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DOE OSTI2014

Assessment of the Cast Stone Low-Temperature Waste Form Technology Coupled with Technetium Removal - 14379

The U.S. Department of Energy Office of Environmental Management (EM) is engaging the national laboratories to provide the scientific and technological rigor to support EM program and project planning, technology development and deployment, project execution, and assessment of program outcomes. As an early demonstration of this new responsibility, Pacific Northwest National Laboratory (PNNL) and Savannah River National Laboratory (SRNL) were chartered to implement a science and technology program addressing low-temperature waste forms for immobilization of DOE aqueous waste streams, including technetium removal as an implementing technology. As a first step, the laboratories examined the technical risks and uncertainties associated with the Cast Stone waste immobilization and technetium removal projects at Hanford. Science and technology gaps were identified for work associated with 1) conducting performance assessments and risk assessments of waste form and disposal system performance, and 2) technetium chemistry in tank wastes and separation of technetium from waste processing streams. Technical approaches to address the science and technology gaps were identified and an initial sequencing priority was suggested. A subset of research was initiated in 2013 to begin addressing the most significant science and technology gaps. The purpose of this paper is to report progress made towards closing these gaps and provide notable highlights of results achieved to date.

Cast Stone Low-Temperature Waste Form Technology C↗

DOE OSTI2019

250 kWth Pilot Testing in Support of a 10 MWe Coal-Direct Chemical Looping Demonstration Feasibility Study

The Coal-Direct Chemical Looping (CDCL) process is emerging as a promising technology capable of high efficiency for producing electricity with low cost for carbon capture. In the CDCL process, coal is fully combusted to form carbon dioxide (CO2) and water via reaction with Fe2O3-based oxygen-carrier particles in a moving-bed reducer reactor. During reaction with coal, the Fe2O3 is reduced to form a mixture of Fe and FeO. The reduced particles are then transported to the combustor reactor where they are re-oxidized with air. The oxidation of the Fe and FeO mixture generates heat that can be used to produce steam for power generation. Once the particles are fully regenerated, they are pneumatically recycled to the reducer reactor where another reduction-oxidation (Redox) cycle begins. The Babcock & Wilcox Company (B&W) and The Ohio State University (OSU) have been developing the CDCL technology based on iron-based metal oxide particles circulating in a moving-bed reducer coupled with an entrained-flow combustor. As part of a Phase I effort of a DOE-sponsored project, B&W identified scale-up technology gaps for the coal-direct chemical looping reactor process, most of which fall under the moving-bed reactor design and operation. However, after the Phase I research, B&W concluded that the CDCL technology has the potential of generating electricity while meeting the DOE goals of greater than 90% CO2 capture and less than 35% increase in levelized cost of electricity (LCOE). B&W then moved to a Phase II project to design, build and demonstrate the CDCL technology at a 250 kWth capacity. B&W finished the construction and commissioning of the pilot test facility in 2017. The approach used to design a 250 kWth pilot-scale CDCL facility to investigate the technology gaps is presented. Important lessons from the commissioning activities that would transfer to commercial plant start-up are also shared. The findings from the test program are being incorporated into a Pre-FEED study for a 10 MWe large pilot demonstration. Under a separately-funded heat integration project, B&W and OSU are developing a multiphase computational fluid dynamic model (MFIX) of the combustor to quantify heat transfer to embedded steam generation surface, utilizing pinch analysis (ASPEN Energy Analyzer) to identify potential improvements of the heat integration scheme, and developing an integrated dynamic model (ProTRAX) of the steam turbine coupled with the chemical looping process to identify potential start-up and transient operation issues. Under an advanced control system for optimizing operation, B&W is supporting OSU to install a rules-based optimizer (B&W’s FocalPoint) on their 25 kWt bench-scale facility on the OSU West Campus. Finally, B&W and OSU were recently selected to perform a Phase I Feasibility study to evaluate installation of the 10 MWe pilot at the Dover Power & Light Municipal Power Plant in Dover, Ohio. The feasibility study includes compiling an Environmental Information Volume and generating a cost estimate for the design, construction and commissioning of the plant as well as lining up commitments from potential project participants and funding contributors. Updates on each project will be presented. The status of the technology development will be discussed. We focus on the progress made to date towards closing the technology gaps under each project.

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2018

Update on Design of 10 MWe Iron-Based Coal Direct Chemical Looping Demonstration Plant

20 FOSSIL-FUELED POWER PLANTS↗

NASA NTRS2015

Physics of the Cosmos Program Annual Technology Report

What's in this Report? What's New? This fifth Program Annual Technology Report (PATR) summarizes the Programs technology development activities for fiscal year (FY) 2015. The PATR serves four purposes.1. Summarize the technology gaps identified by the astrophysics community;2. Present the results of this years technology gap prioritization by the PCOS Technology Management Board (TMB);3. Report on newly funded PCOS Strategic Astrophysics Technology (SAT) projects; and4. Detail progress, current status, and activities planned for the coming year for all technologies supported by PCOS Supporting Research and Technology (SRT) funding in FY 2015. .

PCOS↗

DOE OSTI2013

Preliminary Assessment of the Hanford Tank Waste Feed Acceptance and Product Qualification Programs

The U.S. Department of Energy Office of Environmental Management (EM) is engaging the national laboratories to provide the scientific and technological rigor to support EM program and project planning, technology development and deployment, project execution, and assessment of program outcomes. As an early demonstration of this new responsibility, Savannah River National Laboratory (SRNL) and Pacific Northwest National Laboratory (PNNL) have been chartered to implement a science and technology program addressing Hanford Tank waste feed acceptance and product qualification. As a first step, the laboratories examined the technical risks and uncertainties associated with the planned waste feed acceptance and qualification testing for Hanford tank wastes. Science and technology gaps were identified for work associated with 1) feed criteria development with emphasis on identifying the feed properties and the process requirements, 2) the Tank Waste Treatment and Immobilization Plant (WTP) process qualification program, and 3) the WTP HLW glass product qualification program. Opportunities for streamlining the accetpance and qualification programs were also considered in the gap assessment. Technical approaches to address the science and technology gaps and/or implement the opportunities were identified. These approaches will be further refined and developed as strong integrated teams of researchers from national laboratories, contractors, industry, and academia are brought together to provide the best science and technology solutions. Pursuing the identified approaches will have immediate and long-term benefits to DOE in reducing risks and uncertainties associated with tank waste removal and preparation, transfers from the tank farm to the WTP, processing within the WTP Pretreatment Facility, and in producing qualified HLW glass products. Additionally, implementation of the identified opportunities provides the potential for long-term cost savings given the anticipated facility life of WTP.

HLW glass product qualification↗

DOE OSTI2024

Consortium to Assess Northern Appalachian Resource Yield (CANARY) of CORE-CM for Advanced Materials

The Consortium to Assess Northern Appalachian Resource Yield (CANARY) of CORE-CM for Advanced Materials is conducted by Penn State and its partners. The objectives of the project are to 1) assess and catalog Northern Appalachian (NA) basin CORE-CM resources and waste streams, 2) develop strategies to recover CORE-CM from these streams, 3) assess the infrastructure, industries, and businesses in the NA basin to determine CORE-CM supply chain gaps, 4) review technology gaps related to CORE-CM production, 5) formulate plans to establish Technology Innovation Centers, and 6) develop stakeholder outreach and engagement in educational activities. This final report documents the work conducted throughout the project.

99 GENERAL AND MISCELLANEOUS↗

NASA NTRS2024

Exploration Systems Development Mission Directorate: Moon to Mars Architecture Definition Document

The National Aeronautics and Space Administration (NASA) explores the unknown in air and space, innovates for the benefit of humanity, and inspires the world through discovery. Extending the reach of humanity through the human exploration of the Moon, Mars, and beyond is key to that mission. NASA’s Moon to Mars Strategy and Objectives document establishes long-term goals and objectives for crewed deep space exploration; however, satisfying NASA’s Moon to Mars Objectives requires an innovative approach to the definition, management, and execution of NASA’s Moon to Mars Architecture. An architecture offers a high-level unifying structure and defines a system. It provides rules, guidelines, and constraints that define a cohesive and coherent framework that identifies constituent parts, relationships, and connections and establishes how those parts fit and work together. This Architecture Definition Document (ADD) establishes the process for the decomposition of objectives empowers the agency’s success in achieving human exploration of the cosmos. NASA updates this document annually to reflect the maturation of the architecture and the progress NASA and partners make toward achieving exploration objectives. The ADD is not a manifest or requirements document. Instead, it serves as a tool for the programs, projects, and engineers who will implement and execute NASA’s bold ambitions for crewed exploration of deep space. As established in the Moon to Mars Strategy and Objectives, “Why” we explore encompasses three pillars: Science, Inspiration, and National Posture. Ensuring success in all three areas requires an architectural approach that incorporates innovation, collaboration, and partnerships that can be sustained across a multi-decadal effort. This second revision (Rev-B) of the ADD, developed to support NASA’s 2024 Architecture Concept Review (ACR), incorporates several key updates to support the continued evolution of the architecture. Since the last revision of the ADD, NASA has significantly improved the clarity of the objective decomposition, which distills exploration objectives into the characteristics and needs and use cases and functions needed to achieve them. The updated decomposition incorporates findings from internal studies and diverse stakeholder feedback. A model-based systems engineering approach ensures coherence and consistency, removing inconsistency and repetition. Revision B also incorporates advancements to NASA’s Mars architecture, including insight into initial capabilities, systems, and operations necessary to support the Humans to Mars segment. Updates to objective decomposition for Mars add significant detail to the ADD and hint at areas of forward work and future study. An appendix adds greater depth in the future decisions needed for Mars that will drive lunar needs. They are not the only decisions to be made, but they will have huge effects on subsequent decisions. NASA continues to introduce new exploration systems into the architecture. Two new elements — initial surface habitat and lunar surface cargo lander—successfully passed mission concept review in 2024 as a result of extensive analysis, concept refinement, and studies. These elements and their respective reference missions appear in this revision. NASA also continues to apply architecture processes to cross-agency efforts and coordination with external stakeholders by including definitions of architecture technology gaps — essential areas for engagement across and beyond the agency. The technology gaps appendix identifies areas that need attention and innovation to enable future exploration. In publishing this information, NASA communicates the technologies and capabilities that may benefit from partnership with industry, academia, other U.S. government agencies, and international space agencies. Ultimately, NASA established the Moon to Mars Architecture approach to communicate and facilitate humanity’s journey into the universe according to the principles and recurring tenets of NASA’s Moon to Mars Strategy and Objectives. The NASA architecture team thanks their many stakeholders, participants, and partners for their efforts to review and provide feedback. Their support has been critical to the success of this approach.

Elements↗

DOE OSTI2022

Liquid Salt Combined-Cycle Pilot Plant Design

The work described in this report is responsive to the Office of Fossil Energy program ‘Energy Storage for Fossil Power Generation.’ This Phase I report has been prepared by Pintail Power LLC, with support from Nexant ECA, Electric Power Research Institute (EPRI) and Southern Company Services as a deliverable for the U.S. Department of Energy for NETL Award DE-FE-00320016. The Liquid Salt Combined Cycle™ (LSCC™) technology provides large-scale energy storage integrated with Fossil Electric Generating Units (FEGUs) to meet critical needs in the energy transition by providing: • the lowest cost large-scale storage for time-shifting of renewable energy, • superior fuel efficiency to reduce GHGs from dispatchable resources, • flexible capacity and ramping to balance variability of wind and solar resources, • essential grid stability services to assure reliability of a low-carbon grid. The LSCC approach: • employs equipment that has already been proven in utility service, • uses safe, non-toxic, non-degrading, perpetual-life storage medium, • leverages and repurposes existing FEGU assets, • expands the value stack of energy storage to reduce market, financing, and commodity risks. Pintail Power has developed the LSCC technology to meet the need for reliable, efficient, and cost-effective integration of Variable Renewable Energy (VRE) into a low-carbon electric grid by coupling proven thermal energy storage with proven gas turbines, steam turbines, and heat transfer equipment. This novel approach is intended to address the key issues facing the grid and operators of renewable and fossil generating units including: • Overgeneration and curtailment of renewables, • Need for fast ramping dispatchable resources, • Improved efficiency and flexibility of fossil units, • Additional peaking capacity to support electrification of transportation and heating, • Provision of reliability services to support high penetration of VRE, especially synchronous inertia and fast frequency response. A Technology Readiness assessment by EPRI confirmed that LSCC technology consists of commercially proven hardware used in industrial and utility applications. Although the novel LSCC approach has not yet been demonstrated as a complete system, interfaces between major components have been conservatively specified. A Phase III pilot is planned to demonstrate equipment integration and operation. The patented innovation is removal of the evaporator section from the exhaust heat recovery system, with the evaporation performed by stored energy in a separate steam generator. This arrangement couples renewable and fossil power generation via long-duration energy storage to deliver cost, performance, and operational synergies, including superior charging and discharging flexibility, reduced fuel consumption and lower CO 2 emissions compared to conventional Combined Cycle Power Plants, and low-cost, large-scale energy storage. The LSCC technology is composed of proven equipment integrated with gas turbine exhaust heat in a novel system. During charging, electric heaters raise the salt temperature as it flows from the Cold Salt Tank to the Hot Salt Tank. During discharging, hot salt produces steam from feedwater that is heated with gas turbine exhaust, which also superheats steam to drive a steam turbine. LSCC technology can be added to any combustion-turbine to integrate renewable energy, provide needed grid services, and increase the value of fossil electric generating units based on the technology’s following attributes: • Long-duration storage enables time-shifting of VRE to avoid curtailment and impairment of renewable assets. • Long storage duration combined with fast-charging capability increases arbitrage opportunities by storing more energy when the price is low and discharging more hours when the price is high. • Long storage duration allows resource adequacy to be supplied across multiple days to increase reliability and reduce risk. • The stored energy reduces fuel heat rate and GHG emissions, and increases merit, so the LSCC dispatches earlier and longer to increase the plant’s capacity factor and asset value. • The stored energy enables pre-heating and startup of the steam cycle, without operating the gas turbine, to enable fast startup and ramping when dispatched for discharge. • The steam turbine can operate without the gas turbine so it can provide valuable synchronous inertia during charging without consuming fuel. • Fast frequency response and regulation services can be provided during charging using solid-state heater and pump controls to vary the charge power input in response to grid signals. • The LSCC system can be configured for resilience including black start, islanded/micro-grid operation, and even self-recharging of storage using either gas turbine power or gas turbine exhaust heat. The commercialization plan is to add LSCC technology to existing simple cycle gas turbine power plants with the 50MW GE LM6000 aero-derivative gas turbine as the reference design basis. A Techno-economic assessment of the reference design evaluated the benefits (Levelized Avoided Cost of Energy) and costs (Levelized Cost of Energy). The plant definition included all major systems and budgetary vendor quotes. Pintail Power and NexantECA developed the overall cost estimate for the LSCC plant up to the total plant cost level, following the DOE-NETL cost estimate guidelines at AACE Class 3 (-20%/+30%). This includes the equipment cost, bulk material, direct and indirect labor costs to arrive at the bare erected cost. Engineering costs are factored from the BEC and added to it to arrive at the EPC cost. Process and project contingencies were then factored from the EPC cost and rolled-up to yield the total plant cost of $\$$184 million for 1746 MWh of discharge electricity. • At $\$$105/kWh, the reference plant costs less than any of the Energy Storage Systems evaluated by PNNL in 2020 for the Energy Storage Grand Challenge. Operations and Maintenance cost estimates were scaled from combined cycle practice, assuming that the LSCC unit was co-located with and sharing some labor expense with other units, to arrive at $\$$2.2 million per year. Plant economics were evaluated using prices from the ERCOT Day-Ahead Market for calendar year 2019 (excluding the market disruptions from the COVID pandemic and the February 2020 deep freeze event). Assuming economic dispatch in the ERCOT Day-Ahead market, the reference plant capacity factor would have discharged for 2777 hours at 91.9 MW, a 31.66% capacity factor, with a marginal cost of $\$$25.59/MWh, and a LACE of $\$$82.41/MWh. Fixed charges were calculated according to EIA guidelines to arrive at an LCOE of $\$$83.48. The benefit-to-cost ratio of 0.99 suggests that the reference plant would have been cost-effective and competitive in the market. EPRI interviewed selected utilities to gauge the need for, applicability of and interest in the LSCC system. Several utilities are currently managing increased load growth along with the inclusion of increasing levels of renewable generation, putting pressure on conventional generation by requiring increased turndown requirements and ultimately lower capacity factors. All of the utilities interviewed have CO 2 reduction targets in the 2030-2050 timeframe that will severely limit the participation of fossil generation and require better utilization of carbon free generation. While there is limited opportunity for storage in the current markets, the utilities interviewed stated that there will be a substantial need for long duration energy storage in the future given the expected trends. Utilizing an energy storage system will generally be preferred over new gas capacity in some cases, with the capabilities of the LSCC system being a potential option for retrofit to existing simple cycle gas turbine units, allowing them to deliver greater participation in the market with lower carbon intensity. A technology gap assessment and technology maturation plan identified a pilot-scale demonstration as the final step before commercialization. Key gaps to be addressed during the Phase II FEED (Front-End Engineering Design) are component selection and design, commissioning procedures, and operational procedures and the control system for LSCC charging and discharging. The project team has been expanded to include Wood Group PLC as EPC. The proposed Phase II work leads to a pilot-scale engineering demonstration (TRL 6) to be conducted at Southern Company’s Plant Rowan, where the prototype system will perform “all the functions that will be required of the operational system.” The proposed pilot will facilitate commercialization (TRL-9) by scale-up to utility-scale systems integrated with peaking GTs or directly to facility scale systems using industrial GTs. The conceptual design for the pilot plant focuses on the novel integration aspects of LSCC technology. A slipstream of gas turbine exhaust will feed a waste heat recovery unit coupled to a molten salt steam generator heated by stored energy. The pilot is intended to demonstrate all key operating modes of the LSCC technology during charging, discharging and standby. The pilot equipment will be approximately one-seventh scale of the LM6000 commercial target and is expected to have commercial off-ramp potential for facility-scale applications.

01 COAL, LIGNITE, AND PEAT↗

DOE OSTI2024

NSTX-U – A national User Facility to close the key fusion gaps

This presentation lays out how the NSTX-U Research Program will help close the science and technology gaps for moving towards a Fusion Pilot Plant (FPP) and how this work is aligned with the Bold Decadal Vision. The science gap focuses on determining whether the good confinement trends in Spherical Tokamaks extends to lower collisionalities that are comparable to those expected in FPPs. The technology gap is one of mitigating the power exhaust in FPPs, and NSTX-U is uniquely positioned to test Liquid Metal components in the highest heat flux environment of any existing tokamak, spherical or otherwise.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2012

Advanced Gasification (Annual Report)

The Advanced Gasification team is addressing many factors that impact the current and future development and deployment of gasification-based power generation. For example, the service life of gasifiers does not meet the performance needs of users, failing to achieve an online gasifier availability of 85-95 percent in utility applications and 95 percent in applications such as chemical production. The inability to meet these goals has created a potential roadblock to widespread acceptance and commercialization of advanced gasification technologies, with refractory liners, sensors, and syngas coolers among key components identified as negatively impacting gasifier availability. Ash originating from impurities in gasifier carbon feedstock is the root cause of many problems; attacking or fouling components, leading to their unplanned shutdowns for repair, replacement, or cleaning. Technology gaps exist in the understanding of how fuel properties impact carbon conversion, slag viscosity, and downstream fouling. Fuel flexibility has potential advantages for gasifier operators to lower fuel cost or impact future carbon emission credits, but operators need to know how feedstock changes impact gasifier operation. Mixed feedstock combinations have not been studied as to how ash properties impact gasifier operation, efficiency, and capacity factors. Further gaps exist in technology which specifically target reducing the cost of multiple and mixed feed stocks at 90 percent capture, including low-rank coal (half the U.S. coal supply) and affordable gas clean-up technology.

Additives↗

DOE OSTI2023

Oak Ridge National Laboratory Security by Design: A Plant Design and Component-Based Approach to Technical Solutions to Insider and Outsider Threat

Security costs for nuclear reactors have been shown to rise over the lifecycle of a nuclear facility as new threats, security weaknesses, and the generic threat profile of the plant location change over time. This paper conducts a review of the technological gaps that currently exist in Security by Design (SeBD) based on the literature available and attempts to close those gaps through proposing technological constructs and processes that can integrate safety and security in the design process of a plant, with a primary focus on SMR technology. Under the new modular and mass manufacturing regime, where plant designs attempt to reduce costs with potential economies of scale and modular construction, the current SeBD definitions focusing on state level regulators are not considered adequate since the licensing stage is often too late in the design process to integrate the true cost savings of SeBD. Thus, this paper attempts to remedy the current logic in order to allow for continuous implementation of security alongside the development of the safety concept for the plant. If adopted within the design process the establishment of this type of technology will allow for a technological ecosystem to evolve that will imbed security concepts into the physical design of the components of the plant.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

NASA NTRS2017

Cryogenic Fluid Management Technology Development Roadmaps

Advancement in Cryogenic Fluid Management (CFM) Technologies is essential for achieving NASA's future long duration missions. Propulsion systems utilizing cryogens are necessary to achieve mission success. Current State Of the Art (SOA) CFM technologies enable cryogenic propellants to be stored for several hours. However, some envisioned mission architectures require cryogens to be stored for two years or longer. The fundamental roles of CFM technologies are long term storage of cryogens, propellant tank pressure control and propellant delivery. In the presence of heat, the cryogens will "boil-off" over time resulting in excessive pressure buildup, off-nominal propellant conditions, and propellant loss. To achieve long term storage and tank pressure control, the CFM elements will intercept and/or remove any heat from the propulsion system. All functions are required to perform both with and without the presence of a gravitational field. Which CFM technologies are required is a function of the cryogens used, mission architecture, vehicle design and propellant tank size. To enable NASA's crewed mission to the Martian surface, a total of seventeen CFM technologies have been identified to support an In-Space Stage and a Lander/Ascent Vehicle. Recognizing that FY2020 includes a Decision Point regarding the In-Space Stage Architecture, a set of CFM Technology Development Roadmaps have been created identifying the current Technology Readiness Level (TRL) of each element, current technology "gaps", and existing technology development efforts. The roadmaps include a methodical approach and schedule to achieve a flight demonstration in FY2023, hence maturing CFM technologies to TRL 7 for infusion into the In-Space Stage Preliminary Design.

Stephens, J. R.↗

NASA NTRS2018

Summary of 2017 NASA Workshop on Assessment of Advanced Battery Technologies for Aerospace Applications

A workshop on assessment of battery technologies for future aerospace applications was held in Cleveland, OH on August 16-17. The focus of the workshop, hosted by NASA GRC, was to assess (1) the battery needs for future aerospace missions, (2) the state of battery technology and projected technology advances, and (3) the need for additional investments for future aerospace missions. The workshop had 109 attendees that included internationally recognized technology leaders from academia and national laboratories, high level executives from government and industry, small businesses, and startup companies. A significant portion of the workshop was focused on batteries for electrified aircraft. The presentation will summarize the finding on the state of battery technologies for electrified aircraft and will include assessment of current state of battery technology, gaps in battery technology for application in electrified aircraft, and recommended technology development options for meeting near-term and long-term needs of electrified aircraft.

Misra, Ajay↗

NASA NTRS2018

NASA's Cryogenic Fluid Management Technology Development Roadmaps

The maturation of Cryogenic Fluid Management (CFM) Technologies is essential for achieving NASA's future long duration missions. Propulsion systems utilizing cryogens are necessary to achieve NASA's exploration missions to the moon, Mars, and beyond. Current State Of the Art (SOA) CFM technologies enable cryogenic propellants to be stored for several hours prior to their use. However, some envisioned mission architectures require that cryogens to be stored for two years or longer. The fundamental roles of CFM technologies are long term storage of cryogens, propellant tank pressure control and propellant delivery. In the presence of heat, the cryogens will "boil-off" over time resulting in excessive pressure buildup, off-nominal propellant conditions for engine consumption, and propellant loss. To achieve long term storage and tank pressure control, the CFM elements will intercept and/or remove any heat from the propulsion system. All functions are required to be performed both with and without the presence of a gravitational field. Which CFM technologies are required is a function of the cryogens used, mission architecture, vehicle design and propellant tank size. To enable NASA's crewed missions beyond Low Earth Orbit, a total of twenty-seven CFM technologies have been identified to support various In-Space Stages and Lander/Ascent Vehicles. A set of CFM Technology Development Roadmaps have been created identifying the current Technology Readiness Level (TRL) of each element, current technology "gaps", and existing technology development efforts. The roadmaps include a methodical approach and schedule to achieve a flight demonstration, hence maturing CFM technologies to TRL 6/7 for infusion into the NASA's exploration elements. Additionally, a survey of the aerospace industry was completed to understand their views on the various technologies and how they would be infused. This does not cover all possible technologies, but rather those that are of interest to NASA specifically.

Cryogenic fluid management↗

DOE OSTI2015

High Temperature Transducers for Online Monitoring of Microstructure Evolution

A critical technology gap exists relative to online condition monitoring (CM) of advanced nuclear plant components for damage accumulation; there are not capable sensors and infrastructure available for the high temperature environment. The sensory system, monitoring methodology, data acquisition, and damage characterization algorithm that comprise a CM system are investigated here. Thus this work supports the DOE mission to develop a fundamental understanding of advanced sensors to improve physical measurement accuracy and reduce uncertainty. The research involves a concept viability assessment, a detailed technology gap analysis, and a technology development roadmap.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

DOE OSTI2013

U.S. Department Of Energy Advanced Small Modular Reactor R&D Program: Instrumentation, Controls, and Human-Machine Interface (ICHMI) Pathway

Instrumentation, controls, and human-machine interfaces (ICHMI) are essential enabling technologies that strongly influence nuclear power plant performance and operational costs. The nuclear power industry is currently engaged in a transition from traditional analog-based instrumentation, controls, and human-machine interface systems to implementations employing digital technologies. This transition has primarily occurred in an ad hoc fashion through individual system upgrades at existing plants and has been constrained by licenseability concerns. Although the recent progress in constructing new plants has spurred design of more fully digital plant-wide ICHMI systems, the experience base in the nuclear power application domain is limited. Additionally, development of advanced reactor concepts, such as Generation IV designs and small modular reactors, introduces different plant conditions (e.g., higher temperatures, different coolants, etc.) and unique plant configurations (e.g., multiunit plants with shared systems, balance of plant architectures with reconfigurable co-generation options) that increase the need for enhanced ICHMI capabilities to fully achieve industry goals related to economic competitiveness, safety and reliability, sustainability, and proliferation resistance and physical protection. As a result, significant challenges remain to be addressed to enable the nuclear power industry to complete the transition to safe and comprehensive use of modern ICHMI technology. The U.S. Department of Energy (DOE) has recognized that ICHMI research, development, and demonstration (RD&D) is needed to resolve the technical challenges that may compromise the effective and efficient utilization of modern ICHMI technology and consequently inhibit realization of the benefits offered by expanded utilization of nuclear power. Consequently, several DOE programs have substantial ICHMI RD&D elements within their respective research portfolios. This paper describes current ICHMI research in support of advanced small modular reactors. The objectives that can be achieved through execution of the defined RD&D are to provide optimal technical solutions to critical ICHMI issues, resolve technology gaps arising from the unique measurement and control characteristics of advanced reactor concepts, provide demonstration of needed technologies and methodologies in the nuclear power application domain, mature emerging technologies to facilitate commercialization, and establish necessary technical evidence and application experience to enable timely and predictable licensing. 1 Introduction Instrumentation, controls, and human-machine interfaces are essential enabling technologies that strongly influence nuclear power plant performance and operational costs. The nuclear power industry is currently engaged in a transition from traditional analog-based instrumentation, controls, and human-machine interface (ICHMI) systems to implementations employing digital technologies. This transition has primarily occurred in an ad hoc fashion through individual system upgrades at existing plants and has been constrained by licenseability concerns. Although the recent progress in constructing new plants has spurred design of more fully digital plant-wide ICHMI systems, the experience base in the nuclear power application domain is limited. Additionally, development of advanced reactor concepts, such as Generation IV designs and small modular reactors, introduces different plant conditions (e.g., higher temperatures, different coolants, etc.) and unique plant configurations (e.g., multiunit plants with shared systems, balance of plant architectures with reconfigurable co-generation options) that increase the need for enhanced ICHMI capabilities to fully achieve industry goals related to economic competitiveness, safety and reliability, sustainability, and proliferation resistance and physical protection. As a result, significant challenges remain to be addressed to enable the nuclear power industry to complete the transition to safe and comprehensive use of modern ICHMI technology. The U.S. Department of Energy (DOE) has recognized that ICHMI research, development, and demonstration (RD&D) is needed to resolve the technical challenges that may compromise the effective and efficient utilization of modern ICHMI technology and consequently inhibit realization of the benefits offered by expanded utilization of nuclear power. Consequently, several DOE programs have substantial ICHMI RD&D elements to their respective research portfolio. The objectives that can be achieved through execution of the defined RD&D are to provide optimal technical solutions to critical ICHMI issues, resolve technology gaps arising from the unique measurement and control characteristics of advanced reactor concepts, provide demonstration of needed technologies and methodologies in the nuclear power application domain, mature emerging technologies to facilitate...

Digital I&C↗

DOE OSTI2024

Catalytic Approaches to C–O Activation in Biorenewable Feedstocks

The carbon present in biomass (the largest renewable source on the planet) continues to tempt us as a possible replacement for the carbon we currently obtain from fossil fuels. As we have recently reviewed, the challenges of extracting chemically useful feedstocks from biorenewables, and, especially, cellulosics, is largely under-developed relative to the maturity of the technologies for deriving industrially useful chemicals from petroleum. This ultimately boils down to problems in functionalization catalysis (for oil) versus defunctionalization (for cellulosics). The technology gap for achieving the selective defunctionalization of cellulosic feedstocks is much larger than it is for petroleum functionalization. This assessment suggests that the problem is not that bio-renewable feedstocks are fundamentally flawed from an economic and chemical sustainability perspective, but that we lack the technologies for deoxygenating cellulosic to more valuable chemicals. Bozell and Petersen have argued that integrated biorefineries will require a suite of products for viability (in analogy to an integrated petroleum refinery). These products will range from low-value high-volume energy related products (i.e. fuels) to high-value low-volume compounds focused on specialty markets and pharmaceuticals. The latter, although less impactful in terms of volume, is a critical economic component of the future integrated biorefinery. Our review was stimulated by their assessment of the state of the biorefinery and focused on the available chemistries for achieving low-volume high-value outcomes. To help fill this technology gap, we seek new catalytic technologies for synthesizing high-value chemicals from cellulosics and take the view that the inherent chirality of C 6 O 6 feedstocks will provide valuable materials for specialty and pharmaceutical applications, but only if one can achieve site-selective reactions that don’t denude the stereochemistry inherent to the sugars. Eliminative methods are less desirable as this deoxygenation scheme removes multiple stereocenters. The research plan outlined herein seeks methods for site-selective deoxygenation reactions that lead to high value specialty/pharma products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2018

Instrumentation Framework for Molten Salt Reactors

This report provides an overview of the specialized instrumentation necessary to operate and maintain liquid-fueled molten salt reactors (MSRs). The report does not include non-specialized industrial process control instrumentation, fissile material tracking instrumentation, or digital control/communication technologies. The report focuses on identifying MSR measurement technology gaps, and recommending research, development, and demonstration (RD&D) activities to close the identified gaps. To a large extent modern MSRs can rely on the instrumentation demonstrated during prior MSR development efforts. No fundamental technology gaps have been identified that would prevent operating or maintaining MSRs. However, improved instrumentation technology combined with the integration of modern process modeling and simulation could significantly improve the reliability and decrease the operating costs of future plants. The largest potential impact of new instrumentation technologies is in the integration of maintenance automation into reactor operations. Flow measurement has the largest technology hurdles remaining for to enable deployment of robust systems. Also, the technology for reliable, on-line fuel salt sample acquisition remains at relatively low technology readiness.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗