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At least 73 records · Page 4

Time inversion symmetry in the Dirac and Schrödinger-Pauli theories

The Schrödinger-Pauli theory is generally believed to give a faithful representation of the nonrelativistic and weakly relativistic limit of the Dirac theory. However, the Schrödinger-Pauli theory is fundamentally incomplete in its account of broken time inversion symmetry, e.g., in magnetically ordered systems. Here, in the Dirac theory of the electron, magnetic order breaks time inversion symmetry even in the nonrelativistic limit, whereas time inversion symmetry is effectively preserved in the Schrödinger-Pauli theory in the absence of spin-orbit coupling. In the Dirac theory, the Berry curvature $1/(2m^2 c^2)$ is thus an intrinsic property of nonrelativistic electrons similar to the well-known spin magnetic moment $e\hbar/(2m)$, while this result is missed by the nonrelativistic or weakly relativistic Schrödinger-Pauli equation. In ferromagnetically ordered systems, the intrinsic Berry curvature yields a contribution to the anomalous Hall conductivity independent of spin-orbit coupling.

Winkler, R. [Northern Illinois Univ., DeKalb, IL (↗

Buried Dirac Points in Quantum Spin Hall Insulators: Implications for Majorana Kramers Pair-Based Quantum Computing

Quantum spin Hall insulators (QSHIs) host helical electronic edge states that are protected from backscattering due to time-reversal symmetry (TRS). Despite considerable work investigating QSHI edge states, there is still an open question about their unexpected resilience to large magnetic fields where TRS is undoubtedly broken. In this work, we investigate the transport properties of helical edge states in a QSHI-superconductor (QSHI-SC) junction formed by a In⁢As(15 nm)/Ga⁢Sb(5 nm) double quantum well and a superconducting tantalum (Ta) constriction. We observe a robust conductance plateau up to 2 T, signaling resilient edge-state transport. Using a modified Landauer-Büttiker analysis, we find that the zero-field conductance is consistent with 98% Andreev-reflection probability owing to the high transparency of the (In⁢As/Ga⁢Sb)-Ta interface. Such resilience is consistent with the Dirac point for the edge states being buried in the bulk valence band. We further theoretically show that a buried Dirac point does not affect the robustness of the quasi-one-dimensional topological superconducting phase. We find that a buried Dirac point favors the hybridization of Majorana Kramers pairs (MKPs)—predicted to exist in a QSHI-SC constriction—and fermionic modes in the QSHI vacuum edge resulting in extended MKP states, highlighting the subtle role of buried Dirac points in probing MKPs.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Field-angle dependence of sound velocity in the Weyl semimetal TaAs

The elastic modulus c 44 of a single crystal of the Weyl semimetal TaAs was investigated by measuring relative changes in the sound velocity under application of a magnetic field up to 10 T. Using an ultrasonic pulsed-echo technique, we studied the shear response of the crystal when the angle between the sound wave propagation and the magnetic field is changed. We observe a broken tetragonal symmetry at fields above 6 T, an anisotropy that is likely related to a longitudinal negative magnetoresistance and therefore might provide evidence of the chiral anomaly, one of the main topological signatures of this class of materials. Furthermore, we also observe quantum oscillations in the sound velocity whose frequencies vary with magnetic field orientation. A fan diagram of Landau level indices reveals topological and trivial Berry phases, depending on the field orientation, indicating a sensitivity to different Fermi surface pockets that do or do not enclose Weyl nodes, respectively.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Three-state Potts nematic order in stacked frustrated spin models with SO(3) symmetry

Here, we propose stacked two-dimensional lattice designs of frustrated and SO(3) symmetric spin models consisting of antiferromagnetic (AF) triangular and ferromagnetic (FM) sixfold symmetric sublattices that realize emergent $\mathbb{Z}_{3}$ Potts nematic order. Considering bilinear-biquadratic spin interactions, our models describe an SO(3)-symmetric triangular lattice AF subject to a fluctuating magnetization arising from the FM coupled sublattice. We focus on the classical AFM-FM windmill model and map out the zero- and finite-temperature phase diagram using Monte Carlo simulations and analytical calculations. We discover a state with composite Potts nematic order above the ferrimagnetic three-sublattice up-up-down ground state and relate it to Potts phases in SO(3)-broken Heisenberg and Ising AFMs in external magnetic fields. Finally, we show that the biquadratic exchange in our model is automatically induced by thermal and quantum fluctuations in the purely bilinear Heisenberg model, easing the requirements for realizing these lattice designs experimentally.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Pyrochlore NaYbO2: A Potential Quantum Spin Liquid Candidate

The search for quantum spin liquids (QSL) and chemical doping in such materials to explore superconductivity have continuously attracted intense interest. Here, we report the discovery of a potential QSL candidate, pyrochlore-lattice β-NaYbO2. Colorless and transparent NaYbO2 single crystals, layered α-NaYbO2 (∼250 μm on edge) and octahedral β-NaYbO2 (∼50 μm on edge), were grown for the first time. Synchrotron X-ray single-crystal diffraction unambiguously determined that the newfound β-NaYbO2 belongs to the three-dimensional pyrochlore structure characterized by the R3̅m space group, corroborated by synchrotron X-ray and neutron powder diffraction and pair distribution function. Magnetic measurements revealed no long-range magnetic order or spin glass behavior down to 0.4 K with a low boundary spin frustration factor of 17.5, suggesting a potential QSL ground state. Under high magnetic fields, the potential QSL state was broken and spins order. Our findings reveal that NaYbO2 is a fertile playground for studying novel quantum states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Black holes in magnetic monopoles

We study magnetically charged classical solutions of a spontaneously broken gauge theory interacting with gravity. We show that nonsingular monopole solutions exist only if the Higgs field vacuum expectation value v is less than or equal to a critical value v sub cr, which is of the order of the Planck mass. In the limiting case, the monopole becomes a black hole, with the region outside the horizon described by the critical Reissner-Nordstrom solution. For v less than v sub cr, we find additional solutions which are singular at f = 0, but which have this singularity hidden within a horizon. These have nontrivial matter fields outside the horizon, and may be interpreted as small black holes lying within a magnetic monopole. The nature of these solutions as a function of v and of the total mass M and their relation to the Reissner-Nordstrom solutions is discussed.

Lee, Kimyeong↗

Inducing a tunable skyrmion-antiskyrmion system through ion beam modification of FeGe films

Abstract Skyrmions and antiskyrmions are nanoscale swirling textures of magnetic moments formed by chiral interactions between atomic spins in magnetic noncentrosymmetric materials and multilayer films with broken inversion symmetry. These quasiparticles are of interest for use as information carriers in next-generation, low-energy spintronic applications. To develop skyrmion-based memory and logic, we must understand skyrmion-defect interactions with two main goals—determining how skyrmions navigate intrinsic material defects and determining how to engineer disorder for optimal device operation. Here, we introduce a tunable means of creating a skyrmion-antiskyrmion system by engineering the disorder landscape in FeGe using ion irradiation. Specifically, we irradiate epitaxial B20-phase FeGe films with 2.8 MeV Au 4+ ions at varying fluences, inducing amorphous regions within the crystalline matrix. Using low-temperature electrical transport and magnetization measurements, we observe a strong topological Hall effect with a double-peak feature that serves as a signature of skyrmions and antiskyrmions. These results are a step towards the development of information storage devices that use skyrmions and antiskyrmions as storage bits, and our system may serve as a testbed for theoretically predicted phenomena in skyrmion-antiskyrmion crystals.

74 ATOMIC AND MOLECULAR PHYSICS↗

Altermagnetism classification

Altermagnets are magnetic states with fully compensated spins and broken PT (PT: parity times time reversal) symmetry (i.e., spin-split bands). We classify three kinds of altermagnets in terms of broken P and T. Furthermore, strong altermagnets have spin-split bands without spin-orbit coupling (SOC), and weak altermagnets has spin-split bands only with non-zero SOC. These strong vs. weak altermagnets can be identified from the total number of symmetric spin rotation operations.

Altermagnets↗

Ground magnetometer survey in the Valley of Ten Thousand Smokes, Alaska

A reconnaissance magnetometer survey was conducted with both total- and vertical-field magnetometers. The large, sharp, narrow total magnetic anomalies observed over a zone of relict fumaroles in Broken Mountain Valley showed spectacular agreement with the surficial geology. Such a correlation is a strong indication that accumulations of magnetic minerals have been preserved along these fissure vents at shallow depths. Since large magnetic anomalies were measured near fumarolic markings along all of the traverses, it is proposed that the retention of sublimates along fumarolic vents is common throughout the Valley. The generally concentric contours of the vertical magnetic anomaly at the head of the Valley suggest that the dome of Novarupta is merely the surficial expression of a very massive conical-shaped intrusive centered just northeast of the dome. The magnetometer survey indicates that the pyroclastics in the Valley may be over 150 meters thick. Such an estimate is compatible with the volume of eruptive material needed to compensate for the subsidence surrounding Novarupta as well as a sizable amount of other regional subsidence.

Trible, M. C.↗

MAGSAT investigation of crustal magnetic anomalies in the eastern Indian Ocean

Crustal magnetic anomalies in a region of the eastern Indian Ocean were studied using data from NASA's MAGSAT mission. The investigation region (0 deg to 50 deg South, 75 to 125 deg East) contains several important tectonic features, including the Broken Ridge, Java Trench, Ninetyeast Ridge, and Southeast Indian Ridge. A large positive magnetic anomaly is associated with the Broken Ridge and smaller positive anomalies correlate with the Ninetyeast Ridge and western Australia. Individual profiles of scalar data (computed from vector components) were considered to determine the overall data quality and resolution capability. A set of MAGSAT ""Quiet-Time'' data was used to compute an equivalent source crustal magnetic anomaly map of the study region. Maps of crustal magnetization and magnetic susceptibility were computed from the equivalent source dipoles. Gravity data were used to help interpretation, and a map of the ratio of magnetization to density contrasts was computed using Poisson's relation. The results are consistent with the hypothesis of induced magnetization of a crustal layer having varying thickness and composition.

Sailor, R. V.↗

Magnetization Dependent In-plane Anomalous Hall Effect in a Low-dimensional System

Anomalous Hall Effect (AHE) response in magnetic systems is typically proportional to an out-of-plane magnetization component because of the restriction imposed by system symmetries, which demands that the magnetization, applied electric field, and induced Hall current are mutually orthogonal to each other. Here, we report experimental realization of an unconventional form of AHE in a low-dimensional heterostructure, wherein the Hall response is not only proportional to the out-of-plane magnetization component but also to the in-plane magnetization component. By interfacing a low-symmetry topological semimetal (TaIrTe4) with the ferromagnetic insulator (Cr2Ge2Te6), we create a low-dimensional magnetic system, where only one mirror symmetry is preserved. We show that as long as the magnetization has a finite component in the mirror plane, this last mirror symmetry is broken, allowing the emergence of an AHE signal proportional to in-plane magnetization. Our experiments, conducted on multiple devices, reveal a gate-voltage-dependent AHE response, suggesting that the underlying mechanisms responsible for the Hall effect in our system can be tuned via electrostatic gating. A minimal microscopic model constrained by the symmetry of the heterostructure shows that both interfacial spin-orbit coupling and time-reversal symmetry breaking via the exchange interaction from magnetization are responsible for the emergence of the in-plane AHE. Our work highlights the importance of system symmetries and exchange interaction in low-dimensional heterostructures for designing novel and tunable Hall effects in layered quantum systems.

FOS: Physical sciences↗

Nematic superconductivity in LiFeAs

The role of nematic order for the mechanism of high-temperature superconductivity is highly debated. In most iron-based superconductors (IBSs) the tetragonal symmetry is broken already in the normal state, resulting in orthorhombic lattice distortions, static stripe magnetic order, or both. Superconductivity then emerges, at least at weak doping, already from the state with broken C 4 rotational symmetry. One of the few stoichiometric IBSs, lithium iron arsenide superconducts below 18 K and does not display either structural or magnetic transition in the normal state. Here we demonstrate, using angle-resolved photoemission spectroscopy, that even the superconducting state in LiFeAs is also a nematic one. We observe spontaneous breaking of the rotational symmetry in the gap amplitude on all Fermi surfaces, as well as unidirectional distortion of the Fermi pockets. Remarkably, these deformations are hardly visible above superconducting T c . Our results demonstrate the realization of the phenomenon of superconductivity-induced nematicity in IBSs, emphasizing the intimate relation between them. Furthermore, we suggest a theoretical explanation based on the emergence of a secondary instability inside the superconducting state, which leads to the nematic order and s–d mixing in the gap function.

36 MATERIALS SCIENCE↗

Visualizing broken symmetry and topological defects in a quantum Hall ferromagnet

The interaction between electrons in graphene under high magnetic fields drives the formation of a rich set of quantum Hall ferromagnetic (QHFM) phases with broken spin or valley symmetry. Visualizing atomic-scale electronic wave functions with scanning tunneling spectroscopy (STS), we resolved microscopic signatures of valley ordering in QHFM phases and spectral features of fractional quantum Hall phases of graphene. At charge neutrality, we observed a field-tuned continuous quantum phase transition from a valley-polarized state to an intervalley coherent state, with a Kekulé distortion of its electronic density. Mapping the valley texture extracted from STS measurements of the Kekulé phase, we could visualize valley skyrmion excitations localized near charged defects. Our techniques can be applied to examine valley-ordered phases and their topological excitations in a wide range of materials.

valley symmetry↗

Vortices with magnetic field inversion in noncentrosymmetric superconductors

Superconducting materials with noncentrosymmetric lattices lacking space inversion symmetry exhibit a variety of interesting parity-breaking phenomena, including the magneto-electric effect, spin-polarized currents, helical states, and the unusual Josephson effect. In this paper, we demonstrate, within a Ginzburg-Landau framework describing noncentrosymmetric superconductors with O point group symmetry, that vortices can exhibit an inversion of the magnetic field at a certain distance from the vortex core. In stark contrast to conventional superconducting vortices, the magnetic-field reversal in the parity-broken superconductor leads to non-monotonic intervortex forces, and, as a consequence, to the exotic properties of the vortex matter such as the formation of vortex bound states, vortex clusters, and the appearance of metastable vortex/anti-vortex bound states.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Understanding electronic peculiarities in tetragonal FeSe as local structural symmetry breaking

Traditional band theory of perfect crystalline solids often uses as input the structure deduced from diffraction experiments; when modeled by the minimal unit cell this often produces a spatially averaged model. The present study illustrates that this is not always a safe practice unless one examines if the intrinsic bonding mechanism is capable of benefiting from the formation of a distribution of lower symmetry local environments that differ from the macroscopically averaged structure. This can happen either due to positional or to magnetic symmetry breaking. By removing the constraint of a small crystallographic cell, the energy minimization in the density functional theory finds atomic and spin symmetry breaking, not evident in conventional diffraction experiments but being found by local probes such as atomic pair distribution function analysis. Here in this paper we report that large atomic and electronic anomalies in bulk tetragonal FeSe emerge from the existence of distributions of local positional and magnetic moment motifs. The found symmetry-broken motifs obtained by minimization of the internal energy represent what chemical bonding in the tetragonal phase prefers as intrinsic energy lowering (stabilizing) static distortions. This explains observations of band renormalization, predicts orbital order and enhanced nematicity, and provides unprecedented close agreement with spectral function measured by photoemission and local atomic environment revealed by the pair distribution function. While the symmetry-restricted strong correlation approach has been argued previously to be the exclusive theory needed for describing the main peculiarities of FeSe, we show here that the symmetry-broken mean-field approach addresses numerous aspects of the problem, provides intuitive insight into the electronic structure, and opens the door for large-scale mean-field calculations for similar d -electron quantum materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Magnetism and interlayer bonding in pores of Bernal-stacked hexagonal boron nitride

When single-layer h-BN is subjected to a high-energy electron beam, triangular pores with nitrogen edges are formed. Because of the broken sp 2 bonds, these pores are known to possess magnetic states. Here, we report on the magnetism and electronic structure of triangular pores as a function of their size. Moreover, in the Bernal-stacked h-BN (AB-h-BN), multilayer pores with parallel edges can be created, which is not possible in the commonly fabricated multilayer AA'-h-BN. Given that these pores can be manufactured in a well-controlled fashion using an electron beam, it is important to understand the interactions of pores in neighboring layers. We find that in certain configurations, the edges of the neighboring pores remain open and retain their magnetism, and in others, they form interlayer bonds. We present a comprehensive report on these configurations for small nanopores. We find that at low temperatures, these pores have near degenerate magnetic configurations, and may be utilized in magnetoresistance and spintronics applications. In the process of forming larger multilayer nanopores, interlayer bonds can form, reducing the magnetization. Yet, unbonded parallel multilayer edges remain available at all sizes. Understanding these pores is also helpful in a multitude of applications such as DNA sequencing and quantum emission.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Development of molecular cluster models to probe pyrite surface reactivity

Abstract The recent discovery that anaerobic methanogens can reductively dissolve pyrite and utilize dissolution products as a source of iron and sulfur to meet their biosynthetic demands for these elements prompted the development of atomic‐scale nanoparticle models, as maquettes of reactive surface sites, for describing the fundamental redox steps that take place at the mineral surface during reduction. The given report describes our computational approach for modeling n (FeS 2 ) nanoparticles originated from mineral bulk structure. These maquettes contain a comprehensive set of coordinatively unsaturated Fe (II) sites that are connected via a range of persulfide (S 2 2− ) ligation. In addition to the specific maquettes with n = 8, 18, and 32 FeS 2 units, we established guidelines for obtaining low‐energy structures by considering the pattern of ionic, covalent, and magnetic interactions among the metal and ligand sites. The developed models serve as computational nano‐reactors that can be used to describe the reductive dissolution mechanism of pyrite to better understand the reactive sites on the mineral, where microbial extracellular electron‐transfer reactions can occur.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Magnetic Gears: The Key to Robust, Cost-Effective Hydropower Drivetrains

Based on previous demonstrated success at fabricating 5 and 10 kW scale magnetic gearbox (MGB) prototypes, Emrgy and its partners (the project team) proposed to design and construct a 100 kW scale MGB with a 30:1 gear ratio for the low-head hydro applications. The Statement of Project Objectives included tasks covering: 1) Market Applicability; 2) Technical Metrics; 3) Design (initial); 4) Electromagnetic (EM) Load and Structural Analysis; 5) Modal Analysis; 6) Sealing Design and 7) Final Design during Budget Period 1. Budget Period 2 included tasks covering: 1) Materials Procurement and Test Plan Development; 2) Assembly; and 3) Testing. The Market Applicability study (Task 1) led to a clear conclusion and recommendation toward “Low Head” technologies for maximum market share of both New Stream Reach development as well as powering Non-Powered Dams. The findings of this study also identified the opportunity for a larger scale magnetic gearbox-based drive train as a function of increased torque, as opposed to increased speed. The Technical Metrics Study (Task 2) concluded a horizontal orientation was preferred, examined potential loss mechanisms, concluded that a Halbach Array magnetic design was preferred, established a 30:1 gear ratio as optimal, and established a power rating of 100 kW as optimal. The subsequent initial and final detailed design process included electro-magnetic (EM) load and structural analysis (Task 4), a Modal analysis (for vibration) (Task 5), and a sealing design (Task 6) to assure water impermeability. The final design package (Task 7) included 729 individual parts, 117 unique part numbers, and 15 assemblies. In order to facilitate procurement, the full bill of materials was broken down into several sub-components: 1) custom magnetic parts; 2) custom machined parts; 3) custom casted parts; and 4) commercial off the shelf (COTS) parts. The casted parts were fabricated by Oak Ridge National Laboratory (ORNL) via a Cooperative Research and Development Agreement (CRADA) with Emrgy and funded by the Advanced Manufacturing Office (AMO). The procurement effort (Task 8) ultimately covered three time periods based on challenges encountered in meeting the budgeted cost for the prototype. Following the first effort in the early stages of Budget Period 2 in 2017, a no-cost time extension was granted to seek alternative fabrication and procurement options. The project was re-booted in 2020 based on the new ORNL CRADA that would focus on five (5) of the more difficult and expensive parts using their advanced manufacturing expertise. Procurement efforts for the other custom machined parts resulted in quotations that still exceeded the budget by more than $\$$100k. This was, in part, also due to the concurrent COVID-19 pandemic that caused both supply chain disruptions and labor shortages. As the project continued, pricing and availability degraded further. In Q2 FY’22, it was decided to not proceed with the fabrication of the prototype (Task 9) based on budgetary limitations. Outcomes included a full and detailed design of a 100 kW magnetic gearbox and associated indented bill of materials (BOM) and CAD drawings, a full assembly instruction manual with an associated BOM for materials necessary to support assembly, the fabrication of the double Halbach magnetic array for the rotor/stator system, fabrication of five (5) sand-casted/machined parts (via CRADA with ORNL) and an initial draft of a comprehensive testing plan. The most significant non-outcome was the actual fabrication and testing of the prototype gearbox based on budget limitations. Lessons learned included the need for an Application / Design / Cost trade analysis to better elucidate the cost potential of the MGB in the projected volumes anticipated for future demand. This would better establish the efficacy of the original cost target ($\$$0.80/Watt) and/or the need for reconsideration of designs and applications. Likewise, additional consideration of the prototype nature of the gearbox – single use, short lifetime, etc. - either as a separate exercise or in place of the design process completed, to reduce the cost of the demonstration prototype device. Additionally, project continuity was cited as a significant risk based on the loss of the primary design engineering firm after Budget Period 1. A design analysis exercise was conducted at the conclusion of the project to identify potential areas for cost reduction. One concept considered was the removal of the inner ring of magnets (with associated changes in the outer ring magnets) to enable a horizontal collapse of the design. It was estimated this could reduce cost by 10-25% without impacting performance.

13 HYDRO ENERGY↗