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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Supersonic-nitrogen flow-field measurements with the resonant Doppler velocimeter

The application of the resonant Doppler velocimeter (RDV) for obtaining the mean velocity, temperature, and pressure measurements and flow-field visualization in a supersonic free nitrogen jet is reported. This method utilizes laser-induced fluorescence to determine the spectral absorption of an atomic or molecular species seeded into the flow. A narrow linewidth tunable laser is directed into the flow and the total fluorescence from any point is obtained as the laser is tuned. The velocity of the flow is obtained from the Doppler shifted absorption frequency, and the temperature and pressure of the gas are determined from line broadening measurements. Results are presented for the use of this technique to determine the velocity, temperature, and pressure of the flow of sodium atoms seeded into a supersonic nitrogen jet. It is concluded that the visible signal is sufficiently intense for spatially resolved flow visualization purposes.

Cheng, S.↗

Foreign-gas collision broadening of the far-infrared spectrum of water vapor

The far-infrared rotational spectrum of H2(O-16) has been studied in the spectral range 25-112/cm to measure the foreign-gas collision-broadened linewidths. Measurements of 17 lines broadened by nitrogen and 21 lines broadened by oxygen are reported. The measurements were made at 297 K. From these data, the widths due to air broadening are obtained. The experimental results are compared with recent theoretical calculations and with the case of a constant linewidth, equal to the average experimental width. There is some correlation between the relative experimental linewidths and the theoretical predictions. However, the simple assumption of a constant value for the collision-broadened linewidths gives a better representation for the case of N2- and O2-broadened linewidths than do present detailed theoretical calculations.

Gasster, Samuel D.↗

Laboratory and field studies in rotational spectroscopy at the Jet Propulsion Laboratory

Rotational spectroscopy of atmospheric molecules has long been a hallmark of laboratory and field studies at the Jet Propulsion Laboratory. in addition to maintenance of the millimeter and submillimeter spectral line catalog, the laboratory has actively purued the challenging laboratory tasks of quantitative linewidth measurements and transient species identification.

linewidths↗

Conversion of laser energy to gas kinetic energy

Techniques for the gas-phase absorption of laser energy with ultimate conversion to heat or directed kinetic energy are reviewed. It is shown that the efficiency of resonance absorption by the vibration/rotation bands of the working gas can be enhanced by operating at sufficiently high pressures so that the linewidths of the absorbing transition exceed the line spacing. Within this limit, the gas can absorb continuously over the full spectral region of the band, and bleaching can be minimized since the manifold of molecular vibrational levels can simultaneously absorb the laser radiation.

Caledonia, G. E.↗

100 kHz High-Spectral-Resolution NO-PLIF Measurements for Compressible Flows

In the present work, we use a burst-mode laser and optical parametric oscillator system to perform high-spectral resolution NO-PLIF measurements of an underexpanded jet at a repetition-rate of 100 kHz, with the motivation of multi-parameter measurements of temperature, pressure, and velocity. The laser frequency of the 1064 nm seed laser for the burst-mode laser was scanned during the burst to cover two neighboring absorption line pairs near 226 nm. The peak PLIF signal intensity varies along the axial (z) direction of the underexpanded jet as the laser frequency is scanned, which we attribute to the collisional shift induced by the flow and only revealed due to the narrow linewidth of the laser. A pseudo-Voight fit is applied to the LIF excitation spectra on a pixel-by-pixel basis to measure the spectral position of the peak intensity for the two transition pairs and their amplitude. The spectral position of the peak intensity is used to derive a frequency shift, which is separated into its collisional and Doppler components using the axisymmetric nature of the flow field. The amplitude of the measured peaks is used for two-line rotational thermometry. Challenges for quantitative measurements using such an approach are discussed, including measuring the spatial variations in the energy distribution of the laser sheet at a 100 kHz repetition rate and uncertainty/variability in the step size during the fast frequency scan.

laser induced fluorescence↗

100 kHz High-Spectral-Resolution NO-PLIF Measurements for Compressible Flows

In the present work, we use a burst-mode laser and optical parametric oscillator system to perform high-spectral resolution NO-PLIF measurements of an underexpanded jet at a repetition-rate of 100 kHz, with the motivation of multi-parameter measurements of temperature, pressure, and velocity. The laser frequency of the 1064 nm seed laser for the burst-mode laser was scanned during the burst to cover two neighboring absorption line pairs near 226 nm. The peak PLIF signal intensity varies along the axial (z) direction of the underexpanded jet as the laser frequency is scanned, which we attribute to the collisional shift induced by the flow and only revealed due to the narrow linewidth of the laser. A pseudo-Voight fit is applied to the LIF excitation spectra on a pixel-by-pixel basis to measure the spectral position of the peak intensity for the two transition pairs and their amplitude. The spectral position of the peak intensity is used to derive a frequency shift, which is separated into its collisional and Doppler components using the axisymmetric nature of the flow field. The amplitude of the measured peaks is used for two-line rotational thermometry. Challenges for quantitative measurements using such an approach are discussed, including measuring the spatial variations in the energy distribution of the laser sheet at a 100 kHz repetition rate and uncertainty/variability in the step size during the fast frequency scan.

laser induced fluorescence↗

Portable high-resolution laser monochromator-interferometer with multichannel electronic readout

A high-resolution 0.4-m monochromator is described for use in wavelength diagnosis of tunable pulsed and CW laser sources in the 3000-10,000-A region. The f/20 design uses an echelle grating in an over-and-under Ebert configuration with a scanned photodiode array to provide a real-time multichannel display of spectral output. Absolute wavelength may be determined to 0.1 A with the monochromator, and a Fabry-Perot interferometer attachment extends linewidth measurement capability to 0.01 A or better. Spectra are displayed on a storage oscilloscope, and calculation of laser parameters is explained. The instrument measures 70 cm long x 15 cm wide x 20 cm high.

Morris, M. B.↗

Modification to Scott's method for direct integration of gaseous transmission to improve speed and accuracy

Two limitations to the method of Scott for rapid direct integration of gaseous transmission in a finite spectral interval over an inhomogeneous optical path are discussed. One of these is the inability to use a precomputed form of the Voigt line shape, which can be parameterized via the linewidth alone. This is rectified using the Voigt shape approximation of Kielkopf, which involves a linear combination of three functions which can be pre-computed: the Lorentz shape, the Doppler shape and a correction function. The other limitation involves situations where lines must be treated individually, either line positions must be known with great precision or a uniform value for the widths of all lines in the spectral interval does not describe the transmission adequately. In this case, the strongest lines are treated individually, while the remainder are treated assuming uniform line widths and line positions coincident with positions on the frequency grid, i.e. following Scott's method directly.

Orton, G. S.↗

Dye laser traveling wave amplifier

Injection locking was applied to a cavity-dumped coaxial flashlamp pumped dye laser in an effort to obtain nanosecond duration pulses which have both high energy and narrow-linewidth. In the absence of an injected laser pulse, the cavity-dumped dye laser was capable of generating high energy (approx. 60mJ) nanosecond duration output pulses. These pulses, however, had a fixed center wavelength and were extremely broadband (approx. 6nm FWHM). Experimental investigations were performed to determine if the spectral properties of these outputs could be improved through the use of injection-locking techniques. A parametric study to determine the specific conditions under which the laser could be injection-locked was also carried out. Significant linewidth reduction to 0.0015nm) of the outputs was obtained through injection-locking but only at wavelengths near the peak lasing wavelength of the dye. It was found, however; that by inserting weakly dispersive tuning elements in the laser cavity, these narrow-linewidth outputs could be obtained over a wide (24nm) tuning range. Since the tuning elements had low insertion losses, the tunability of the output was obtained without sacrificing output pulse energy.

Davidson, F.↗

Simple, Compact, High-Resolution Monochromatic X-Ray Source for Characterization of X-Ray Calorimeter Arrays

X-ray calorimeters routinely achieve very high spectral resolution, typically a few eV full width at half maximum (FWHM). Measurements of calorimeter line shapes are usually dominated by the natural linewidth of most laboratory calibration sources. This compounds the data acquisition time necessary to statistically sample the instrumental line broadening and can add systematic uncertainty if the intrinsic line shape of the source is not well known. To address these issues, we have built a simple, compact monochromatic x-ray source using channel cut crystals. A commercial x-ray tube illuminates a pair of channel cut crystals that are aligned in a dispersive configuration to select the Kα1 line of the x-ray tube anode material. The entire device, including the x-ray tube, can be easily hand-carried by one person and may be positioned manually or using a mechanical translation stage. The output monochromatic beam provides a collimated image of the anode spot with magnification of unity in the dispersion direction (typically 100 μm–200 μm for the x-ray tubes used here) and is unfocused in the cross-dispersion direction so that the source image in the detector plane appears as a line. We measured output count rates as high as 10 count/s/pixel for the Hitomi soft x-ray spectrometer, which had 819 μm square pixels. We implemented different monochromator designs for energies of 5.4 keV (one design) and 8.0 keV (two designs), which have effective theoretical FWHM energy resolution of 0.125 eV, 0.197 eV, and 0.086 eV, respectively; these are well-suited for optimal calibration measurements of state-of-the art x-ray calorimeters. We measured an upper limit for the energy resolution of our Cr Kα1 monochromator of 0.7 eV FWHM at 5.4 keV, consistent with the theoretical prediction of 0.125 eV.

M A Leutenegger↗

Analysis of mode-locked and intracavity frequency-doubled Nd:YAG laser

The paper presents analytical and computer studies of the CW mode-locked and intracavity frequency-doubled Nd:YAG laser which provide new insight into the operation, including the detuning behavior, of this type of laser. Computer solutions show that the steady-state pulse shape for this laser is much closer to a truncated cosine than to a Gaussian; there is little spectral broadening for on-resonance operation; and the chirp is negligible. This leads to a simplified analytical model carried out entirely in the time domain, with atomic linewidth effects ignored. Simple analytical results for on-resonance pulse shape, pulse width, signal intensity, and harmonic conversion efficiency in terms of basic laser parameters are derived from this model. A simplified physical description of the detuning behavior is also developed. Agreement is found with experimental studies showing that the pulsewidth decreases as the modulation frequency is detuned off resonance; the harmonic power output initially increases and then decreases; and the pulse shape develops a sharp-edged asymmetry of opposite sense for opposite signs of detuning.

Siegman, A. E.↗

Improved spectroscopic line parameters for the ozone molecule

Recently available spectral O3 line parameters are summarized and progress in remote sensing based on these parameters is discussed. Particular attention is given to covering line positions, line intensities and linewidths for both the main isotopic species (O-16)3 and the isotopic variants (O-16)(O-18)(O-16) and (O-16)(O-16)(O-18).

Flaud, J.-M.↗

Passive Microwave Spectral Imaging of Amospheric Structure

The primary objective of this research was to improve the scientific foundation necessary to full realization of the meteorological potential of the NOAA Advanced Microwave Sounding Unit (AMSU) recently first launched on the NOAA-15 satellite in May, 1998. These advances were made in four main areas: (1) improvements, based on aircraft observations, in the atmospheric transmittance expressions used for interpreting AMSU and similar data; (2) development of neural network retrieval methods for cloud top altitude estimates of approximately 1-km accuracy under cirrus shields--the altitude is that of the larger ice particles aloft, which is related to precipitation rate; (3) analysis of early AMSU flight data with respect to its precipitation sensitivity and fine-scale thermal structure; and (4) improvements to the 54-GHz and 118-GHz MTS aircraft imaging spectrometer now operating on the NASA ER-2 aircraft. More specifically, the oxygen transmittance expressions near 118 GHz were in better agreement with aircraft data when the temperature dependence exponent of the 118.75-GHz linewidth was increased from the MPM92 value (Liebe et al., 1992) of 0.8 to 0.97+/-0.03. In contrast, the observations 52.5-55.8 GHz were consistent with the MPM92 model. Neural networks trained on comparisons of 118-GHz spectral data and coincident stereoscopic video images of convective cells observed from 20-km altitude yielded agreement in their peak altitudes within as little as 1.36 km rms, much of which is stereoscopic error. Imagery using these methods produced useful characterizations for Cyclone Oliver in 1993 and other storms (Schwartz et al., 1996; Spina et al., 1998). Similar neural network techniques yielded simulated rms errors in relative humidity retrievals of 6-14 percent over ocean and 6-15 percent over land at pressure levels from 1013 to 131 mbar (Cabrera-Mercader and Staelin, 1995).

Staelin, David H.↗

Intensity and linewidth measurements in the 13.7-micron fundamental bands of (C-12)2H2 and (C-12)(C-13)H2 at planetary atmospheric temperatures

The absolute intensities and collision-broadened half-widths of several lines in the P-,Q-, and R-branches of the nu5-fundamental band of (C-12)2H2 have been measured at various temperatures between 147 and 295 K employing the Doppler-limited spectral resolution (about 10 exp -4/cm) of a tunable diode laser spectrometer. The absolute intensities of R(5), R(7), R(9), and R(20) in the same fundamental belonging to (C-12)(C-13)H2 have also been measured at 294 K. The temperature dependence of the collision-broadened half-width has been determined for some of the lines broadened by planetary atmospheric gases, namely, He, Ar, H2, and N2. Four self-broadened linewidths of (C-12)2H2, as well as three H2-broadened linewidths and a self-broadened half-width of (C-12)(C-13)H2, have also been retrieved from the measurements.

Varanasi, Prasad↗

A high spectral resolution VLA search for H I absorption towards A496, A1795, and A2584

In this paper, we present the results of a Very Large Array (VLA) search for H I absorption with high spectral resolution (1.6 km/s) towards A496, A1795, A2584, and A2597. These observations are well matched to the properties of cold, optically thick H I clouds, where the line width is given by the width of an individual cloud rather than the dispersion in an ensemble of clouds. We do not detect any H I absorption with narrow linewidths in these clusters. Our limits mainly apply to clouds which are larger than a few tenths parsec-i.e., if the clouds are much smaller than the background radio source and have a low covering factor in velocity space, they could still escape detection. The estimated limits on column density (for clouds in this regime of parameter space) are 2-3 orders of magnitude less than the 10(exp 21)/sq cm required to explain the x-ray absorption seen in some cooling flow clusters. The combination of our high spectral resolution H I absorption searches with the existing lower spectral resolution H I absorption searches and the searches for H I emission makes it unlikely that atomic hydrogen is the dominant component of the cold x-ray absorbing gas in the inter-cloud medium (ICM).

O'Dea, Christopher P.↗

NASA Space Laser Technology

Over the next two decades, the number of space based laser missions for mapping, spectroscopy, remote sensing and other scientific investigations will increase several fold. The demand for high wall-plug efficiency, low noise, narrow linewidth laser systems to meet different systems requirements that can reliably operate over the life of a mission will be high. The general trends will be for spatial quality very close to the diffraction limit, improved spectral performance, increased wall-plug efficiency and multi-beam processing. Improved spectral performance will include narrower spectral width (very near the transform limit), increased wavelength stability and or tuning (depending on application) and lasers reaching a wider range of wavelengths stretching into the mid-infrared and the near ultraviolet. We are actively developing high efficiency laser transmitter and high-sensitivity laser receiver systems that are suitable for spaceborne applications.

Electro-Optics↗