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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Development and Utility of a Four-Channel Scanner for Wildland Fire Research and Applications

The Airborne Infrared Disaster Assessment System (AIRDAS) is a four-channel scanner designed and built at NASA-Ames for the specific task of supporting research and applications on fire impacts on terrestrial and atmospheric processes and also of serving as a vital instrument in the assessment of natural and man-induced disasters. The system has been flown on numerous airframes including the Navajo, King-Air, C0130, and Lear Jet 310 and a 206. The system includes a configuration composed of a 386 PC computer workstation, a non-linear detector amplifier, a sixteen-bit digitizer, dichroic filters, and Exabyte 8500 5Gb Tape output, VHS tape output, a Rockwell GPS and a 2-axis gyro. The AIRDAS system collects digital data in four wavelength regions, which can be filtered: band 1 (0.61-0.68 microns), band 2 (1.57-1.7 microns), band 3 (3.6-5.5 microns), and band 4 (5.5-13.0 microns), an FOV of 108 degrees, an IFOV of 2.62 mrads, and a digitized swath width of 720 pixels. The inclusion of the non-linear detector amplifier allows for the accurate measurement of emitted temperature from fires and hot spots. Lab testing of the scanner has indicated temperature assessments of 800 C without detector saturation. This has advantages over previous systems which were designed for thermal measurement of earth background temperatures, and were ill-equipped for accurate determination of high intensity conditions. The scanner has been flown successfully on data collection missions since 1992 in the western US as well as Brazil. These and other research and applications responses will be presented along with an assessment of future directions with the system.a

Ambrosia, Vincent G.↗
DOE OSTI2023

Effects of elevated-temperature deposition on the atomic structure of amorphous Ta 2 O 5 films

Brownian thermal noise as a result of mechanical loss in optical coatings will become the dominant source of noise at the most sensitive frequencies of ground-based gravitational-wave detectors. Experiments found, however, that a candidate material, amorphous Ta 2 O 5 , is unable to form an ultrastable glass and, consequently, to yield a film with significantly reduced mechanical loss through elevated-temperature deposition alone. X-ray scattering PDF measurements are carried out on films deposited and subsequently annealed at various temperatures. Inverse atomic modeling is used to analyze the short and medium range features in the atomic structure of these films. Furthermore, in silico deposition simulations of Ta 2 O 5 are carried out at various substrate temperatures and an atomic level analysis of the growth at high temperatures is presented. It is observed that upon elevated-temperature deposition, short range features remain identical, whereas medium range order increases. After annealing, however, both the short and medium range orders of films deposited at different substrate temperatures are nearly identical. A discussion on the surface diffusion and glass transition temperatures indicates that future pursuits of ultrastable low-mechanical-loss films through elevated temperature deposition should focus on materials with a high surface mobility, and/or lower glass transition temperatures in the range of achievable deposition temperatures.

36 MATERIALS SCIENCE↗
NASA NTRS1986

A reanalysis of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds

New theoretical and experimental results have prompted a reinvestigation of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds. These results pertain principally but not exclusively to the reaction between HOC(+) and H2, which was previously calculated by DeFrees et al. (1984) to possess a large activation energy barrier. New calculations, reported here, indicate that this activation energy barrier is quite small and may well be zero. In addition, experimental results at higher energy and temperature indicate strongly that the reaction proceeds efficiently at interstellar temperatures. If HOC(+) does indeed react efficiently with H2 in interstellar clouds, the calculated HCO(+)/HOC(+) abundance ratio rises to a substantially greater value under standard dense cloud conditions than is deduced via the tentative observation of HOC(+) in Sgr B2.

Jarrold, M. F.↗
DOE OSTI2022

Accurate Fe–He machine learning potential for studying He effects in BCC-Fe

Nanostructured Ferritic Alloys (NFAs) containing oxide nanoparticles are prospective advanced structural materials in future fusion reactors. Lacking fusion neutron sources with an adequate flux, modeling is critical to understand radiation damage in the NFAs, including helium effects. Machine learning interatomic potentials (MLPs) have been demonstrated to be capable of describing atomic interactions in chemically complex systems with comparable accuracy to density functional theory (DFT) but with much less computational costs. Hence, MLPs are chosen to study He bubble accumulation in chemically complex NFAs. As a preliminary step, we develop a Fe–He potential, based on ~10,000 atomic configurations. The developed MLP accurately predicts the bulk properties of BCC-Fe compared to DFT, including the lattice constant (2.832 Å), elastic constants (c 11 = 271 GPa, c 12 = 141, c 44 = 93), and phonon frequencies (maximum error < 3.5%). The MLP predicts He binding energies in He n V bubbles and He n clusters with a mean absolute error (MAE) of only ~70 meV, which is ~3 to ~5 times smaller than the MAE of binding energies estimated using empirical potentials. The MLP also accurately predicts the migration barrier of interstitial He (64 meV). Furthermore, the MLP correctly predicts the maximum number of He atoms (critical size) at which a He n V bubble (He n cluster) can kick-out a self-interstitial atom (SIA), forming a bigger He n V 2 bubble (He n V bubble). Subsequently, we use the MLP to perform molecular dynamics simulations to investigate the effect of temperature on the critical size of He n V bubbles and He n clusters. We find that the critical size decreases with increasing temperature — indicating that smaller bubbles and clusters can kick-out an SIA at higher temperatures, thereby escalating the He bubble growth. We report the current Fe–He MLP can be further developed to include all chemical interactions in NFAs.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Effect of Melt-Spinning Parameters on the Structure and Properties of Ni 55.5 Mn 18.8 Ga 24 Si 1.7 Heusler Alloy Ribbons

Ni–Mn-based Heusler alloys are known to demonstrate magnetic shape memory and giant magnetocaloric effect (MCE). These effects depend on the phases, crystallographic and magnetic phase transitions, and the crystallographic texture characteristics. These structural characteristics, in turn, are a function of the processing parameters. In the current work, Ni 55.5 Mn 18.8 Ga 24 Si 1.7 Heusler alloy was processed by melt-spinning under a helium atmosphere. This process results in a fine microstructure. The ribbon that was produced with a narrower nozzle width, faster wheel speed, and higher cast temperature, indicating a faster cooling rate, had double the magnetic entropy change close to room temperature. However, the other ribbon demonstrated a large entropy change over a broader temperature range, extending its usability. The effect of the melt-spinning process parameters on the developing microstructure, crystallographic structure and texture, transformation temperatures, and the magnetic entropy change were studied to explain the difference in magnetocaloric behavior.

36 MATERIALS SCIENCE↗
NASA NTRS1976

Static force tests of a sharp leading edge delta-wing model at ambient and cryogenic temperatures with a description of the apparatus employed

A sharp leading edge delta-wing model was tested through an angle-of-attack range at Mach numbers of 0.75, 0.80, and 0.85 at both ambient and cryogenic temperatures in the Langley 1/3-meter transonic cryogenic tunnel. Total pressure was varied with total temperature in order to hold test Reynolds number constant at a given Mach number. Agreement between the aerodynamic data obtained at ambient and cryogenic temperatures indicates that flows with leading-edge vortex effects are duplicated properly at cryogenic temperatures. The test results demonstrate that accurate aerodynamic data can be obtained by using conventional force-testing techniques if suitable measures are taken to minimize temperature gradients across the balance and to keep the balance at ambient (warm) temperatures during cryogenic operation of the tunnel.

Kilgore, R. A.↗
NASA NTRS1987

Polyphase alloys as rechargeable electrodes in advanced battery systems

The rechargeability of electrochemical cells is often limited by negative electrode problems. These may include loss of capacity, increased impedance, macroscopic shape change, dendrite growth, or a tendency for filamentary or whisker growth. In principle, these problems can be reduced or eliminated by the use of alloys that undergo either displacement or insertion reactions at reactant species activities less than unity, rather than pure elements. The fundamental reasons for some of these problems with elemental electrodes, as well as the basic principles involved in the different behavior of alloys, are briefly discussed. More information is now available concerning the thermodynamic and kinetic properties of a number of alloys of potential interest for use as electrodes in elevated temperature lithium battery systems. Recent results have extended these results down to ambient temperatures, indicating that some such materials may be of interest for use with new low temperature molten salt electrolytes, or with organic solvent electrolytes. The all solid mixed conductor matrix concept is also reviewed.

Huggins, Robert A.↗
NASA NTRS1994

Method development for compensating temperature effects in pressure sensitive paint measurements

Pressure sensitive luminescent paints (PSP) have recently emerged as a viable technique for aerodynamic pressure measurements. The technique uses a surface coating which contains probe molecules that luminesce when excited by light of an appropriate wavelength. The photoluminescence of these materials is known to be quenched by the presence of molecular oxygen. Since oxygen is a fixed mole fraction of the air, the coating's luminescence intensity varies inversely with air pressure. Digital imaging of the luminescence varying across a coated surface produces a pressure distribution map over that surface. One difficulty encountered with this technique is the temperature effect on the luminescence intensity. Present PSP formulations have significant sensitivity to temperature. At the moment, the most practical way of correcting for temperature effects is to calibrate the paint in place at the operating temperatures by using a few well-placed pressure taps. This study is looking at development of temperature indicating coatings that can be applied and measured concurrently with PSP, and use the temperature measurement to compute the correct pressure. Two methods for this dual paint formulation are proposed. One method will use a coating that consists of temperature sensitive phosphors in a polymer matrix. This is similar in construction to PSP, except that the probe molecules used are selected primarily for their temperature sensitivity. Both organic phosphors (e.g., europium thenoyltrifluoroacetonate, bioprobes) and inorganic phosphors (e.g., Mg4(F)GeO6:Mn, La2O2S:Eu, Radelin Type phosphors, Sylvania Type phosphors) will be evaluated for their temperature sensing potential. The next method will involve a novel coating composing of five membered heterocyclic conducting polymers which are known to show temperature dependent luminescence (e.g., poly(3-alkylthiopene), poly(3-alkylselenophene), poly(3-alkylfuran)). Both methods will involve applying a bottom layer of temperature sensitive coating followed by a top coating of PSP. An oxygen-impermeable polymer can be used as the temperature sensitive coating matrix, or it can be layered in between the coatings to prevent oxygen quenching of the bottom coating's luminescence. The probe molecules of the coatings will be excited by a broad band of light, with the different emissions detected and measured at their distinct wavelengths. Developmental research of these coatings is still in progress; however, preliminary results look very promising.

Demandante, Carlo Greg N.↗
DOE OSTI2023

Analysis of Frost Prevention for Heat Recovery Ventilation in an Arctic Facility

Sub-Arctic environments present a unique challenge for the continuous operation of mechanical ventilation systems in occupied buildings where cold temperatures create complications for maintaining adequate air quality, efficiency, and system operability. Heat recovery ventilation is most difficult at the coldest temperatures, when there is the greatest availability to transfer heat between airstreams, due to the potential for frost accumulation in the exhaust airstream. Frost limits heat transfer and creates the potential for subsequent blockage of airflow. A successful frost prevention strategy is necessary to ensure that recovery ventilation systems function in locations with a large amount of annual heating degree days. Commonly, this is achieved by preheating outdoor air above freezing temperatures via airflow through a glycol-water mix hydronic coil before heat exchange occurs. Preheating the outdoor air proactively inhibits frost formation but is associated with a penalty to recovery efficiency. A commercial-scale heat recovery ventilator in a facility in Fairbanks, Alaska was analyzed for sensible recovery effectiveness and exhaust temperature at different winter conditions. The system utilized the common defrost strategy of preheating the air above-freezing with a static temperature control scheme. The heat transfer efficiency of the recovery ventilator was observed to be poor at various winter conditions with elevated exhaust temperatures indicating lost heat recovery effectiveness. Using prior findings on strategies for sub-freezing temperatures along with observed field conditions it was determined that a dynamic relationship between the coil and the exterior conditions would reduce the energy required to preheat the air and allow the heat exchanger to maximize effectiveness due to temperate difference. This reduction in preheated temperature of the air is achieved by modulating the temperature of the coil to keep the discharge air stream above a certain dewpoint temperature threshold, likely leading to energy savings for other sub-Arctic facilities using this frost control strategy.

ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION↗
NASA NTRS2013

Analysis of Saturn's Thermal Emission at 2.2-cm Wavelength: Spatial Distribution of Ammonia Vapor

This work focuses on determining the latitudinal structure of ammonia vapor in Saturn's cloud layer near 1.5 bars using the brightness temperature maps derived from the Cassini RADAR (Elachi et al., 2004) instrument, which works in a passive mode to measure thermal emission from Saturn at 2.2-cm wavelength. We perform an analysis of five brightness temperature maps that span epochs from 2005 to 2011, which are presented in a companion paper by Janssen et al. (2013a, this issue). The brightness temperature maps are representative of the spatial distribution of ammonia vapor, since ammonia gas is the only effective opacity source in Saturn's atmosphere at 2.2-cm wavelength. Relatively high brightness temperatures indicate relatively low ammonia relative humidity (RH), and vice versa. We compare the observed brightness temperatures to brightness temperatures computed using the Juno atmospheric microwave radiative transfer (JAMRT) program which includes both the means to calculate a tropospheric atmosphere model for Saturn and the means to carry out radiative transfer calculations at microwave frequencies. The reference atmosphere to which we compare has a 3x solar deep mixing ratio of ammonia (we use 1.352x10(exp -4) for the solar mixing ratio of ammonia vapor relative to H2; see Atreya, 2010) and is fully saturated above its cloud base. The maps are comprised of residual brightness temperatures-observed brightness temperature minus the model brightness temperature of the saturated atmosphere.

Atmospheres↗
DOE OSTI2021

Dislocation interactions in olivine control postseismic creep of the upper mantle

Changes in stress applied to mantle rocks, such as those imposed by earthquakes, commonly induce a period of transient creep, which is often modelled based on stress transfer among slip systems due to grain interactions. However, recent experiments have demonstrated that the accumulation of stresses among dislocations is the dominant cause of strain hardening in olivine at temperatures ≤600 °C, raising the question of whether the same process contributes to transient creep at higher temperatures. Here, we demonstrate that olivine samples deformed at 25 °C or 1150–1250 °C both preserve stress heterogeneities of ~1 GPa that are imparted by dislocations and have correlation lengths of ~1 μm. The similar stress distributions formed at these different temperatures indicate that accumulation of stresses among dislocations also provides a contribution to transient creep at high temperatures. The results motivate a new generation of models that capture these intragranular processes and may refine predictions of evolving mantle viscosity over the earthquake cycle.

58 GEOSCIENCES↗
DOE OSTI2024

Exploring the impact of Cr-doping on the crystallographic and magnetic structure of Mn 5 Si 3 antiferromagnetic alloy

Here, the role of Cr-doping on the structural and magnetic ground states of Mn 5 Si 3 alloy has been investigated through temperature-dependent neutron powder diffraction (NPD) and X-ray absorption fine structure (XAFS) techniques. All the Cr-doped alloys of nominal composition Mn 5-x Cr x Si 3 (for x = 0.05, 0.1, and 0.2) undergo two first-order magneto-structural phase transitions from hexagonal (space group: P6 3 /mcm) paramagnetic → orthorhombic (space group: Ccmm) collinear antiferromagnetic → orthorhombic (space group: Cc2m) non-collinear antiferromagnetic phase on cooling from room temperature. NPD studies at different constant temperatures indicate that both anti ferromagnetic phases are commensurate in nature and can be represented by q = (0,1,0) magnetic propagation vector for all the Cr-doped alloys. Such doping at the Mn-site results in a significant modification of the non-collinear antiferromagnetic structure (both moment size and orientation) and hence affects the unusual magnetic properties, like inverted hysteresis loop, thermomagnetic irreversibility, etc. The XAFS measurements were performed to interpret the local environment of doped Cr atoms in detail, which is critical for a microscopic understanding of the unusual properties of this class of Cr-doped Mn 5 Si 3 alloys. The analysis confirms the elemental state of Cr in the doped alloys and indicates a high degree of preservation of local crystallographic structure with varying Cr concentration and sample temperature. Doping induces intriguing changes in XAFS patterns, elucidated through different types of scattering mechanisms associated with the central absorbing Cr atom.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Thermal transport properties of IrSbSe

Here we report a thermal transport study of IrSbSe, which crystallizes in a noncentrosymmetric cubic structure with the P2 1 3 space group and shows a narrow-gap semiconducting behavior. The large discrepancy between the activation energy for conductivity [E ρ = 128(2) meV] and for thermopower [E S = 17.7 (9) meV] from 200 to 300 K indicates a polaronic transport mechanism. The electrical resistivity varies as exp (T 0 /T) 1/4 and thermopower varies as T 1/2 at low temperatures, indicating that it evolves into Mott variable-range hopping dominant conduction with decreasing temperature. IrSbSe shows a relatively low value of thermal conductivity (~1.65 W/Km) and thermopower of about 0.24 mV/K around 100 K, yet poor electrical conductivity. On the other hand, a high vacancy defect concentration on both Ir and Sb atomic sites of up to 15% suggests a high defect tolerance and points to the possibility of a future improvement of carrier density by chemical substitution or defect optimization.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1961

Experimental Investigation of an Air-Cooled Turbine Operating in a Turbojet Engine at Turbine Inlet Temperatures up to 2500 F

An experimental investigation was made of an air-cooled turbine at average turbine inlet temperatures up to 2500 F. A modified production-model 12-stage axial-flow-compressor turbojet engine operating in a static sea-level stand was used as the test vehicle. The modifications to the engine consisted of the substitution of special combustor and turbine assemblies and double-walled exhaust ducting for the standard parts of the engine. All of these special parts were air-cooled to withstand the high operating temperatures of the investigation. The air-cooled turbine stator and rotor blades were of the corrugated-insert type. Leading-edge tip caps were installed on the rotor blades to improve leading-edge cooling by diverting the discharge of coolant to regions of lower gas pressure toward the trailing edge of the blade tip. Caps varying in length from 0.15- to 0.55-chord length were used in an attempt to determine the optimum cap length for this blade. The engine was operated over a range of average turbine inlet temperatures from about 1600 to about 2500 F, and a range of average coolant-flow ratios of 0.012 to 0.065. Temperatures of the air-cooled turbine rotor blades were measured at all test conditions by the use of thermocouples and temperature-indicating paints. The results of the investigation indicated that this type of blade is feasible for operation in turbojet engines at the average turbine inlet temperatures and stress levels tested(maximums of 2500 F and 24,000 psi, respectively). An average one-third-span blade temperature of 1300 F could be maintained on 0.35-chord tip cap blades with an average coolant-flow ratio of about 0.022 when the average turbine inlet temperature was 2500 F and cooling-air temperature was about 260 F. All of the leading-edge tip cap lengths improved the cooling of the leading-edge region of the blades, particularly at low average coolant-flow ratios. At high gas temperatures, such parts as the turbine stator and the combustor liners are likely to be as critical as the turbine rotor blades.

Cochran, Reeves P.↗
NASA NTRS1973

Electrical properties of dry rocks

The mechanism by which atmospheric moisture affects the conductivity and dielectric constant of rock specimens was studied in time and frequency domains. It is suggested that adsorbed water molecules alter the surface conductivity in a manner similar to that observed in semiconductors and insulators. Powdered basalts show a low-frequency dispersion produced by the atmospheric moisture remaining in the pore system of the sample in a high vacuum; this effect is attributed to isolated adsorption centers. Simulated lunar permafrost at 100 K and a vacuum of 10 to the -8th power torr together with data on lunar samples contaminated with atmospheric moisture and the dielectric properties of ice at various temperatures indicate that, if permafrost exists in the moon it should present a relaxation peak at approximately 300 Hz; for temperatures up to 263 K it may go up to 20 KHz. It is concluded that in order to have electrical steady state conditions in rock samples it is necessary to have volume charge accumulations at interfaces within the sample and at the electrode sample interface. A method for measuring heterogeneous dielectrics with non-negligible ohmic and dielectric conductivities is proposed and experimentally verified.

Morrison, H.↗
NASA NTRS2008

Temperatures and Composition in the Saturn System from Cassini CIRS

We summarize recent observations by the Composite Infrared Spectrometer of Saturn, its rings, Titan, and the icy satellites. Limb observations of Saturn show vertical oscillations of temperatures and zonal-wind shears in the equatorial region that may be related to a temporal oscillation similar to the terrestrial QBO and Jupiter's QQO. There is also evidence of subsidence at mid-northern latitudes driven by the equatorial activity. Nadir-viewing observations show compact warm spots in the troposphere and stratosphere at both (summer and winter) poles, likely associated with subsidence. Observations of Titan have defined better the characteristics of the northern winter polar vortex, with 190 m/s winds surrounding a cold atmosphere at 1 microbar. The very warm polar stratopause at 10 microbar and the enhanced abundances of organic compounds suggest subsidence within the vortex. Analysis of the zonal structure in temperature indicates that the stratospheric zonal winds rotate about an axis that is displaced approximately 4.1 deg from the IAU pole. Additional flybys, including a close one in March 2008, continue to characterize the endogenic activity in Enceladus s south polar region. Temperature maps of bright and dark terrains on Iapetus indicate that its ice is approximately stable to sublimation in the bright regions and highly unstable in the dark regions. Thermal mapping of Saturn s rings continues to constrain their composition, and observations at different solar phase angles, spacecraft elevations, solar elevations, and local hour angles have elucidated the effects of ring-particle shadowing and vertical motions on the thermal structure, and revealed the presence of small-scale structure associated with self-gravity wakes.

Flasar, F. Michael↗
NASA NTRS1982

Application of a gripping system to test a uniaxial graphite fiber reinforced composite /PMR 15/Celion 6000/ in tension at 316 C

A gripping system has been developed to test uniaxial, 0 deg orientation PMR 15/Celion 6000 composites at elevated temperatures. The method involves compression of grit-blasted laminate between grit-blasted metal to give a non-slipping interface for load transfer. Tensile testing at both 316 C and room temperature indicated that deformation was elastic to fracture and that the variation in tensile properties for one laminate is the same as that for several panels. In addition, the tensile properties for uniaxial PMR 15/Celion 6000 are identical at 316 C and room temperature. For nominally 51 volume percent fiber, the elastic modulus is 119.6 GPa, the fracture stress is 1370 MPa, and the strain to fracture is about 1.15 percent. In addition, data are presented which indicate that the gripping system can be used for long term, elevated temperature testing of composite materials.

Whittenberger, J. D.↗