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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Grain engineering for efficient near-infrared perovskite light-emitting diodes

Metal halide perovskites show promise for next-generation light-emitting diodes, particularly in the near-infrared range, where they outperform organic and quantum-dot counterparts. However, they still fall short of costly III-V semiconductor devices, which achieve external quantum efficiencies above 30% with high brightness. Among several factors, controlling grain growth and nanoscale morphology is crucial for further enhancing device performance. This study presents a grain engineering methodology that combines solvent engineering and heterostructure construction to improve light outcoupling efficiency and defect passivation. Solvent engineering enables precise control over grain size and distribution, increasing light outcoupling to ~40%. Constructing 2D/3D heterostructures with a conjugated cation reduces defect densities and accelerates radiative recombination. The resulting near-infrared perovskite light-emitting diodes achieve a peak external quantum efficiency of 31.4% and demonstrate a maximum brightness of 929 W sr -1 m -2 . These findings indicate that perovskite light-emitting diodes have potential as cost-effective, high-performance near-infrared light sources for practical applications.

42 ENGINEERING↗

Additively Manufactured Tamper Evident Container

Los Alamos National Laboratory has developed a revolutionary and reliable new tamper evident container (TEC) to monitor and protect the health, security, and distribution of high-value assets, technological advancements, products, materials and more that are critical to the operations of businesses and government organizations. Unlike traditional tamper evident seals, the entire TEC serves as a seal, with encrypted on-board electronics able to continuously monitor and log structural health data including but not limited to force, temperature, pressure, humidity, orientation, radiation, acceleration, or vibration as needed. Analog and encrypted digital boards safely stored inside the TEC permanently record the complete integrity history of the protected items and have the ability to alert the TEC owners or take immediate defensive actions should a disruptive or tamper event take place.

36 MATERIALS SCIENCE↗

Radiation-pressure-driven mass loss from quasi-stellar objects.

It is shown that radiation pressure acting on the material in the outer envelopes of QSOs will cause mass outflow unless the mass M of the QSO exceeds a critical value Ms. If the QSOs are at cosmological distances, Ms is on the order of 10 to 100 billion solar masses, and otherwise scales according to intrinsic luminosity. Radiation-pressure-driven mass loss could be responsible for the absorption-line spectra observed in many QSOs. If so, the presence of blueshifted absorption lines in some but not all QSOs indicates that typically M is of the same order as Ms. It is also suggested that under radiative acceleration certain ratios of emission-line to absorption-line redshifts may be preferred as a result of a line-locking mechanism. Inferences are made concerning the magnitude of the gravitational component of the redshift. Possible tests of various aspects of the model are discussed.

Mushotzky, R. F.↗

Mass ejection from the O4f star Zeta Puppis

Profiles of P Cygni lines and displaced absorption lines observed in high-resolution Copernicus UV scans of Zeta Pup from 907 to 1738 A are compared with profile calculations to derive an optical-depth scale of the lines as a function of height or velocity in the expanding envelope. The degrees of ionization of the elements C, N, O, Si, and S under equilibrium conditions at electron temperatures of 20,000 to 1 million K, radiation temperatures of 20,000 to 50,000 K, and electron number densities of 100 million to 1 trillion per cu cm are computed with a dilution factor of 0.1, taking into account collisional ionization by electrons, radiative ionization from the ground state, radiative recombination, and dielectric recombination. Observed and predicted relative ionization fractions are then compared to determine the electron and radiation temperatures. Crude and refined estimates of the mass-loss rate and velocity law are made, and radiative acceleration in the expanding envelope is analyzed. The derived model for Zeta Pup is found to have a mass-loss rate of about 7.2 millionths of a solar mass per year, a wind velocity that increases slowly outward and reaches 700 km/s about 28 solar masses, and a nearly isothermal envelope with an electron temperature of approximately 200,000 K.

Lamers, H. J. G. L. M.↗

Interaction between emission-line filaments and highly energetic explosions in QSOs

The conditions under which QSO line-emitting regions can survive a relativistic explosion are investigated along with the question of whether past and future observations can place constraints on both predicted highly energetic outbursts of ultrarelativistic plasma or LF electromagnetic radiation and the line-emitting gas. Observed properties of QSO emission-line regions are reviewed, and the interaction between a relativistic explosion and a dense cloud is analyzed for the cases of a sudden release of relativistic plasma and an outburst of LF electromagnetic waves. Bremsstrahlung X-ray emission from shocked QSO filaments is calculated, the evolution of dense QSO clouds is examined, and radiative acceleration is excluded as the process responsible for the high bulk velocities of filaments, at least in sources that display energetic outbursts. An alternative mechanism involving highly energetic explosions is proposed.

Marscher, A. P.↗

Comparison of winds in the Small Magellanic Cloud and galactic early-type stars

IUE low-resolution spectra of 11 OB stars in the Small Magellanic Cloud reveal considerably lower wind velocities than corresponding galactic stars. The reduced effectiveness of radiative acceleration due to lower abundances of heavy elements in the SMC is believed to be responsible for this effect. The absorption strengths of the SMC P Cygni profiles are somewhat weaker in Si IV and much weaker in C IV. Crude estimates of relative mass-loss rates suggest that the observed differences may be dominated by the differing relative abundances of Si and C, although a lower degree of wind ionization or lower mass-loss rates for the SMC stars cannot be ruled out.

Bruhweiler, F. C.↗

Radiative Amplification of Acoustic Waves in Hot Stars

The discovery of broad P Cygni profiles in early type stars and the detection of X-rays emitted from the envelopes of these stars made it clear, that a considerable amount of mechanical energy has to be present in massive stars. An attack on the problem, which has proven successful when applied to late type stars is proposed. It is possible that acoustic waves form out of random fluctuations, amplify by absorbing momentum from stellar radiation field, steepen into shock waves and dissipate. A stellar atmosphere was constructed, and sinusoidal small amplitude perturbations of specified Mach number and period at the inner boundary was introduced. The partial differential equations of hydrodynamics and the equations of radiation transfer for grey matter were solved numerically. The equation of motion was augmented by a term which describes the absorption of momentum from the radiation field in the continuum and in lines, including the Doppler effect and allows for the treatment of a large number of lines in the radiative acceleration term.

Wolf, B. E.↗

An X-ray survey of hot white dwarf stars - Evidence for a m(He)/n(H) versus Teff correlation

Observations of 13 white dwarf and subdwarf stars using the Einstein Observatory High Resolution Image are reported. Included are stars of classes DA, DB, DAV, sDO, and sDB, with optically determined effective temperatures in the range 10,000-60,000 K. X-ray emission was detected from two of the 13: the very hot (55,000 K) DA1 star WD 2309 + 105 (= EG 233), with a count rate one-fifth that of HZ 43, and the relatively cool (26,000 K) DA3 star WD 1052 - 273 (=GD 125). The effective temperatures determined from ultraviolet and optical observations were used to place limits on the He content of the white dwarf photospheres, presuming that trace photospheric He is the missing opacity source which quenches the thermal X-rays in these stars. When presently obtained results were combined with those available from the literature evidence was found for a correlation between Teff and n(He)/n(H), in which HZ 43 is a conspicuous exception to the general trend. Both this correlation and the exceptional behavior of HZ 43 are qualitatively accounted for by a radiative acceleration model, in which the rate of upward movement of the He is a function of temperature and surface gravity

Petre, R.↗

The temperature structure in accretion flows onto massive protostars

Radiation transfer problems involved in the infall of dust and gas during star formation are studied. Dust properties are discussed, and modifications of spherical radiative transfer equations are presented that permit forward scattering by dust to be treated for the small size of the star relative to the inner radius of the shell. A procedure for deriving the stellar radiation field incident on the inner edge of the shell is developed. The temperature correction procedure of Cassinelli and Hartmann (1975) for extended stellar atmospheres is modified so that the multitemperature nature of the grains in the cloud may be derived. Temperature distributions for three schematic models in which the density is prespecified are discussed. Radiative acceleration of grains is addressed, showing that the proper mean opacity differs by a large factor from the Rosseland mean opacity that is commonly used. Emergent fluxes for the models are given.

Wolfire, Mark G.↗

Further observations of the peculiar hot helium-rich degenerate KPD 0005 + 5106

KPD 0005 + 5106 observations including high- and low-resolution IUE and Voyager UV spectra, high-resolution spectra at optical wavelengths, and a low-resolution spectrum at red wavelengths are presented. The only detected transitions from a heavier element assignable to the stellar photosphere is the N V 1240 A doublet; hydrogen and some probable CNO ions are also detected in the emission. It is suggested that the detected nitrogen is most likely due to selective radiative acceleration processes.

Downes, Ronald A.↗

An Exosat X-ray observation of one orbital cycle of 4U 1700-37/HD 153919

Exosat observations of close to one complete binary cycle of 4U 1700-37/HD 153919 are presented, and X-ray absorption variations are determined as a function of orbital phase in order to study the properties of the stellar wind of the companion HD 153919. The decrease noted in absorption between eclipse egress and phase 0.5 may be due to X-rays from a neutron star being absorbed by an inner wind with a radial velocity law close to that predicted by Castor et al. (1975). Under the assumption that the X-ray source is powered by material captured from the steller wind, the absorption variations with orbital phase and the time-average luminosity have been modeled to investigate the suppression of the radiative acceleration of the wind via the ionization of the wind by the X-ray source.

Haberl, F.↗

Shock-generated X-ray emission in radiatively driven winds - A model for Tau Scorpii

A one-dimensional radiation-hydrodynamics code is used to numerically investigate the structure and evolution of shocks in the winds of hot stars. Results are presented for the specific case of Tau Sco, a well-studied main-sequence B star for which there are X-ray data from the Einstien satellite's Solid State Spectrometer. A phenomenological radiative acceleration term and a mass-loss rate consistent with UV observations, are used to determine the time dependence of the temperatures within and X-ray emission from an isolated shock region. The driving acceleration leads to the formation of a two-component shock zone with 'forward' and 'reverse' shocks, each with their own characteristic temperature. A denser cold region forms between the two shocks, which could potentially account for the presence of narrow absorption features that are observed in the UV P Cygni profiles of many hot stars. The X-ray emission spectra from the shocks in the calculations are in good general agreement with two-temperature model fits to Einstein X-ray observations.

Macfarlane, Joseph J.↗

A search for evidence of past and ongoing mass loss in the hot DO degenerates PG 1159 - 035, PG 1034 + 001, and KPD 0005 + 5106

The results are reported of a search for evidence of mass loss from three very hot, helium-rich degenerate stars, PG 1034 + 001, PG 1159 - 035, and KPD 0005 + 5106, based upon a search for weak, velocity-displaced line features in high-resolution IUE spectra. The search was entirely negative for PG 1159 - 035 and resulted in the detection of Si IV in PG 1034 + 001 at the same redshifted velocity as the other detected far-ultraviolet resonance doublets. The presence of photospheric silicon in a DO star at 80,000 K is not predicted by current radiative acceleration theory. For KPD 0005 + 5106 there is no convincing far-ultraviolet spectroscopic detection of either past or ongoing mass loss. The high-ionization resonance doublets of C IV, Si IV, and N v share the same velocity broadening as the interstellar lines but are velocity displaced by + 10 km/s relative to the local interstellar medium. Their origin is ascribed to an expanding, photoionized H II region around KPD 0005 + 5106.

Fritz, Matthew L.↗

Hydrodynamic simulations of stellar wind disruption by a compact X-ray source

This paper presents two-dimensional numerical simulations of the gas flow in the orbital plane of a massive X-ray binary system, in which the mass accretion is fueled by a radiation-driven wind from an early-type companion star. These simulations are used to examine the role of the compact object (either a neutron star or a black hole) in disturbing the radiatively accelerating wind of the OB companion, with an emphasis on understanding the origin of the observed soft X-ray photoelectric absorption seen at late orbital phases in these systems. On the basis of these simulations, it is suggested that the phase-dependent photoelectric absorption seen in several of these systems can be explained by dense filaments of compressend gas formed in the nonsteady accreation bow shock and wake of the compact object.

Blondin, John M.↗

The formation of protostellar disks. I - 1 M(solar)

Hydrodynamical calculations of the collapse of an axisymmetric, rotating one solar mass protostellar cloud, including the effects of radiative transfer and radiative acceleration but without magnetic fields, are presented. The results include calculations of infrared protostellar spectra as a function of time and viewing angle. A numerical algorithm involving explicit nested grids is used to resolve the region of initial disk formation and at the same time to include the outer regions in the calculation. The central part of the protostar is modeled approximately. Initial conditions are systematically varied to investigate their influence on the evolution and final configuration of central star plus circumstellar disk. The initial state for the standard case is a centrally condensed molecular cloud core of one solar mass with a mean density of 8 x 10 exp -18 g/cu cm and a specific angular momentum at the outer edge of 7 x 10 exp 20 sq cm/s. The collapse is followed for 8 x 10 exp 4 yr, at which point 0.45 solar mass is contained in a rapidly rotating central object and most of the remainder in a surrounding equilibrium disk. The stability of this final structure is qualitatively analyzed.

Yorke, Harold W.↗

Studies of the gas tori of Titan and Triton

Progress in the development of the model for the circumplanetary distribution of atomic hydrogen in the Saturn system produced by a Titan source is discussed. Because of the action of the solar radiation acceleration and the obliquity of Saturn, the hydrogen distribution is shown to undergo seasonal changes as the planet moves about the Sun. Preliminary model calculations show that for a continuous Titan source, the H distribution is highly asymmetric about the planet and has a density maximum near the dusk side of Saturn, qualitatively similar to the pattern recently deduced by Shemansky and Hall from observations acquired by the UVS instruments aboard the Voyager spacecrafts. The investigation of these Voyager data will be undertaken in the next project year.

Smyth, William H.↗

Nonaxisymmetric evolution in protostellar disks

We present a two-dimensional, multigridded hydrodynamical simulation of the collapse of an axisymmetric, rotating, 1 solar mass protostellar cloud, which forms a resolved, hydrotastic disk. The code includes the effects of physical viscosity, radiative transfer and radiative acceleration but not magnetic fields. We examine how the disk is affected by the inclusion of turbulent viscosity by comparing a viscous simulation with an inviscid model evolved from the same initial conditions, and we derive a disk evolutionary timescale on the order of 300,000 years if alpha = 0.01. Effects arising from non-axisymmetric gravitational instabilities in the protostellar disk are followed with a three-dimensional SPH code, starting from the two-dimensional structure. We find that the disk is prone to a series of spiral instabilities with primary azimulthal mode number m = 1 and m = 2. The torques induced by these nonaxisymmetric structures elicit material transport of angular momentum and mass through the disk, readjusting the surface density profile toward more stable configurations. We present a series of analyses which characterize both the development and the likely source of the instabilities. We speculate that an evolving disk which maintains a minimum Toomre Q-value approximately 1.4 will have a total evolutionary span of several times 10(exp 5) years, comparable to, but somewhat shorter than the evolutionary timescale resulting from viscous turbulence alone. We compare the evolution resulting from nonaxisymmetric instabilities with solutions of a one-dimensional viscous diffusion equation applied to the initial surface density and temperature profile. We find that an effective alpha-value of 0.03 is a good fit to the results of the simulation. However, the effective alpha will depend on the minimum Q in the disk at the time the instability is activated. We argue that the major fraction of the transport characterized by the value of alpha is due to the action of gravitational torques, and does not arise from inherent viscosity within the smoothed particle hydrodynamics method.

Laughlin, Gregory↗