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At least 73 records · Page 4

LMC clusters - Age calibration and age distribution revisited

The empirical age relation for star clusters in the Large Magellanic Cloud presented by Elson and Fall (1985) are reexamined using ages based only on main-sequence turnoffs. The present sample includes 57 clusters, 24 of which have color-magnitude diagrams published since 1985. The new calibration is very similar to that found previously, and the scatter in the relation corresponds to uncertainties of about a factor of 2 in age. The age distribution derived from the new calibration does not differ significantly from that derived in earlier work. It is compared with age distributions estimated by other authors for different samples of clusters, and the results are discussed.

Elson, Rebecca A.↗

Aging and mixing as pseudo-chemical-reactions between, and on, particles: Perspectives on particle interaction and multi-modal ages in hillslopes and streams

The particle-tracking method was recently extended to allow inter-particle mass transfer and arbitrarily complex reactions by allowing each particle to represent any number of distinct chemical compounds. This methodology allows the tracking (and broadening due to mixing) of the age probability density function (PDF) on each particle. Aquifer heterogeneity leads to channeling and multi-modal age PDFs in stream samples. This observation supports the concept of age classes but clearly shows the more complicated interplay of dispersion, mixing, and travel times on the age distributions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mechanical and Chemical Properties of Harvested Hypalon Cable Jacket Subjected to Accelerated Thermal Aging

For nuclear power plants (NPPs) that are considering second license renewal for their operation beyond 60 years, knowledge of long-term operation, condition monitoring, and viability for the reactor components including reactor pressure vessel, concrete structures, and cable systems is essential. Such knowledge will provide NPPs with a game plan to predict performance and to estimate costs that are associated with monitoring or replacement programs for the affected systems. For cable systems that encompass a wide variety of materials, manufacturers, and in-plant location, accelerated aging of harvested cable jacket and insulation can provide insight as to remaining useful life and methods for monitoring. Accelerated thermal aging in air at temperatures between 80°C and 120°C was carried out on a multi-conductor control rod cable that had been in-service for over 30 years and was made by Boston Insulated Wire with Hypalon cable jacket and ethylene-propylene rubber insulation. From elongation at break (EAB) measurements and supporting Arrhenius analysis of the jacket material, an activation energy of 97.84 kJ/mol was estimated and the time to degradation, as represented by 50% EAB at the expected maximum operating temperature of 45°C, was estimated as consistent with 80 years. These values were slightly below previous measurements and could either be attributed to in-service degradation or variations in material properties from a given manufacturer. In addition, results from indenter modulus measurements and Fourier transform infrared spectroscopy suggest possible markers that could be beneficial to monitor cable conditions.

cable aging, cable insulation, Hypalon, second lic↗

Investigating the role of adipose tissue in mobility and aging: design and methods of the Adipose Tissue ancillary to the Study of Muscle, Mobility, and Aging (SOMMA-AT)

Background Age-related changes in adipose tissue affect chronic medical diseases and mobility disability but mechanism remains poorly understood. The goal of this study is to define methods for phenotyping unique characteristics of adipose tissue from older adults. Methods Older adults enrolled in study of muscle, mobility, and aging selected for the adipose tissue ancillary (SOMMA-AT; N = 210, 52.38% women, 76.12 ± 4.37 years) were assessed for regional adiposity by whole-body magnetic resonance (AMRA) and underwent a needle-aspiration biopsy of abdominal subcutaneous adipose tissue (ASAT). ASAT biopsies were flash frozen, fixed, or processed for downstream applications and deposited at the biorepository. Biopsy yields, qualitative features, adipocyte sizes, and concentration of adipokines secreted in ASAT explant conditioned media were measured. Inter-measure Spearman correlations were determined. Results Regional, but not total, adiposity differed by sex: women had greater ASAT mass (8.20 ± 2.73 kg, p < .001) and biopsy yield (3.44 ± 1.81 g, p < .001) than men (ASAT = 5.95 ± 2.30 kg, biopsy = 2.30 ± 1.40 g). ASAT mass correlated with leptin (r = 0.54, p < .001) and not resistin (p = .248) and adiponectin (p = .353). Adipocyte area correlated with ASAT mass (r = 0.34, p < .001), BMI (r = 0.33, p < .001), adiponectin (r = −0.22, p = .005) and leptin (r = 0.18, p = .024) but not with resistin (p = .490). Conclusion In addition to the detailed ASAT biopsy processing in this report, we found that adipocyte area correlated with ASAT mass, and both measures related to some key adipokines in the explant conditioned media. In conclusion, these results, methods, and biological repositories underscore the potential of this unique cohort to impact the understanding of aging adipose biology on disease, disability, and other aging tissues.

60 APPLIED LIFE SCIENCES↗

Non-Destructive Evaluation of Polyolefin Thermal Aging Using Infrared Spectroscopy

Fourier transform infrared (FTIR) spectroscopy is an information-rich method that reveals chemical bonding near the surface of polymer composites. FTIR can be used to verify composite composition, identify chemical contaminants and expose composite moisture content. Polymer matrix changes due to thermal exposure including loss of additives, chain scission, oxidation and changes in crystallinity may also be determined using FTIR spectra. Portable handheld instruments using non-contact reflectance or surface contact attenuated total reflectance (ATR) may be used for non-destructive evaluation (NDE) of thermal aging in polymer and composite materials of in-service components. We report the use of ATR FTIR to track oxidative thermal aging in ethylene-propylene rubber (EPR) and chlorinated polyethylene (CPE) materials used in medium voltage nuclear power plant electrical cable insulation and jacketing. Mechanical property changes of the EPR and CPE materials with thermal degradation for correlation with FTIR data are tracked using indenter modulus (IM) testing. IM is often used as a local NDE metric of cable jacket health. The FTIR-determined carbonyl index was found to increase with IM and may be a valuable NDE metric with advantages over IM for assessing cable remaining useful life.

aging↗

Precipitation-site competition in duplex stainless steels: Cu clusters vs spinodal decomposition interfaces as nucleation sites during thermal aging

Competing microstructural evolution mechanisms can exist simultaneously when duplex stainless steels are operating for several decades in a high temperature service environment. Such competition between different microstructural evolution pathways can be difficult to ascertain using simple model alloy systems necessitating detailed structural and compositional analysis of phase transformation mechanisms in complex alloys Thus, in this study duplex stainless steels with complex but well understood chemistries were used to investigate the relative importance of different heterogeneous nucleation sites – specifically spinodal decomposition and Cu clustering – on precipitation of Ni-Si-Mn particles during long term thermal aging. Precipitation of Ni-Si-Mn particles in duplex stainless steels and ferritic steels during thermal aging and irradiation is known to have profound effect on mechanical properties. Using duplex stainless steels with custom modified compositions along with atom probe tomography characterization and first-passage kinetic Monte Carlo (FPKMC) simulations it is revealed that while the interface between Cr and Fe formed during spinodal decomposition can be a pathway for diffusion of Ni, Si, Mn, and Cu, it is not a site that encourages precipitation of Ni-Si-Mn rich particles. Instead, the presence of a higher concentration of Cu in these steels leads to formation of small Cu clusters with high energy interfaces that act as nucleation sites for Ni-Si-Mn particles because of its strong interaction particularly with Ni increasing the chemical driving force for precipitation. These results will help inform predictive models for the use of duplex stainless steels and other precipitation-hardened alloys for extended operation at high temperatures.

Duplex stainless steel, Thermal aging, Precipitati↗

Effects of long-term thermal aging on bulk and local mechanical behavior of ferritic-austenitic duplex stainless steels

Ferritic-austenitic duplex stainless steels (DSS) undergo significant thermal aging embrittlement in service in light water reactors. Specimens of cast CF–3 and CF–8 DSS have been laboratory aged for up to 17,200 h at four different temperatures (280, 320, 360, 400 °C) in order to characterize the aging evolution and mechanical properties. Standard Charpy V-Notch (CVN) impact testing and tensile testing are employed to measure the progression of embrittlement of the steels. Concurrently, nanoindentation measurements are performed to measure the hardening of the individual ferrite and austenite phases. Atom probe tomography (APT) analysis of the ferrite and austenite phases elucidates the relationship between spinodal decomposition of the ferrite and the mechanical effects of aging. The results are discussed to relate the effects of the local microstructure and property changes in the ferrite phase on the overall bulk mechanical evolution of these steels.

Schwarm, Samuel C.↗

A direct measurement of the forward shock speed in supernova remnant 0509–67.5: Constraints on the age, ambient density, shock compression factor, and electron–ion temperature equilibration

Two Hubble Space Telescope narrow-band Hα images separated in time by 1.03 years are used for a proper motion measurement of the forward shock of the LMC supernova remnant 0509–67.5, the only spectroscopically confirmed LMC remnant of Ia origin. We measure a global shock speed of 6500 ± 200 km s{sup −1} and constrain the pre-shock neutral hydrogen density to be 0.084 ± 0.003 cm{sup −3}, for a typical mean number of Hα photons produced per neutral hydrogen atom entering the forward shock. Previously published broad Hα line widths from two locations on the rim and our corresponding shock speed measurements are consistent with Balmer shock models that do not include effects of cosmic-ray acceleration. For the northeastern rim location, we limit the post-shock electron temperature to 10% of the proton temperature by also using the broad-to-narrow flux ratio. Hydrodynamic simulations for different initial ejecta density profiles constrain the age and ambient medium density; for an exponential ejecta profile and initial explosion energy of 1.4 × 10{sup 51} erg, the remnant’s age is 310{sub −30}{sup +40} years. For all evolutionary models explored, the expansion parameter falls in the range of 0.41–0.73, indicating that the remnant is still firmly in the ejecta-dominated phase of its evolution. Our measured neutral hydrogen density of the ambient medium, combined with the shocked density obtained in Williams et al., disfavors forward shock compression factors greater than ∼7.

79 ASTRONOMY AND ASTROPHYSICS↗

The ages of A-stars. I. Interferometric observations and age estimates for stars in the Ursa major moving group

We have observed and spatially resolved a set of seven A-type stars in the nearby Ursa Major moving group with the Classic, CLIMB, and PAVO beam combiners on the Center for High Angular Resolution Astronomy Array. At least four of these stars have large rotational velocities (vsini ≳ 170 km s{sup −1}) and are expected to be oblate. These interferometric measurements, the stars’ observed photometric energy distributions, and vsini values are used to computationally construct model oblate stars from which stellar properties (inclination, rotational velocity, and the radius and effective temperature as a function of latitude, etc.) are determined. The results are compared with MESA stellar evolution models to determine masses and ages. The value of this new technique is that it enables the estimation of the fundamental properties of rapidly rotating stars without the need to fully image the star. It can thus be applied to stars with sizes comparable to the interferometric resolution limit as opposed to those that are several times larger than the limit. Under the assumption of coevality, the spread in ages can be used as a test of both the prescription presented here and the MESA evolutionary code for rapidly rotating stars. With our validated technique, we combine these age estimates and determine the age of the moving group to be 414 ± 23 Myr, which is consistent with, but much more precise than previous estimates.

79 ASTRONOMY AND ASTROPHYSICS↗

Coastal songbird condition on migratory stopover varies by geographical location and bird age

Abstract The period of migration can pose significant energetic challenges as birds attempt to reach their destinations. Suitable stopover habitat is, therefore, important to the success of migrating individuals, especially as they move along major migration corridors and geographic features, like coastlines. In this study, we used metrics of individual body condition (i.e. fat score, size-corrected body mass, and refueling rate) of fall migrants as they moved across the Gulf of Maine region, a complex coastal landscape. We investigated the extent to which these body condition indices varied by stopover site geography (island vs. mainland) and how these spatial patterns varied with species-specific characteristics such as migratory distance, foraging guild, and age. Geography was an important factor explaining variation in all 3 condition indices, and age explained additional variance in 2 of the 3. In general, individuals captured on islands exhibited significantly lower energetic condition than individuals on the mainland, and this pattern held true across all migratory strategies and foraging guilds. Immature individuals had, on average, lower energy reserves, with less fat and lower size-corrected mass than adults among all stopover sites. We also found that at all sites, size-corrected body mass, on average, significantly increased over the capture day, providing evidence that both island and mainland sites provided energetically beneficial stopover habitat. Our finding that birds offshore are in lower body condition at capture than those along the coast is suggestive that birds use mainland sites for longer stopover bouts than island sites, or that poorer condition birds reorient to land during over-water movements disproportionately use off-shore islands as their initial landing area. Decreases in either island or mainland stopover site availability or quality may affect individual fitness, with population-level consequences, but through different ways.

Zoology↗

Ageing and quenching through the Ageing Diagram – II. Physical characterization of galaxies

The connection between quenching mechanisms, which rapidly turn star-forming systems into quiescent, and the properties of the galaxy population remains difficult to discern. In this work we investigate the physical properties of MaNGA and SAMI galaxies at different stages of their star formation history. Specifically, we compare galaxies with signatures of recent quenching (Quenched) – Hα in absorption and low D n (4000) – with the rest of the low star-forming and active population (Retired and Ageing, respectively). The analysis is performed in terms of characteristics such as the total stellar mass, half-light radius, velocity-to-dispersion ratio, metallicity, and environment. We find that the Ageing population comprises a heterogeneous mixture of galaxies, preferentially late-type systems, with diverse physical properties. Retired galaxies, formerly Ageing or Quenched systems, are dominated by early-type high-mass galaxies found both at low and dense environments. Most importantly, we find that recently quenched galaxies are consistent with a population of compact low-mass satellite systems, with higher metallicities than their Ageing analogues. We argue that this is compatible with being quenched after undergoing a star-burst phase induced by environmental processes (e.g. ram pressure). However, we also detect a non-negligible fraction of field central galaxies likely quenched by internal processes. This study highlights that, in order to constrain the mechanisms driving galaxy evolution, it is crucial to distinguish between old (Retired) and recently quenched galaxies, thus requiring at least two estimates of the specific star formation rate over different time-scales.

79 ASTRONOMY AND ASTROPHYSICS↗

Ages of intermediate-age Magellanic Cloud star clusters

Ages of intermediate-age Large Magellanic Cloud star clusters have been estimated without locating the faint, unevolved portion of cluster main sequences. Six clusters with established color-magnitude diagrams were selected for study: SL 868, NGC 1783, NGC 1868, NGC 2121, NGC 2209, and NGC 2231. Since red giant photometry is more accurate than the necessarily fainter main-sequence photometry, the distributions of red giants on the cluster color-magnitude diagrams were compared to a grid of 33 stellar evolutionary tracks, evolved from the main sequence through core-helium exhaustion, spanning the expected mass and metallicity range for Magellanic Cloud cluster red giants. The time-dependent behavior of the luminosity of the model red giants was used to estimate cluster ages from the observed cluster red giant luminosities. Except for the possibility of SL 868 being an old globular cluster, all clusters studied were found to have ages less than 10 to the 9th yr. It is concluded that there is currently no substantial evidence for a major cluster population of large, populous clusters greater than 10 to the 9th yr old in the Large Magellanic Cloud.

Flower, P. J.↗

The Shergottite Age Paradox and the Relative Probabilities of Ejecting Martian Meteorites of Differing Ages

The apparent paradox that the majority of impacts yielding Martian meteorites appear to have taken place on only a few percent of the Martian surface can be resolved if all the shergottites were ejected in a single event rather than in multiple events as expected from variations in their cosmic ray exposure and crystallization ages. If the shergottite-ejection event is assigned to one of three craters in the vicinity of Olympus Mons that were previously identified as candidate source craters for the SNC (Shergottites, Nakhlites, Chassigny) meteorites, and the nakhlite event to another candidate crater in the vicinity of Ceraunius Tholus, the implied ages of the surrounding terranes agree well with crater density ages. EN,en for high cratering rates (minimum ages), the likely origin of the shergottites is in the Tharsis region, and the paradox of too many meteorites from too little terrane remains for multiple shergottite-ejection events. However, for high cratering rates it is possible to consider sources for the nakhlltes which are away from the Tharsis region. The meteorite-yielding impacts may have been widely dispersed with sources of the young SNC meteorites in the northern plains, and the source of the ancient orthopyroxenite, ALH84001, in the ancient southern uplands. Oblique-impact craters can be identified with the sources of the nakhlites and the orthopyroxenite,, respectively, in the nominal cratering rate model, and with the shergottites and orthopyroxenite, respectively, in the high cratering rate model. Thus, oblique impacts deserve renewed attention as an ejection mechanism for Martian meteorites.

Borg, L. E.↗

Radiometric Ages of Martian Meteorites compared to Martian Surfaces Ages

The surprisingly young Rb-Sr age of the Shergotty meteorite contributed to early suggestions that it might be of martian origin. their redox state and oxygen isotopic compositions linked the shergottites to the clino-pyroxenite nakhlites and the dunite Chassigny, causing them to be grouped as SNC meteorites. These characteristics, but especially the similarity of the elemental and isotopic compositions of gases trapped in shergottites to those of the martian atmosphere, have caused the martian origin of the SNC and related meteorites to be widely accepted. Although the young ages were one of the early hints of a martian origin for the SNC meteorites, their interpretation has remained somewhat ambiguous. We will review the radiometric ages of the martian meteorites and attempt to place them into the context of martian surface ages.

Nyquist, L. E.↗

Effect of boron and carbon addition on microstructure and mechanical properties of the aged gamma-prime strengthened alumina-forming austenitic alloys [Effect of boron and carbon addition on microstructure and mechanical properties of the aged gamma-prime alumina-forming austenitic alloys]

Here, the goal of this work was to understand the effects of aging at 800 °C on the microstructures and mechanical properties of two recently-developed AFA stainless steels based on Fe-14Cr-32Ni-3Nb-3Al-2Ti (wt.%), one of which contained small additions of boron and carbon. To that end both the size distributions and growth kinetics of the B2, Laves phase, L1 2 precipitates present were quantified. While the lattice parameter, morphology, size and coarsening behavior of the L1 2 precipitates was the same in both AFA alloys, the B and C enhanced the grain boundary coverage by both Laves phase and B2-NiAl precipitates, but suppressed their coarsening. These interstitial additions also suppressed the formation of twins and discontinuous precipitation, which were observed in the B and C-free material. It is shown that the yield strength at 700 °C is largely controlled by the size of the L1 2 precipitates, with the largest strengthening effect obtained after aging for 2.4 h for both AFA alloys. Longer aging time led to a loss of strength mainly due to the coarsening of the L1 2 precipitates.

36 MATERIALS SCIENCE↗