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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Spectroscopy of the Kleinmann-Low nebula - Scattering in a solid absorption band

Spectroscopic observations (2.4-3.6 microns) of BN, IRc 2, 3, and 4, and three scattering locations in the KL reflection nebula are reported. A previous report (Knacke et al., 1982) of a 2.97-micron spectral feature in the BN object is not confirmed in the new data. The 2.97-micron feature is observed in sources in the KL nebula, and the spectrum is distorted by a nearby hydrogen line. All the spectra are dominated by absorption along the radiation path, making scattering effects difficult to separate. Scattering could broaden the 3.1-micron interstellar-ice feature, but the effects appear to be small. Except for a long-wavelength wing, the spectra can be modeled reasonably well with core-mantle, silicate-water-ice grains. The wing position and intensity indicate bands of C-H groups of ammonia-ice mixtures.

Knacke, R. F.↗
NASA NTRS1979

Jupiter's atmospheric composition and cloud structure deduced from absorption bands in reflected sunlight

The spectrum of sunlight reflected by Jupiter is analyzed by comparing observations of Woodman (1979) with multiple-scattering computations. The analysis yields information on the vertical cloud structure at several latitudes and on the abundance of CH4 and NH3 in the atmosphere of Jupiter. The abundances of CH4 and NH3 suggest that all ices and rocks are overabundant on Jupiter by a factor of 2 or more, providing an important constraint on models for the formation of Jupiter from the primitive solar nebula. The pressure level of the clouds, the gaseous NH3 abundance, the mean temperature profile, and the Clausius-Clapeyron relation suggest that these clouds are predominantly ammonia crystals with the cloud bottom at 600-700 mb. A diffuse distribution of aerosols exists between 150 and 500 mb, and the spectral variation of albedo reflects a changing bulk absorption coefficient of the material composing the aerosols and is diagnostic of the aerosol composition.

Sato, M.↗
DOE OSTI2024

How Aqueous Solvation Impacts the Frequencies and Intensities of Infrared Absorption Bands in Flavin: The Quest for a Suitable Solvent Model

FTIR spectroscopy accompanied by quantum chemical simulations can reveal important information about molecular structure and intermolecular interactions in the condensed phase. Simulations typically account for the solvent either through cluster quantum mechanical (QM) models, polarizable continuum models (PCM), or hybrid quantum mechanical/molecular mechanical (QM/MM) models. Recently, we studied the effect of aqueous solvent interactions on the vibrational frequencies of lumiflavin, a minimal flavin model, using cluster QM and PCM models. Those models successfully reproduced the relative frequencies of four prominent stretching modes of flavin’s isoalloxazine ring in the diagnostic 1450–1750 cm−1 range but poorly reproduced the relative band intensities. Here, we extend our studies on this system and account for solvation through a series of increasingly sophisticated models. Only by combining elements of QM clusters, QM/MM, and PCM approaches do we obtain an improved agreement with the experiment. The study sheds light more generally on factors that can impact the computed frequencies and intensities of IR bands in solution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1972

Near infrared iron absorption bands: Applications to geologic mapping and mineral exploration

A spectroscopic analysis of the difference in reflectance of iron-rich and iron-poor minerals was made. Attempts were made to use these minima contrast in geological mapping and metallic mineral exploration of large areas from near infrared and visible satellite images. Data cover pertinent laboratory spectroscopic investigations, applications of spectral differences to the discrimination of two important metamorphic rock types, and mineral exploration by aircraft in Beartooth Mountains, Montana.

Rowan, L. C.↗
NASA NTRS1972

Iron-absorption band analysis for the discrimination of iron-rich zones

The author has identified the following significant results. Analysis of ERTS-1 images of Nevada has followed two courses: comparative lineament mapping and spectral reflectance evaluation. The comparative lineament mapping was conducted by mapping lineaments on 9 x 9 inch prints of MSS bands 5 and 7, transferring the data to a base map, and comparing the results with existing geologic maps. The most significant results are that lineaments are more numerous on the band 7 images, and approximately 100 percent more were mapped than appear on existing maps. Geologic significance of these newly mapped lineaments will not be known until they are checked in the field: many are probably faults. Spectral analysis has been limited to visual comparison among the four MSS bands. In general, higher scene contrast is shown in the near infrared bands (6 and 7) than in the visible wavelength bands (4 and 5). The economic implications of these results derive chiefly from the greater efficiency that can be obtained by using near infrared as well as visible wavelength images.

Rowan, L. C.↗
NASA NTRS1973

Iron absorption band analysis for the discrimination of iron rich zones

The author has identified the following significant results. A lineament study of the Nevada test site is near completion. Two base maps (1:500,000) have been prepared, one of band 7 lineaments and the other of band 5 lineaments. In general, more lineaments and more faults are seen on band 5. About 45% of the lineaments appear to be faults and contacts, the others being predominantly streams, roads, railway tracks, and mountain crests. About 25% of the lineaments are unidentified so far. Special attention is being given to unmapped extensions of faults, groups of unmapped lineaments, and known mineralized areas and alteration zones. Earthquake epicenters recorded from 1869 to 1963 have been plotted on the two base maps. Preliminary examination as yet indicates no basic correlation with the lineaments. Attempts are being made to subtract bands optically, using an I2S viewer, an enlarger, and a data color viewer. Success has been limited so far due to technical difficulties, mainly vignetting and poor light sources, within the machines. Some vegetation and rock type differences, however, have been discerned.

Rowan, L. C.↗
NASA NTRS1973

Iron-absorption band analysis for the discrimination of iron-rich zones

The author has identified the following significant results. Lineament analysis of the area was initiated on individual images and then expanded areally by the use of mosaics at the 1:1,000,000 scale. Principal trends are NE, NW, NNE-NNW, and ENE. Several previously unrecognized lineaments are mapped which may be the surface manifestations of major fault or fracture zones. Three lineaments are especially noteworthy. Two of these, the Walker Lane and the Midas Trench lineament system, transect the prediominantly NNE-NNW trending mountain ranges for more than 500 km. A third major lineament, formed by the alinement of several topographic escarpments 10-20 km long, is orthogonal to the Midas Trench lineament. This lineament is marked by a distinct positive magnetic anomaly for approximately 200 km. Further visual analysis of ERTS-1 images has resulted in the delineation of 50 circular or elliptical features which are presumed to be volcanic or intrusive centers. A comparison with the 78 Tertiary volcanic centers mapped in the study area in 1970 indicates some good agreement between the proposed and known volcanic centers. The coincidence of some major lineaments and productive ore bodies implies a genetic relationship.

Rowan, L. C.↗
NASA NTRS1973

Iron-absorption band analysis for the discrimination of iron-rich zones

The author has identified the following significant results. Study has concentrated on the two primary aspects of the project, structural analysis through evaluation of lineaments and circular features and spectral analyses through digital computer-processing techniques. Several previously unrecognized lineaments are mapped which may be the surface manifestations of major fault or fracture zones. Two of these, the Walker Lane and the Midas Trench lineament system, transect the predominantly NNE-NNW-trending moutain ranges for more than 500 km. Correlation of major lineaments with productive mining districts implies a genetic relationship, the 50 circular or elliptical features delineated suggest a related role for Tertiary volcanism. Color-ratio composites have been used to identify limonitic zones and to discriminate mafic and felsic rock by combing diazo color transparencies of three different ratios. EROS Data Center scene identification number for color composite in this report is ER 1 CC 500. Refinement of enhancement procedures for the ratio images is progressing. Fieldwork in coordination with both spectral and structural analyses is underway.

Rowan, L. C.↗
NASA NTRS1974

Iron-absorption band analysis for the discrimination of iron-rich zones

The author has identified the following significant results. Most major rock units and unaltered and altered areas in the study area can be discriminated on the basis of visible and near-infrared spectral reflectivity differences recorded from satellite altitude. These subtle spectral differences are detectable by digital ratioing of the MSS bands and subsequent stretching to increase the contrast to enhance spectral differences. Hydrothermally altered areas appear as anomalous color patches within the volcanic-rock areas. A map has been prepared which can be regarded as an excellent reconnaissance exploration map, for use in targeting areas for more detailed geological, geochemical, and geophysical studies. Mafic and felsic rock types are easily discriminated on the color stretched-ratio composite. The ratioing process minimizes albedo effects, leaving only the recorded characteristic spectral response. The spectra of unaltered rocks appear different from those of altered rocks, which are typically dominated by limonite and clay minerals. It seems clear that differences in spectral shape can provide a basis for discrimination of geologic material, although the relations between visible and near-infrared spectral reflectivity and mineralogical composition are not yet entirely understood.

Rowan, L. C.↗