Results from the thermal control coatings experiment on OSO-III.
OSO 3 thermal control coatings solar radiation absorptance and emittance changes from near earth space environment flight test data
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OSO 3 thermal control coatings solar radiation absorptance and emittance changes from near earth space environment flight test data
Proton and electromagnetic radiation effects test on thermal control coatings by simulation, using xenon source and low energy accelerator
UV irradiation effects on ZnO spacecraft thermal control coating pigments, discussing photo-Hall, luminescence and electron paramagnetic resonance measurements
Surface recombination centers protecting against discoloration of thermal control coatings due to chemical changes induced by photoproduced holes and electrons in oxide pigments
Induction plasma calcining of pigment particles for thermal control coatings on space vehicles
The development and formulation of electrically conductive thermal control coating was undertaken for use on the International Sun Earth Explorer spacecraft. The primary effort was to develop a coating with a bulk resistivity of less than 100,000 ohm/sqm, an optical absorptance of approximately 0.55, and a normal emittance of 0.90. The required stability in space called for a bulk resistivity of less than 100,000 ohm/sq m, an absorptance of less than 0.67, and a normal emittance of 0.90 after exposure to approximately 4 x 10 to the 16th proton/sq cm of solar-wind particles and 5300 equivalent sun-hours. These exposures represent 2 years of ISEE flight conditions. Both the unsuccessful formulation efforts and the successful use of oxide pigments fired at 1448 K are described. Problems relative to the reactivity of specific coating vehicles exposed to high humidity are discussed.
Many of the thermal control surfaces exposed to the space environment during the 5.8 year LDEF mission experienced changes in fluorescence. All of the thermal control coatings flown on LDEF experiments S0069 and A0114 were characterized for fluorescence under ambient conditions. Some of the black coatings, having protective overcoats, appear bright yellow under ultraviolet exposure. Urethane based coatings exhibited emission spectra shifts toward longer wavelengths in the visible range. Zinc oxide pigment based coatings experienced a quenching of fluorescence, while zinc orthotitanate pigment based and other ceramic type coatings had no measurable fluorescence.
This report summarizes the condition of polyurethane thermal control coatings subjected to 69 months of low earth orbit (LEO) exposure on the Long Duration Exposure Facility (LDEF) mission. Specimens representing all environmental aspects obtainable by LDEF were analyzed. Widely varying changes in the thermo-optical and mechanical properties of these materials were observed, depending on atomic oxygen and ultraviolet radiation fluences. High atomic oxygen fluences, regardless of ultraviolet radiation exposure levels, resulted in near original optical properties for these coatings but with a degradation in their mechanical condition. A trend in solar absorptance increase with ultraviolet radiation fluence was observed. Contamination, though observed, exhibited minimal effects.
Additional experimental data were desired to support the selection of candidate thermal control coatings and solid film lubricants for the McDonnell Douglas Aerospace (MDA) Space Station hardware. The third Evaluation of Oxygen Interactions With Materials Mission (EOIM-3) flight experiment presented an opportunity to study the effects of the low Earth orbit environment on thermal control coatings and solid film lubricants. MDA provided five solid film lubricants and two anodic thermal control coatings for EOIM-3. The lubricant sample set consisted of three solid film lubricants with organic binders one solid film lubricant with an inorganic binder, and one solid film lubricant with no binder. The anodize coating sample set consisted of undyed sulfuric acid anodize and cobalt sulfide dyed sulfuric acid anodize, each on two different substrate aluminum alloys. The organic and inorganic binders in the solid film lubricants experienced erosion, and the lubricating pigments experienced oxidation. MDA is continuing to assess the effect of exposure to the low Earth orbit environment on the life and friction properties of the lubricants. Results to date support the design practice of shielding solid film lubricants from the low Earth orbit environment. Post-flight optical property analysis of the anodized specimens indicated that there were limited contamination effects and some atomic oxygen and ultraviolet radiation effects. These effects appeared to be within the values predicted by simulated ground testing and analysis of these materials, and they were different for each coating and substrate.
UV stability of several white thermal control coatings spectrally characterized in vacuum for application to Lunar Orbiter project
Earth reflected solar radiation and stability of satellite thermal control coatings, noting intensity distribution shifting toward UV region and coatings degradation rate
Vacuum UV degradation of thermal control coatings on ATS-1 satellite, comparing with laboratory simulation
Ferricyanide/ferrocyanide couple prevents zinc oxide pigment degradation in thermal control coatings. Chemical couple retards physical optical property changes.
The investigation of space environmental effects on LDEF thermal control coatings by the Materials Special Investigation Group is continuing. Analyses of chromic acid anodize, A276 white paint, and Z306 black paint were conducted, assessing performance as functions of environmental exposure. Test results from additional coatings, such as on scuff plates, M003, and the black chromium plate solar absorber, were obtained. Guidelines for the use of these materials and comparisons to ground based test data will be presented.
Report describes tests of variety of thermal-control coating materials, including white paints, second-surface-metalized fluorinated ethylene propylene, aluminum anodized in sulfuric acid, and plasma-sprayed alumina.
Analytical studies, ground-test data, and flight data before 1967 indicated that degradation of Apollo thermal-control coatings could be expected, possibly to an extent requiring spacecraft design changes to accomplish the worst-case lunar-landing mission. On the Apollo 9 mission, specimens of Apollo thermal-control coatings were retrieved by the astronauts during the extravehicular activity. These specimens were the first to be returned to earth from space unaffected by entry conditions. Subsequent measurements of the thermophysical properties (solar absorptance and hemispherical emittance) of the thermal-control-sample coatings revealed degradation levels well within the design capability of the Apollo spacecraft.
A process for providing a thermal control solar stable surface coating for aluminum surfaces adapted to be exposed to solar radiation wherein selected values within the range of 0.10 to 0.72 thermal emittance (epsilon sub tau) and 0.2 to 0.4 solar absorptance (alpha subs) are reproducibly obtained by anodizing the surface area in a chromic acid solution for a selected period of time. The rate voltage and time, along with the parameters of initial epsilon sub tau and alpha subs, temperature of the chromic acid solution, acid concentration of the solution and the material anodized determines the final values of epsilon/tau sub and alpha sub S. 9 Claims, 5 Drawing Figures.
Many different passive thermal control materials were flown as part of the Materials on International Space Station Experiment. Engineers and scientists at the Marshall Space Flight Center have analyzed a number of these materials, including Z93P zinc oxide/potassium silicate coating, YB-71P zinc orthotitanate/potassium silicate coating, NZOT, which is a low-cost alternative to YB-71P, several electrically conductive/static dissipative thermal control coatings, as well as black coatings for part marking and automated rendezvous and capture. These were exposed to the low Earth orbital environment of atomic oxygen, ultraviolet radiation, thermal cycling, and hard vacuum, though atomic oxygen exposure was very limited for some samples. Results from the one-year exposure of MISSE-3 and MISSE-4 are compared to the four-year exposure of MISSE-1 and MISSE-2. Solar absorptance, infrared emittance, and mass measurements indicate the durability of these materials to withstand the space environment. The effect of contamination from an active space station on the performance of white thermal control coatings is discussed.