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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Global Carbon Budget 2016

Accurate assessment of anthropogenic carbon dioxide (CO 2 ) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere – the “global carbon budget” – is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates and consistency within and among components, alongside methodology and data limitations. CO 2 emissions from fossil fuels and industry ( E FF ) are based on energy statistics and cement production data, respectively, while emissions from land-use change ( E LUC ), mainly deforestation, are based on combined evidence from land-cover change data, fire activity associated with deforestation, and models. The global atmospheric CO 2 concentration is measured directly and its rate of growth ( G ATM ) is computed from the annual changes in concentration. The mean ocean CO 2 sink ( S OCEAN ) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in S OCEAN is evaluated with data products based on surveys of ocean CO 2 measurements. The global residual terrestrial CO 2 sink ( S LAND ) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models. We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as ±1 σ , reflecting the current capacity to characterise the annual estimates of each component of the global carbon budget. For the last decade available (2006–2015), E FF was 9.3 ± 0.5 GtC yr -1 , E LUC 1.0 ± 0.5 GtC yr -1 , G ATM 4.5 ± 0.1 GtC yr -1 , S OCEAN 2.6 ± 0.5 GtC yr -1 , and S LAND 3.1 ± 0.9 GtC yr -1 . For year 2015 alone, the growth in E FF was approximately zero and emissions remained at 9.9 ± 0.5 GtC yr -1 , showing a slowdown in growth of these emissions compared to the average growth of 1.8 % yr -1 that took place during 2006–2015. Also, for 2015, E LUC was 1.3 ± 0.5 GtC yr -1 , G ATM was 6.3 ± 0.2 GtC yr -1 , S OCEAN was 3.0 ± 0.5 GtC yr -1 , and S LAND was 1.9 ± 0.9 GtC yr -1 . G ATM was higher in 2015 compared to the past decade (2006–2015), reflecting a smaller S LAND for that year. The global atmospheric CO 2 concentration reached 399.4 ± 0.1 ppm averaged over 2015. For 2016, preliminary data indicate the continuation of low growth in E FF with +0.2 % (range of -1.0 to +1.8 %) based on national emissions projections for China and USA, and projections of gross domestic product corrected for recent changes in the carbon intensity of the economy for the rest of the world. In spite of the low growth of E FF in 2016, the growth rate in atmospheric CO 2 concentration is expected to be relatively high because of the persistence of the smaller residual terrestrial sink ( S LAND ) in response to El Niño conditions of 2015–2016. From this projection of E FF and assumed constant E LUC for 2016, cumulative emissions of CO 2 will reach 565 ± 55 GtC (2075 ± 205 GtCO 2 ) for 1870–2016, about 75 % from E FF and 25 % from E LUC . This living data update documents changes in the methods and data sets used in this new carbon budget compared with previous publications of this data set (Le Quéré et al., 2015b, a, 2014, 2013). All observations presented here can be downloaded from the Carbon Dioxide Information Analysis Center ( doi:10.3334/CDIAC/GCP_2016 ).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1981

Regional eddy vorticity transport and the equilibrium vorticity budgets of a numerical model ocean circulation

A mean vorticity budget analysis is presented of Holland's (1978) numerical ocean general circulation experiment. The stable budgets are compared with classical circulation theory to emphasize the ways in which the mesoscale motions of the model alter (or leave unaltered) classical vorticity balances. The basinwide meridional transports of vorticity by the mean flow and by the mesoscale flow in the mean are evaluated to establish the role(s) of the mesoscale in the larger scale equilibrium vorticity transports. The vorticity equation for this model fluid system is presented and the budget analysis method is described. Vorticity budgets over the selected regions and on a larger scale are given, and a summary of budget results is provided along with remarks about the utility of this type of analysis.

Harrison, D. E.↗
NASA NTRS2001

Satellite Retrieval of Atmospheric Water Budget over Gulf of Mexico- Caribbean Basin: Seasonal Variability

This study presents results from a multi-satellite/multi-sensor retrieval system designed to obtain the atmospheric water budget over the open ocean. A combination of hourly-sampled monthly datasets derived from the GOES-8 5 Imager and the DMSP 7-channel passive microwave radiometer (SSM/I) have been acquired for the Gulf of Mexico-Caribbean Sea basin. Whereas the methodology is being tested over this basin, the retrieval system is designed for portability to any open-ocean region. Algorithm modules using the different datasets to retrieve individual geophysical parameters needed in the water budget equation are designed in a manner that takes advantage of the high temporal resolution of the GOES-8 measurements, as well as the physical relationships inherent to the SSM/I passive microwave signals in conjunction with water vapor, cloud liquid water, and rainfall. The methodology consists of retrieving the precipitation, surface evaporation, and vapor-cloud water storage terms in the atmospheric water balance equation from satellite techniques, with the water vapor advection term being obtained as the residue needed for balance. Thus, we have sought to develop a purely satellite-based method for obtaining the full set of terms in the atmospheric water budget equation without requiring in situ sounding information on the wind profile. The algorithm is partly validated by first cross-checking all the algorithm components through multiple-algorithm retrieval intercomparisons. More fundamental validation is obtained by directly comparing water vapor transports into the targeted basin diagnosed from the satellite algorithm to those obtained observationally from a network of land-based upper air stations that nearly uniformly surround the basin. Total columnar atmospheric water budget results will be presented for an extended annual cycle consisting of the months of October-97, January-98, April-98, July-98, October-98, and January-1999. These results are used to emphasize the changing relationship in E-P, as well as in the varying roles of storage and advection in balancing E-P both on daily and monthly time scales and on localized and basin space scales. Results from the algorithm-to-algorithm intercomparisons will also be presented in the context of sensitivity testing to help understand the intrinsic uncertainties in the water budget terms.

Smith, Eric A.↗
NASA NTRS2001

Cloud Microphysics Budget in the Tropical Deep Convective Regime

Cloud microphysics budgets in the tropical deep convective regime are analyzed based on a 2-D cloud resolving simulation. The model is forced by the large-scale vertical velocity and zonal wind and large-scale horizontal advections derived from TOGA COARE for a 20-day period. The role of cloud microphysics is first examined by analyzing mass-weighted mean heat budget and column-integrated moisture budget. Hourly budgets show that local changes of mass-weighted mean temperature and column-integrated moisture are mainly determined by the residuals between vertical thermal advection and latent heat of condensation and between vertical moisture advection and condensation respectively. Thus, atmospheric thermodynamics depends on how cloud microphysical processes are parameterized. Cloud microphysics budgets are then analyzed for raining conditions. For cloud-vapor exchange between cloud system and its embedded environment, rainfall and evaporation of raindrop are compensated by the condensation and deposition of supersaturated vapor. Inside the cloud system, the condensation of supersaturated vapor balances conversion from cloud water to raindrop, snow, and graupel through collection and accretion processes. The deposition of supersaturated vapor balances conversion from cloud ice to snow through conversion and riming processes. The conversion and riming of cloud ice and the accretion of cloud water balance conversion from snow to graupel through accretion process. Finally, the collection of cloud water and the melting of graupel increase raindrop to compensate the loss of raindrop due to rainfall and the evaporation of raindrop.

Li, Xiao-Fan↗
NASA NTRS1997

Earth Radiation Budget Experiment (ERBE) Data Sets for Global Environment and Climate Change Studies

For a number of years there has been considerable interest in the earth's radiation budget (ERB) or energy balance, and entails making the best measurements possible of absorbed solar radiation, reflected shortwave radiation (RSW), thermal outgoing longwave radiation (OLR), and net radiation. ERB data are fundamental to the development of realistic climate models and studying natural and anthropogenic perturbations of the climate. Much of the interest and investigations in the earth's energy balance predated the age of earth-orbiting satellites (Hunt et al., 1986). Beginning in the mid 1960's earth-orbiting satellites began to play an important role in making measurements of the earth's radiation flux although much effort had gone into measuring ERB parameters prior to 1960 (House et al., 1986). Beginning in 1974 and extending until the present time, three different satellite experiments (not all operating at the same time) have been making radiation budget measurements almost continually in time. Two of the experiments were totally dedicated to making radiation budget measurements of the earth, and the other experiment flown on NOAA sun-synchronous AVHRR weather satellites produced radiation budget parameters as a by-product. The heat budget data from the AVHRR satellites began collecting data in June 1974 and have operated almost continuously for 23 years producing valuable data for long term climate monitoring.

Bess, T. Dale↗
NASA NTRS2004

Use of GOES, SSM/I, TRMM Satellite Measurements Estimating Water Budget Variations in Gulf of Mexico - Caribbean Sea Basins

This study presents results from a multi-satellite/multi-sensor retrieval system designed to obtain the atmospheric water budget over the open ocean. A combination of 3ourly-sampled monthly datasets derived from the GOES-8 5-channel Imager, the TRMM TMI radiometer, and the DMSP 7-channel passive microwave radiometers (SSM/I) have been acquired for the combined Gulf of Mexico-Caribbean Sea basin. Whereas the methodology has been tested over this basin, the retrieval system is designed for portability to any open-ocean region. Algorithm modules using the different datasets to retrieve individual geophysical parameters needed in the water budget equation are designed in a manner that takes advantage of the high temporal resolution of the GOES-8 measurements, as well as the physical relationships inherent to the TRMM and SSM/I passive microwave measurements in conjunction with water vapor, cloud liquid water, and rainfall. The methodology consists of retrieving the precipitation, surface evaporation, and vapor-cloud water storage terms in the atmospheric water balance equation from satellite techniques, with the water vapor advection term being obtained as the residue needed for balance. Thus, the intent is to develop a purely satellite-based method for obtaining the full set of terms in the atmospheric water budget equation without requiring in situ sounding information on the wind profile. The algorithm is validated by cross-checking all the algorithm components through multiple- algorithm retrieval intercomparisons. A further check on the validation is obtained by directly comparing water vapor transports into the targeted basin diagnosed from the satellite algorithms to those obtained observationally from a network of land-based upper air stations that nearly uniformly surround the basin, although it is fair to say that these checks are more effective m identifying problems in estimating vapor transports from a leaky operational radiosonde network than in verifying the transport estimates determined from the satellite algorithm system Total columnar atmospheric water budget results are presented for an extended annual cycle consisting of the months of October-97, January-98, April-98, July-98,October-98, and January 1999. These results are used to emphasize the changing relationship in E-P, as well as in the varying roles of storage and advection in balancing E-P both on daily and monthly time scales and on localized and basin space scales. Results from the algorithm-to-algorithm intercomparisons are also presented in the context of sensitivity testing to help understand the intrinsic uncertainties in evaluating the water budget terms by an all-satellite algorithm approach.

Smith, Eric A.↗
NASA NTRS2006

Monthly-Diurnal Water Budget Variability Over Gulf of Mexico-Caribbean Sea Basin from Satellite Observations

This study presents results from a multi-satellite/multi-sensor retrieval system design d to obtain the atmospheric water budget over the open ocean. A combination of hourly-sampled monthly datasets derived from the GOES-8 5-channel Imager, the TRMM TMI radiometer, and the DMSP 7-channel passive microwave radiometers (SSM/I) have been acquired for the combined Gulf of Mexico-Caribbean Sea basin. Whereas the methodology has been tested over this basin, the retrieval system is designed for portability to any open-ocean region. Algorithm modules using the different datasets to retrieve individual geophysical parameters needed in the water budget equation are designed in a manner that takes advantage of the high temporal resolution of the GOES-8 measurements, as well as the physical relationships inherent to the TRMM and SSM/I passive microwave measurements in conjunction with water vapor, cloud liquid water, and rainfall. The methodology consists of retrieving the precipitation, surface evaporation, and vapor-cloud water storage terms in the atmospheric water balance equation from satellite techniques, with the water vapor advection term being obtained as the residue needed for balance. Thus, the intent is to develop a purely satellite-based method for obtaining the full set of terms in the atmospheric water budget equation without requiring in situ sounding information on the wind profile. The algorithm is validated by cross-checking all the algorithm components through multiple-algorithm retrieval intercomparisons. A further check on the validation is obtained by directly comparing water vapor transports into the targeted basin diagnosed from the satellite algorithms to those obtained observationally from a network of land-based upper air stations that nearly uniformly surround the basin, although it is fair to say that these checks are more effective in identifying problems in estimating vapor transports from a "leaky" operational radiosonde network than in verifying the transport estimates determined from the satellite algorithm system. Total columnar atmospheric water budget results are presented for an extended annual cycle consisting of the months of October-97, January-98, April-98, July-98,October-98, and January- 1999. These results are used to emphasize the changing relationship in E-P, as well as in the varying roles of storage and advection in balancing E-P both on daily and monthly time scales and on localized and basin space scales. Results from the algorithm-to-algorithm intercomparisons are also presented in the context of sensitivity testing to help understand the intrinsic uncertainties in evaluating the water budget terms by an all-satellite algorithm approach.

Smith, E. A.↗
NASA NTRS2007

Quantifying the Global Fresh Water Budget: Capabilities from Current and Future Satellite Sensors

The global water cycle is complex and its components are difficult to measure, particularly at the global scales and with the precision needed for assessing climate impacts. Recent advances in satellite observational capabilities, however, are greatly improving our knowledge of the key terms in the fresh water flux budget. Many components of the of the global water budget, e.g. precipitation, atmospheric moisture profiles, soil moisture, snow cover, sea ice are now routinely measured globally using instruments on satellites such as TRMM, AQUA, TERRA, GRACE, and ICESat, as well as on operational satellites. New techniques, many using data assimilation approaches, are providing pathways toward measuring snow water equivalent, evapotranspiration, ground water, ice mass, as well as improving the measurement quality for other components of the global water budget. This paper evaluates these current and developing satellite capabilities to observe the global fresh water budget, then looks forward to evaluate the potential for improvements that may result from future space missions as detailed by the US Decadal Survey, and operational plans. Based on these analyses, and on the goal of improved knowledge of the global fresh water budget under the effects of climate change, we suggest some priorities for the future, based on new approaches that may provide the improved measurements and the analyses needed to understand and observe the potential speed-up of the global water cycle under the effects of climate change.

Hildebrand, Peter↗
NASA NTRS2010

Global Energy and Water Budgets in MERRA

Reanalyses, retrospectively analyzing observations over climatological time scales, represent a merger between satellite observations and models to provide globally continuous data and have improved over several generations. Balancing the Earth s global water and energy budgets has been a focus of research for more than two decades. Models tend to their own climate while remotely sensed observations have had varying degrees of uncertainty. This study evaluates the latest NASA reanalysis, called the Modern Era Retrospective-analysis for Research and Applications (MERRA), from a global water and energy cycles perspective. MERRA was configured to provide complete budgets in its output diagnostics, including the Incremental Analysis Update (IAU), the term that represents the observations influence on the analyzed states, alongside the physical flux terms. Precipitation in reanalyses is typically sensitive to the observational analysis. For MERRA, the global mean precipitation bias and spatial variability are more comparable to merged satellite observations (GPCP and CMAP) than previous generations of reanalyses. Ocean evaporation also has a much lower value which is comparable to observed data sets. The global energy budget shows that MERRA cloud effects may be generally weak, leading to excess shortwave radiation reaching the ocean surface. Evaluating the MERRA time series of budget terms, a significant change occurs, which does not appear to be represented in observations. In 1999, the global analysis increments of water vapor changes sign from negative to positive, and primarily lead to more oceanic precipitation. This change is coincident with the beginning of AMSU radiance assimilation. Previous and current reanalyses all exhibit some sensitivity to perturbations in the observation record, and this remains a significant research topic for reanalysis development. The effect of the changing observing system is evaluated for MERRA water and energy budget terms.

Bosilovich, Michael G.↗
NASA NTRS2016

Global Carbon Budget 2016

Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere the global carbon budget is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates and consistency within and among components, alongside methodology and data limitations. CO2 emissions from fossil fuels and industry (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models. We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as +/- 1(sigma), reflecting the current capacity to characterize the annual estimates of each component of the global carbon budget. For the last decade available (2006-2015), EFF was 9.3+/-0.5 GtC/yr, ELUC 1.0+/-0.5 GtC/yr,GATM 4.5+/-0.1 GtC/yr, SOCEAN 2.6+/-0.5 GtC/yr, and SLAND 3.1+/-0.9 GtC/yr. For year 2015 alone, the growth in EFF was approximately zero and emissions remained at 9.9+/-0.5 GtC/yr, showing a slowdown in growth of these emissions compared to the average growth of 1.8/yr that took place during 2006-2015.Also, for 2015, ELUC was 1.3+/-0.5 GtC/yr, GATM was 6.3+/-0.2 GtC/yr, SOCEAN was 3.0+/-0.5 GtC/yr, and SLAND was 1.9+/-0.9 GtC/yr. GATM was higher in 2015 compared to the past decade (2006-2015), reflecting a smaller SLAND for that year. The global atmospheric CO2 concentration reached 399.4+/-0.1 ppm averaged over 2015. For 2016, preliminary data indicate the continuation of low growth in EFF with +0.2% (range of -1.0 to +1.8% ) based on national emissions projections for China and USA, and projections of gross domestic product corrected for recent changes in the carbon intensity of the economy for the rest of the world. In spite of the low growth of EFF in 2016, the growth rate in atmospheric CO2 concentration is expected to be relatively high because of the persistence of the smaller residual terrestrial sink (SLAND) in response to El Nino conditions of 2015-2016. From this projection of EFF and assumed constant ELUC for 2016, cumulative emissions of CO2 will reach 565+/-55 GtC (2075+/-205 GtCO2) for 1870-2016, about 75% from EFF and 25% from ELUC. This living data update documents changes in the methods and data sets used in this new carbon budget compared with previous publications of this data set.

Quéré, Corinne Le↗
NASA NTRSDate not supplied

Budgets of Reynolds Stresses and Turbulent Heat Flux for Hypersonic Turbulent Boundary Layers Subject to Pressure Gradients

In this paper, the budget terms in the transport equations of the Reynolds stresses, the turbulent kinetic energy (TKE), the internal energy, and the turbulent heat flux are computed using a direct numerical simulation (DNS) database of hypersonic turbulent boundary layers (TBLs) subject to favorable pressure gradients (FPG). Study of the Reynolds stress and TKE budgets shows that FPG has a damping effect on turbulence production, transport, and destruction. The semilocal scaling fails to collapse the Reynolds stress and TKE budget terms between the zero pressure gradient (ZPG) and the strong FPG cases, suggesting that the mechanical nonequilibrium due to FPG leads to changes in Reynolds-stress and TKE transport that cannot be captured by Morkovin’s hypothesis. Minimal change is seen in the internal energy budget in the presence of FPG, indicating a minimal impact due to FPG on the mean thermal field. While the near-wall transport of wall-normal turbulent heat flux is largely governed by the balance between the turbulent viscous-thermal transport term and the turbulent viscous-thermal dissipation term, the transport of the streamwise turbulent heat flux is influenced by contributions from almost all of the budget terms. For the strong FPG case in particular, production due to both the mean and the fluctuating strain rates begins to play a significant role in the near-wall transport of the streamwise turbulent heat flux, and their inclusion or modeling may be required to accurately predict turbulent heat fluxes for a strong FPG.

Reynolds stress↗
DOE OSTI2024

Harmonizing direct and indirect anthropogenic land carbon fluxes indicates a substantial missing sink in the global carbon budget since the early 20th century

Inconsistencies in the calculation of the two anthropogenic land flux terms of the global carbon cycle are investigated. The two terms—the direct anthropogenic flux (caused by direct human disturbance in anthromes, currently a carbon source to the atmosphere) and the indirect anthropogenic flux (caused indirectly by human activities that lead to global change and affecting all biomes, currently an atmospheric carbon sink)—are typically calculated independently, resulting in inconsistent underlying assumptions. We harmonize the estimation of the two anthropogenic land flux terms by incorporating previous estimates of these inconsistencies. We recalculate the global carbon budget (GCB) and apply change-point analysis to the cumulative budget imbalance. Cumulative over 1850–2018 (1959–2018), harmonization results in a 13% lesser (4% greater) land use source from anthromes and a 20% (23%) lesser land sink. This recalculation yields a greater non-closure of the GCB, indicating a missing carbon sink averaging 0.65 Pg C year -1 since the early 20th century. The imbalance likely results from a combination of method discontinuity and structural errors in the assessment of the direct anthropogenic land use flux, greater ocean carbon uptake, structural errors in land models, and in how these land terms are quantified for the budget. We caution against overconfidence in considering the GCB a solved problem and recommend further study of methodological discontinuities in budget terms. We strongly recommend studies that quantify the direct and indirect anthropogenic land fluxes simultaneously to ensure consistency, with a deeper understanding of human disturbance and legacy effects in anthromes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Dynamics, Radiation, and Overall Energy Budget of Earthquake Rupture With Coseismic Off-Fault Damage

Earthquake ruptures dynamically activate coseismic off–fault damage around fault cores. Systematic field observation efforts have shown the distribution of off–fault damage around main faults, while numerical modeling using elastic–plastic off–fault material models have demonstrated the evolution of coseismic off–fault damage during earthquake ruptures. Laboratory–scale microearthquake experiments have pointed out the enhanced high–frequency radiation due to the coseismic off–fault damage. However, the detailed off–fault fracturing mechanisms, subsequent radiation, and its contribution to the overall energy budget remain to be fully understood because of limitations of current observational techniques and model formulations. Here, we constructed a new physics–based dynamic earthquake rupture modeling framework, based on the combined finite–discrete element method, to investigate the fundamental mechanisms of coseismic off–fault damage, and its effect on the rupture dynamics, the radiation and the overall energy budget. We conducted a 2–D systematic case study with depth and showed the mechanisms of dynamic activation of the coseismic off–fault damage. We found the decrease in rupture velocity and the enhanced high–frequency radiation in near field due to the coseismic off–fault damage. We then evaluated the overall energy budget, which shows a significant contribution of the coseismic off–fault damage to the overall energy budget even at depth, where the damage zone width becomes narrower. Here, the present numerical framework for the dynamic earthquake rupture modeling thus provides new insights into earthquake rupture dynamics with the coseismic off–fault damage.

58 GEOSCIENCES↗
DOE OSTI2012

Summertime photochemistry during CAREBeijing-2007: ROx budgets and O3 formation

We analyze summertime photochemistry near the surface in Beijing, China, using a 1-D photochemical model (Regional chEmical and trAnsport Model, REAM-1D) constrained by in situ observations, focusing on the budgets of ROx (OH + HO2 + RO2) radicals and O3 formation. While the modeling analysis focuses on near-surface photochemical budgets, the implications for the budget of O3 in the planetary boundary layer are also discussed. In terms of daytime average, the total ROx primary production rate near the surface in Beijing is 6.6 ppbv per hour (ppbv h{sup 1}, among the highest found in urban atmospheres. The largest primary ROx source in Beijing is photolysis of oxygenated volatile organic compounds (OVOCs), which produces HO2 and RO2 at 2.5 ppbv h{sup 1}1 and 1.7 ppbv h{sup 1}, respectively. Photolysis of excess HONO from an unknown heterogeneous source is the predominant primary OH source at 2.2 ppbv h{sup 1}, much larger than that of O1D+H2O (0.4 ppbv h{sup 1}). The largest ROx sink is via OH + NO2 reaction (1.6 ppbv h{sup 1}), followed by formation of RO2NO2 (1.0 ppbv h{sup 1}) and RONO2 (0.7 ppbv h{sup 1}). Due to the large aerosol surface area, aerosol uptake of HO2 appears to be another important radical sink, although the estimate of its magnitude is highly variable depending on the uptake coefficient value used. The daytime average O3 production and loss rates near the surface are 32 ppbv h{sup 1} and 6.2 ppbv h{sup 1}, respectively. Assuming NO2 to be the source of excess HONO, the NO2 to HONO transformation leads to considerable O3 loss and reduction of its lifetime. Our observation-constrained modeling analysis suggests that oxidation of VOCs (especially aromatics) and heterogeneous reactions (e.g. HONO formation and aerosol uptake HO2) play potentially critical roles in the primary radical budget and O3 formation in Beijing. One important ramification is that O3 production is neither NOx nor VOC limited, but in a transition regime where reduction of either NOx or VOCs could result in reduction of O3 production. The transition regime implies more flexibility in the O3 control strategies than a binary system of either NOx or VOC limited regime. The co-benefit of concurrent reduction of both NOx and VOCs in reducing column O3 production integrated in the planetary boundary layer is significant. Further research on the spatial extent of the transition regime over the polluted eastern China is critically important for controlling regional O3 pollution.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Fish energy budget under ocean warming and flame retardant exposure

Highlights: • Energy proportion spent for growth dominated the mode of energy allocation (56–68%). • Energy channelled for R was around 26%, followed by excretion (F: 4–16%; U: 2–3%). • Energy budget parameters were significantly affected by warming and BDE-209 exposure. • Higher levels occurred under warming conditions: for weight, protein, ash and RGR. • Higher levels occurred under both stressors: for FE, AER, RMR and K{sub 1}. Climate change and chemical contamination are global environmental threats of growing concern for the scientific community and regulatory authorities. Yet, the impacts and interactions of both stressors (particularly ocean warming and emerging chemical contaminants) on physiological responses of marine organisms remain unclear and still require further understanding. Within this context, the main goal of this study was to assess, for the first time, the effects of warming (+ 5 °C) and accumulation of a polybrominated diphenyl ether congener (BDE-209, brominated flame retardant) through dietary exposure on energy budget of the juvenile white seabream (Diplodus sargus). Specifically, growth (G), routine metabolism (R), excretion (faecal, F and nitrogenous losses, U) and food consumption (C) were calculated to obtain the energy budget. The results demonstrated that the energy proportion spent for G dominated the mode of the energy allocation of juvenile white seabream (56.0–67.8%), especially under the combined effect of warming plus BDE-209 exposure. Under all treatments, the energy channelled for R varied around 26% and a much smaller percentage was channelled for excretion (F: 4.3–16.0% and U: 2.3–3.3%). An opposite trend to G was observed to F, where the highest percentage (16.0 ± 0.9%) was found under control temperature and BDE-209 exposure via diet. In general, the parameters were significantly affected by increased temperature and flame retardant exposure, where higher levels occurred for: i) wet weight, relative growth rate, protein and ash contents under warming conditions, ii) only for O:N ratio under BDE-209 exposure via diet, and iii) for feed efficiency, ammonia excretion rate, routine metabolic rate and assimilation efficiency under the combination of both stressors. On the other hand, decreased viscerosomatic index was observed under warming and lower fat content was observed under the combined effect of both stressors. Overall, under future warming and chemical contamination conditions, fish energy budget was greatly affected, which may dictate negative cascading impacts at population and community levels. Further research combining other climate change stressors (e.g. acidification and hypoxia) and emerging chemical contaminants are needed to better understand and forecast such biological effects in a changing ocean.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Turbulence kinetic energy budget and conditional sampling of momentum, scalar, and intermittency fluxes in thermally stratified wind farms

A description of the turbulence kinetic energy budget is investigated to understand the dynamics and turbulence energy transfer between the atmospheric boundary layer and large wind farms. The turbulence kinetic energy budget terms are a dominant factor in explaining the energy supply process in wind farms. Large eddy simulations are used to generate the thermally stratified wind turbine array boundary layer, where stable and unstable conditions are considered. The wakes represent a sink of mean kinetic energy, and turbulence transport redistributes energy in the wake region. The energy balance between the budget terms is dependent on the physical location in the wind farm. During the unstable scenario, turbulence is driven by the production, transport, and buoyancy terms. Further, the contribution of the turbulence kinetic energy budget terms is reduced with increasing atmospheric stability, especially above the shear layer, where the mechanical production is the dominant term. Pressure diffusion redistributes the turbulent energy from the streamwise direction into the other components of the normal Reynolds stresses. This distinctive feature of the changing thermal stratification is presented through the quadrant analysis. The momentum ejection and sweep frequencies are both comparable and dominant. The scalar flux shows an increase in the contribution of the negative correlation in the quadrants. The quadrant analysis is extended to account for intermittency based on the pointwise Holder exponents. As a result, positive correlations are dominant in the wake and in higher layers of the domain for both considered cases.

17 WIND ENERGY↗
DOE OSTI2023

Data-driven precision determination of the material budget in ALICE

The knowledge of the material budget with a high precision is fundamental for measurements of direct photon production using the photon conversion method due to its direct impact on the total systematic uncertainty. Moreover, it influences many aspects of the charged-particle reconstruction performance. In this article, two procedures to determine data-driven corrections to the material-budget description in ALICE simulation software are developed. One is based on the precise knowledge of the gas composition in the Time Projection Chamber. The other is based on the robustness of the ratio between the produced number of photons and charged particles, to a large extent due to the approximate isospin symmetry in the number of produced neutral and charged pions. Both methods are applied to ALICE data allowing for a reduction of the overall material budget systematic uncertainty from 4.5% down to 2.5%. Using these methods, a locally correct material budget is also achieved. The two proposed methods are generic and can be applied to any experiment in a similar fashion.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Low ozone dry deposition rates to sea ice during the MOSAiC field campaign: Implications for the Arctic boundary layer ozone budget

Dry deposition to the surface is one of the main removal pathways of tropospheric ozone (O 3 ). We quantified for the first time the impact of O 3 deposition to the Arctic sea ice on the planetary boundary layer (PBL) O 3 concentration and budget using year-round flux and concentration observations from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) campaign and simulations with a single-column atmospheric chemistry and meteorological model (SCM). Based on eddy-covariance O 3 surface flux observations, we find a median surface resistance on the order of 20,000 s m –1 , resulting in a dry deposition velocity of approximately 0.005 cm s –1 . This surface resistance is up to an order of magnitude larger than traditionally used values in many atmospheric chemistry and transport models. The SCM is able to accurately represent the yearly cycle, with maxima above 40 ppb in the winter and minima around 15 ppb at the end of summer. However, the observed springtime ozone depletion events are not captured by the SCM. In winter, the modelled PBL O 3 budget is governed by dry deposition at the surface mostly compensated by downward turbulent transport of O 3 towards the surface. Advection, which is accounted for implicitly by nudging to reanalysis data, poses a substantial, mostly negative, contribution to the simulated PBL O 3 budget in summer. During episodes with low wind speed (<5 m s –1 ) and shallow PBL (<50 m), the 7-day mean dry deposition removal rate can reach up to 1.0 ppb h –1 . Our study highlights the importance of an accurate description of dry deposition to Arctic sea ice in models to quantify the current and future O 3 sink in the Arctic, impacting the tropospheric O 3 budget, which has been modified in the last century largely due to anthropogenic activities.

54 ENVIRONMENTAL SCIENCES↗