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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Theory Guided Fine‐Tune of Strain Effects in Pt Ternary Alloy via Rare Earth Templating: Achieving High Performance PEMFCs Catalysts

The sluggish kinetics and insufficient durability of platinum-based catalysts remain crucial barriers limiting proton-exchange-membrane fuel cells (PEMFCs) deployment. Here, we report a theory-guided synthesis combined with rare-earth templating to realize a previously inaccessible Pt 5 Co-like phase with tailored atomic-scale strain. Guided by density functional theory (DFT) calculations, we identified that a Pt 5 Co-like sublayer can induce a unique mild compressive strain (−1.24%) to the Pt(111) shell and an optimal *OH binding energy shift (ΔE ≈ 0.11 eV). This shift positions the alloy catalyst near the apex of the oxygen reduction reaction activity volcano. This prediction guided the synthesis of ternary alloy Pt 5 (Ce)Co@Pt multilayer nanoparticles, featuring a Ce-stabilized core, a Pt 5 Co-like sublayer, and a Pt-rich shell. This catalyst demonstrates both exceptionally high activity and durability, achieving a mass activity of 2.6 A∙mg Pt −1 in rotating disk electrode testing. In fuel cell membrane electrode assembly tests, Pt 5 (Ce)Co@Pt achieves a current density of 1.9 A∙cm −2 at 0.7 V under heavy-duty vehicle conditions. Remarkably, it maintains 1.2 A∙cm −2 after 1 80 000 AST cycles, doubling the U.S. DOE 2025 target. This work demonstrates a rational design strategy that DFT-guided strain engineering integrates with rare-earth templating to advance Pt-based catalysts for fuel cell applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Conceptual design and analysis of a large antenna utilizing electrostatic membrane management

Conceptual designs and associated technologies for deployment 100 m class radiometer antennas were developed. An electrostatically suspended and controlled membrane mirror and the supporting structure are discussed. The integrated spacecraft including STS cargo bay stowage and development were analyzed. An antenna performance evaluation was performed as a measure of the quality of the membrane/spacecraft when used as a radiometer in the 1 GHz to 5 GHz region. Several related LSS structural dynamic models differing by their stiffness property (and therefore, lowest modal frequencies) are reported. Control system whose complexity varies inversely with increasing modal frequency regimes are also reported. Interactive computer-aided-design software is discussed.

Brooks, A. L.↗

Proton Exchange Membrane (PEM) Water Electrolysis: Cell-Level Considerations for Gigawatt-Scale Deployment

Hydrogen produced with no greenhouse gas emissions is termed “green hydrogen” and will be essential to reaching decarbonization targets set forth by nearly every country as per the Paris Agreement. Proton exchange membrane water electrolyzers (PEMWEs) are expected to contribute substantially to the green hydrogen market. However, PEMWE market penetration is insignificant, accounting for less than a gigawatt of global capacity. Achieving substantive decarbonization via green hydrogen will require PEMWEs to reach capacities of hundreds of gigawatts by 2030. This paper serves as an overarching roadmap for cell-level improvements necessary for gigawatt-scale PEMWE deployment, with insights from three well-established hydrogen technology companies included. Analyses will be presented for economies of scale, renewable energy prices, government policies, accelerated stress tests, and component-specific improvements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Primary Objective Grating Astronomical Telescope

It has been 370 years since a seventeenth century French mathematician, Mersenne, presciently sketched out an astronomical telescope based on dual parabolic reflectors. Since that time the concept of the primary objective has been virtually unchanged. Now a new class of astronomical telescope with a primary objective grating (POG) has been studied as an alternative. The POG competes with mirrors, in part, because diffraction gratings provide the very chromatic dispersion that mirrors defeat. The resulting telescope deals effectively with long-standing restrictions on multiple object spectroscopy (MOS). Other potential benefits include unprecedented apertures and collection areas. The new design also favors space deployment as a gossamer membrane. The inventor, Tom Ditto, first discovered that higher-order diffraction images contain hidden depth cues, for which he was granted a seminal range finding patent in 1987. Subsequently, he invented and patented 3D localizers, profilometers and microscopes using POGs. The POG telescope was placed in the public domain to expedite research. The function of a telescopes primary objective is to collect flux and to deliver images. Both functions dictate that size matters, and bigger is better. For that reason, there has been a steady push over the past century to ramp up the size of the primary mirror. However, for every doubling of mirror diameter, the elapsed time between initial effort and first light has also doubled. Meanwhile, costs escalated beyond the mirror alone, because larger instruments required larger enclosures and better pointing mechanisms. One key catalog of observation, spectrographic data, is far more difficult to amass than two-dimensional imagery. While the number of observable objects has increased with mirror size, the capacity to take spectra has not increased proportionately. In the best of circumstances, spectrograms are available for one per cent of the all objects surveyed. Spectroscopy was a historical afterthought introduced in the nineteenth century shortly after the invention of the diffraction grating and over a century after Newtons 1670 telescope. Spectroscopy is generally accomplished using a diffraction grating as the disperser in the secondary. The light being delivered to the spectrograph is first captured by a primary mirror which provides no chromatic magnification by itself. Sizeable spectrographs could not be deployed while diffraction gratings were rare commodities scribed using mechanical ruling engines that produced one grating line at a time. Today diffraction gratings are commonplace. Their recent availability is a product of both the invention of holography and the mass replication of surface microstructures. Holography permits all lines in a grating to be made simultaneously in a single photographic exposure. Holograms can then be reproduced by embossing processes. The improvement in replication is analogous to how Gutenberg changed the availability of books. The masters may be expensive, but the copies are not. Computer science is another technology that emerged in the second half of the twentieth century without which our proposed spectrographic instrument could not function due to the complexity of image processing required in data reduction. The employment of very large diffraction gratings as primary objectives for astronomical telescopes requires a novel

spectroscopy↗

Deployment Technology of a Heliogyro Solar Sail for Long Duration Propulsion

Interplanetary, multi-mission, station-keeping capabilities will require that a spacecraft employ a highly efficient propulsion-navigation system. The majority of space propulsion systems are fuel-based and require the vehicle to carry and consume fuel as part of the mission. Once the fuel is consumed, the mission is set, thereby limiting the potential capability. Alternatively, a method that derives its acceleration and direction from solar photon pressure using a solar sail would eliminate the requirement of onboard fuel to meet mission objectives. MacNeal theorized that the heliogyro-configured solar sail architecture would be lighter, less complex, cheaper, and less risky to deploy a large sail area versus a masted sail. As sail size increases, the masted sail requires longer booms resulting in increased mass, and chaotic uncontrollable deployment. With a heliogyro, the sail membrane is stowed as a roll of thin film forming a blade when deployed that can extend up to kilometers. Thus, a benefit of using a heliogyro-configured solar sail propulsion technology is the mission scalability as compared to masted versions, which are size constrained. Studies have shown that interplanetary travel is achievable by the heliogyro solar sail concept. Heliogyro solar sail concept also enables multi-mission missions such as sample returns, and supply transportation from Earth to Mars as well as station-keeping missions to provide enhanced warning of solar storm. This paper describes deployment technology being developed at NASA Langley Research Center to deploy and control the center-of-mass/center-of-pressure using a twin bladed heliogyro solar sail 6-unit (6U) CubeSat. The 6U comprises 2x2U blade deployers and 2U for payload. The 2U blade deployers can be mounted to 6U or larger scaled systems to serve as a non-chemical in-space propulsion system. A single solar sail blade length is estimated to be 2.4 km with a total area from two blades of 720 m2; total allowable weight of a 6U CubeSat is approximately 8 kg. This makes the theoretical characteristic acceleration of approximately 0.75 mm/s2 at I AU (astronomical unit), when compared to IKAROS (0.005 mm/s2) and NanoSail-D (0.02 mm/s2).

Peerawan, Wiwattananon↗

Thermal-Structural Analysis of Sunshield Membranes

Future large infrared space telescopes, such as the James Webb Space Telescope (JWST), will require deployable sunshields to provide passive cooling for optics and instruments. Deployable sunshield structures for such applications typically consist of multiple thin-film membrane layers supported by deployable booms. The mechanical design of the sunshield must accommodate thermal strains due to layer-to-layer temperature differences as well as potentially large in-plane temperature gradients within individual film layers. This paper describes a thermal-structural analysis for predicting the stress state in a thin-film membrane subject to both mechanical thermal loads that could aid in the mechanical design of future sunshield structures. First the temperature field predicted by a thermal analysis is mapped to a structural finite element model, and then the structural response is predicted using a nonlinear static analysis. The structural model uses membrane elements in conjunction with a tension field material model to predict the response of the thin-film membrane layer. The tension field material model accounts for no-compression behavior associated with wrinkling and slackness. This approach was used to study the problem of a single membrane layer from the NASA reference concept for the JWST sunshield. Results from the analysis show that the membrane can experience a loss of tensile preload due to the presence of an in-plane temperature gradient representative of the cold-side layer temperature distribution predicted for the reference concept JWST.

Johnston, John↗

Ionomer-free and recyclable porous-transport electrode for high-performing proton-exchange-membrane water electrolysis

Abstract Clean hydrogen production requires large-scale deployment of water-electrolysis technologies, particularly proton-exchange-membrane water electrolyzers (PEMWEs). However, as iridium-based electrocatalysts remain the only practical option for PEMWEs, their low abundance will become a bottleneck for a sustainable hydrogen economy. Herein, we propose high-performing and durable ionomer-free porous transport electrodes (PTEs) with facile recycling features enabling Ir thrifting and reclamation. The ionomer-free porous transport electrodes offer a practical pathway to investigate the role of ionomer in the catalyst layer and, from microelectrode measurements, point to an ionomer poisoning effect for the oxygen evolution reaction. The ionomer-free porous transport electrodes demonstrate a voltage reduction of > 600 mV compared to conventional ionomer-coated porous transport electrodes at 1.8 A cm −2 and <0.1 mg Ir cm −2 , and a voltage degradation of 29 mV at average rate of 0.58 mV per 1000-cycles after 50k cycles of accelerated-stress tests at 4 A cm −2 . Moreover, the ionomer-free feature enables facile recycling of multiple components of PEMWEs, which is critical to a circular clean hydrogen economy.

08 HYDROGEN↗

Wirelessly Controllable Inflated Electroactive Polymer (EAP) Reflectors

Inflatable membrane reflectors are attractive for deployable, large aperture, lightweight optical and microwave systems in micro-gravity space environment. However, any fabrication flaw or temperature variation may results in significant aberration of the surface. Even for a perfectly fabricated inflatable membrane mirror with uniform thickness, theory shows it will form a Hencky curve surface but a desired parabolic or spherical surface. Precision control of the surfaceshape of extremely flexible membrane structures is a critical challenge for the success of this technology. Wirelessly controllable inflated reflectors made of electroactive polymers (EAP) are proposed in this paper. A finite element model was configured to predict the behavior of the inflatable EAP membranes under pre-strains, pressures and distributed electric charges on the surface. To explore the controllability of the inflatable EAP reflectors, an iteration algorism was developed to find the required electric actuation for correcting the aberration of the Hencky curve to the desired parabolic curve. The correction capability of the reflectors with available EAP materials was explored numerically and is presented in this paper.

Electroactive polymer (EAP)↗

TPSAS-NF1676L-18560-DND

The heliogyro is a helicopter-like spinning solar sail concept, conceived by MacNeal in the 1960s and studied by JPL in the 1970s. The heliogyro is a mission-enabling technology: - Membrane solar sail “blades” are compactly stowed on reels and easily deployed. - No elaborate management of large, 2-D membranes structures needed, so architecture may be scaled to very large sizes. - Lightweight due to centrifugal stiffening. Despite these advantages, development has lagged heavier, square-rigged solar sail designs (e.g., Sunjammer) due to the difficulty of fullscale ground testing. Dynamics need to be validated by (validated) analysis, followed by an affordable flight demonstration, to advance the maturity of heliogyro solar sailing technology.

Keats Wilkie↗

Developing Enzyme Immobilization with Fibrous Membranes: Longevity and Characterization Considerations

Fibrous membranes offer broad opportunities to deploy immobilized enzymes in new reactor and application designs, including multiphase continuous flow-through reactions. Enzyme immobilization is a technology strategy that simplifies the separation of otherwise soluble catalytic proteins from liquid reaction media and imparts stabilization and performance enhancement. Flexible immobilization matrices made from fibers have versatile physical attributes, such as high surface area, light weight, and controllable porosity, which give them membrane-like characteristics, while simultaneously providing good mechanical properties for creating functional filters, sensors, scaffolds, and other interface-active biocatalytic materials. This review examines immobilization strategies for enzymes on fibrous membrane-like polymeric supports involving all three fundamental mechanisms of post-immobilization, incorporation, and coating. Post-immobilization offers an infinite selection of matrix materials, but may encounter loading and durability issues, while incorporation offers longevity but has more limited material options and may present mass transfer obstacles. Coating techniques on fibrous materials at different geometric scales are a growing trend in making membranes that integrate biocatalytic functionality with versatile physical supports. Biocatalytic performance parameters and characterization techniques for immobilized enzymes are described, including several emerging techniques of special relevance for fibrous immobilized enzymes. Diverse application examples from the literature, focusing on fibrous matrices, are summarized, and biocatalyst longevity is emphasized as a critical performance parameter that needs increased attention to advance concepts from lab scale to broader utilization. This consolidation of fabrication, performance measurement, and characterization techniques, with guiding examples highlighted, is intended to inspire future innovations in enzyme immobilization with fibrous membranes and expand their uses in novel reactors and processes.

59 BASIC BIOLOGICAL SCIENCES↗

Development and Commercialization of a Nanosegrated Oxygen Evolution Reaction Electrocatalyst (CRADA)

This collaborative project leverages advanced characterization tools, catalyst treatment and electrochemical testing capabilities at LBNL to help commercialize a bimetallic nanosegrated catalysts for oxygen evolution reaction in proton-exchange membrane water electrolyzers. This project also has three industrial partners who are involved in catalyst scale-up synthesis, large electrode fabrication and large electrode electrochemical testing. This project investigates a broad range of topics including electrocatalysis, ink rheology and electrode fabrication and testing. This knowledge could help bridge the performance and durability gap from laboratory-developed materials (such as electrocatalysts) to applications in commercial devices. The research results also bring fundamental understanding of possible degradation mechanisms that occur under extremely oxidative potentials including material and morphological changes. The project will help accelerate the deployment of proton-exchange membrane water electrolyzers. The public benefits could include creating jobs and increasing public awareness of potential clean technologies for green hydrogen production. Ultimately, the project will help national wide effort of flighting climate change and achieving carbon neutrality by 2050.

30 DIRECT ENERGY CONVERSION↗

Test progress on the electrostatic membrane reflector

An extemely lightweight type of precision reflector antenna, being developed for potential deployment from the space shuttle, uses electrostatic forces to tension a thin membrane and form it into a concave reflector surface. The typical shuttle-deployed antenna would have a diameter of 100 meters and an RMS surface smoothness of 10 to 1 mm for operation at 1 to 10 GHz. NASA Langley Research Center built and is currently testing a subscale (16 foot diameter) model of the membrane reflector portion of such an antenna. Preliminary test results and principal factors affecting surface quality are addressed. Factors included are the effect of the perimeter boundary, splicing of the membrane, the long-scale smoothness of commercial membranes, and the spatial controllability of the membrane using voltage adjustments to alter the electrostatic pressure. Only readily available commercial membranes are considered.

Mihora, D. J.↗

Solar Cruiser TRAC Boom Development

The TRAC boom studied is a 30 meter, high-aspect ratio and highly nonlinear structural element planned for the NASA Solar Cruiser spacecraft where it would serve as the solar sail’s skeletal system designed to deploy the packaged reflective sail membrane as well as support operational sail tension loads for flight. Key design drivers for this boom are understanding and characterizing load-deformation behavior and quantifying buckling performance–under flight conditions (zero gravity). Knowing that the full-scale solar sail system cannot be feasibly tested for flight conditions under Earth’s gravity, a building block approach is methodically followed to verify finite element analysis (FEA) predictions and to evolve the finite element model (FEM) accordingly, beginning with the lowest level complexity to match global elastic behavior to the highest level complexity to bound theoretical responses under conservative expected flight conditions. Although the testing campaign for the TRAC boom has not developed yet to produce a full-scale test data point that loads the boom to failure, the fidelity of simulations have evolved with success and warrant further interest and work on this high-aspect ratio, but highly stable, deployable structural boom.

Lee Nguyen↗

Free-flying solar reflector spacecraft

Results of investigations of requirements and design concepts for large solar-reflecting spacecraft are given. The emphasis is on the one kilometer diameter self contained spacecraft that can be packaged and launched in the space shuttle. The configuration consists of a compression rim stabilized by stays coming from each end of the central compression hub. The stays are stowed on reels on the ends of the hub. The hub consists of two Astromasts which are deployed after launch. The reflector membrane is a two micron thick Kapton film with a vapor deposited aluminum coating.

Hedgepeth, J. M.↗

Determination of Electromagnetic Properties of Mesh Material Using Advanced Radiometer Techniques

The need for a large diameter deployable antenna to map soil moisture with a 10 kilometer or better resolution using a microwave radiometer is discussed. A 6 meter deployable antenna is also needed to map sea surface temperature on the Navy Remote Ocean Sensor System (NROSS). Both of these deployable antennas require a mesh membrane material as the reflecting surface. The determination of the electromagnetic properties of mesh materials is a difficult problem. The Antenna and Microwave Research Branch (AMRB) of Langley Research Center was asked to measure the material to be used on MROSS by NRL. A cooperative program was initiated to measure this mesh material using two advanced radiometer techniques.

Arrington, R. F.↗

Deployable antenna

A deployable antenna and method for using wherein the deployable antenna comprises a collapsible membrane having at least one radiating element for transmitting electromagnetic waves, receiving electromagnetic waves, or both.

Fink, Patrick W.↗

Telescope Formation at L2 for Observing Earth's Atmosphere

Two documents describe a proposed Earth-atmosphere observatory to orbit the Sun at the Sun-Earth L2 Lagrange point -- a point of unstable equilibrium in the shadow of the Earth, about 1.5 million km from the Earth along an outward projection of the Earth-Sun axis. The observatory would comprise two spacecraft flying in precision formation: (1) a primary-aperture spacecraft, from which would be deployed a 25-m diameter membrane primary mirror aimed at the Earth, and (2) a secondary-telescope spacecraft at the focal plane of the primary mirror, 125-m distant along the axis towards the Earth. The secondary telescope would be aimed at the primary mirror and slowly rotated to scan the focused annular image of the visible illuminated portion of the Earth's atmosphere during continuous occultation of the Sun.

Mettler, Edward↗