutate with long-duration exposure? How will these contaminants migrate from their source in conditions encountered in space or on other planetary surfaces? This project aims to answer some of these questions by bringing together key stakeholder communities to develop a human forward contamination test, analysis, and integration plan. A system engineering approach to identify the experiments, analysis, and modeling needed to develop the contamination control protocols required will be used as a roadmap to integrate the many different parts of this problem - from launch to landing, living, and working on another planetary surface.

Bell, M. S.↗

Contamination effects on Space Station Freedom electric power system performance

One design issue for Space Station Freedom (SSF) is the potential performance decrease of the electric power system (EPS) solar arrays and radiators as a result of contamination on sensitive surfaces. The authors discuss SSF potential contamination sources and contamination effects on the solar array and radiator performance due to these sources. With these contamination consideration, the SSF EPS is designed for the induced contamination environment at an optimal cost. The efforts on contamination protection and control are undergoing continual update because of the changes in the SSF configuration and in the contamination requirements, and observations from recent flight and laboratory test data are continuously being incorporated into the design.

Lu, Cheng-Yi↗

Design of an Adsorption Bed for Exploration Trace Contaminant Control

The state-of-the-art in long mission duration spacecraft trace contaminant control processes relies on physical and chemical adsorption for contaminant removal. Target species for adsorption include low and semivolatile organic compounds while chemisorption is utilized for metabolic ammonia control. When adsorption is employed in conjunction with a high temperature oxidation process, a complementary impact on cabin air quality may be realized. The adsorption bed also serves to guard the downstream oxidation catalyst from foulants and potential poisons which may decrease its lifetime and activity. To this end, a packed adsorption guard-bed was sized to control a statistical contaminant load model over a simulated Mars transit mission duration. The updated load model incorporates flight air-quality data and contemporary metabolic source emission literature. The guard-bed was operated in tandem with an exploration prototype thermal catalytic oxidizer. The exploration guard-bed prototype included design considerations from recent flight technology demonstrations and changes intended to improve compatibility with enriched oxygen exploration cabin environments as compared to the prior-art of contaminant control system design.

Trace Contaminant Control↗

Source Contaminant Control for the Heat Melt Compactor

The Logistics Reduction and Repurposing project includes the heat melt compactor (HMC), a device that compacts waste containing plastic into a tile that will minimize volume, and may be used as materials for radiation shielding. During the process, a small purge gas stream is directed through the HMC chamber to transport out gasses and humidity released from the process. NASA Marshall Space Flight Center is tasked with developing and delivering a contamination control system to clean the purge gas prior to exhausting it back into the cabin for crew inhalation.

Roman, Monsi↗

Study of surfaces using near infrared optical fiber spectrometry

The measurement and control of cleanliness for critical surfaces during manufacturing and in service provides a unique challenge for fulfillment of environmentally benign operations. Of particular interest has been work performed in maintaining quality in the production of bondline surfaces in propulsion systems and the identification of possible contaminants. This work requires an in-depth study of the possible sources of contamination, methodologies to identify contaminants, discrimination between contaminants and chemical species caused by environment, and the effect of particular contaminants on the bondline integrity of the critical surfaces. This presentation will provide an introduction to the use of optical fiber spectrometry in a nondestructive measurement system for process monitoring and how it can be used to help clarify issues concerning surface chemistry. Correlation of the Near Infrared (NIR) spectroscopic results with Optical Stimulated Electron Emission (OSEE) and ellipsometry will also be presented.

Workman, G. L.↗

NASA Tech Briefs, July 2006

Topics covered include: Airport Remote Tower Sensor Systems; Implantable Wireless MEMS Sensors for Medical Uses; Embedded Sensors for Measuring Surface Regression; Coordinating an Autonomous Earth-Observing Sensorweb; Range-Measuring Video Sensors; Stability Enhancement of Polymeric Sensing Films Using Fillers; Sensors for Using Times of Flight to Measure Flow Velocities; Receiver Would Control Phasing of a Phased-Array Antenna; Modern Design of Resonant Edge-Slot Array Antennas; Carbon-Nanotube Schottky Diodes; Simplified Optics and Controls for Laser Communications; Coherent Detection of High-Rate Optical PPM Signals; Multichannel Phase and Power Detector; Using Satellite Data in Weather Forecasting: I; Using Dissimilarity Metrics to Identify Interesting Designs; X-Windows PVT Widget Class; Shuttle Data Center File-Processing Tool in Java; Statistical Evaluation of Utilization of the ISS; Nanotube Dispersions Made With Charged Surfactant; Aerogels for Thermal Insulation of Thermoelectric Devices; Low-Density, Creep-Resistant Single-Crystal Superalloys; Excitations for Rapidly Estimating Flight-Control Parameters; Estimation of Stability and Control Derivatives of an F-15; Tool for Coupling a Torque Wrench to a Round Cable Connector; Ultrasonically Actuated Tools for Abrading Rock Surfaces; Active Struts With Variable Spring Stiffness and Damping; Multiaxis, Lightweight, Computer-Controlled Exercise System; Dehydrating and Sterilizing Wastes Using Supercritical CO2; Alpha-Voltaic Sources Using Liquid Ga as Conversion Medium; Ice-Borehole Probe; Alpha-Voltaic Sources Using Diamond as Conversion Medium; White-Light Whispering-Gallery-Mode Optical Resonators; Controlling Attitude of a Solar-Sail Spacecraft Using Vanes; and Wire-Mesh-Based Sorber for Removing Contaminants from Air.

Source record↗

Multispectral imaging system for contaminant detection

An automated inspection system for detecting digestive contaminants on food items as they are being processed for consumption includes a conveyor for transporting the food items, a light sealed enclosure which surrounds a portion of the conveyor, with a light source and a multispectral or hyperspectral digital imaging camera disposed within the enclosure. Operation of the conveyor, light source and camera are controlled by a central computer unit. Light reflected by the food items within the enclosure is detected in predetermined wavelength bands, and detected intensity values are analyzed to detect the presence of digestive contamination.

Poole, Gavin H.↗

Cleanroom Contamination Identification Method Development

During fabrication, assembly, and testing of spacecraft and flight hardware it is vital to avoid contaminants that can cause degradation and could result in significant failure. Yet, there is no existing contamination monitoring method that provides the identity of airborne particles in a cleanroom facility. Knowing the particle identities, would allow scientists and engineers to determine the source of the contaminants and prevent setbacks before they occur or cause damage. Current cleanliness monitoring methods include airborne particle counters (APCs), fallout filters, and visual inspections. Particle counts from APCs are the primary metric used to define a cleanroom class and hence its level of cleanliness, but do not provide identification nor can they differentiate between large and small sizes of particles. In addition, using fallout filters is not a proactive, timely, or representative approach to cleanroom contamination monitoring because these samples are only retrieved after 30 days and are placed away from spacecraft processing to avoid interference with operations. In contrast, the forced air sampling method can collect a sample within an hour at any location required and provide results in less than a day. This system uses a cassette and filter sample medium to capture airborne particles which are then taken to a scanning electron microscope with energy dispersive spectroscopy (SEM/EDS) to identify and size the captured particles. Development of forced air sampling into an established laboratory capability will allow for fast sampling and routine identification of unknown contamination sources within the cleanroom. The test method development required market research for an air sampling cassette that increases sample collection efficiency and a filter with low enough background contamination to allow differentiation between a blank (control) and the collected sample. It was determined that a conductive black cassette and a polycarbonate filter were the best options. Conductive black cassettes, in comparison to the standard styrene, are manufactured using polypropylene filled with carbon. This makes the cassette conductive and minimizes the tendency of particles to stick to the wall of the cassette due to electrostatic force. In previous trials a mixed cellulose ester (MCE) filter was used to capture the contaminants, however the rougher surface of the filter contributed to entrapment of the particles within the filter structure and made it harder to identify the particles. In comparison, track etched polycarbonate filters have random cylindrical pores and a smooth surface which contributes to uniform sample distribution on the surface of the filter. Future work includes: testing the system using control samples to determine the efficiency and suitability of the medium, performing sample collection in various environments to establish ideal operating parameters and analyzing contaminant particles using SEM/EDS and assistant characterization techniques. Once fully developed, employing the forced air sampling method will help to prevent damage to spacecraft, avoid schedule delays, and allow for mission success.

Hernandez Melendez, Jailyn M.↗

Maintenance of contamination sensitive surfaces on board long-term space vehicles

In the current age, highly sensitive instruments are being flown on spacecraft, and questions of contamination have become important. The present investigation is concerned with the available approaches which can provide long-term protection for contamination sensitive surfaces. Aspects and sources of spacecraft contamination are examined, taking into account materials outgassing, particulates, propulsion system interaction, overboard venting, man-made and cosmic debris, and atomic oxygen/ambient atmosphere interaction. Suitable protection approaches provided by current technology are discussed, giving attention to aperture covers, a possibility for a retractable cover design, gaseous purges, options for prolonging the lifetime of the thermal control system, and plume shields. Some new possibilities considered are related to an early warning system for excessive amounts of contamination, a molecular/wake shield, and the use of atomic oxygen.

Phillips, A.↗

Statement of contamination problem

Space station contamination information is given. There are five major areas in which there are task requirements: (1) potential contaminants need to be identified, i.e., both the sources and types of contaminants, (2) the scope and magnitude of contaminant effects need to be determined, i.e., toxicological effects, microbacteriological effects and impurities, (3) mathematical models for predictive methods need to be developed. (4) state-of-the-art and advanced technologies for monitoring contaminants and for methods of decontamination need to be identified, and (5) automated monitoring and control systems need to be designed.

Hoffler, W.↗

International Space Station External Contamination Status

PResentation slides examine external contamination requirements; International Space Station (ISS) external contamination sources; ISS external contamination sensitive surfaces; external contamination control; external contamination control for pre-launch verification; flight experiments and observations; the Space Shuttle Orbiter waste water dump, materials outgassing, active vacuum vents; example of molecular column density profile, modeling and analysis tools; sources of outgassing induced contamination analyzed to date, quiescent sources, observations on optical degradation due to induced external contamination in LEO; examples of typical contaminant and depth profiles; and status of the ISS system, material outgassing, thruster plumes, and optical degradation.

Mikatarian, Ron↗