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At least 73 records · Page 4

Improving UV Resistance of High Strength Fibers Used In Large Scientific Balloons

For the last three decades, NASA has been involved in the development of giant balloons that are capable of lifting heavy payloads of equipment (such as large telescopes and scientific instruments) to the upper atmosphere. While the use of such balloons has led to scientific discoveries, the demand for competitive science payloads and observational programs continues to rise. The NASA Balloon Program Office has entered a new phase of research to develop an Ultra Long Duration Balloon (ULDB) that will lift payloads of up to 3,600 kg to altitudes of up to 40 km. The flight duration is targeted to ranges between 30 to 100 days. Attaining these target durations requires the development of a super-pressure balloon design. The use of textile structures have already been established in these missions in the form of high strength tendons essential for the super pressure pumpkin design. Unfortunately, high strength fibers lose significant strength upon exposure to Ultra Violet (UV) radiation. Such UV degradation poses a serious challenge for the development of the ULDB. To improve the mission performance of the ULDB, new methods for protecting the tendons from the environmental effects need to be developed. NASA and NC State University College of Textiles are undertaking a research program to address these issues. Four tracks have been identified to prepare finishes that are believed to enhance the resistance of high strength fibers to UV. These tracks are: (a) self-polymerizing, (b) diffusion application, (c) polymer-filled with 30-40% UV absorber, and (d) combination of dyeing plus surface application. Four high performance fibers have been selected for this research investigation. These are Vectran (trademark), Spectra (trademark), Kevlar (trademark) and, PBO (Zylon (trademark)). This work will address the current progress of evaluating the performance of the UV finishes. This will be accomplished by comparing the tensile properties (strength, breaking elongation, modulus, etc) of untreated, unexposed to UV fibers; untreated exposed to UV fibers; and treated exposed to UV fibers.

Said, M.↗

Assessment of Resistance of Bacillus Horneckiae Endospores to UV Radiation and Function of Their Extraneous Layer in Resistance

Spore-forming microbes are highly resistant to various physical and chemical conditions, which include ionizing and UV radiation, desiccation and oxidative stress, and the harsh environment of outer space or planetary surfaces. The spore's resistance might be due to their metabolically dormant state, and/or by the presence of a series of protective structures that encase the interior-most compartment, the core, which houses the spore chromosome. These spores have multiple layers surrounding the cell that are not found in vegetative cells, and some species have an outer layer of proteins and glycoproteins termed the "exosporium" or a fibrous "extraneous layer" (EL). Bacillus horneckiae is an EL-producing novel sporeformer isolated from a Phoenix spacecraft assembly clean room, and it has previously demonstrated resistance to UV radiation up to 1000 J/m(sup 2). The EL appears to bind B. horneckiae spores into large aggregations, or biofilms, and may confer some UV resistance to the spores. Multiple culturing and purification schemes were tried to achieve high purity spores because vegetative cells would skew UV resistance results. An ethanol-based purification scheme produced high purity spores. Selective removal of the EL from spores was attempted with two schemes: a chemical extraction method and physical extraction (sonication). Results from survival rates in the presence and absence of the external layer will provide a new understanding of the role of biofilms and passive resistance that may favor survival of biological systems in aggressive extra-terrestrial environments. The chemical extraction method decreased viable counts of spores and lead to an inconclusive change UV resistance relative to non-extracted spores. The physical extraction method lead to non-aggregated spores and did not alter viability; however, it produced UV resistance profiles similar to non-extracted spores. In addition to the EL-removal study, samples of B. horneckiae spores dried on aluminum coupons and exposed to increasing UV (200-400 nm range) levels (0 to 8.0 x 105 kJ/m(sup 2)) were tested for viability, which indicated that the maximum UV exposure level that still resulted in viable spores was 5.0 x 10? kJ/m(sup 2).

resistance↗

Validation of an Erythema-Weighted UV Model Using Broadband Solar Irradiance Measurements From Eleven U.S. Sites: Preprint

Erythema-weighted UV solar irradiance (UV-E) has a potential impact on human health if the recommended maximum exposure times are exceeded. In spite of this, it is not measured at most sites that measure Global Horizontal Irradiance (GHI). However, since UV-E is highly correlated with GHI and total ozone content it can be estimated from this information with sufficient accuracy to assisst in public health recommendations. The Power Model (PM) provides a simple method to estimate the erythema-weighted UV irradiance (UV-E) from measured GHI, total ozone column and air mass. In this work, the performance of the PM method is assessed using high-quality data from 11 sites in the continental U.S. (part of SURFRAD and SOLRAD networks) and total ozone estimates publicly available from the MERRA-2 re-analysis database. A three year period (2021- 2023) at 1-minute frequency is considered. The results (for time aggregations of 5 and 60 minutes) show a high Pearson's correlations (> 0.99), consistently positive mean bias deviations (below 13%) and dispersions in the 8-19% range at all sites. Relative values are expressed in terms of the corresponding measurement mean. The performance indicators remain consistent across time resolutions (5 or 60 minutes), suggesting that the model's performance is robust and not significantly affected by short-term variability (which is captured by GHI). Spatial patterns reveal higher biases and RMSD in northern and eastern locations. These values represent a significant improvement over widely used satellite-based global UV-E estimates and open the possibility of using the PM with satellite-based GHI estimates for operational UV-E mapping over the contiguous U.S. territory.

14 SOLAR ENERGY↗

Nanolignin-based high internal phase emulsions for efficient protection of curcumin against UV degradation

As an emulsifier, lignin exhibits excellent UV resistance on drug-loaded emulsion systems for drug delivery. However, due to the structural variation and complexity of lignins from various origins, their UV shielding performance varies with the techniques for lignin extraction, which impacts properties and the protection efficiency of lignin-based HIPEs (high internal phase emulsions). In this work, lignin nanoparticles, prepared from three lignin preparations of Eucalyptus, were used in HIPEs delivery systems to protect curcumin from degradation by UV radiation. Structures of the lignin preparations were characterized using 2D HSQC (heteronuclear single-quantum coherence) NMR (nuclear magnetic resonance), 31 P NMR, and GPC (gel permeation chromatography). The residual curcumin level after 36h UV exposure in the nanolignin-based HIPEs was over 72%, much higher than that (< 10% after 24 h UV exposure) in the oil phase without lignin, indicating that the nanolignin-based HIPEs with enhanced UV shielding ability protect curcumin better. Of the three lignin preparations, AL (alkali lignin), with the lowest molecular weight, highest contents of phenolic hydroxyl and carboxyl groups, and highest S/G ratio, displayed the best anti-UV radiation ability and the most uniform nanoparticle size.

59 BASIC BIOLOGICAL SCIENCES↗

UV Capabilities of the CETUS Multi-Object Spectrometer (MOS) and NUV/FUV Camera

The Cosmic Evolution Through UV Spectroscopy (CETUS) concept enables parallel observations by the UV multiobject spectrometer (MOS) and near-UV/far-UV camera which operate simultaneously but independently with their separate field of views. The near-UV MOS can target up to 100 objects at a time without confusion with nearby sources or background zodiacal light. This multiplexing will allow over 100,000 galaxies to be observed over a typical mission lifetime. The MOS includes a next-generation micro-shutter array (NGMSA), an efficient aspheric Offner-like spectrometer design with a convex grating, and nanotube light traps for suppressing unwanted wavelengths. The NUV/FUV Camera has the capability to image in a range of sub-bands from 115-400 nm at the same time the MOS is operating at 180-350 nm. The UV camera has a similar Offner-like relay, selectable filters, and two separate detectors to optimize observing in either the far-UV (115-175 nm) or the near-UV (180-400 nm) utilizing a CsI Micro-Channel Plate detector (MCP) and a CCD respectively.

The Cosmic Evolution Through UV Spectroscopy (CETU↗

Ground-based retrievals of aerosol column absorption in the UV spectral region and their implications for GEMS measurements

Quantifying the spectral variation of column aerosol absorption in the ultraviolet (UV) and visible (Vis) wavelengths is required for accurate satellite-based aerosol and trace-gas retrievals. Retrievals of the column-averaged imaginary part of refractive index and single scattering albedo (SSA) in the UV–Vis range have been performed at Yonsei University, Seoul, Korea, since 2016 by combining co-located measurements from the NASA Aerosol Robotic Network (AERONET) Cimel sun-sky photometer, the Ultraviolet Multifilter Rotating Shadowband Radiometer (UV-MFRSR), the SKYNET Prede sky radiometer, and the NASA Pandora sun spectrometer. We investigated the spectral variation of column-averaged imaginary part of refractive index for UV–Vis wavelengths to refine models used in our aerosol retrieval algorithm to process measurements from the upcoming Geostationary Environment Monitoring Satellite (GEMS). The retrieved imaginary part of refractive index for highly absorbing fine pollution particles (BC), dust (DS), and non-absorbing (NA) particles in the selected UV–Vis range (380–440 nm) showed 0–20%, 30%, and 0–40% of spectral dependence, respectively. Retrievals of Ozone Monitoring Instrument (OMI) measurement data using the improved aerosol model showed improved correlation with AERONET data compared to the old algorithm that did not properly account for aerosol absorption effects. These results corroborate the advantage of using local climatology derived from ground-based UV–Vis spectral aerosol absorption measurements for satellite GEMS aerosol retrievals over East Asia. Moreover, this study reveals that spectral variations in the UV column aerosol absorption in East Asia differ from those in other regions.

ultraviolet (UV) and visible (Vis) wavelengths↗

Value Proposition of UV-Absorbers in PV Module Encapsulation

Various common crystalline silicon cell technologies were exposed to UVA radiation (1.24 Wm-2 nm-1 at 340 nm peak) on the front and back faces at 45 degrees Celsius for periods up to 3000 h, representing about 3 y of solar exposure in Phoenix, Arizona, USA. The resulting degradation of the open-circuit voltage and short-circuit current is presented. Of the various cell types examined, significant levels of degradation were seen in all cases. Less degradation was generally found after UV irradiation of cell fronts and older cell types, whereas a bifacial PERC type exposed on the rear showed about 25% degradation in short circuit current, attributable to lack of a diffused surface field. Selected cells were exposed to UV irradiation with the addition of long pass UV filters to replicate UV-absorbers in encapsulants. Modern cell designs are sensitive to UV-ID because of reduced or eliminated front and back surface field and increased dependence on high quality surface passivation. Single transformation of the independent variable (t, kW h/m^2) could be used to achieve a linear model of the data to extrapolate to 50 y. Solar Advisor Model (SAM) shows appropriate filtering of UV-irradiation can improve LCOE and net present value of plant. Some advanced cell types are seen to be UV-resistant (cell level solutions also exist). Solutions therefore exist on the cell, glass, and encapsulant level. Changes over time in each of these would also need to be considered (solarization, encapsulant browning...).

ENGINEERING,SOLAR ENERGY↗

High speed ultraviolet digital image correlation (UV-DIC) for dynamic strains at extreme temperatures

Digital Image Correlation (DIC) is a camera-based method of measuring full-field displacements and strains from the surface of a deforming object. It can be applied at any length scale (determined by the lenses) and any time scale (determined by the camera), and because it is non-contacting, it can also be used at temperatures much higher than can be withstood by bonded strain gauges. At extreme temperatures, materials emit light in the form of blackbody radiation, which can saturate the camera sensor. It has previously been shown that the emitted light can be effectively screened by using ultraviolet (UV) cameras, lenses, and filters; however, commercially available UV cameras are relatively slow, which limits the speed of combined UV-DIC measurements. In this study, a UV intensifier was paired with a high-speed camera, and its ability to perform UV-DIC at high temperature and high speed was investigated. The system was compared over three different experiments: (A) a quasi-static thermal expansion test at high temperature, (B) a vibration test at room temperature, and (C) the same vibration test repeated at high temperature. The system successfully performed DIC up to at least 1600 °C at frame rates of 5000 fps, which is more than 100 times faster than other examples of UV-DIC in the literature. In all cases, measurements made using the UV intensifier were much noisier than those made without the intensifier, but the intensifier enabled measurements at temperatures well above those which an unfiltered high-speed camera otherwise saturates.

47 OTHER INSTRUMENTATION↗

Lignin as a UV Light Blocker—A Review

Lignin is the by-product of pulp and paper industries and bio-refining operations. It is available as the leading natural phenolic biopolymer in the market. It has chromophore functional groups and can absorb a broad spectrum of UV light in range of 250–400 nm. Using lignin as a natural ingredient in sunscreen cream, transparent film, paints, varnishes and microorganism protection has been actively investigated. Both in non-modified and modified forms, lignin provides enhancing UV protection of commercial products with less than a 10% blend with other material. In mixtures with other synthetic UV blockers, lignin indicated synergic effects and increased final UV blocking potential in compare with using only synthetic UV blocker or lignin. However, using lignin as a UV blocker is also challenging due to its complex structure, polydispersity in molecular weight, brownish color and some impurities that require more research in order to make it an ideal bio-based UV blocker.

59 BASIC BIOLOGICAL SCIENCES↗

CLASSY IV. Exploring UV Diagnostics of the Interstellar Medium in Local High- z Analogs at the Dawn of the JWST Era

The Cosmic Origins Spectrograph (COS) Legacy Archive Spectroscopic SurveY (CLASSY) provides the first high resolution spectral catalog of 45 local high-z analogs in the ultraviolet (UV; 1200–2000 Å) to investigate their stellar and gas properties. Here we present a toolkit of UV interstellar medium (ISM) diagnostics, analyzing the main emission lines of CLASSY spectra (N IV] λλ1483,87, C IV λλ1548,51, He IIλ1640, O III]λλ1661,6, Si III] λλ1883,92, C III] λ1907,9). Specifically, our aim is to provide accurate diagnostics for the reddening E(B - V), electron density n e , electron temperature T e , metallicity 12+log(O/H), and ionization parameter log(U), taking the different ISM ionization zones into account. We calibrate our UV toolkit using well-known optical diagnostics, analyzing archival optical spectra for all CLASSY targets. We find that UV density diagnostics estimate n e values that are ~1–2 dex higher (e.g., n e (C III] λλ1907,9) ~ 10 4 cm -3 ) than those inferred from their optical counterparts (e.g., n e ([S II]λλ6717,31) ~ 10 2 cm -3 ; n e ([Ar IV]λλ4714,41) ~ 10 3 cm -3 ). T e derived from the hybrid ratio [O III] λ1666/λ5007 proves to be reliable, implying differences in determining 12+log(O/H) compared to the optical counterpart O III] λ4363/[O III] λ5007 within ~ ±0.3 dex. We also investigate the relation between the stellar and gas E(B - V), finding consistent values at high specific star formation rates (sSFRs; log sSFR ≳ -8 yr -1 ), while at low sSFRs we confirmed an excess of dust attenuation in the gas. Finally, we investigate UV line ratios and equivalent widths to provide correlations with 12+log (O/H) and log(U), but note that there are degeneracies between the two. With this suite of UV-based diagnostics, we illustrate the pivotal role CLASSY plays in understanding the chemical and physical properties of high-z systems that JWST can observe in the rest-frame UV.

79 ASTRONOMY AND ASTROPHYSICS↗

Effect of UV irradiation on evaporated ZnS films

Evaporated ZnS films used as a component in reflectance enhancing or decreasing multilayer coatings for mirrors, transparent optical materials, and vacuum UV reflecting optics, are investigated with reference to the reflectance loss under UV irradiation and the formation of ZnO as a result of the decomposition of ZnS in the presence of oxygen. Reflectance measurements over a broad wavelength range reveal that the UV induced reflectance losses are generally restricted to wavelengths shorter than 4000 A and are most severe in the vacuum UV region. After 134 hr of UV exposure initially polycrystalline film of 150-200 A thick is completely converted to amorphous ZnO. The results demonstrate that caution should be exercised in employing ZnS as the outer layer in an optical coating system designed for use in the UV and vacuum UV regions.

Hass, G.↗

Global Mapping of Underwater UV Irradiances and DNA-Weighted Exposures using TOMS and SeaWiFS Data Products

The global stratospheric ozone-layer depletion results In an increase in biologically harmful ultraviolet (UV) radiation reaching the surface and penetrating to ecologically significant depths in natural waters. Such an increase can be estimated on a global scale by combining satellite estimates of UV irradiance at the ocean surface from the Total Ozone Mapping Spectrometer (TOMS) satellite instrument with the SeaWIFS satellite ocean-color measurements in the visible spectral region. In this paper we propose a model of seawater optical properties in the UV spectral region based on the Case I water model in the visible range. The inputs to the model are standard monthly SeaWiFS products: chlorophyll concentration and the diffuse attenuation coefficient at 490nm. Penetration of solar UV radiation to different depths in open ocean waters is calculated using the RT (radiative transfer) quasi-single scattering approximation (QSSA). The accuracy of the QSSA approximation in the water is tested using more accurate codes. The sensitivity study of the underwater UV irradiance to atmospheric and oceanic optical properties have shown that the main environmental parameters controlling the absolute levels of the UVB (280-320nm) and DNA-weighted irradiance underwater are: solar-zenith angle, cloud transmittance, water optical properties, and total ozone. Weekly maps of underwater UV irradiance and DNA-weighted exposure are calculated using monthly-mean SeaWiFS chlorophyll and diffuse attenuation coefficient products, daily SeaWiFS cloud fraction data, and the TOMS-derived surface UV irradiance daily maps. The final products include global maps of weekly-average UVB irradiance and DNA-weighted daily exposures at 3m and 10m, and depths where the UVB irradiance and DNA-weighted dose rate at local noon are equal to 10% of their surface values.

Vasilkov, Alexander↗

The effects of UV radiation A and B on diurnal variation in photosynthesis in three taxonomically and ecologically diverse microbial mats

Photosynthetic primary production, the basis of most global food chains, is inhibited by UV radiation. Evaluating UV inhibition is therefore important for assessing the role of natural levels of UV radiation in regulating ecosystem behavior as well as the potential impact of stratospheric ozone depletion on global ecosystems. As both photosynthesis and UV fluxes are subject to diurnal variations, we examined the diurnal variability of the effect of UV radiation on photosynthesis in three diverse algal mats. In one of the mats (Cyanidium caldarium) a small mean decrease in primary productivity over the whole day occurred when both UVA and UVB were screened out. In two of the mats (Lyngbya aestuarii and Zygogonium sp.) we found a mean increase in the total primary productivity over the day when UVB alone was screened and a further increase when UVA and UVB were both screened out. Variations in the effects of UV radiation were found at different times of the day. This diurnal variability may be because even under the same solar radiation flux, there are different factors that may control photosynthetic rate, including nutritional status and other physiological processes in the cell. The results show the importance of assessing the complete diurnal productivity. For some of the time points the increase in the mean was still within the standard deviations in primary productivity, illustrating the difficulty in dissecting UV effects from other natural variations.

Ultraviolet Rays↗

The UV Scattering Halo of the Central Source Associated with Eta Carinae

Eta Carinae is one of the most massive and luminous stars within our galaxy. It consists of a compact central source which suffers circumstellar and interstellar extinction, local dense knots which emit strong narrow nebular-like emission lines, and an outer dusty nebula called the Homunculus. The optical spectrum of the central star, first observed directly and without obvious nebular contamination by the HST, can be modeled successfully using a hot star with a radius (at the wind sonic point) of 60\,R\odot. The central star is losing mass, via a dense stellar wind, at the prodigious rate of 10(exp -3)\,M\odot/yr. Its effective temperature is low (< 10,000\,K), and is determined entirely by the wind properties. Until now the UV spectrum has not been explained. We show that HST UV spectrum, and the FUSE FUV spectrum, can both be understood using the same underlying model that explains the optical spectrum. To do so, however, it is necessary to take into account the occultation of the central source by dust. It is also important to realize that in the UV, the HST is partially resolving the central source. Due to strong mass loss, the wind is optically thick in UV resonance lines even at large radii. The UV resonance lines are responsible for the UV halo seen around Eta Carinae, and provide a partial explanation of why Eta Carinae can even be seen at UV wavelengths.

Hillier, D. J.↗

UV Spectral Diagnostics of Galaxy Evolution

New instrumentation now enable deep spectral surveys of galaxies at younger ages. At a redshift, z=1, all galaxies are less than 6 Gyr old and hence, have not yet formed horizontal-branch stars. Also, at z=1, the restframe-UV comes into view, and with it, a new set of spectral diagnostics. UV spectral features are especially important because most of the UV flux comes from stars at the main-sequence turnoff (MSTO). Hence, UV spectral diagnostics enable the most recent star formation episode of high-redshift galaxies to be estimated directly from MSTO stars. In preparation for these high-redshift spectral surveys, we are developing UV spectral templates for stellar populations younger than 6 Gyr using UV-optical spectra of stars observed by HST/STIS. We are also starting to supplement these observations with theoretical spectral grids of stars of various metallicities. In this paper, we present a progress report on UV spectral templates and spectral diagnostics.

Heap, Sara R.↗

UV Spectral Diagnostics

New instrumentation now enable deep spectral surveys of galaxies at younger ages. At a redshift, z=l, all galaxies are less than 6 Gyr old and hence, have not yet formed horizontal-branch stars. Also, at z=1, the restframe-UV comes into view, and with it, a new set of spectral diagnostics. UV spectral features are especially important because most of the UV flux comes from stars at the main-sequence turnoff (MSTO). Hence, UV spectral diagnostics enable the most recent star formation episode of high-redshift galaxies to be estimated directly from MSTO stars. In preparation for these high-redshift spectral surveys, we are developing UV spectral templates for stellar populations younger than 6 Gyr using UV-optical spectra of stars observed by HST/STIS. We are also starting to supplement these observations with theoretical spectral grids of stars of various metallicities. In this paper, we present a progress report on UV spectral templates and spectral diagnostics.

Heap, Sara R.↗

Recent Progress Made in the Development of High-Energy UV Transmitter

In this paper, the status of an all-solid-state UV converter development for ozone sensing applications is discussed. A high energy Nd:YAG laser for pumping the UV converter arrangement was recently reported. The pump is an all-solid-state, single longitudinal mode, and conductively cooled Nd:YAG laser operating at 1064 nm wavelength. Currently, this pump laser provides an output pulse energy of greater than 1J/pulse at 50 Hz PRF and a pulsewidth of 22 ns with an electrical-to-optical system efficiency of greater than 7% and a M(sup 2) value of approx. 2. The spatial profile of the output beam is a rectangular super Gaussian. This Nd:YAG pump laser has been developed to pump the nonlinear optics based UV converter arrangement to generate 320 nm and 308 nm wavelengths by means of 532 nm wavelength. Previously, this UV converter arrangement has demonstrated IR-to-UV conversion efficiency of 24% using a flash lamp pumped laser providing a round, flat top spatial profile. Recently, the UV converter was assembled and tested at NASA LaRC for pumping with the diode pumped Nd:YAG laser. With current spatial profile, the UV converter was made operational. Current efforts to maximize the nonlinear conversion efficiency by refining its spatial profile to match RISTRA OPO requirements are progressing.

Prasad, Narasimha S.↗

Global Increase in UV Irradiance during the Past 30 Years (1979-2008) Estimated from Satellite Data

Zonal average ultraviolet irradiance (flux ultraviolet, F(sub uv)) reaching the Earth's surface has significantly increased since 1979 at all latitudes except the equatorial zone. Changes are estimated in zonal average F(sub uv) caused by ozone and cloud plus aerosol reflectivity using an approach based on Beer's law for monochromatic and action spectrum weighted irradiances. For four different cases, it is shown that Beer's Law leads to a power law form similar to that applied to erythemal action spectrum weighted irradiances. Zonal and annual average increases in F(sub uv) were caused by decreases in ozone amount from 1979 to 1998. After 1998, midlatitude annual average ozone amounts and UV irradiance levels have been approximately constant. In the Southern Hemisphere, zonal and annual average UV increase is partially offset by tropospheric cloud and aerosol transmission decreases (hemispherical dimming), and to a lesser extent in the Northern Hemisphere. Ozone and 340 nm reflectivity changes have been obtained from multiple joined satellite time series from 1978 to 2008. The largest zonal average increases in F(sub uv) have occurred in the Southern Hemisphere. For clear-sky conditions at 50 S, zonal average F(sub uv) changes are estimated (305 nm, 23%; erythemal, 8.5%; 310 nm, 10%; vitamin D production, 12%). These are larger than at 50 N (305 nm, 9%; erythemal, 4%; 310 nm, 4%; vitamin D production, 6%). At the latitude of Buenos Aires, Argentina (34.6 S), the clear-sky Fuv increases are comparable to the increases near Washington, D. C. (38.9 N): 305 nm, 9% and 7%; erythemal, 6% and 4%; and vitamin D production, 7% and 5%, respectively.

Herman, Jay R.↗