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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Impact of Assimilating GOES-Derived Land Surface Variables into the PSU/NCAR MM5

Land surface processes are known to have a profound impact on the overlying atmosphere over a wide range of spatial and temporal scales. Many atmospheric numerical models include special parameterizations to improve the specification and partitioning of surface fluxes which are critical to the accurate prediction of warm season boundary layer behavior, organized mesoscale circulations, and convective precipitation. However, the added degrees of freedom resulting from the inclusion of vegetation and soil schemes require the specification of additional surface parameters such as vegetative resistances, green vegetation fraction, leaf area index, soil physical and hydraulic characteristics, and the vertical distribution of soil moisture. As satellite data have become more readily available in recent years, many investigations have attempted to use these new measurements to infer missing components of the surface energy budget. Sensitivity studies have shown land-skin temperature (LST) tendencies during the mid-morning hours are strongly sensitive to the surface moisture availability (a function of soil wetness and vegetation) and less sensitive to other parameters such as surface roughness. Based upon results from these and other studies, developed a simple technique that dynamically assimilates Geostationary Operational Environmental Satellite (GOES) derived land-surface products into the surface energy budget of a mesoscale model. The purpose of this paper is to demonstrate that assimilating the GOES satellite data has the potential to improve the representation of land surface characteristics within the model without prior knowledge of the land surface characteristics. The assimilation technique is presented in Section 2 and the numerical experiments are detailed in Section 3. Preliminary results and conclusions are presented in Sections 4 and 5, respectively.

Lapenta, William M.↗

Nonvolatile Memory Solution for Near-Term NASA Missions

Nonvolatile memory (NVM) system that could reliably function in extreme environments is one of the most critical components for many spacecrafts being developed for NASA missions to be launched in next four to seven years. NVM supports the computer system in saving and updating critical state data required for a warm restart after power cycling or in case of a power bus failure. It also provides a power independent mass storage capacity for the scientific data gathered by the instruments. In some cases the window for gathering such data is very small and occurs only once in a given mission. Commercially popular and fully developed Flash NVM technology is inappropriate for many reasons such as the limited read write cycles with slower access speeds, radiation intolerance, higher Single Event Upsets (SEU) rates, etc. It is desirable to have an NVM system based upon a robust cell technology making it immune to the SEUs and with sufficient radiation hardness. Availability of such NVM system seems to be still 5 to 10 years in the future. Meanwhile, it is possible to provide an interim hybrid solution by combining the existing rad-hard technologies. Additional information is contained in the original extended abstract.

Patel, J. U.↗

Reconciling Contrasting Relationships Between Relative Dispersion and Volume-Mean Radius of Cloud Droplet Size Distributions

Cloud droplet spectral relative dispersion is critical to parameterizations of cloud radiative properties, warm-rain initiation, and aerosol-cloud interactions in models; however, there is no consistent relationship between relative dispersion and volume-mean radius in literature, which hinders improving relative dispersion parameterization and calls for physical explanation. Here we show, by analyzing aircraft observations of cumulus clouds during Routine AAF [Atmospheric Radiation Measurement (ARM) Aerial Facility] Clouds with Low Optical Water Depths (CLOWD) Optical Radiative Observations, that the correlation between relative dispersion and volume-mean radius changes from positive to negative as volume-mean radius increases. With the new observation, we postulate that the sign of the correlation is determined by whether or not condensation (evaporation) occurs simultaneously with significant new activation (deactivation). The hypothesis is validated by simulations of both an adiabatic cloud parcel model and a parcel model accounting for entrainment-mixing. A new quantity, first bin strength, is introduced to quantify this new observation. Theoretical analysis of truncated gamma and modified gamma size distributions further supports the hypothesis and reconciles the contrasting relationships between relative dispersion and volume-mean radius, including the results in polluted fog observations. The results could shed new light on the so-called “twilight zone” between cloudy and cloud-free air, which in turn affects evaluation of aerosol-cloud interactions and retrieval of aerosol optical depth.

Lu, Chunsong↗

Performance Assessment of High-Efficiency Refrigerated Display Cases With Low Global Warming Potential Refrigerants

As California policy makers enforce new regulations such as SB 1383 to achieve state greenhouse gas reduction goals, it will be critical to understand the energy efficiency implications of low global warming potential (GWP) refrigerants in commercial refrigeration applications. The goal of this research project, funded by Commonwealth Edison, was to assess the energy performance of two high-efficiency medium-temperature, self-contained, reach-in display cases that utilized natural refrigerant propane (R-290, GWP = 3), and hydrofluorocarbon (HFC) drop-in hydrofluoroolefin R-513A (GWP = 573). Performance of these display cases was compared to a baseline fixture using HFC (R-134A, GWP = 1301) under equal conditions in a controlled environment chamber. These display cases were selected due to their widespread use in convenience stores and small supermarkets. The high-efficiency cases were equipped with energy-efficient lighting, improved panel insulation, high-efficiency evaporator and condenser fan motors, and high-effectiveness heat exchangers. The test method used in this project was foundationally inspired by the ANSI/ASHRAE 72-2018 standard method to evaluate each case under equivalent conditions (ASHRAE 2018). However, minor modifications to this methodology were implemented to better represent more realistic operation of the units. While maintaining equivalent target product temperature, the energy-efficient fixtures A (containing R-290, improved insulation, heat exchangers with a higher overall heat transfer coefficient (higher UA), and more efficient lighting and fan motors) and B (containing R-513A, improved fans, and higher UA-heat exchangers, and more efficient lighting and fan motors) consumed 61.8% to 32.6% less energy, respectively, than a baseline case using R-134A refrigerant. The daily energy consumption of the R-290, R-513A, and baseline display cases at the upper limit of environmental conditions was 4.30, 7.59, and 11.26 kWh/day, respectively.

alternative refrigerants↗

Data driven pathway analysis and forecast of global warming and sea level rise

Climate change is a critical issue of our time, and its causes, pathways, and forecasts remain a topic of broader discussion. In this paper, we present a novel data driven pathway analysis framework to identify the key processes behind mean global temperature and sea level rise, and to forecast the magnitude of their increase from the present to 2100. Based on historical data and dynamic statistical modeling alone, we have established the causal pathways that connect increasing greenhouse gas emissions to increasing global mean temperature and sea level, with its intermediate links encompassing humidity, sea ice coverage, and glacier mass, but not for sunspot numbers. Our results indicate that if no action is taken to curb anthropogenic greenhouse gas emissions, the global average temperature would rise to an estimated 3.28 °C (2.46–4.10 °C) above its pre-industrial level while the global sea level would be an estimated 573 mm (474–671 mm) above its 2021 mean by 2100. However, if countries adhere to the greenhouse gas emission regulations outlined in the 2021 United Nations Conference on Climate Change (COP26), the rise in global temperature would lessen to an average increase of 1.88 °C (1.43–2.33 °C) above its pre-industrial level, albeit still higher than the targeted 1.5 °C, while the sea level increase would reduce to 449 mm (389–509 mm) above its 2021 mean by 2100.

54 ENVIRONMENTAL SCIENCES↗

Spatial pattern of lake evaporation increases under global warming linked to regional hydroclimate change

Abstract Lakes are critical natural resources that are vulnerable to climate change. In a warmer climate, lake evaporation is projected to increase globally, but with substantial variation between regions. Here, based on ensemble projections of climate and lake models and an attribution method, we show that future lake evaporation increase is strongly modulated by regional hydroclimate change. Specifically, a drying hydroclimate will amplify evaporation increase by enlarging surface vapor pressure deficit and reducing cloud shortwave reflection. Future lake evaporation increase is amplified in tropical America, the Mediterranean and Southeast China with drier future hydroclimates, and dampened in high latitudes and the Tibetan Plateau with wetter future hydroclimates. Such spatially coupled changes in lake evaporation and hydroclimate have important implications on regional lake water balance and volume change, which can aggravate water scarcity and flood risks.

54 ENVIRONMENTAL SCIENCES↗

Leveraging Groundwater Dynamics to Improve Predictions of Summer Low-Flow Discharges

Summer streamflow predictions are critical for managing water resources; however, warming-induced shifts from snow to rain regimes impact low-flow predictive models. Additionally, reductions in snowpack drive earlier peak flows and lower summer flows across the western United States increasing reliance on groundwater for maintaining summer streamflow. However, it remains poorly understood how groundwater contributions vary interannually. Here, we quantify recession limb groundwater (RLGW), defined as the proportional groundwater contribution to the stream during the period between peak stream flow and low flow, to predict summer low flows across three diverse western US watersheds. We ask (a) how do snow and rain dynamics influence interannual variations of RLGW contributions and summer low flows?; (b) which watershed attributes impact the effectiveness of RLGW as a predictor of summer low flows? Linear models reveal that RLGW is a strong predictor of low flows across all sites and drastically improves low-flow prediction compared to snow metrics at a rain-dominated site. Results suggest that strength of RLGW control on summer low flows may be mediated by subsurface storage. Subsurface storage can be divided into dynamic (i.e., variability saturated) and deep (i.e., permanently saturated) components, and we hypothesize that interannual variability in dynamic storage contribution to streamflow drives RLGW variability. In systems with a higher proportion of dynamic storage, RLGW is a better predictor of summer low flow because the stream is more responsive to dynamic storage contributions compared to deep-storage-dominated systems. Overall, including RLGW improved low-flow prediction across diverse watersheds.

54 ENVIRONMENTAL SCIENCES↗

Mountain-wave drag in the stratosphere and mesosphere inferred from observed winds and a simple mountain-wave parameterization scheme

A daily analysis of mountain-wave propagation through observed, global wind, and temperature fields in January and August is presented. Winds and temperatures are obtained from the daily 18-level NMC Climate Analysis Center. Mountain-wave properties are deduced from a simple, gravity wave parameterization scheme in which the effects of topographic anisotropy (ridge orientation) are explicitly included. Planetary waves in the northern winter stratosphere are found to play an important role in modulating the magnitude and distribution of inferred mountain-wave drag in the middle atmosphere. The Aleutian anticyclone is found to effectively block mountain waves generated over western North America from reaching the mesosphere by inducing local mountain-wave-critical levels in the stratosphere. Stratospheric sudden warmings have a similar effect at all longitudes so that during months with sudden warmings the average inferred drag in the mesosphere is reduced by a factor of 4 to 5 from its normal value. Partly as a consequence of larger planetary-wave filtering in the Northern Hemisphere, inferred mountain-wave drag in the southern winter mesosphere is found to be comparable to that in the northern winter mesosphere. Almost all of the mountain wave drag exerted on the southern middle atmosphere is found to originate over the southern Andes and Antarctic Peninsula.

Bacmeister, Julio T.↗

Measurements of Ice Particles in Tropical Cirrus Anvils: Importance in Radiation Balance

Cirrus is important in the radiation balance of the global atmosphere, both at solar and thermal infrared (IR) wavelengths. In particular cirrus produced by deep convection over the oceans in the tropics may be critical in controlling processes whereby energy from warm tropical oceans is injected to different levels in the tropical atmosphere to subsequently influence not only tropical but mid latitude climate. Details of the cloud composition may differentiate between a net cooling or warming at these levels. The cloud composition may change depending on the input of nuclei from volcanic or other sources. Observations of cirrus during the FIRE-2 Project over Coffeyville, Kansas and by satellite demonstrate that cirrus, on occasion, is composed not only of larger particles with significant fall velocity (few hundred micrometers, 0.5 m/s) but much more numerous small particles, size 10-20 micrometers, with small fall velocity (cm/s), which may sometimes dominate the radiation field. This is consistent with emissivity measurements. In the thermal IR, ice absorption is strong, so that ice particles only 10 micrometers thick are opaque, at some wavelengths; on the other hand at other wavelengths and in the visible, ice is only moderately to weakly absorbing. It follows that for strongly absorbing wavelengths the average projected area of the ice particles is the important parameter, in weakly absorbing regions it is the volume (mass) of ice which is important. The shape of particles and also their internal structure may also have significant effect on their radiative properties. In order to access the role of cirrus in the radiation budget it is necessary to measure the distribution of ice particles sizes, shapes and concentrations in the regions of interest. A casual observation of any cirrus cloud shows that there is variability down to a scale of at least a few 100 m; this is confirmed by radar and lidar remote sensing. Thus aircraft measurements designed to give insight into the spatial distribution of radiation properties of ice crystals must be capable of examination of concentration, size and shape over a distance ideally of 100 m or less and to detect particles down to a size below which radiative effects are no longer significant.

Foster, Theodore↗

Physical and Optical/Radiative Characteristics of Aerosol and Cloud Particles in Tropical Cirrus: Importance in Radiation Balance

Whether cirrus clouds heat or cool the Earth-atmosphere system depends on the relative importance of the cloud shortwave albedo effect and the cloud thermal greenhouse effect. Both are determined by the distribution of ice condensate with cloud particle size. The microphysics instrument package flown aboard the NASA DC-8 in TOGA/COARE included an ice crystal replicator, a 2D Greyscale Cloud Particle Probe and a Forward Scattering Spectrometer Aerosol Probe. In combination, the electro-optical instruments permitted particle size measurements between 0.5 micrometer and 2.6 millimeter diameter. Ice crystal replicas were used to validate signals from the electrooptical instruments. Both optical and scanning electron microscopy were utilized to analyze aerosol and ice particle replicas between 0.1 micrometer and several 100 micrometer diameter. In first approximation, the combined aerosol-cloud particle spectrum in several clouds followed a power law N alpha D(sup -2.5). Thus, large cloud particles carried most of the condensate mass, while small cloud and aerosol particles determined the surface area. The mechanism of formation of small particles is growth of (hygroscopic, possibly ocean-derived) aerosol particles along the Kohler curves. The concentration of small particles is higher and less variable in space and time, and their tropospheric residence time is longer, than those of large cloud particles because of lower sedimentation velocities. Small particles shift effective cloud particle radii to sizes much smaller than the mean diameter of the cloud particles. This causes an increase in shortwave reflectivity and IR emissivity, and a decrease in transmissivity. Occasionally, the cloud reflectivity increased with altitude (decreasing temperature) stronger than did cloud emissivity, yielding enhanced radiative cooling at higher altitudes. Thus, cirrus produced by deep convection in the tropics may be critical in controlling processes whereby energy from warm tropical oceans is injected to different levels in the atmosphere to subsequently influence not only tropical but mid-latitude climate.

Pueschel, R. F.↗

Light Absorption in the Stratosphere: Trend, Soot Aerosol Concentration and Contribution by...

The light absorption coefficient, Beta(a) of the stratospheric aerosol is an important quantity that determines its radiative effects. When combined with the aerosol scattering coefficient, Beta(a) it becomes possible to evaluate the aerosol single scatter albedo, omega = Beta(s)/(Beta(s) + Beta(a)) which is essential for modeling the overall radiative effects of the stratospheric aerosol. Pollack1 determined that omega = 0.98 is a critical value that separates stratospheric cooling from warming.

Pueschel, R. F.↗

Gene-informed decomposition model predicts lower soil carbon loss due to persistent microbial adaptation to warming

Abstract Soil microbial respiration is an important source of uncertainty in projecting future climate and carbon (C) cycle feedbacks. However, its feedbacks to climate warming and underlying microbial mechanisms are still poorly understood. Here we show that the temperature sensitivity of soil microbial respiration ( Q 10 ) in a temperate grassland ecosystem persistently decreases by 12.0 ± 3.7% across 7 years of warming. Also, the shifts of microbial communities play critical roles in regulating thermal adaptation of soil respiration. Incorporating microbial functional gene abundance data into a microbially-enabled ecosystem model significantly improves the modeling performance of soil microbial respiration by 5–19%, and reduces model parametric uncertainty by 55–71%. In addition, modeling analyses show that the microbial thermal adaptation can lead to considerably less heterotrophic respiration (11.6 ± 7.5%), and hence less soil C loss. If such microbially mediated dampening effects occur generally across different spatial and temporal scales, the potential positive feedback of soil microbial respiration in response to climate warming may be less than previously predicted.

54 ENVIRONMENTAL SCIENCES↗

Necromass responses to warming: A faster microbial turnover in favor of soil carbon stabilisation

Microbial byproducts and residues (hereafter ‘necromass’) potentially play the most critical role in soil organic carbon (SOC) sequestration. However, little is known about the influence of climate warming on necromass accumulation in the agroecosystem and the underlying mechanisms associated with microbial life strategies. Here, in order to address these knowledge gaps, we used amino sugars as biomarkers of microbial necromass, and investigated their variation through an 8-year trial in an agroecosystem with two warming levels (+1.6 and + 3.2 °C) compared to ambient temperature. The results showed that the lower warming level had no impact on total microbial necromass carbon. Conversely, warming the soil 3.2 °C above ambient increased total microbial necromass by 17 % and its contribution to SOC by 21.3 %, mainly by increasing fungal necromass (+19.8 %), whereas +3.2 °C warming had no impact on bacterial necromass. At the phylum level, compared with the ambient control, +3.2 °C warming induced an increase in the abundance of Proteobacteria and a decrease in both Acidobacteria and Actinobacteria, whereas in the fungal community, Ascomycota increased and Mortierellomycota decreased. This indicates that r-strategists outcompete K-strategists in warmer climates, which led to increased microbial necromass production and accumulation, as supported by the positive correlation between r-strategists and microbial necromass. Stronger microbial competition for resources also resulted in a higher biomass turnover rate, greater cell death, and greater production of microbial necromass. This was supported by the lower bacterial and fungal network complexity and trophic links under warming conditions. In addition, the necromass generated from accelerated microbial turnover further offsets warming-induced deceases in microbial biomass. Consequently, bulk SOC did not change, despite microbial necromass having a much greater response to warming than the soil C pool. Therefore, future climate warming may influence the composition and persistence of SOC during microbial degradation.

54 ENVIRONMENTAL SCIENCES↗

Role of non-CO 2 greenhouse gas emissions in limiting global warming

Unfortunately, current climate pledges are insufficient to achieve the aspirational goal of limiting global warming to 1.5°C. Here, we discuss the critical role that non-CO 2 greenhouse gas emissions might play in global climate change stabilization and challenges and opportunities to pivot research and policy focus toward accelerated reductions of non-CO 2 gases.

54 ENVIRONMENTAL SCIENCES↗

Overcoming Metastable CO 2 Adsorption in a Bulky Diamine-Appended Metal-Organic Framework

We report carbon capture at fossil fuel-fired power plants is a critical strategy to mitigate anthropogenic contributions to global warming, but widespread deployment of this technology is hindered by a lack of energy-efficient materials that can be optimized for CO 2 capture from a specific flue gas. As a result of their tunable, step-shaped CO 2 adsorption profiles, diamine-functionalized metal-organic frameworks (MOFs) of the form diamine-Mg 2 (dobpdc) (dobpdc 4- = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) are among the most promising materials for carbon capture applications. Here, we present a detailed investigation of dmen-Mg 2 (dobpdc) (dmen = 1,2-diamino-2-methylpropane), one of only two MOFs with an adsorption step near the optimal pressure for CO 2 capture from coal flue gas. While prior characterization suggested that this material only adsorbs CO 2 to half capacity (0.5 CO 2 per diamine) at 1 bar, we show that the half-capacity state is actually a metastable intermediate. Under appropriate conditions, the MOF adsorbs CO 2 to full capacity, but conversion from the half-capacity structure happens on a very slow time scale, rendering it inaccessible in traditional adsorption measurements. Data from solid-state magic angle spinning nuclear magnetic resonance spectroscopy, coupled with van der Waals-corrected density functional theory, indicate that ammonium carbamate chains formed at half capacity and full capacity adopt opposing configurations, and the need to convert between these states likely dictates the sluggish post-half-capacity uptake. By use of the more symmetric parent framework Mg 2 (pc-dobpdc) (pc-dobpdc 4- = 3,3'-dioxidobiphenyl-4,4'-dicarboxylate), the metastable trap can be avoided and the full CO 2 capacity of dmen-Mg 2 (pc-dobpdc) accessed under conditions relevant for carbon capture from coal-fired power plants.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

From peak to plummet: impending decline of the warm Arctic-cold continents phenomenon

Abstract This study assesses the projected trajectory of Warm Arctic-Cold Continent (WACC) events in East Asia and North America through large ensemble simulation for the upcoming decades. It analyses the evolution of the geographical boundaries of threshold cold temperatures, revealing a significant northward shift as a sign of global warming’s impact on the southward advancement of Arctic cold air. While validating the intensification of the WACC phenomenon until the 2020 s, echoing earlier studies, the findings indicate a marked decrease beginning in the 2030s. If warming is not curbed, this shift suggests a critical modification in the WACC pattern, prompting a re-evaluation of existing theories and models for extreme winter weather events. The results have major implications, spurring communities impacted by WACC to anticipate future changes and encouraging the climate forecasting community to update conceptual models for improved adaptation and mitigation approaches.

Meteorology & Atmospheric Sciences↗

Polyphenol rewiring of the microbiome reduces methane emissions

Methane mitigation is regarded as a critical strategy to combat the scale of global warming. Currently, ~40% of methane emissions originate from microbial sources, which is causing strategies to suppress methanogens—either through direct toxic effects or by diverting their substrates and energy—to gain traction. Problematically, current microbial methane mitigation knowledge lacks detailed microbiome-centered insights, limiting translation across conditions and ecosystems. Here we utilize genome-resolved metatranscriptomes and metabolomes to assess the impact of a proposed methane inhibitor, catechin, on greenhouse gas emissions for high-methane-emitting peatlands. In microcosms, catechin drastically reduced methane emissions by 72%–84% compared to controls. Longitudinal sampling allowed for reconstruction of a catechin degradation pathway involving Actinomycetota and Clostridium, which break down catechin into smaller phenolic compounds within the first 21 days, followed by degradation of phenolic compounds by Pseudomonas_E from Days 21 to 35. These genomes co-expressed hydrogen-uptake genes, suggesting hydrogenases may act as a hydrogen sink during catechin degradation and consequently reduce hydrogen availability to methanogens. In support of this idea, there was decreased gene expression by hydrogenotrophic and hydrogen-dependent methylotrophic methanogens under catechin treatment. There was also reduced gene expression from genomes inferred to be functioning syntrophically with hydrogen-utilizing methanogens. We propose that catechin metabolic redirection effectively starves hydrogen-utilizing methanogens, offering a potent avenue for curbing methane emissions across diverse environments including ruminants, landfills, and constructed or managed wetlands.

54 ENVIRONMENTAL SCIENCES↗

Sphingomonas clade and functional distribution with simulated climate change

Microbes are essential for the functioning of all ecosystems, and as global warming and anthropogenic pollution threaten ecosystems, it is critical to understand how microbes respond to these changes. We investigated the climate response of Sphingomonas, a widespread gram-negative bacterial genus, during an 18-month microbial community reciprocal transplant experiment across a Southern California climate gradient. We hypothesized that after 18 months, the transplanted Sphingomonas clade and functional composition would correspond with site conditions and reflect the Sphingomonas composition of native communities. We extracted Sphingomonas sequences from metagenomic data across the gradient and assessed their clade and functional composition. Representatives of at least 12 major Sphingomonas clades were found at varying relative abundances along the climate gradient, and transplanted Sphingomonas clade composition shifted after 18 months. Site had a significant effect (PERMANOVA; P < 0.001) on the distribution of both Sphingomonas functional (R 2 = 0.465) and clade composition (R 2 = 0.400), suggesting that Sphingomonas composition depends on climate parameters. Additionally, for both Sphingomonas clade and functional composition, ordinations revealed that the transplanted communities shifted closer to the native Sphingomonas composition of the grassland site compared with the site they were transplanted into. Overall, our results indicate that climate and substrate collectively determine Sphingomonas clade and functional composition.

59 BASIC BIOLOGICAL SCIENCES↗