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Ternary and quaternary oxides of Bi, Sr and Cu

Before the discovery of superconductivity in an oxide of Bi, Sr, and Cu, the system Bi-Sr-Cu-O had not been studied, although several solid phases had been identified in the two-component regions of the ternary system Bi2O3-Si-O-CuO. The oxides Sr2CuO3, SrCu2O2, SrCuO2, and Bi2CuO4 were then well known and characterized, and the phase diagram of the binary system Bi2O3-SrO had been established in the temperature range 620 to 1000 C. Besides nine solutions of compositions Bi(2-2x) Sr(x) O(3-2x) and different symmetries, this diagram includes three definite compounds of stoichiometries Bi(2)BrO4. Bi2Sr2O5, and Bi2Sr3O6 (x - 0.50, 0.67 and 0.75 respectively), only the second of which with known unit-cell of orthorhombic symmetry, dimensions (A) a = 14.293(2), b = 7.651(2), c = 6.172(1), and z = 4. The first superconducting oxide in the system Bi-Sr-Cu-O was initially formulated as Bi2Sr2Cu2O(7+x), with an orthorhombic unit-cell of parameters (A) a = 5.32, b = 26.6, c = 48.8. In a preliminary study the same oxide was formulated with half the copper content, Bi(2)Sr(2)CuO(6+x), and index its reflections assuming an orthorhombic unit-cell of dimensions (A) a = 5.390(2), b = 26.973(8), c = 24.69(4). Subsequent studies by diffraction techniques have confirmed the composition 2:2:1. A new family of oxygen-deficient perovskites, was characterized, after identifying by x ray diffraction the phases present in the products of thermal treatments of about 150 mixtures of analytical grade Bi2O3, Sr(OH)2-8H2O and CuO at different molar ratios. X ray diffraction data are presented for some other oxides of Bi and Sr, as well as for various quaternary oxides, among them an oxide of Bi, Sr, and Cu.

Casais, M. T.↗

Imaging Systems for Size Measurements of Debrisat Fragments

The overall objective of the DebriSat project is to provide data to update existing standard spacecraft breakup models. One of the key sets of parameters used in these models is the physical dimensions of the fragments (i.e., length, average-cross sectional area, and volume). For the DebriSat project, only fragments with at least one dimension greater than 2 mm are collected and processed. Additionally, a significant portion of the fragments recovered from the impact test are needle-like and/or flat plate-like fragments where their heights are almost negligible in comparison to their other dimensions. As a result, two fragment size categories were defined: 2D objects and 3D objects. While measurement systems are commercially available, factors such as measurement rates, system adaptability, size characterization limitations and equipment costs presented significant challenges to the project and a decision was made to develop our own size characterization systems. The size characterization systems consist of two automated image systems, one referred to as the 3D imaging system and the other as the 2D imaging system. Which imaging system to use depends on the classification of the fragment being measured. Both imaging systems utilize point-and-shoot cameras for object image acquisition and create representative point clouds of the fragments. The 3D imaging system utilizes a space-carving algorithm to generate a 3D point cloud, while the 2D imaging system utilizes an edge detection algorithm to generate a 2D point cloud. From the point clouds, the three largest orthogonal dimensions are determined using a convex hull algorithm. For 3D objects, in addition to the three largest orthogonal dimensions, the volume is computed via an alpha-shape algorithm applied to the point clouds. The average cross-sectional area is also computed for 3D objects. Both imaging systems have automated size measurements (image acquisition and image processing) driven by the need to quickly and accurately measure tens of thousands of debris fragments. Moreover, the automated size measurement reduces potential fragment damage/mishandling and ability for accuracy and repeatability. As the fragment characterization progressed, it became evident that the imaging systems had to be revised. For example, an additional view was added to the 2D imaging system to capture the height of the 2D object. This paper presents the DebriSat project's imaging systems and calculation techniques in detail; from design and development to maturation. The experiences and challenges are also shared.

Shiotani, B.↗

Self-Consistent Simulation of the Brownian Stage of Dust Growth

It is a widely accepted view that in proto-planetary accretion disks the collision and following sticking of dust particles embedded in the gas eventually leads to the formation of planetesimals (coagulation). For the smallest dust grains, Brownian motion is assumed to be the dominant source of their relative velocities leading to collisions between these dust grains. As the dust grains grow they eventually couple to the turbulent motion of the gas which then drives the coagulation much more efficiently. Many numerical coagulation simulations have been carried out to calculate the fractal dimension of the aggregates, which determines the duration of the ineffective Brownian stage of growth. Predominantly on-lattice and off-lattice methods were used. However, both methods require simplification of the astrophysical conditions. The aggregates found by those methods had a fractal dimension of approximately 2 which is equivalent to a constant, mass-independent friction time. If this value were valid for the conditions in an accretion disk, this would mean that the coagulation process would finally 'freeze out' and the growth of a planetesimal would be impossible within the lifetime of an accretion disk. In order to investigate whether this fractal dimension is model independent, we simulate self-consistently the Brownian stage of the coagulation by an N-particle code. This method has the advantage that no further assumptions about homogeneity of the dust have to be made. In our model, the dust grains are considered as aggregates built up of spheres. The equation of motion of the dust grains is based on the probability density for the diffusive transport within the gas atmosphere. Because of the very low number density of the dust grains, only 2-body-collisions have to be considered. As the Brownian stage of growth is very inefficient, the system is to be simulated over long periods of time. In order to find close particle pairs of the system which are most likely to undergo a collision, we use a particle-in-cell (PIC) method for the early stages of the simulation where the system is still very homogeneous and a tree method later when the particles are more clustered.

Kempf, S.↗

Turbulent Methane-Air Combustion

This study is aimed at enhancing the understanding of turbulent premixed methane-air combustion. Such understanding is essential since: (1) many industries are now pursuing lighter hydrocarbon alternative fuels and the use of premixed flames to reduce pollutant emissions, and (2) the characteristic dimensions and flow rates of most industrial combustors are often large for flows to be turbulent. The specific objectives of the study are: (1) to establish the effects of process variables (e.g., flow rate, fuel/air ratio, chlorinated hydro-carbons, and pressure) on the emissions and flow structure (velocity distribution, streamlines, vorticity and flame shape), and (2) to develop a mechanistic model to explain the observed trends. This includes the acquisition of Dantec FlowMap Particle Image Velocimeter. The design and fabrication of the premixed burner has also been completed. The study is now at the stage of testing of equipment and analytical instruments. The presentation will give details on the tasks completed and on the current and future plans. The project is progressing well and all activities are on schedule. The outlook for the success of the project is bright.

Yaboah, Yaw D.↗

The attractor dimension of solar decimetric radio pulsations

The temporal characteristics of decimetric pulsations and related radio emissions during solar flares are analyzed using statistical methods recently developed for nonlinear dynamic systems. The results of the analysis is consistent with earlier reports on low-dimensional attractors of such events and yield a quantitative description of their temporal characteristics and hidden order. The estimated dimensions of typical decimetric pulsations are generally in the range of 3.0 + or - 0.5. Quasi-periodic oscillations and sudden reductions may have dimensions as low as 2. Pulsations of decimetric type IV continua have typically a dimension of about 4.

Kurths, J.↗

Structure of 4-methylpyridinium Hydrogen Sulfide

4-Methylpyridinium hydrogen sulfide, (C6H7NH)HS, M(sub r) = 127.21, consists of C6H7NH(+) cations and HS(-) anions. Z = 2 for the crystal with monoclinic space group Cm (#8), dimensions of a = 8.679(2) A, b = 7.964(1) A, and c = 4.860(2) A, an angle beta of 101.10(2) degrees, and a volume of V = 329.6(3) A(exp 3). R = 0.039 and R(sub w) = 0.048 for 385 reflections with F(sub o)(exp 2) greater than 3 sigma(F(sub o)(exp 2)) and 59 variables. Both the C6H7NH(+) cation and the HS(-) anion lie on crystallographic mirror planes with the N,S, two carbon atoms, and two hydrogen atoms positioned in the planes. The hydrogen atom of the HS(-) anion was not located.

Andras, Maria T.↗

Experimental investigation of the relationship between impact crater morphology and impacting particle velocity and direction

Interpretation of the wealth of impact data available from the Long Duration Exposure Facility, in terms of the absolute and relative populations of space debris and natural micrometeoroids, requires three dimensional models of the distribution of impact directions, velocities and masses of such particles, as well as understanding of the impact processes. Although the stabilized orbit of LDEF provides limited directional information, it is possible to determine more accurate impact directions from detailed crater morphology. The applicability of this technique has already been demonstrated but the relationship between crater shape and impactor direction and velocity has not been derived in detail. We present the results of impact experiments and simulations: (1) impacts at micron dimensions using the Unit's 2MV Van de Graaff accelerator; (2) impacts at mm dimensions using a Light Gas Gun; and (3) computer simulations using AUTODYN-3D from which an empirical relationship between crater shape and impactor velocity, direction and particle properties we aim to derive. Such a relationship can be applied to any surface exposed to space debris or micrometeoroid particles for which a detailed pointing history is available.

Mackay, N. G.↗

Hybrid simulations of the saturated Farley-Buneman instability in the ionosphere

Numerical simulations of the Farley-Buneman instability in 2-1/2 dimensions using particle ions and fluid electrons show the growth, saturation and nonlinear behavior of two-stream waves. This hybrid technique models the saturated state of the instability for a much longer period of time than the pure particle codes that preceded it. While focusing principally on modeling the topside E region equatorial electrojet, many of these results apply to the auroral two-stream instability as well. The following features are seen in all our hybrid simulations: (1) wave growth at an angle offset from the electron drift direction where the angle depends on the strength of the driving electric field, (2) nonlinear coupling to waves traveling perpendicular to the propagation direction of the principal two-stream waves, (3) a saturated wave phase velocity at or above the sound speed but well below the velocity predicted by linear theory and (4) phase velocities which remain almost constant as a simulated radar sweeps from a horizontal direction to nearly vertical. The nonlinear electron motion dominates the behavior of these waves. Further, these simulations indicate that ion kinetic effects are not essential for the saturation of the instability and that electron temperature effects have a minor impact on the final saturated state.

Oppenheim, Meers↗

On the connection between multigrid and cyclic reduction

A technique is shown whereby it is possible to relate a particular multigrid process to cyclic reduction using purely mathematical arguments. This technique suggest methods for solving Poisson's equation in 1-, 2-, or 3-dimensions with Dirichlet or Neumann boundary conditions. In one dimension the method is exact and, in fact, reduces to cyclic reduction. This provides a valuable reference point for understanding multigrid techniques. The particular multigrid process analyzed is referred to here as Approximate Cyclic Reduction (ACR) and is one of a class known as Multigrid Reduction methods in the literature. It involves one approximation with a known error term. It is possible to relate the error term in this approximation with certain eigenvector components of the error. These are sharply reduced in amplitude by classical relaxation techniques. The approximation can thus be made a very good one.

Merriam, M. L.↗

Strange attractors in weakly turbulent Couette-Taylor flow

An experiment is conducted on the transition from quasi-periodic to weakly turbulent flow of a fluid contained between concentric cylinders with the inner cylinder rotating and the outer cylinder at rest. Power spectra, phase-space portraits, and circle maps obtained from velocity time-series data indicate that the nonperiodic behavior observed is deterministic, that is, it is described by strange attractors. Various problems that arise in computing the dimension of strange attractors constructed from experimental data are discussed and it is shown that these problems impose severe requirements on the quantity and accuracy of data necessary for determining dimensions greater than about 5. In the present experiment the attractor dimension increases from 2 at the onset of turbulence to about 4 at a Reynolds number 50-percent above the onset of turbulence.

Brandstater, A.↗

Effect of sound on boundary layer stability

Experiments are conducted in the Arizona State University Unsteady Wind Tunnel with a zero-pressure-gradient flat-plate model that has a 67:1 elliptical leading edge. Boundary-layer measurements are made of the streamwise fluctuating-velocity component in order to identify the amplified T-S waves that are forced by downstream-traveling sound waves. Measurements are taken with circular 3-D roughness elements placed at the Branch 1 neutral stability point for the frequency under consideration, and then with the roughness element downstream of Branch 1. These roughness elements have a principal chord dimension equal to 2 lambda(sub TS)/pi of the T-S waves under study and are 'stacked' in order to resemble a Gaussian height distribution. Measurements taken just downstream of the roughness (with leading-edge T-S waves, surface roughness T-S waves, instrumentation sting vibrations, and the Stokes wave subtracted) show the generation of 3-D T-S waves, but not in the characteristic heart-shaped disturbance field predicted by 3-D asymptotic theory. Maximum disturbance amplitudes are found on the roughness centerline. However, some near-field characteristics predicted by numerical modeling are observed.

Saric, William S.↗

Effect of sound on boundary layer stability

Experiments are conducted in the Arizona State University Unsteady Wind Tunnel with a zero-pressure-gradient flat-plate model that has a 67:1 elliptical leading edge. Boundary-layer measurements are made of the streamwise fluctuating-velocity component in order to identify the amplified T-S waves that are forced by downstream-travelling, sound waves. Measurements are taken with circular 3-D roughness elements placed at the Branch 1 neutral stability point for the frequency under consideration, and then with the roughness element downstream of Branch 1. These roughness elements have a principal chord dimension equal to 2(lambda)(sub TS)/pi, of the T-S waves under study and are 'stacked' in order to resemble a Gaussian height distribution. Measurements taken just downstream of the roughness (with leading-edge T-S waves, surface roughness T-S waves, instrumentation sting vibrations and the Stokes wave subtracted) show the generation of 3-D-T-S waves, but not in the characteristic heart-shaped disturbance field predicted by 3-D asymptotic theory. Maximum disturbance amplitudes are found on the roughness centerline. However, some near-field characteristics predicted by numerical modelling are observed.

Saric, William S.↗

Advancement of X-Ray Microscopy Technology and its Application to Metal Solidification Studies

The technique of x-ray projection microscopy is being used to view, in real time, the structures and dynamics of the solid-liquid interface during solidification. By employing a hard x-ray source with sub-micron dimensions, resolutions of 2 micrometers can be obtained with magnifications of over 800 X. Specimen growth conditions need to be optimized and the best imaging technologies applied to maintain x-ray image resolution, contrast and sensitivity. It turns out that no single imaging technology offers the best solution and traditional methods like radiographic film cannot be used due to specimen motion (solidification). In addition, a special furnace design is required to permit controlled growth conditions and still offer maximum resolution and image contrast.

Kaukler, William F.↗

Advancement of X-Ray Microscopy Technology and Its Application to Metal Solidification Studies

The technique of x-ray projection microscopy is being used to view, in real time, the structures and dynamics of the solid-liquid interface during solidification. By employing a hard x-ray source with sub-micron dimensions, resolutions of 2 microns can be obtained with magnifications of over 800 X. Specimen growth conditions need to be optimized and the best imaging technologies applied to maintain x-ray image resolution, contrast and sensitivity. It turns out that no single imaging technology offers the best solution and traditional methods like radiographic film cannot be used due to specimen motion (solidification). In addition, a special furnace design is required to permit controlled growth conditions and still offer maximum resolution and image contrast.

Kaukler, William F.↗

Evaluation of Open Cell Foam Heat Transfer Enhancement for Liquid Rocket Engine

As NASA pursues the exploration mission, advanced propulsion for the next generation of spacecraft will be needed. These new propulsion systems will require higher performance and increased durability, despite current limitations on materials. A break-through technology is needed in the thrust chamber. In this paper the idea of using a porous metallic foam is examined for its potential cooling enhancement capabilities. The goal is to increase the chamber wall cooling without creating an additional pressure drop penalty. A feasibility study based on experiments at laboratory-scale conditions was performed and analysis at rocket conditions is underway. In the experiment, heat transfer and pressure drop data were collected using air as the coolant in a copper or nickel foam filled annular channel. The foam-channel performance was evaluated based on comparison with conventional microchannel cooling passages under equal pressure drop conditions. The heat transfer enhancement of the foam channel over the microchannel ranges from 130% to 172%. The enhancement is relatively independent of the pressure drop and increases with decreasing pore size. A direct numerical simulation model of the foam heat exchange has been built. The model is based on the actual metal foam microstructure of thin ligaments (0.2- 0.3 mm in diameter) that form a network of interconnected open-cells. The cell dimension is around 2 mm. The numerical model was built using the FLUENT CFD code. Comparison of the pressure drop results predicted by the current model with those experimental data of Leong and Jin [8] shows favorable comparisons. Pressure drop predictions have been made using hydrogen as a coolant at typical rocket conditions. Conjugate heat transfer analysis using the foam filled channel is planned for the future.

Chung, J. N.↗

Photonic Bandgap (PBG) Shielding Technology

Photonic Bandgap (PBG) shielding technology is a new approach to designing electromagnetic shielding materials for mitigating Electromagnetic Interference (EM!) with small, light-weight shielding materials. It focuses on ground planes of printed wiring boards (PWBs), rather than on components. Modem PSG materials also are emerging based on planar materials, in place of earlier, bulkier, 3-dimensional PBG structures. Planar PBG designs especially show great promise in mitigating and suppressing EMI and crosstalk for aerospace designs, such as needed for NASA's Constellation Program, for returning humans to the moon and for use by our first human visitors traveling to and from Mars. Photonic Bandgap (PBG) materials are also known as artificial dielectrics, meta-materials, and photonic crystals. General PBG materials are fundamentally periodic slow-wave structures in I, 2, or 3 dimensions. By adjusting the choice of structure periodicities in terms of size and recurring structure spacings, multiple scatterings of surface waves can be created that act as a forbidden energy gap (i.e., a range of frequencies) over which nominally-conductive metallic conductors cease to be a conductor and become dielectrics. Equivalently, PBG materials can be regarded as giving rise to forbidden energy gaps in metals without chemical doping, analogous to electron bandgap properties that previously gave rise to the modem semiconductor industry 60 years ago. Electromagnetic waves cannot propagate over bandgap regions that are created with PBG materials, that is, over frequencies for which a bandgap is artificially created through introducing periodic defects

Bastin, Gary L.↗

High Energy Interactions in Massive Binaries: An Application to a Most Mysterious Binary

Extremely massive stars (50M and above) are exceedingly rare in the local Universe but are believed to have composed the entire first generation of stars, which lived fast, died young and left behind the first generation of black holes and set the stage for the formation of lower mass stars suitable to support life. There are significant uncertainties about how this happened (and how it still happens), mostly due to our poor knowledge of how stars change mass as they evolve. Extremely massive stars give mass back to the ISM via strong radiatively-driven winds and sometimes through sporadic eruptions of the most massive and brightest stars. Such mass loss plays an important role in the chemical and dynamical evolution of the local interstellar medium prior to the supernova explosion. Below we discuss how high energy thermal (and, in some cases, non-thermal) emission, along with modern simulations in 2 and 3 dimensions, can be used to help determine a physically realistic picture of mass loss in a well-studied, mysterious system.

Corcoran, Michael↗