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At least 73 records · Page 4

Age of Allan Hills 82102, a meteorite found inside the ice

The terrestrial age of a meteorite that was recovered from below the surface of Antarctic ice is reported, and it is argued that this represents a measurement of the age of the ice itself. The cosmogenic radionuclides Be-10, C-14, Al-26, Cl-36, and Mn-53 are measured in the meteorite and Be-10 and Cl-36 in the ice. A terrestrial age of 11,000 yr is obtained for the meteorite, which suggests that the snow accumulation area where it fell was only a few tens of km away.

Nishiizumi, K.↗

An improved offset generator developed for Allan deviation measurement of ultra stable frequency standards

Measuring the performance of ultra stable frequency standards such as the Superconducting Cavity Maser Oscillator (SCMO) necessitates improvement of some test instrumentation. The frequency stability test equipment used at JPL includes a 1 Hz Offset Generator to generate a beat frequency between a pair of 100 MHz signals that are being compared. The noise floor of the measurement system using the current Offset Generator is adequate to characterize stability of hydrogen masers, but it is not adequate for the SCMO. A new Offset Generator with improved stability was designed and tested at JPL. With this Offset Generator and a new Zero Crossing Detector, recently developed at JPL, the measurement flow was reduced by a factor of 5.5 at 1 second tau, 3.0 at 1000 seconds, and 9.4 at 10,000 seconds, compared against the previous design. In addition to the new circuit designs of the Offset Generator and Zero Crossing Detector, tighter control of the measurement equipment environment was required to achieve this improvement. The design of this new Offset Generator are described, along with details of the environment control methods used.

R. L. Hamell↗

Rubidium-Strontium Formation Age of Allan Hills 84001 Carbonates

Our preferred age for the formation of carbonates in the martian meteorite ALH 84001 is 3.90 plus or minus 0.04 Ga for Lambda (Rubidium 87) equals 0.01402 Ga (exp -1), or 3.85 plus or minus 0.04 Ga for Lambda (Rubidium 87) = 0.0142 Ga(exponent -1). This age is determined by a three-point Rb-Sr isochron defined by leachates of high-graded carbonate-rich material. Major cation and especially phosphorous analyses of the leachates permit contributions from igneous whitlockite to be recognized for low-acidity leachates, and the corresponding data are omitted from the isochron. Data for the two highest acidity leachates plot close to the preferred isochron, but are omitted because we believe they contain contributions leached from the pyroxene substrate on which most of the carbonates are found. Nevertheless, the isochron age for all five highest-acidity leachates is 3.94 plus or minus 0.04 Ga, and is within error of the age obtained for the more restricted data set. All leachates used to define the isochron have major cation compositions that are singular to those obtained by microprobe analyses of the carbonate rosettes and are consistent with progressive digestion of the carbonates according to their composition. The age thus obtained for the carbonates is about 600 m.y. younger than the crystalization age of ALH 84001 determined by Sm-Nd analyses but is within error limits of the age of impact metamorphism inferred from the Rb-Sr and Ar-Ar systematics of silicates. which yield ages of 3.85 plus or minus 0.05 Ga and 4.05- 3.80 Ga to 4.3-3.8 Ga, respectively. Similarities between the carbonate crystallization age and the age of impact metamorphism as determined by Ar-Ar and Rb-Sr suggest that the carbonate formation is impact-related. Nevertheless, both high and low- temperature scenarios for the origin of the carbonates are possible.

Borg, L. E.↗

Rare Potassium-Bearing Mica in Allan Hills 84001: Additional Constraints on Carbonate Formation

There have been presented several intriguing observations suggesting evidence of fossil life in martian orthopyroxenite ALH 84001. These exciting and controversial observations have stimulated extensive debate over the origin and history of ALH 84001, but many issues still remain unresolved. Among the most important is the question of the temperature at which the carbonates, which host the putative microfossils, formed. Oxygen- isotopic data, while showing that the carbonates are generally out of isotopic equilibria with the host rock, cannot constrain their temperature of formation. Both low- and high-temperature scenarios are plausible depending on whether carbonate growth occurred in an open or closed system. Petrographic arguments have generally been used to support a high-temperature origin but these appear to be suspect because they assume equilibrium between carbonate compositions that are not in contact. Some observations appear to be consistent with shock mobilization and growth from immiscible silicate-carbonate melts at high temperatures. Proponents of a low-temperature origin for the carbonates are hampered by the fact that there is currently no evidence of hydrous phases that would indicate low temperatures and the presence of a hydrous fluid during the formation of the carbonates. However, the absence of hydrous phases does not rule out carbonate formation at low temperatures, because the carbonate forming fluids may have been extremely CO2 rich, such that hydrous phases would not have been stabilized. In this study, I have carried out additional Transmission electron microscopy (TEM) studies of ALH-84001 and have found evidence of very rare phyllosilicates, which appear to be convincingly of pre-terrestrial origin. At present these observations are limited to one occurrence: further studies are in progress to determine if the phyllosilicates are more widespread.

Brearley, A. J.↗

How do the Properties of Allan Hills 84001 Compare With Accepted Criteria for Evidence of Ancient Life?

Criteria for Past Life: To be confident that any sample contains evidence of past life or biogenic activity, one must determine beyond a shadow of a doubt that certain well-established features or biomarker signatures are present in the sample. In the case of martian samples, the criteria for past life have not been established because if life existed on the planet, we have no way of knowing its detailed characteristics. Lacking independent evidence about the nature of possible past life on Mars, the scientific community must use, for the time being, the criteria established for ancient samples from the Earth: (1) Do we know the geologic context of the sample? Is it compatible with past life? (2) Do we know the age of the sample and its stratigraphic location? Are they understood enough to relate possible life to geologic history? (3) Does the sample contain evidence of cellular morphology? (4) What structural remains of colonies or communities exist within the samples? (5) Is there any evidence of biominerals showing chemical or mineral disequilibria? (6) Is there any evidence of stable isotope patterns unique to biology? (7) Are there any organic biomarkers present? (8) Are the features indigenous to the sample? For acceptance of past life in a geologic sample, essentially all of these criteria must he met.

Gibson, E. K., Jr.↗

Mineral Biomarkers in Martian Meteorite Allan Hills 84001?

The occurrence of fine-grained magnetite in the Fe-rich rims surrounding carbonate globules in the martian meteorite ALH84001, originally described in , have been proposed as fossil remains of primitive martian organisms. Here we report observations on size and shape distributions of magnetites from ALH84001 and compare them to biogenic and inorganic magnetite crystals of terrestrial origin. While some magnetite morphology is not unequivocally diagnostic for its biogenicity, such as cubodial forms of magnetite, which are common in inorganically formed magnetites, other morphologies of magnetite (parallel-epiped or elongated prismatic and arrowhead forms) are more likely signatures of biogenic activity. Some ALH 84001 magnetite particles described below have unique morphology and length-to-width ratios that are indistinguishable from a variety of terrestrial biogenic magnetite and distinct from all known inorganic forms of magnetite.

Thomas-Keprta, K. L.↗

Mineralization of Bacteria in Terrestrial Basaltic Rocks: Comparison With Possible Biogenic Features in Martian Meteorite Allan Hills 84001

The identification of biogenic features altered by diagenesis or mineralization is important in determining whether specific features in terrestrial rocks and in meteorites may have a biogenic origin. Unfortunately, few studies have addressed the formation of biogenic features in igneous rocks, which may be important to these phenomena, including the controversy over possible biogenic features in basaltic martian meteorite ALH84001. To explore the presence of biogenic features in igneous rocks, we examined microcosms growing in basaltic small-scale experimental growth chambers or microcosms. Microbial communities were harvested from aquifers of the Columbia River Basalt (CRB) group and grown in a microcosm containing unweathered basalt chips and groundwater (technique described in. These microcosms simulated natural growth conditions in the deep subsurface of the CRB, which should be a good terrestrial analog for any putative martian subsurface ecosystem that may have once included ALH84001. Here we present new size measurements and photomicrographs comparing the putative martian fossils to biogenic material in the CRB microcosms. The range of size and shapes of the biogenic features on the CRB microcosm chips overlaps with and is similar to those on ALH84001 chips. Although this present work does not provide evidence for the biogenicity of ALH84001 features, we believe that, based on criteria of size, shape, and general morphology, a biogenic interpretation for the ALH84001 features remains plausible.

Thomas-Keprta, K. L.↗

Alteration Products and Secondary Minerals in Martian Meteorite Allan Hills 84001

The martian meteorites contain alteration products and secondary minerals that are a critical part of understanding their near-surface histories on both Mars and Earth. In some martian meteorites, suspected martian preterrestrial alteration products can be distinguished from terrestrial weathering effects Using scanning electron microscopy (SEM), field emission SEM (FE-SEM), transmission electron microscopy (TEM), and energy-dispersive X-ray analysis (EDS), we are studying natural fracture surfaces of ALH 84001 chips, including samples from both the interior and the exterior of the meteorite. Exterior samples include fusion crust surfaces, which are important in determining the extent of terrestrial weathering of meteorites. The focus of this study is weathering features and secondary minerals other than the distinctive carbonate globules that continue to be studied by many researchers.

Wentworth, S. J.↗

Evidence for a Second Generation of Magnesite in Martian Meteorite Allan Hills 84001

Single-stage formation mechanisms for carbonate and other secondary minerals in ALH84001 are rapidly being revised to include multiple stages of carbonate growth and later thermal and mechanical events including alteration. In an effort to confirm some of these more complex histories we have been studying carbonate-bearing regions within this meteorite. Magnesitic carbonates found in contact with unique 'slab' carbonates in two thin sections of ALH84001 show indications of being of a later generation. The results of our observations help clarify the origins of the carbonate and related minerals in ALH84001, and how these minerals can be used to understand the history of interactions between the martian crust and its volatile inventory.

Corrigan, C. M.↗

Eleven new meteorites from Antarctica, 1976-1977

Basic petrographic, mineralogic, and chemical descriptions are given for all eleven meteorites recovered by the U.S.-Japan team in Antarctica during the austral summer 1976-1977. The meteorites are: Mt. Baldr a (H6), Mt. Baldr b (H6), Allan Hills 1 (L6), Allan Hills 2 (coarsest octahedrite, chemical group IA), Allan Hills 3 (L6), Allan Hills 4 (LL3), Allan Hills 5 (eucrite), Allan Hills 6 (H6), Allan Hills 7 (L6), Allan Hills 8 (H6), and Allan Hills 9 (L6).

Olsen, E. J.↗

Terrestrial Ages of Antarctic Meteorites- Update 1999

We are continuing our ongoing study of cosmogenic nuclides in Antarctic meteorites. In addition to the studies of exposure histories of meteorites, we study terrestrial ages and pairing of Antarctic meteorites and desert meteorites. Terrestrial ages of Antarctic meteorites provide information on meteorite accumulation mechanisms, mean weathering lifetimes, and influx rates. The determination of Cl-36(half-life=3.01 x 10(exp 5) y) terrestrial ages is one of our long-term on-going projects, however, in many instances neither Cl-36 or C-14 (5,730 y) yields an accurate terrestrial age. Using Ca-14 (1.04 x 10(exp 5) y) for terrestrial age determinations solves this problem by filling the c,ap in half-life between 14-C and Cl-36 ages. We are now applying the new Ca-41- Cl-36 terrestrial age method as well as the Cl-36-Be-10 method to Antarctic meteorites. Our measurements and C-14 terrestrial age determinations by the University of Arizona group are always complementary. We have measured Cl-36 in over 270 Antarctic meteorites since our previous compilation of terrestrial ages. Since a large number of meteorites have been recovered from many different icefields in Antarctica, we continue to survey the trends of terrestrial ages for different icefields. We have also measured detailed terrestrial ages vs. sample locations for Allan Hills, Elephant Moraine, and Lewis Cliff Icefields, where meteorites have been found with very long ages. The updated histograms of terrestrial ages of meteorites from the Allan Hills Main Icefield and Lewis Cliff Icefield are shown. These figures include C-14 ages obtained by the University of Arizona group. Pairs of meteorites are shown as one object for which the age is the average of all members of the same fall. The width of the bars represents 70,000 years, which was a typical uncertainty for Cl-36 ages. We reduced the uncertainty of terrestrial age determinations to approx. 40,000 years by using pairs of nuclides such as Ca-41-Cl-36 or Cl-36-Be-10. Meteorites found at the Allan Hills Icefields are much older than any other meteorites. The terrestrial ages cover a wide range and are as old as 2 My. Many of the Lewis Cliff meteorites are as old as the Allan Hills meteorites. So far, no clear correlation has been found between the terrestrial ages and the locations of the Lewis Cliff meteorites.

Nishiizumi, Kunihiko↗

Chemical and physical studies of type 3 chondrites. II Thermoluminescence of sixteen type 3 ordinary chondrites and relationships with oxygen isotopes

Thermoluminescence (TL) sensitivity values for sixteen type 3 ordinary chondrites, fourteen of them from Antarctica, have been measured. The values obtained (normalized to the TL sensitivity of the Dhajala meteorite) range from 1.6 (Allan Hills A77216) to 0.010 (Allan Hills A77176), and include two (Reckling Peak A80207 and Allan Hills A77176) that are particularly low. They fill a hiatus in the TL distribution that previously existed between St. Mary's County and Bishunpur, the latter being a meteorite with one of the lowest TL sensitivities known. The histogram of TL sensitivity values now shows a single distribution with higher values preferred; it resembles the histogram for L chondrites occupying the petrologic types 3, 4, 5, and 6. There is a tendency for the TL sensitivity of meteorites to decrease as delta O-18 increases. Theoretically, it is possible that the range of delta O-18 values observed may reflect progressive loss of O in the form of CO at very low temperatures, but very restrictive physical conditions and a complex history seem to be required.

Sears, D. W. G.↗

Terrestrial Kr-81-Kr ages of Antarctic meteorites

The production rate of Ar-38 in meteorites P(38), has been determined, as a function of the sample's chemical composition, from Kr-81-Kr exposure ages of four eucrite falls. The cosmogenic Kr-78/Kr-83 ratio is used to estimate the shielding dependence of P(38). From the 'true' Ar-38 exposure ages and the apparent Kr-81-Kr exposure ages of nine Antarctic eucrite finds, terrestrial ages are calculated. They range from about 300,000 ages (Pecora Escarpment 82502) to very recent falls (Thiel Mountains 82502). Polymict eucrites from the Allan Hills (A78132, A79017, and A81009) have within the limits of error the same exposure age (15.2 x 10 to the 6th ages) and the same terrestrial age (110,000 ages). This is taken as strong evidence that these meteorites are fragments of the same fall. A similar case is the Elephant Moraine polymict eucrites A79005, A79006, and 82600 with an exposure age of 26 x 10 to the 6th ages and a terrestrial age of 180,000 ages. EETA 79004 may be different from this group because its exposure age and terrestrial age are 21 x 10 to the 6th ages and 250,000 ages, respectively. The distribution of terrestrial ages of Allan Hills meteorites is discussed. Meteorites from this blue ice field have two sources: directly deposited falls and meteorites transported to the Allen Hills inside the moving Antarctic ice sheet. During the surface residence time meteorites decompose due to weathering processes. The weathering 'half-life' is about 160,000 ages. From the different age distributions of Allan Hills and Yamato meteorites, it is concluded that meteorite concentrations of different Antarctic ice fields need different explanations.

Freundel, M.↗

Antarctic Meteorite Location Map Series

Antarctica has been a prolific source of meteorites since meteorite concentrations were discovered in 1969. The Antarctic Search For Meteorites (ANSMET) project has been active over much of the Trans-Antarctic Mountain Range. The first ANSMET expedition (a joint U.S.-Japanese effort) discovered what turned out to be a significant concentration of meteorites at the Allan Hills in Victoria Land. Later reconnaissance in this region resulted in the discovery of meteorite concentrations on icefields to the west of the Allan Hills, at Reckling Moraine, and Elephant Moraine. Antarctic meteorite location maps (reduced versions) of the Allan Hills main, near western, middle western, and far western icefields and the Elephant Moraine icefield are presented. Other Antarctic meteorite location maps for the specimens found by the ANSMET project are being prepared.

Schutt, John↗