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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Orienting Superconductive Crystals For High Current Density

Proposed technique for controlled distortion of crystal grains in newly discoverd superconductor YBa2Cu3O7-x increases current-carrying capacity. Helps to ensure grains in this and other anisotropic materials all oriented in same direction so charge carriers transferred readily from one grain to another. Specimen of YBa2Cu3O7-x heated in oxygen atmosphere compressed in one direction as slowly cooled below transition temperature. Under these conditions, oxygen atoms tend to rearrange so as to relieve stress created by compression.

Shlichta, Paul J.↗

Characterization of YBa2Cu3O7, including critical current density Jc, by trapped magnetic field

Spatial distributions of persistent magnetic field trapped by sintered and melt-textured ceramic-type high-temperature superconductor (HTS) samples have been studied. The trapped field can be reproduced by a model of the current consisting of two components: (1) a surface current Js and (2) a uniform volume current Jv. This Js + Jv model gives a satisfactory account of the spatial distribution of the magnetic field trapped by different types of HTS samples. The magnetic moment can be calculated, based on the Js + Jv model, and the result agrees well with that measured by standard vibrating sample magnetometer (VSM). As a consequence, Jc predicted by VSM methods agrees with Jc predicted from the Js + Jv model. The field mapping method described is also useful to reveal the granular structure of large HTS samples and regions of weak links.

Chen, In-Gann↗

Photoelectrolysis of water at high current density - Use of ultraviolet laser excitation

The behavior of TiO2 and SrTiO3 photoanodes in cells for the photoelectrolysis of H2O has been investigated for high-intensity 351-,364-nm excitation from an Ar ion laser. Intensities up to 380 W/sq cm have been used. For TiO2 a small amount of surface decomposition is found after irradiation at high intensity, whereas SrTiO3 undergoes no detectable changes. Current-voltage properties for both electrodes are essentially independent of light intensity up to the level of 380 W/sq cm, and there is little if any change in quantum efficiency for electron flow. Photocurrent densities have been shown to exceed 5 A/sq cm for O2 evolution. Data show that the energy storage rate associated with the SrTiO3 photoelectrolysis can exceed 30 W/sq cm; this represents the highest demonstrated rate of sustained optical-to-chemical energy conversion.

Bocarsly, A. B.↗

A study of enhancing critical current densities (J(sub c)) and critical temperature (T(sub c)) of high-temperature superconductors

The development of pure phase 123 and Bi-based 2223 superconductors has been optimized. The pre-heat processing appears to be a very important parameter in achieving optimal physical properties. The synthesis of pure phases in the Bi-based system involves effects due to oxygen partial pressure, time, and temperature. Orientation/melt-sintering effects include the extreme c-axis orientation of Yttrium 123 and Bismuth 2223, 2212, and 2201 phases. This orientation is conductive to increasing critical currents. A procedure was established to substitute Sr for Ba in Y-123 single crystals.

Vlasse, Marcus↗

Photoelectrolysis of water at high current density - Use of laser light excitation of semiconductor-based photoelectrochemical cells

In the present paper, some results are given for UV laser light irradiation of the photoanode (SnO2, SrTiO3, or TiO2) in a cell for the light-driven electrolysis of H2O, at radiation intensities of up to 380 W/sq cm. The properties of the anode material are found to be independent of light intensity. Conversion of UV light to stored chemical energy in the form of 2H2/O2 from H2O was driven at a rate of up to 30 W/sq cm. High O2 evolution rates at the irradiated anodes without changes in the current-voltage curves are attributed to the excess oxidizing power associated with photogenerated holes. A test for this sort of hypothesis for H2 evolution at p-type materials is proposed.

Wrighton, M. S.↗

Clamp provides efficient connection for high-density currents

Electrical connector clamp /bus bar/ gives high contact-surface efficiency for providing a high current to thin wall stainless steel tubing containing hydrogen gas. It uses lead solder film to provide the electrical equivalent of a fusion bond without degrading the grain structure, permitting disassembly and reuse of the components.

Mc Carthy, J. R.↗

Field Emission Study of Carbon Nanotubes: High Current Density from Nanotube Bundle Arrays

We have investigated the field emission behavior of lithographically patterned bundles of multiwalled carbon nanotubes arranged in a variety of array geometries. Such arrays of nanotube bundles are found to perform significantly better in field emission than arrays of isolated nanotubes or dense, continuous mats of nanotubes, with the field emission performance depending on the bundle diameter and inter-bundle spacing. Arrays of 2-micrometers diameter nanotube bundles spaced 5 micrometers apart (edge-to-edge spacing) produced the largest emission densities, routinely giving 1.5 to 1.8 A/cm(sup 2) at approximately 4 V/micrometer electric field, and greater than 6 A/cm(sup 2) at 20 V/micrometers.

field emissions↗

Electrochemical Method of Making Porous Particles Using a Constant Current Density

Provided is a particle that includes a first porous region and a second porous region that differs from the first porous region. Also provided is a particle that has a wet etched porous region and that does have a nucleation layer associated with wet etching. Methods of making porous particles are also provided.

Ferrari, Mauro↗

Relations between the Birkeland currents, the auroral electrojet indices and high latitude Joule heating

Field-aligned currents were postulated by Birkeland (1908) to explain the magnetic perturbations in the auroral zone. Theoretical models have been developed to examine the effect of these currents on the ionosphere. These models, in general, involve very extensive computer programs, and it is difficult to see how their very complicated boundary conditions and assumptions affect the relationships between the Birkeland currents and magnetic activity. In the present investigation, a simplified analysis is used to study the average behavior of the large-scale ionospheric current paths and to examine the interrelationships of various parameters. The relationship of the parameters of the current deposition regions to the magnetic indices is investigated along with the polar cap potential. Attention is given to the experimental values of coefficients, and relations between the Birkeland current densities, current intensities, currents, and the AL, AU, AE indices are discussed.

Nisbet, J. S.↗

A theoretical study of heterojunction and graded band gap type solar cells

A computer program was designed for the analysis of variable composition solar cells and applied to several proposed solar cell structures using appropriate semiconductor materials. The program simulates solar cells made of a ternary alloy of two binary semiconductors with an arbitrary composition profile, and an abrupt or Gaussian doping profile of polarity n-on-p or p-on-n with arbitrary doping levels. Once the device structure is specified, the program numerically solves a complete set of differential equations and calculates electrostatic potential, quasi-Fermi levels, carrier concentrations and current densities, total current density and efficiency as functions of terminal voltage and position within the cell. These results are then recorded by computer in tabulated or plotted form for interpretation by the user.

Sutherland, J. E.↗