Opportunities and challenges of electrochemical water treatment integrated with renewable energy at the water-energy nexus
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Kumar, Arkadeep (ORCID:000000022159267X)↗
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A DATA EFFICIENT SPARSE MODELING FRAMEWORK FOR POWER ESTIMATION IN WATER TREATMENT SENSING OPERATIONS
With increasing freshwater scarcity, advanced process design mechanisms such as Closed-Circuit Reverse Osmosis (CCRO) and Digital/Physical Twin systems are gaining traction in water treatment and reuse operations. While digital and physical twin models enable improved system insight and control, their development is often expensive and computationally intensive, requiring large volumes of synthetic or experimental data to characterize underlying process dynamics. This work introduces a sparse surrogate modeling framework to estimate power consumption from measured flow and pressure variables, along with their nonlinear polynomial and interaction expansions. To ensure model reliability and reduce overfitting, a two-stage pipeline is proposed. First, a dynamic data filtering algorithm is employed to remove uninformative observations and transient operational states. Second, a sparse penalized regression technique is applied to select a minimal set of parsimonious features. The proposed model achieves high sparsity, retaining only 7 out of 34 candidate features (≈79.41% sparsity) while delivering a root mean square error (RMSE) of 0.072 on the test dataset.
Mukherjee, Subrata [ORNL] (ORCID:0000000309930338)↗
Technology for Water Treatment
There are approximately 500,000 water cooling towers in the United States, all of which must be kept clear of "scale" and corrosion and free of pollutants and bacteria. Electron Pure, Ltd. manufactures a hydro cooling tower conditioner as well as an automatic pool sanitizer. The pool sanitizer consists of two copper/silver electrodes placed in a chamber mounted in the pool's recirculation system. The tower conditioner combines the ionization system with a water conditioner, pump, centrifugal solids separator and timer. The system saves water, eliminates algae and operates maintenance and chemical free. The company has over 100 distributors in the U.S. as well as others in 20 foreign countries. The buildup of scale and corrosion is the most costly maintenance problem in cooling tower operation. Jet Propulsion Laboratory successfully developed a non-chemical system that not only curbed scale and corrosion, but also offered advantages in water conservation, cost savings and the elimination of toxic chemical discharge. In the system, ozone is produced by an on-site generator and introduced to the cooling tower water. Organic impurities are oxidized, and the dissolved ozone removes bacteria and scale. National Water Management, a NASA licensee, has installed its ozone advantage systems at some 200 cooling towers. Customers have saved money and eliminated chemical storage and discharge.
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METSiCloPs in Cooling Tower Water, Final Presentation: Water Treatment at FSI [Slides]
Motivation: According to current projections, FSI could require anywhere from 83-288 MGY of water. Reducing excessive dependence on external water supply by making operations as water-lean as possible in the face of water availability fluctuations seasonally. The amount of Silica occurring naturally in New Mexico is several multiples higher than most of the country, with average values of 90 ppm, but reaching as high as 113 ppm. Since its saturation concentration at ambient temperatures is about 150 ppm, this corresponds to cycles of concentration as low as 1-2 for untreated water in cooling towers (i.e., the water is circulated through the towers only once or twice before they are dumped into the outfall), thereby making operations highly water intensive. There is, therefore, there is a strong need and internal motivation to remove Silica from the water that is circulated in the cooling towers.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Machine learning models of intermittent operation of RO wellhead water treatment for salinity reduction and nitrate removal
Machine learning models were developed for intermittent multi-mode operation of a wellhead reverse osmosis water purification and desalination system to predict salt passage, nitrate passage, and permeate flux. The models, based on long short-term memory (LSTM) recurrent neural network (RNN) architecture, included an attention mechanism to increase model performance in proximity of the regulatory limit for nitrate. Training and testing of the models for the Startup, Production, Shutdown and Flushing operational modes were based on operational data (consisting of 22 process variables per data sample) acquired every 2–5 s over a six-month period. The significant sets of model input attributes for the different operational modes were assessed via Spearman ranking correlation, Self-Organizing Map (SOM) analysis and feed forward feature selection (FFFS). Although the variability of nitrate passage, salt passage and permeate flux was significant over the four operational modes, prediction performance for the three outcomes were with R2 and Average Absolute Relative Error (AARE) of 0.78–0.95 and 2.96–6.16 %, respectively. Model updates post membrane elements replacement demonstrated similar levels of prediction accuracy. The study results suggest that there is merit in exploring the utility of multi-mode models for sensor fault detection, data imputation, and for potential use in model-predictive control.
Intermittent RO operation↗
Adapting a drinking water treatment technology for arsenic removal to the context of a small, low-income California community
Not Available
54 ENVIRONMENTAL SCIENCES↗
Utilization of immobilized urease for waste water treatment
The feasibility of using immobilized urease for urea removal from waste water for space system applications is considered, specifically the elimination of the urea toxicity problem in a 30-day Orbiting Frog Otolith (OFO) flight experiment. Because urease catalyzes the hydrolysis of urea to ammonia and carbon dioxide, control of their concentrations within nontoxic limits was also determined. The results of this study led to the use of free urease in lieu of the immobilized urease for controlling urea concentrations. An ion exchange resin was used which reduced the NH3 level by 94% while reducing the sodium ion concentration only 10%.
Husted, R. R.↗
Contaminated water treatment
Method and system for processing of a liquid ("contaminant liquid") containing water and containing urine and/or other contaminants in a two step process. Urine, or a contaminated liquid similar to and/or containing urine and thus having a relatively high salt and urea content is passed through an activated carbon filter to provide a resulting liquid, to remove most of the organic molecules. The resulting liquid is passed through a semipermeable membrane from a membrane first side to a membrane second side, where a fortified drink having a lower water concentration (higher osmotic potential) than the resulting liquid is positioned. Osmotic pressure differential causes the water, but not most of the remaining inorganic (salts) contaminant(s) to pass through the membrane to the fortified drink. Optionally, the resulting liquid is allowed to precipitate additional organic molecules before passage through the membrane.
Gormly, Sherwin J.↗
Produced Water Treatment Technologies: An Overview
Chapter 1 of <em>Solid-Liquid Separation Technologies: Applications for Produced Water.</em> Current and emerging produced water technologies are briefly reviewed. These technologies enable the reuse, safe disposal, and reinjection of produced water..
Gamwo, Isaac↗
Conceptual design of a water treatment system to support a manned Mars colony
The initial tasks addressed by the Prairie View A&M University team were the conceptual design of a breathable-air manufacturing system, a means of drilling for underground water, and a method for storing water for future use. Subsequently, the design objective of the team for the 1987-1988 academic year was the conceptual design of an integrated system for the supply of quality water for biological consumption, farming, residential and industrial use. The source of water for these applications is assumed to be artesian or subsurface. The first step of the project was to establish design criteria and major assumptions. The second step of the effort was to generate a block diagram of the expected treatment system and assign tasks to individual students. The list of processes for water purification and wastewater treatment given above suggests that there will be a need for on-site chemicals manufacturing for ion-exchange regeneration and disinfection. The third step of the project was to establish a basis for the design capacity of the system. A total need of 10,000 gal/day was assumed to be required. It was also assumed that 30,000 gallon raw-water intake volume is needed to produce the desired effluent volume.
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Mars surface-based factory: Computer control of a water treatment system to support a space colony on Mars
In a continued effort to design a surface-based factory on Mars for the production of oxygen and water, the Design Group at Prairie View A&M University made a preliminary study of the surface and atmospheric composition on Mars and determined the mass densities of the various gases in the martian atmosphere. Based on the initial studies, the design group determined oxygen and water to be the two products that could be produced economically under the martian conditions. Studies were also made on present production techniques to obtain water and oxygen. Analyses were made to evaluate the current methods of production that were adaptable to the martian conditions. The detailed report was contained in an Interim Report submitted to NASA/USRA in Aug. of 1986. Even though the initial effort was the production of oxygen and water, we found it necessary to produce some diluted gases that can be mixed with oxygen to constitute 'breathable' air. In Phase 2--Task 1A, the Prairie View A&M University team completed the conceptual design of a breathable-air manufacturing system, a means of drilling for underground water, and storage of water for future use. The design objective of the team for the 1987-1988 academic year was the conceptual design of an integrated system for the supply of quality water for biological consumption, farming, and residential and industrial use. The design has also been completed. Phase 2--Task 1C is the present task for the Prairie View Design Team. This is a continuation of the previous task, and the continuation of this effort is the investigation into the extraction of water from beneath the surface and an alternative method of extraction from ice formations on the surface of Mars if accessible. In addition to investigation of water extraction, a system for computer control of extraction and treatment was developed with emphasis on fully automated control with robotic repair and maintenance. It is expected that oxygen- and water-producing plants on Mars will be limited in the amount of human control that will be available to operate large and/or isolated plants. Therefore, it is imperative that computers be integrated into plant operation with the capability to maintain life support systems and analyze and replace defective parts or systems with no human interface.
Brice, R.↗
Solar-driven evaporators for water treatment: challenges and opportunities
Solar-driven evaporation is an emerging process to acquire freshwater from saline water or wastewater, in which photothermal materials play a crucial role. Additionally, significant effort has been devoted to promoting energy conversion efficiency by material and device design. In the current review, we discuss the major factors affecting evaporator efficiency and long-term performance, including selection of photothermal materials, promotion of evaporation efficiency, and solutions to the problem of scaling. Both the material components and structure will affect the absorption and reflection of the incident light, and the evaporation efficiency can be enhanced by reducing heat loss, enlarging surface area, and recycling latent heat. Scaling can be addressed by tailoring surface properties and structure.
54 ENVIRONMENTAL SCIENCES↗
Intensified Flue Gas Desulfurization Water Treatment for Reuse, Solidification, and Discharge
The goal of this final project report is to summarize the work conducted on project DE-FE0031555. In accordance with the Statement of Project Objectives (SOPO), the University of Kentucky Center for Applied Energy Research (UK CAER) (Recipient) developed a hybrid electrochemical-membrane technology for treating wet flue gas desulfurization (WFGD) blowdown from coal-fired power generation plants that (1) removes government-regulated species and total suspended solids (TSS) via electrocoagulation with solid/liquid separation to avoid further treatments by a biological method specifically for selenium, and (2) reduces total dissolved solids (TDS) in a nanofiltration unit to promote water recycle and reduce freshwater intake. Additional technological configurations were pursued, including (1) nanofiltration combined with zeolite dewatering for a near-zero liquid discharge (ZLD) scenario, and (2) polishing discharge from zeolite dewatering using capacitive deionization (CDI) with 90+% salt rejection to produce water with less than 100ppm TDS for more beneficial use. Project results verified that UK CAER’s hybrid approach addressed the complexities of WFGD blowdown with simplified unit operation at relatively low capital investment by demonstrating: (1) an effective in-situ generated solid sorbent material, green-rust (GR), that specifically removes regulated dissolved species in WFGD blowdown, including selenium, arsenic, and nitrates; (2) a low-cost, high flux nanofiltration treatment that removes both monovalent and divalent species at >80% rejection to adequately provide water recycle and extend the life of FGD equipment by mitigating chloride aided pitting corrosion mechanisms; and (3) a solidification and stabilization process using pozzolanic agents that retain regulated species and satisfy the Resource Conservation and Recovery Act (RCRA) leachate requirements. UK CAER proved electrocoagulation with GR to be an intensified solution for effluent limit guidelines (ELG), and based on preliminary techno-economic analysis (TEA), in comparison to DOE’s Case 1 for Biological Wastewater Treatment that had a purchased equipment cost (PEC) of $\$$5.26 million and a Total plant cost (TPC) of $\$$30.0 million, the EC process had a PEC of $\$$2.67 million and the TPC of $\$$17.0 million. While the electricity consumption for Case 1 was 53 kW, it was 110 kW for the EC process due to dissolving iron for a three-stage reaction design. However, electricity consumption for the EC process could be significantly reduced by adopting a counter-current reactor design for at least a 6-stage chemical reaction operation.
01 COAL, LIGNITE, AND PEAT↗
Mars surface based factory. Phase 2, task 1C: Computer control of a water treatment system to support a space colony on Mars
In a continued effort to design a surface based factory on Mars for the production of oxygen and water, a preliminary study was made of the surface and atmospheric composition on Mars and determined the mass densities of the various gases in the Martian atmosphere. Based on the initial studies, oxygen and water were determined to be the two products that could be produced economically under the Martian conditions. Studies were also made on present production techniques to obtain water and oxygen. Analyses were made to evaluate the current methods of production that were adaptable to the Martian conditions. Even though the initial effort was the production of oxygen and water, it was found necessary to produce some diluted gases that can be mixed with the oxygen produced to constitute 'breathable' air. The conceptual design of a breathable air manufacturing system, a means of drilling for underground water, and storage of water for future use were completed. The design objective was the conceptual design of an integrated system for the supply of quality water for biological consumption, farming, residential and industrial use.
Fuller, John↗
Water Treatment Systems for Long Spaceflights
Space exploration will require new life support systems to support the crew on journeys lasting from a few days to several weeks, or longer. These systems should also be designed to reduce the mass required to keep humans alive in space. Water accounts for about 80 percent of the daily mass intake required to keep a person alive. As a result, recycling water offers a high return on investment for space life support. Water recycling can also increase mission safety by providing an emergency supply of drinking water, where another supply is exhausted or contaminated. These technologies also increase safety by providing a lightweight backup to stored supplies, and they allow astronauts to meet daily drinking water requirements by recycling the water contained in their own urine. They also convert urine into concentrated brine that is biologically stable and nonthreatening, and can be safely stored onboard. This approach eliminates the need to have a dedicated vent to dump urine overboard. These needs are met by a system that provides a contaminant treatment pouch, referred to as a urine cell or contaminant cell, that converts urine or another liquid containing contaminants into a fortified drink, engineered to meet human hydration, electrolyte, and caloric requirements, using a variant of forward osmosis (FO) to draw water from a urine container into the concentrated fortified drink as part of a recycling stage. An activated carbon pretreatment removes most organic molecules. Salinity of the initial liquid mix (urine plus other) is synergistically used to enhance the precipitation of organic molecules so that activated carbon can remove most of the organics. A functional osmotic bag is then used to remove inorganic contaminants. If a contaminant is processed for which the saline content is different than optimal for precipitating organic molecules, the saline content of the liquid should be adjusted toward the optimal value for that contaminant. A first urine treatment method converts urine into a fortified sports drink, resembling Gatorade, using a first urine cell.
FLynn, Michael T.↗
Membrane-Confined Iron Oxychloride Nanocatalysts for Highly Efficient Heterogeneous Fenton Water Treatment
Heterogeneous advanced oxidation processes (AOPs) allow for the destruction of aqueous organic pollutants via oxidation by hydroxyl radicals ( • OH). However, practical treatment scenarios suffer from the low availability of short-lived • OH in aqueous bulk, due to both mass transfer limitations and quenching by water constituents, such as natural organic matter (NOM). In this work, we overcome these challenges by loading iron oxychloride catalysts within the pores of a ceramic ultrafiltration membrane, resulting in an internal heterogeneous Fenton reaction that can degrade organics in complex water matrices with pH up to 6.2. With • OH confined inside the nanopores (~ 20 nm), this membrane reactor completely removed various organic pollutants with water fluxes of up to 100 L m –2 h –1 (equivalent to a retention time of 10 s). This membrane, with a pore size that excludes NOM (>300 kDa), selectively exposed smaller organics to •OH within the pores under confinement and showed excellent resiliency to representative water matrices (simulated surface water and sand filtration effluent samples). Moreover, the membrane exhibited sustained AOPs (>24 h) and could be regenerated for multiple cycles. Our results suggest the feasibility of exploiting ultrafiltration membrane-based AOP platforms for organic pollutant degradation in complex water scenarios.
36 MATERIALS SCIENCE↗
Application of NASA's Advanced Life Support Technologies for Waste Treatment, Water Purification and Recycle, and Food Production in Polar Regions
NASA's advanced life support technologies are being combined with Arctic science and engineering knowledge to address the unique needs of the remote communities of Alaska through the Advanced Life Systems for Extreme Environments (ALSEE) project. ALSEE is a collaborative effort involving NASA, the State of Alaska, the University of Alaska, the North Slope Borough of Alaska, and the National Science Foundation (NSF). The focus is a major issue in the state of Alaska and other areas of the Circumpolar North, the health and welfare of its people, their lives and the subsistence lifestyle in remote communities, economic opportunity, and care for the environment. The project primarily provides treatment and reduction of waste, purification and recycling of water. and production of food. A testbed is being established to demonstrate the technologies which will enable safe, healthy, and autonomous function of remote communities and to establish the base for commercial development of the resulting technology into new industries. The challenge is to implement the technological capabilities in a manner compatible with the social and economic structures of the native communities, the state, and the commercial sector. Additional information is contained in the original extended abstract.
Bubenheim, David L.↗
Water Treatment Systems Make a Big Splash
In the 1960s, NASA's Manned Space Center (now known as Johnson Space Center) and the Garrett Corporation, Air Research Division, conducted a research program to develop a small, lightweight water purifier for the Apollo spacecraft that would require minimal power and would not need to be monitored around-the-clock by astronauts in orbit. The 9-ounce purifier, slightly larger than a cigarette pack and completely chlorine-free, dispensed silver ions into the spacecraft s water supply to successfully kill off bacteria. A NASA Technical Brief released around the time of the research reported that the silver ions did not impart an unpleasant taste to the water. NASA s ingenuity to control microbial contamination in space caught on quickly, opening the doors for safer methods of controlling water pollutants on Earth.
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