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At least 73 records · Page 4

Change in the thermionic work function of semiconductor powders exposed to electromagnetic radiation

The variations of the thermoelectronic work function of titanium dioxide, submitted to an ultraviolet or visible and infrared radiation, in the presence of oxygen, are studied by the vibrating condenser method. It is shown that during the ultraviolet irradiation, a desorption of a first species of oxygen simultaneously occurs with the adsorption of a second species of oxygen and that this phenomenon is found for any structure of TiO2 (anatase or rutile) any texture, oxygen pressure, radiation intensity, and nature of introduced dopes.

Bourasseau, S.

Variation in the thermionic work function of semiconductor powders exposed to electromagnetic radiation

The study of the variation of thermoelectronic work function potential of TiO2 in the presence of isobutane shows that this gas is not adsorbed on this solid, in either the presence or the absence of ultraviolet radiation. These results, as well as those obtained in a previous work, lead to the mechanism of the photo-oxidation of isobutane at room temperature, in which excited atomic oxygen is the active species.

Bourasseau, S.

Work function measurements by the field emission retarding potential method

Using the field emission retarding potential method true work functions have been measured for the following monocrystalline substrates: W(110), W(111), W(100), Nb(100), Ni(100), Cu(100), Ir(110) and Ir(111). The electron elastic and inelastic reflection coefficients from several of these surfaces have also been examined near zero primary beam energy.

Swanson, L. W.

Thermionic scanner pinpoints work function of emitter surfaces

In the electron tube testing, a thermionic scanner makes accurate spatial resolution measurements of the metallic surface work functions of emitters. The scanner determines the emitter function and its local departures from the mean value on a point-by-point basis for display on an oscilloscope.

Rasor, N. S.

Work function measurements by the field emission retarding potential method.

Description of the theoretical foundation of the field electron retarding potential method, and review of its experimental application to the measurement of single crystal face work functions. The results obtained from several substrates are discussed. An interesting and useful fallout from the experimental approach described is the ability to accurately measure the elastic and inelastic reflection coefficient for impinging electrons to near zero-volt energy.

Strayer, R. W.

Work function measurement of lanthanum-boron compounds

The relationship between emission properties and sample composition is studied for lanthanum-boron compounds. Specifically, the La-B system is considered between 1400 and 2100 K and between LaB(4.24) and LaB(29.2) to determine the phase relationship, chemical activity of the compounds, vapor composition, and vaporization rate. The results indicate that: (1) a blue-colored phase near LaB(9) exists between a purple-colored LaB(6) and elemental boron, (2) vaporization is sufficiently more rapid than diffusion so that great compositional differences exist between the surface and the interior, (3) an activation energy lowers the boron vaporization rate from LaB(6), and (4) a steady-state surface composition between LaB(6.04) and LaB(6.07) exists for freely vaporizing materials as a function of interior composition, purity, and temperature. It is noted that the ultimate life of a thermionic diode is governed by electrode vaporization rate whereas efficiency is governed by the electrode work function.

Jacobson, D. L.