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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1983

Statistical mechanics of neocortical interactions - Dynamics of synaptic modification

A recent study has demonstrated that several scales of neocortical interactions can be consistently analyzed with the use of methods of modern nonlinear nonequilibrium statistical mechanics. The formation, stability, and interaction of spatial-temporal patterns of columnar firings are explicitly calculated, to test hypothesized mechanisms relating to information processing. In this context, most probable patterns of columnar firings are associated with chemical and electrical synaptic modifications. It is stressed that synaptic modifications and shifts in most-probable firing patterns are highly nonlinear and interactive sets of phenomena. A detailed scenario of information processing is calculated of columnar coding of external stimuli, short-term storage via hysteresis, and long-term storage via synaptic modification.

Ingber, L.↗
NASA NTRS1995

Excitable dynamics in high-Lewis number premixed gas combustion at normal and microgravity

Freely-propagating, premixed gas flames in high-Lewis (Le) number, quiescent mixtures are studied experimentally in tubes of various diameter at normal (lg) and microgravity (mu g). A premixture of lean butane and oxygen diluted with helium, argon, neon, nitrogen or a mixture of multiple diluents is examined such that the thermal diffusivity of the mixture (and to a lesser extent, the mass diffusivity of the rate-limiting component) is systematically varied. In effect, different diluents allow variation of the Le without changing the chemistry. The flames are recorded with high speed cinematography and their stability is visually assessed. Different modes of propagation were observed depending on the diameter of the tubes (different conductive heat loss), the composition of the mixture and the g-level. At 1g, four modes of propagation were observed in small and intermediate diameter tubes (large conductive heat loss): (1) steadily propagating flames, (2) radial and longitudinal pulsating flames, (3) 'wavering' flames, and (4) rotating spiral flames. As the diameter of the tube increases, the radial modes become more pronounced while the longitudinal modes systematically disappear. Also, multiple, simultaneous, spatially-separated 'pacemaker' sites are observed in intermediate and large diameter tubes. Each site starts as a small region of high luminosity and develops into a flamelet which assumes the form of one of the fore mentioned modes. These flamelets eventually interact, annihilate each other in their regions of intersection and merge at their newly created free-ends. For very large tubes, radially-propagating wave-trains (believed to be 'trigger waves') are observed. These are analogous to the radial pulsations observed in the smaller diameter tubes. At mu g, three modes of propagation have been observed: (1) steadily propagating flames, (2) radial and longitudinal pulsating flames, and (3) multi-armed, rotating flames. Since the pulsating mode exists at mu g and 1g, buoyant flicker is not the mechanism which drives the pulsations. Moreover, all of the instabilities at 1g and mu g have characteristic frequencies on the O(100Hz). This value is lower than the fundamental, longitudinal acoustic frequencies of the tubes which suggests that the instabilities are not acoustically driven. The patterns formed by this reaction bear remarkable similarities with the patterns formed in most excitable media when the behavior of the system is driven by couplings between chemical reaction and diffusion (e.g., Belousov-Zhabotinsky reaction, Patterns in slime molds, spiral waves in the retina of a bird's eye). While it is recognized that the chemical mechanism associated with this premixed gas reaction is exponentially sensitive to temperature and undoubtedly different from those which govern previously observed excitable media (most are isothermal, or weakly exothermic, liquid phase reactions), similar spatial and temporal patterns should not come as a complete surprise considering heat and mass diffusion are self similar. It is concluded that this premixed gas system is a definitive example of a diffusive-thermal, gas-phase oscillator based on these experimental results and their favorable comparison with theory.

Pearlman, Howard↗
NASA NTRS2001

Cyrano "Nose" The Smell of Success

Cyrano Sciences, Inc. has commercialized a simple, accurate, non- invasive tool that enables "machines to smell". The Cyranose 320 is used for quality control purposes in the food and chemical industries. Using a sensor array and onboard pattern recognition algorithms, the lightweight, portable device works by exposing an array of polymer composite sensors to the chemical components in a vapor. When the sensors come in contact with the vapor, the polymer expands like a sponge, changing the resistance of the composites. The change in resistance is measured, and from that measurement, the presence of a pre-trained substance is determined with a quick and accurate diagnosis. This real-time, portable device enables food companies to spot test raw materials for batch-to-batch consistency, spoilage, or contamination. The Cyranose 320 is also used by chemical and petrochemical companies for quick assessment of the chemical status associated with various industrial processes. Profiling a chemical environment in a hazardous materials situation allows emergency crews to accurately select fire retardants, containment strategies, and protective gear. Future applications for the Cyranose 320 are fast growing and other uses of this technology are on the horizon.

Source record↗
NASA NTRS1970

Vanadium and copper in chondrites

V and Cu emission spectrographic analyses in chondrite types, noting distribution patterns between groups based on meteorite chemical fractionation mechanisms

Bingham, E.↗
NASA NTRS1978

Rare-gas-rich separates from carbonaceous chondrites

This paper describes an analysis of carbon-rich separates prepared by demineralization of colloidal fractions after disaggregation of bulk samples of the type C2 meteorites Murray, Murchison, and Cold Bokkeveld, as well as a methanol colloid extracted from acid-resistant residues of the Allende meteorite (type C3V) obtained by dissolution of most of the minerals in HCl and HF acids. The carbonaceous separates, or lAlates (a coined word designating colloids prepared sometimes before and sometimes after acid treatment), are characterized incompletely and with difficulty. A stepwise heating experiment on a Murray lAlate is discussed which revealed bimodal release of all noble gases, with similar patterns for Ar, Kr, and Xe. Chemical reactions are suggested as the likely mechanism for gas release. The results are shown to support the concept of a carbonaceous gas carrier uniformly present in meteorites of various types.

Reynolds, J. H.↗
NASA NTRS1987

Influence of suction and curvature on the growth of Goertler vortices on an airfoil

Laser velocimetry (LV) was used to study the development of Goertler vortices in a laminar boundary layer on a 1.83 m chord airfoil model. The vortex pattern was visualized using a sublimating chemical technique. A fixed, essentially uniform vortex spacing was observed throughout the test region for any given freestream velocity but the vortex wavelength varied significantly with change in freestream velocity. An appreciable, abrupt decrease in streak contrast indicated vortex damping in the convex region and was confirmed by disturbance functions determined from LV measurements. Moderate variation in suction levels did not alter the vortex spacing but appreciably modified the vortex strength. The experimental results on the growth of Goertler vortices along the concave surface and the effect of suction are compared with results from linear stability theory.

Mangalam, S. M.↗
NASA NTRS1986

Boundary layer transition

The boundary layer stability, its active control by sound and surface heating and the effect of curvature are studied numerically and experimentally for subsonic flow. In addition, the experimental and flight test data are correlated using the stability theory for supersonic Mach numbers. Active transition fixing and feedback control of boundary layer by sound interactions are experimentally investigated at low speed over an airfoil. Numerical simulation of active control by surface heating and cooling in air shows that by appropriate phase adjustment a reduction in the level of perturbation can be obtained. This simulation is based on the solution of two-dimensional compressible Navier-Stokes equations for a flat plate. Goertler vortices are studied experimentally on an airfoil in the Low Turbulence Pressure Tunnel (LTPT). The flow pattern was visualized using the sublimating chemical technique and data were obtained using a three component laser velocimeter. The effect of curvature on swept leading-edge stability on a cylinder was numerically studied. The results suggest that transition is dominated by traveling disturbance waves and that the waves with the greatest total amplification has an amplitude ratio of e sup 11. Experimental data from the quiet supersonic tunnel and flight tests are analyzed using linear compressible stability theory.

Maestrello, L.↗
NASA NTRS1995

Using foreground/background analysis to determine leaf and canopy chemistry

Spectral Mixture Analysis (SMA) has become a well established procedure for analyzing imaging spectrometry data, however, the technique is relatively insensitive to minor sources of spectral variation (e.g., discriminating stressed from unstressed vegetation and variations in canopy chemistry). Other statistical approaches have been tried e.g., stepwise multiple linear regression analysis to predict canopy chemistry. Grossman et al. reported that SMLR is sensitive to measurement error and that the prediction of minor chemical components are not independent of patterns observed in more dominant spectral components like water. Further, they observed that the relationships were strongly dependent on the mode of expressing reflectance (R, -log R) and whether chemistry was expressed on a weight (g/g) or are basis (g/sq m). Thus, alternative multivariate techniques need to be examined. Smith et al. reported a revised SMA that they termed Foreground/Background Analysis (FBA) that permits directing the analysis along any axis of variance by identifying vectors through the n-dimensional spectral volume orthonormal to each other. Here, we report an application of the FBA technique for the detection of canopy chemistry using a modified form of the analysis.

Pinzon, J. E.↗
NASA NTRS2013

How Cities Breathe: Ground-Referenced, Airborne Hyperspectral Imaging Precursor Measurements To Space-Based Monitoring

Methane's (CH4) large global warming potential (Shindell et al., 2012) and likely increasing future emissions due to global warming feedbacks emphasize its importance to anthropogenic greenhouse warming (IPCC, 2007). Furthermore, CH4 regulation has far greater near-term climate change mitigation potential versus carbon dioxide CO2, the other major anthropogenic Greenhouse Gas (GHG) (Shindell et al., 2009). Uncertainties in CH4 budgets arise from the poor state of knowledge of CH4 sources - in part from a lack of sufficiently accurate assessments of the temporal and spatial emissions and controlling factors of highly variable anthropogenic and natural CH4 surface fluxes (IPCC, 2007) and the lack of global-scale (satellite) data at sufficiently high spatial resolution to resolve sources. Many important methane (and other trace gases) sources arise from urban and mega-urban landscapes where anthropogenic activities are centered - most of humanity lives in urban areas. Studying these complex landscape tapestries is challenged by a wide and varied range of activities at small spatial scale, and difficulty in obtaining up-to-date landuse data in the developed world - a key desire of policy makers towards development of effective regulations. In the developing world, challenges are multiplied with additional political access challenges. As high spatial resolution satellite and airborne data has become available, activity mapping applications have blossomed - i.e., Google maps; however, tap a minute fraction of remote sensing capabilities due to limited (three band) spectral information. Next generation approaches that incorporate high spatial resolution hyperspectral and ultraspectral data will allow detangling of the highly heterogeneous usage megacity patterns by providing diagnostic identification of chemical composition from solids (refs) to gases (refs). To properly enable these next generation technologies for megacity include atmospheric radiative transfer modeling the complex and often aerosol laden, humid, urban microclimates, atmospheric transport and profile monitoring, spatial resolution, temporal cycles (diurnal and seasonal which involve interactions with the surrounding environment diurnal and seasonal cycles) and representative measurement approaches given traffic realities. Promising approaches incorporate contemporaneous airborne remote sensing and in situ measurements, nocturnal surface surveys, with ground station measurement

Leifer, Ira↗
NASA NTRS2021

State of the Climate in 2020: Global Oceans

This chapter details 2020 global patterns in select observed oceanic physical, chemical, and biological variables relative to long-term climatologies, their differences between 2020 and 2019, and puts 2020 observations in the context of the historical record. In this overview we address a few of the highlights, first in haiku, then paragraph form: La Niña arrives, shifts winds, rain, heat, salt, carbon: Pacific—beyond. Compiled by NOAA’s National Centers for Environmental Information, "State of the Climate in 2020" is based on contributions from scientists from around the world. It provides a detailed update on global climate indicators, notable weather events, and other data collected by environmental monitoring stations and instruments located on land, water, ice, and in space. The full report is available from: https://doi.org/10.1175/2021BAMSStateoftheClimate.1.

Gregory C Johnson↗
NASA NTRS1978

Apollo 17 mare basalt regression and classification studies

Regression and pattern recognition techniques were applied to 16 chemical species in 34 Apollo 17 basalts. The classification scheme of Pratt et al., (1977) was used. Data were absent for 8 MnO, 3 Hf, 3 Tb, and 8 Cr2O3 analyses. Linear regression studies were utilized to predict these and values obtained were added to the original data base. Pattern recognition techniques were then applied to predict classifications for 30 different Apollo 17 rake basalts analyzed by Murali et al., (1977).

Pratt, D. D.↗
NASA NTRS1982

The lunar regolith - Comparative studies of the Apollo and Luna sites. Chemistry of soils from Apollo 17, Luna 16, 20, and 24

The present investigation represents an extension of a comparative regolith study reported by Labotka et al. (1980) to the Apollo 17 site and to the east limb of the moon (Luna 16, 20, and 24 sites). Chemical systematics are considered, taking into account major and minor element characteristics, and large ion-lithophile patterns (K, REE, and Th). Attention is also given to chemical mixing calculations and the significance of the fine fraction. It is found that the chemistries of 1000-90, 90-20, and 20-10 micrometer size fractions are very similar to each other but quite different from the 'less than 10 micrometer' fine fractions. The 'less than 10 micrometer' fine fractions, which comprise about 5 to 20% of the bulk soils, are consistently more feldspathic and enriched in LIL-rich material relative to the coarse fractions in all soils. The KREEP type is different at each site and is largely derived locally.

Laul, J. C.↗
NASA NTRS1980

Trace elements in ocean ridge basalt glasses - Implications for fractionations during mantle evolution and petrogenesis

Seven documented and fresh glassy selvages from ocean floor basalt pillows were analyzed for trace elements including Ag, Au, Bi, Br, Ni, Pd, and Zn using radiochemical activation analysis. Glasses from DSDP leg 24, site 238 in the Indian Ocean have a trace element pattern which reflects secondary processes at a shallow depth. Chemical fractionations in petrogenesis of tholeiitic basalts indicate that (Ir, Os), Au, Pd, Ni, and Re are strongly fractionated in igneous processes; the unfractionated chondritic mantle pattern thus imposes constraints on mantle evolution models. Finally, the limited Rb/Cs fractionation in oceanic tholeiites reflects the low abundance of volatiles and hydrous silicates in normal ocean ridge basalts.

Hertogen, J.↗
NASA NTRS2010

The Abundance Pattern in the Hot ISM of NGC 4472: Insights and Anomalies

Important clues to the chemical and dynamical history of elliptical galaxies are encoded in the abundances of heavy elements in the X-ray emitting plasma. We derive the hot ISM abundance pattern in inner (0.2.3R(sub e)) and outer (2.3.4.6R(sub e)) regions of NGC 4472 from analysis of Suzaku spectra, supported by analysis of co- spatial XMM-Newton spectra. The low background and relatively sharp spectral resolution of the Suzaku XIS detectors, combined with the high luminosity and temperature in NGC 4472, enable us to derive a particularly extensive abundance pattern that encompasses O, Ne, Mg, Al, Si, S, Ar, Ca, Fe, and Ni in both regions. We apply simple chemical evolution models to these data, and conclude that the abundances are best explained by a combination of alpha-element enhanced stellar mass loss and direct injection of Type Ia supernova (SNIa) ejecta. We thus confirm the inference, based on optical data, that the stars in elliptical galaxies have supersolar [alpha/Fe] ratios, but find that that the present-day SNIa rate is approximately 4.6 times lower than the standard value. We find SNIa yield sets that reproduce Ca and Ar, or Ni, but not all three simultaneously. The low abundance of O relative to Ne and Mg implies that standard core collapse nucleosynthesis models overproduce O by approximately 2.

Loewenstein, Michael↗
NASA NTRS1980

Development of test methods for scale model simulation of aerial applications in the NASA Langley Vortex Facility

Methods have been developed at the Langley Vortex Research Facility to simulate and measure the deposition patterns of aerially applied sprays and granular materials by means of tests with small-scale models of agricultural and dynamically scaled test particles. Interactions between the aircraft wake and the dispersed particles are studied with the aim of modifying wake characteristics and dispersal techniques in order to increase swath width, improve deposition pattern uniformity, and minimize drift. This paper examines the particle sizing analysis, test methods for particle dispersal from the model aircraft, and measurement and computer analysis of test deposition patterns. Results that indicate improved control of chemical drift by winglets are presented to demonstrate test methods.

Jordan, F. L., Jr.↗
NASA NTRS1999

Stoichiometry of the large conductance bacterial mechanosensitive channel of E. coli. A biochemical study

MscL, a 15 kDa transmembrane protein, is the only component involved in the formation of a 3 nS channel in the inner membrane of Escherichia coli that opens in response to mechanical or osmotic stress. While previous data had suggested that the functional MscL complex might be a hexamer, a recent crystallographic study of the MscL homologue from M. tuberculosis reveals a pentameric structure. The present work further examines the stoichiometry of the E. coli MscL using a variety of biochemical approaches. Detergent-purified 6His-MscL in solution and MscL in the membrane could be chemically crosslinked with the products displaying ladderlike patterns on SDS gels. Three crosslinking agents (EDC, DMS, and DMA) used at saturating concentrations invariably generated pentamers as the largest product. DSS produced additional bands corresponding to larger complexes although the pentamer band appeared to be the predominant product at high levels of crosslinker. It is not clear whether these extra bands reflect a difference in the crosslinking chemistry of DSS or whether its spacer arm is the longest of those used, or a combination of both facts. For the detergent-solubilized 6His-MscL both sedimentation equilibrium and gel chromatography showed the presence of multiple species. Thus the longer spacer arm could permit both intra- and intercomplex linkages. Nonetheless, the patterns obtained with all agents are consistent with and strongly suggest a pentameric organization for the MscL channel. Expression of MscL as genetically engineered double or triple subunit tandems yields low numbers of functional channels as compared to expressed monomers. The double-tandem assemblies must have an even number of subunits and crosslinking in the membrane confirmed hexamerization. Gel chromatography clearly demonstrated that the channels formed from the double tandems were larger than those formed from WT MscL, consistent with the native channel being pentameric. The observation that both double and triple tandems form channels of normal conductance implies that the pentameric assembly is to some degree independent of the number of subunit repeats in the polypeptide precursor. The channel is thus a pentameric core with the 'extra' subunits left out of the functional complex. From sedimentation equilibrium and size-exclusion chromatography, we also conclude that MscL complexes are not in a dynamic equilibrium with monomers, but are pre-assembled; and thus, their gating properties must result from changes in the conformation of the entire complex induced by the mechanical stress.

NASA Discipline Cell Biology↗
NASA NTRS2009

Use of DSC and DMA to Study Rubber Crystallization as a Possible Cause for a Tear in a Neoprene Glove Used in a Space Shuttle Pressurized Astronaut Suit

The Advanced Crew Escape Suit (ACES) is a pressurized suit normally worn by astronauts during launch and landing phases of Space Shuttle operations. In 2008, a large tear (0.5 -1 in. long, between the pinky and ring finger) in the ACES left-hand glove made of neoprene latex rubber was found during training for Shuttle flight STS-124. An investigation to help determine the cause(s) of the glove tear was headed by the NASA Johnson Space Center (JSC) in Houston, Texas. Efforts at JSC to reproduce the actual glove tear pattern by cutting/tearing or rupturing were unsuccessful. Chemical and material property data from JSC such as GC-MS, FTIR, DSC and TGA mostly showed little differences between samples from the torn and control gloves. One possible cause for the glove tear could be a wedding ring/band worn by a male astronaut. Even with a smooth edge, such a ring could scratch the material and initiate the tear observed in the left-hand glove. A decision was later made by JSC to not allow the wearing of such a ring during training or actual flight. Another possible cause for the ACES glove tear is crystallinity induced by strain in the neoprene rubber over a long period of time and use. Neoprene is one several elastomeric materials known to be susceptible to crystallization, and such a process is accelerated with exposure of the material to cold temperatures plus strain. When the temperature is lowered below room temperature, researchers have shown that neoprene crystallization may be maintained at temperatures as high as 45-50 F, with a maximum crystallization rate near 20-25 F (1). A convenient conditioning temperature for inducing neoprene crystallization is a typical freezer that is held near 0 F. For work at the NASA Marshall Space Flight Center (MSFC), samples were cut from several areas/locations (pinky/ring finger crotch, index finger and palm) on each of two pairs of unstrained ACES gloves for DSC and DMA thermal analysis testing. The samples were conditioned in a freezer for various times up to about 14 days. Some rectangular conditioned samples were unstrained, while most were subjected to strains up to 250% with the aid of two slotted aluminum blocks and two aluminum clamps per sample. Trends were observed to correlate DSC data (heat of fusion) and DMA data (linear CTE and stress for iso-strain testing) with: (a) sample location on each glove; and (b) level of strain during conditioning. Control samples cut as is from each glove location were also tested by DSC and DMA.

Wingard, Doug↗