Search NASA⌕ Search

SEARCH · Search NASA

Results for “Sulphur”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

The Origin of Titan's External Oxygen: Further Constraints from ALMA Upper Limits on CS and CH2NH

Titan's atmospheric inventory of oxygen compounds (H2O, CO2, CO) are thought to result from photochemistry acting on externally supplied oxygen species (O+, OH, H2O). These species potentially originate from two main sources: (1) cryogenic plumes from the active moon Enceladus and (2) micrometeoroid ablation. Enceladus is already suspected to be the major O+ source, which is required for CO creation. However, photochemical models also require H2O and OH influx to reproduce observed quantities of CO2 and H2O. Here, we exploit sulphur as a tracer to investigate the oxygen source because it has very different relative abundances in micrometeorites (S/O approx. 10(exp -2) and Enceladus' plumes (S/O approx. 10(exp -5). Photochemical models predict most sulphur is converted to CS in the upper atmosphere, so we use Atacama Large Millimeter/submillimeter Array (ALMA) observations at approx. 340 GHz to search for CS emission. We determined stringent CS 3 sigma stratospheric upper limits of 0.0074 ppb (uniform above 100 km) and 0.0256 ppb (uniform above 200 km). These upper limits are not quite stringent enough to distinguish between Enceladus and micrometeorite sources at the 3 sigma level and a contribution from micrometeorites cannot be ruled out, especially if external flux is toward the lower end of current estimates. Only the high flux micrometeorite source model of Hickson et al. can be rejected at 3 sigma. We determined a 3 sigma stratospheric upper limit for CH2NH of 0.35 ppb, which suggests cosmic rays may have a smaller influence in the lower stratosphere than predicted by some photochemical models. Disk-averaged C3H4 and C2H5CN profiles were determined and are consistent with previous ALMA and Cassini/CIRS measurements.

Teanby, N.A.↗
NASA NTRS2021

Investigation of several proxies to estimate sulfuric acid concentration in volcanic plume conditions

Sulfuric acid (H2SO4) is commonly accepted as a key precursor for atmospheric new particle formation (NPF). However, direct measurements of [H2SO4] remain challenging, thus preventing the determination of this important quantity, and, consequently, a complete understanding of its contribution to the NPF process. Several proxies have been developed to bridge the gaps, but their ability to predict [H2SO4] in very specific conditions such as those encountered in volcanic plumes (including in particular high sulphur dioxide mixing ratios) has not been evaluated so far. In this context, the main objective of the present study was to develop new proxies for daytime [H2SO4] in volcanic plume conditions and compare their performance to that of the proxies available in the literature. In specific, the data collected at Maïdo during the OCTAVE 2018 campaign, in the volcanic eruption plume of the Piton de la Fournaise, were first used to derive seven proxies based on the knowledge of sulphur dioxide (SO2) mixing ratio, global radiation, condensation sink (CS) and relative humidity (RH). In three of the seven proxies (F1–F3), all variables were given equal weight in the prediction of [H2SO4], while adjusted powers were allowed for the different variables in the other four proxies (A1–A4). Proxies A1–A4 were overall found to perform better compared to F1–F3, with, in specific, improved predictive ability for [H2SO4] > 2 × 108 per cu.cm. The CS was observed to play an important role in regulating [H2SO4], while, in contrast, the inclusion of RH did not improve the predictions. A last expression accounting for an additional sink term related to cluster formation, S1, was also tested and showed a very good predictive ability over the whole range of measured [H2SO4]. The newly developed proxies were in a second step further evaluated using airborne measurements performed in the passive degassing plume of Etna during the STRAP 2016 campaign. Increased correlations between observed and predicted [H2SO4] were obtained when the dependence of predicted [H2SO4] over CS was the lowest, and when the dependence over [SO2] was concurrently the highest. The best predictions were finally retrieved by the simple formulation of F2 (in which [SO2] and radiation alone were assumed to explain the variations of [H2SO4] with equal contributions), with a pre factor adapted to the STRAP data. All in all, our results illustrate the fairly good capacity of the proxy available in the literature to describe [H2SO4] in volcanic plume conditions, but highlight at the same time the benefit of the newly developed proxies for the prediction of the highest concentrations ([H2SO4] > 2–3 × 108 per cu.cm). Also, the contrasting behaviours of the new proxies in the two investigated datasets indicate that in volcanic plumes like in other environments, the relevance of a proxy can be affected by changes in environmental conditions, and that location specific coefficients do logically improve the predictions.

new particle formation↗
NASA NTRS1970

Intumescent Coatings as Fire Retardants

Fire-retardant paint, when activated by the heat of fire, reacts to form a thick, low-density, polymeric coating or char layer. Water vapor and sulphur dioxide are released during the intumescent reaction.

Fish, R. H.↗
NASA NTRS1973

Research for applications of remote sensing to state and local governments (ARSIG)

Remote sensing and its application to problems confronted by local and state planners are reported. The added dimension of remote sensing as a data gathering tool has been explored identifying pertinent land use factors associated with urban growth such as soil associations, soil capability, vegetation distribution, and flood prone areas. Remote sensing within rural agricultural setting has also been utilized to determine irrigation runoff volumes, cropping patterns, and land use. A variety of data sources including U-2 70 mm multispectral black and white photography, RB-57 9-inch color IR, HyAC panoramic color IR and ERTS-1 imagery have been used over selected areas of Arizona including Tucson, Arizona (NASA Test Site #30) and the Sulphur Springs Valley.

Foster, K. E.↗
NASA NTRS1973

Grain boundary mobility in anion doped MgO

Certain anions OH(-), F(-) and Gl(-) are shown to enhance grain growth in MgO. The magnitude of their effect decreases in the order in which the anions are listed and depends on their location (solid-solution, second phase) in the MgO lattice. As most anions exhibit relatively high vapor pressures at sintering temperatures, they retard densification and invariably promote residual porosity. The role of anions on grain growth rates was studied in relation to their effect on pore mobility and pore removal; the atomic process controlling the actual rates was determined from observed kinetics in conjunction with the microstructural features. With respect to controlling mechanisms, the effects of all anions are not the same. OH(-) and F(-) control behavior through creation of a defect structure and a grain boundary liquid phase while Cl(-) promotes matter transport within pores by evaporation-condensation. Studies on an additional anion, S to the minus 2nd power gave results which were no different from undoped MgO, possibly because of evaporative losses during hot pressing. Hence, the effect of sulphur is negligible or undetermined.

Kapadia, C. M.↗
NASA NTRS1974

Optical properties of particles in planetary atmospheres - Laboratory studies

The laboratory techniques employed for the determination of optical constants are discussed briefly. The values obtained for the real n and imaginary k parts of the refractive indices of water, ice, and liquid ammonia are presented graphically. Work currently in progress on solid ammonia and on sulphuric acid is discussed. Other approaches to studies of the properties of aerosols in planetary atmospheres are presented briefly.

Williams, D.↗
NASA NTRS1975

Interpretation of Mariner 10 infrared observations of Venus

The infrared radiometer experiment on Mariner 10 measured limb-darkening curves for Venus in two spectral intervals, one near 11 microns and the other near 45 microns. These are analyzed in terms of the vertical opacity profile at each wavelength over a limited altitude range, approximately 60 to 80 km above the surface of the planet. Accurate multiple-scattering calculations are used to show that both opacity profiles are consistent with a model containing a cloud of sulphuric acid droplets with radii of 1.1 microns and a small amount of water vapor. Profiles of particle number density and humidity vs height are presented.

Taylor, F. W.↗
NASA NTRS1976

Improved wet-slug capacitor

Capacitor uses all-tantalum seals and straight, ungelled, 30-percent sulphuric acid electrolyte to reduce leakage from order of milliamperes to low-microampere region. Design offers better reliability in severe environments encountered in military and industrial electronics systems.

Ward, C. M.↗
NASA NTRS1978

Shear strength of metal - SiO2 contacts

The strength of the bond between metals and SiO2 was studied by measuring the static coefficient of friction of metals contacting alpha-quartz in ultrahigh vacuum. It was found that copper with either chemisorbed oxygen, nitrogen, or sulphur exhibited higher contact strength on stoichiometric SiO2 than did clean copper. Since the surface density of states induced by these species on copper is similar, it appears that the strength of the interfacial bond can be related to the density of states on the metal surface.

Pepper, S. V.↗
NASA NTRS1978

Characteristics and combustion of future hydrocarbon fuels

As the world supply of petroleum crude oil is being depleted, the supply of high-quality crude oil is also dwindling. This dwindling supply is beginning to manifest itself in the form of crude oils containing higher percentages of aromatic compounds, sulphur, nitrogen, and trace constituents. The result of this trend is described and the change in important crude oil characteristics, as related to aircraft fuels, is discussed. As available petroleum is further depleted, the use of synthetic crude oils (those derived from coal and oil shale) may be required. The principal properties of these syncrudes and the fuels that can be derived from them are described. In addition to the changes in the supply of crude oil, increasing competition for middle-distillate fuels may require that specifications be broadened in future fuels. The impact that the resultant potential changes in fuel properties may have on combustion and thermal stability characteristics is illustrated and discussed in terms of ignition, soot formation, carbon deposition flame radiation, and emissions.

Rudey, R. A.↗
NASA NTRS1978

Shear strength of metal - SiO2 contacts

The strength of the bond between metals and SiO2 is studied by measuring the static coefficient of friction of metals contacting alpha-quartz in ultrahigh vacuum. It was found that copper with either chemisorbed oxygen, nitrogen or sulphur exhibited higher contact strength on stoichiometric SiO2 than did clean copper. Since the surface density of states induced by these species on copper is similar, it appears that the strength of the interfacial bond can be related to the density of states on the metal surface.

Pepper, S. V.↗
NASA NTRS1977

Electrophoresis pattern of serum from mice exposed to different concentrations of sulfur dioxide

Three day old mice were continuously exposed to sulphur dioxide concentrations at 0ppm, 0.05ppm, 0.15ppm and 1ppm for eight weeks. At the end of the experiment, blood samples were collected and centrifuged for electrophoresis studies of the serum in 5 percent acrylamide gel. The length of bands of different serum proteins from the SO2 exposed mice was at a variance as compared with the length of bands from the control exposed mice and alpha-1 band seems to be missing from the serum of SO2 exposed mice.

Singh, J.↗
NASA NTRS1979

The Jovian boundary layer as formed by magnetic-anomaly effects

A model is presented in which a plasma boundary layer of Jupiter is formed from plasma of internal origin. It is proposed that, unlike the Earth's boundary layer, which is thought to consist principally of solar wind plasma, Jupiter's boundary layer consists principally of sulphur and oxygen from the Io plasma torus, plus a small component of hydrogen from Jupiter's ionosphere. Fresh plasma is supplied to the boundary layer once each planetary rotation period by a convection pattern that rotates with Jupiter.

Dessler, A. J.↗
NASA NTRS1980

A comparative study of cosmic ray intensity variations during 1972-1977 using spacecraft and ground-based observations

A study of cosmic ray intensity variations using data registered by Detector C on Pioneer 10 and the Sulphur Mountain neutron monitor is presented. The spacecraft data were corrected for temperature, Radioisotope Thermoelectric Generator background, and contamination by energetic solar particle events. A consistent long-term solar cycle variation intensity is observed, but additional contribution is observed in the neighborhood of 5.1 AU which is attributed to energetic electrons of Jovian origin. The spectral variation in long-term changes of the cosmic ray intensity is studied by comparing the low-energy and high-energy data, and an average value of their ratio during 1972-1977 was found to agree with the value for the 1965-1972 interval.

Venkatesan, D.↗
NASA NTRS1980

Regional price targets appropriate for advanced coal extraction

A methodology is presented for predicting coal prices in regional markets for the target time frames 1985 and 2000 that could subsequently be used to guide the development of an advanced coal extraction system. The model constructed is a supply and demand model that focuses on underground mining since the advanced technology is expected to be developed for these reserves by the target years. Coal reserve data and the cost of operating a mine are used to obtain the minimum acceptable selling price that would induce the producer to bring the mine into production. Based on this information, market supply curves can be generated. Demand by region is calculated based on an EEA methodology that emphasizes demand by electric utilities and demand by industry. The demand and supply curves are then used to obtain the price targets. The results show a growth in the size of the markets for compliance and low sulphur coal regions. A significant rise in the real price of coal is not expected even by the year 2000. The model predicts heavy reliance on mines with thick seams, larger block size and deep overburden.

Terasawa, K. L.↗
NASA NTRS1981

Apparatus for high-pressure and low-temperature experiments

A new type of apparatus for high-pressure experiments at low temperature (1.5 K) is presented. It uses a flat diamond anvil with a spherical indentor. It utilizes a load ring placed under the sample, so that the load (and hence pressure) can be measured in situ at low temperature. The apparatus was successfully used to investigate the high-conductivity state of sulphur. It can be used to investigate other thin film samples.

Golopentia, D. A.↗