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At least 73 records · Page 4

Passive Microwave Brightness Temperature Assimilation to Improve Snow Mass Estimation across Complex Terrain in Pakistan, Afghanistan, and Tajikistan

An ensemble Kalman filter is used to assimilate Advanced Microwave Scanning Radiometer-2 (AMSR2) observations of passive microwave (PMW) brightness temperatures (spectral differences, ΔT b ) into land surface model estimates of snow mass over northwestern high mountain Asia (HMA). Trained support vector machines serve as the observation operator and map the geophysical modeled variables into ΔT b space within the assimilation framework. Evaluation of the assimilation routine is carried out through comparison of assimilated snow mass estimates with an in situ dataset. The assimilation framework helps improve the land surface model estimates through PMW ΔT b assimilation, particularly in terms of decreasing the domain-wide bias. The assimilation framework proved more effective during the (dry) snow accumulation season and decreased the bias and root-mean-square error (RMSE) in snow mass estimates at 76% and 58% of the comparative pixels, respectively. During the snow ablation season, the PMW brightness temperature signal contained less information related to snow mass due to the presence of other concurrent geophysical features that effectively serve as noise during the snow mass update. The utilization of PMW ΔT b for accurate snow mass estimation in complex terrain such as HMA is dependent on a multitude of factors for optimal results; however, it does add utility to the land surface model if the relevant pitfalls are taken into consideration prior to the state variable update.

Jawairia Ahmad↗

A study of psychrophilic organisms isolated from the manufacture and assembly areas of spacecraft to be used in the Viking mission

The effect of storage of dry heat treated Teflon ribbons under nitrogen gas followed by high vacuum on the recovery of hardy organisms from the ribbons was studied. A similar experiment was performed on spore crops of hardy organisms recovered previously from Cape Canaveral. Hardy organisms have been inoculated onto slides and subjected to an artificial Martian environment in an attempt to demonstrate their growth in this environment. Additional experiments using the artificial Martian environment include response of soil samples from the VAB with both constant temperature and freeze-thaw cycles. These experiments were performed with dried soil and soil containing added water. Other investigations included the effect of heatshock on soil samples, psychrophilic counts of new soil samples from the manufacture area of the Viking spacecraft, effect of pour plate versus spread plate on psychrophilic counts, and preparation of spore crops of hardy organisms from Cape Canaveral.

Foster, T. L.↗

Remote Sensing of Aerosol Water Fraction, Dry Size Distribution and Soluble Fraction Using Multi-Angle, Multi-Spectral Polarimetry

A framework to infer volume water fraction, soluble fraction and dry size distributions of fine mode aerosol from multi-angle, multi-spectral polarimetry retrievals of column-averaged ambient aerosol properties is presented. The method is applied to observations of the Research Scanning Polarimeter (RSP) obtained during two NASA aircraft campaigns, namely the Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment (ACTIVATE) and the Cloud, Aerosol, and Monsoon Processes-Philippines Experiment (CAMP2Ex). All aerosol retrievals are statistically evaluated using in situ data. Volume water fraction is inferred from the retrieved ambient real part of the refractive index, assuming a dry refractive index of 1.54 and by applying a volume mixing rule to obtain the effective ambient refractive index. The uncertainties in inferred volume water fraction resulting from this simplified model are discussed and estimated to be lower than 0.2 and decreasing with increasing volume water fraction. The daily mean retrieved volume water fractions correlate well with the in situ values with a mean absolute difference of 0.09. Polarimeter-retrieved ambient effective radius for daily data is shown to increase as a function of volume water fraction as expected. Furthermore, the effective variance of the size distributions also increases with increasing effective radius, which we show is consistent with an external mixture of soluble and insoluble aerosol. The relative variations of effective radius and variance over an observation period are then used to estimate the soluble fraction of the aerosol. Daily results of soluble fraction correlate well with in situ observed sulfate mass fraction with a correlation coefficient of 0.79. Subsequently, inferred water and soluble fractions are used to derive dry fine-mode size distributions from their ambient counterparts. While dry effective radii obtained in situ and from RSP show similar ranges, in situ values are generally substantially smaller during the ACTIVATE deployments, which may be due to biases in RSP retrievals or in the in situ observations, or both. Both RSP and in situ observations indicate the dominance of aerosol with low hygroscopicity during the ACTIVATE and CAMP2Ex campaigns. Furthermore, RSP indicates a high degree of external mixing of particles with low and high hygroscopicity. These retrievals of fine mode water volume fraction and soluble fraction may be used for the evaluation of water uptake in atmospheric models. Furthermore, the framework allows to estimate the variation in the concentration of fine-mode aerosol larger than a specific dry radius limit, which can be used as a proxy for the variation in cloud condensation nucleus concentrations. This framework may be applied to multi-angle, multi-spectral satellite data expected to be available in the near future.

Bastiaan Van Diedenhoven↗

Remote Sensing of Aerosol Water Fraction, Dry Size Distribution and Soluble Fraction Using Multi-Angle, Multi-Spectral Polarimetry

A framework to infer volume water fraction, soluble fraction and dry size distributions of fine-mode aerosol from multi-angle, multi-spectral polarimetry retrievals of column-averaged ambient aerosol properties is presented. The method is applied to observations of the Research Scanning Polarimeter (RSP) obtained during two NASA aircraft campaigns, namely the Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment (ACTIVATE) and the Cloud, Aerosol, and Monsoon Processes Philippines Experiment (CAMP2Ex). All aerosol retrievals are statistically evaluated using in situ data. Volume water fraction is inferred from the retrieved ambient real part of the refractive index, assuming a dry refractive index of 1.54 and by applying a volume mixing rule to obtain the effective ambient refractive index. The uncertainties in inferred volume water fraction resulting from this simplified model are discussed and estimated to be lower than 0.2 and decreasing with increasing volume water fraction. The daily mean retrieved volume water fractions correlate well with the in situ values with a mean absolute difference of 0.09. Polarimeter-retrieved ambient effective radius for daily data is shown to increase as a function of volume water fraction as expected. Furthermore, the effective variance of the size distributions also increases with increasing effective radius, which we show is consistent with an external mixture of soluble and insoluble aerosol. The relative variations of effective radius and variance over an observation period are then used to estimate the soluble fraction of the aerosol. Daily results of soluble fraction correlate well with in situ-observed sulfate mass fraction with a correlation coefficient of 0.79. Subsequently, inferred water and soluble fractions are used to derive dry fine-mode size distributions from their ambient counterparts. While dry effective radii obtained in situ and from RSP show similar ranges, in situ values are generally substantially smaller during the ACTIVATE deployments, which may be due to biases in RSP retrievals or in the in situ observations, or both. Both RSP and in situ observations indicate the dominance of aerosol with low hygroscopicity during the ACTIVATE and CAMP2Ex campaigns. Furthermore, RSP indicates a high degree of external mixing of particles with low and high hygroscopicity. These retrievals of fine-mode water volume fraction and soluble fraction may be used for the evaluation of water uptake in atmospheric models. Furthermore, the framework allows us to estimate the variation in the concentration of fine-mode aerosol larger than a specific dry radius limit, which can be used as a proxy for the variation in cloud condensation nucleus concentrations. This framework may be applied to multi-angle, multi-spectral satellite data expected to be available in the near future.

Amount of water in particulate matter↗

Reverse-osmosis membranes by plasma polymerization

Thin allyl amine polymer films were developed using plasma polymerization. Resulting dry composite membranes effectively reject sodium chloride during reverse osmosis. Films are 98% sodium chloride rejective, and 46% urea rejective.

Hollahan, J. R.↗

Effective permittivity of dielectric mixtures

General mixing formulas are derived for discrete scatterers immersed in a host medium. The inclusion particles are assumed to be ellipsoidal. The electric field inside the scatterers is determined by quasi-static analysis, assuming the diameter of the inclusion particles to be much smaller than one wavelength. The results are applicable to general multiphase mixtures, and the scattering ellipsoids of the different phases can have different sizes and arbitrary ellipticity distribution and axis orientation, i.e., the mixture may be isotropic or anisotropic. The resulting mixing formula is nonlinear and is suitable for iterative solutions. The formula contains a quantity called the apparent permittivity, and with different choices of this quantity, the result leads to the generalized Lorentz-Lorenz formula, the generalized Polder-van Santen formula, and the generalized coherent potential-quasicrystalline approximation formula. The results are applied to calculating the complex effective permittivity of dry and wet snow, and sea ice.

Sihvola, Ari H.↗

Arctic ice surface temperature retrieval from AVHRR thermal channels

The relationship between AVHRR thermal radiances and the surface (skin) temperature of Arctic snow-covered sea ice is examined through forward calculations of the radiative transfer equation, providing an ice/snow surface temperature retrieval algorithm for the central Arctic Basin. Temperature and humidity profiles with cloud observations collected on an ice island during 1986-1987 are used. Coefficients that correct for atmospheric attenuation are given for three Arctic clear sky 'seasons', as defined through statistical analysis of the daily profiles, for the NOAA 7, 9, and 11 satellites. Modeled directional snow emissivities, different in the two split-window (11 and 12 micron) channels, are used. While the sensor scan angle is included explicitly in the correction equation, its effect in the dry Arctic atmosphere is small, generally less than 0.1 K. Using the split-window channels and scan angle, the rms error in the estimated ice surface temperature is less than 0.1 K in all seasons. Inclusion channel 3(3.7 microns) during the winter decreases the rms error by less than 0.003

Key, J.↗

Analysis of the lettuce data from the variable pressure growth chamber at NASA Johnson Space Center: A three-stage nested design model

A model of three-stage nested experimental design was applied to analyze the lettuce data obtained from the variable pressure growth chamber test bed at NASA-Johnson Space Center. From the results of an application of the analysis of variance and covariance on the data set, it was noted that all of the (uncontrollable) factors, Side, Zone, Height and (controllable) PAR (photosynthetically active radiation), had nonhomogeneous effects on the dry weight of the edible biomass of lettuce per pot. Incidentally, the variations accountable to the (uncontrollable) factorial heterogeneities are merely 9 percent and 17 percent of the total variation for both the first and second crop test, respectively. After adjusting for the PAR as a covariate in the no-intercept model, the accountable variations to all the four factors are 94 percent and 92 percent for the first and the second crop test, respectively. With the use of a no-intercept simple linear regression model, the accountable variations to the factor PAR are 92 percent and 90 percent for the first and the second crop test, respectively. Evidently, the (controllable) factor PAR is the dominating one.

Lee, Tze-San↗

Effect of Control Mode and Test Rate on the Measured Fracture Toughness of Advanced Ceramics

The effects of control mode and test rate on the measured fracture toughness of ceramics were evaluated by using chevron-notched flexure specimens in accordance with ASTM C1421. The use of stroke control gave consistent results with about 2% (statistically insignificant) variation in measured fracture toughness for a very wide range of rates (0.005 to 0.5 mm/min). Use of strain or crack mouth opening displacement (CMOD) control gave approx. 5% (statistically significant) variation over a very wide range of rates (1 to 80 μm/m/s), with the measurements being a function of rate. However, the rate effect was eliminated by use of dry nitrogen, implying a stress corrosion effect rather than a stability effect. With the use of a nitrogen environment during strain controlled tests, fracture toughness values were within about 1% over a wide range of rates (1 to 80 micons/m/s). CMOD or strain control did allow stable crack extension well past maximum force, and thus is preferred for energy calculations. The effort is being used to confirm recommendations in ASTM Test Method C1421 on fracture toughness measurement.

silicon nitride↗

Effect of Control Mode and Load Rate on Fracture Toughness of Brittle Ceramics

The effects of control mode and rate on the fracture toughness of ceramics were measured by using chevron-notched flexure specimen in accordance with ASTM C1421. The use of stroke control gave consistent results with about 2% variation in measured fracture toughness for a very wide range of rates (0.005 to 0.5 mm/min). Use of strain or CMOD control gave an approximately 5% variation over a very wide range of rates, with the measurements being a function of rate. However, the effect was eliminated by use of dry nitrogen, implying a stress corrosion effect rather than a stability effect. With the use of nitrogen for strain control, fracture toughness values were within about 1% over a wide range of rates (1 to 80 micro-epsilon/sec.). CMOD or strain control did allow stable crack extension well past maximum load, and thus is preferred for energy calculations. The effort is being used to confirm recommendations in ASTM International standard C1421 on fracture toughness measurement.

control mode↗

Effect of Control Mode and Test Rate on Fracture Toughness of Advanced Ceramics

The effects of control mode and rate on the fracture toughness of ceramics were measured by using chevron-notched flexure specimen in accordance with ASTM C1421. The use of stroke control gave consistent results with about 2% variation in measured fracture toughness for a very wide range of rates (0.005 to 0.5 mm/min). Use of strain or CMOD control gave ~5% variation over a very wide range of rates, with the measurements being a function of rate. However, the effect was eliminated by use of dry nitrogen, implying a stress corrosion effect rather than a stability effect. With the use of nitrogen for strain control, fracture toughness values were within about 1% over a wide range of rates (1 to 80 /s). CMOD or strain control did allow stable crack extension well past maximum load, and thus is preferred for energy calculations. The effort is being used to confirm recommendations in ASTM International standard C1421 on fracture toughness measurement.

fracture toughness↗

Hydrocarbon Burn Facility, SWMU 007 Per- and Polyfluoroalkyl Substances (PFAS) Assessment Report Addendum

This document discusses the Per-and Polyfluoroalkyl Substances (PFAS) assessment activities performed from May through August 2023 at the Hydrocarbon Burn Facility (HBF) located at Kennedy Space Center (KSC), Florida. HBF was used for firefighting training between 1966 and 1994. Aqueous film-forming foams (AFFFs) that contained PFAS were used as suppressants for fighting petroleum fuel fires during training. PFAS sampling was first completed at HBF in 2015. This PFAS Assessment Report Addendum (ARA) is a continuation of sampling efforts, with an overall objective to further delineate PFAS concentrations in groundwater to the pGCTLs and the United States Environmental Protection Agency (EPA) Tapwater Regional Screening Levels (RSLs) dated November 2023 and better understand groundwater to surface water interaction at the Site. The field activities presented in this PFAS ARA were conducted between May and August 2023 and included the collection of 132 direct push groundwater samples and the collection of five colocated surface water, sediment, and pore water samples from locations south/southeast of HBF in August 2023. Exceedances of the pGCTLs and Tapwater RSLs were observed in the direct push groundwater results; however, groundwater has been delineated to the pGCTLs. Exceedances of the Florida provisional Surface Water Screening Levels (pSWSLs) were observed in surface water and porewater, and concentrations of PFAS in these media confirm PFAS migration within surface channels to the south of the HBF site area. Maximum sediment concentrations, which correlate with the maximum surface water and porewater concentrations, demonstrate that PFAS impacted surface water is the source of sediment impacts. Overall, elevated concentrations of PFAS are centered on the HBF site area that trend north and south along the surface water filled swales and along the edge of Banana River. Based on analytical results, not all surface water features in this area exhibit evidence of transport. PFAS migration/transport appears to be more dominant in surface water features during the wet season. Discharges to the Banana River primarily occur where surface water facilitates transport. In contrast, groundwater transport is more effective during the dry season. During precipitation events in either the dry season or the wet season, there appears to be migration from the intermediate groundwater zone to the shallow zone into the surface water features. Additional sampling and data collection is recommended to support further refinement of PFAS groundwater delineation, a remedial alternative evaluation, and the fate and transport model.

Jennifer Buel↗

CO2 (dry ice) cleaning system

Tomco Equipment Company has participated in the dry ice (solid carbon dioxide, CO2) cleaning industry for over ten years as a pioneer in the manufacturer of high density, dry ice cleaning pellet production equipment. For over four years Tomco high density pelletizers have been available to the dry ice cleaning industry. Approximately one year ago Tomco introduced the DI-250, a new dry ice blast unit making Tomco a single source supplier for sublimable media, particle blast, cleaning systems. This new blast unit is an all pneumatic, single discharge hose device. It meters the insertion of 1/8 inch diameter (or smaller), high density, dry ice pellets into a high pressure, propellant gas stream. The dry ice and propellant streams are controlled and mixed from the blast cabinet. From there the mixture is transported to the nozzle where the pellets are accelerated to an appropriate blasting velocity. When directed to impact upon a target area, these dry ice pellets have sufficient energy to effectively remove most surface coatings through dry, abrasive contact. The meta-stable, dry ice pellets used for CO2 cleaning, while labeled 'high density,' are less dense than alternate, abrasive, particle blast media. In addition, after contacting the target surface, they return to their equilibrium condition: a superheated gas state. Most currently used grit blasting media are silicon dioxide based, which possess a sharp tetrahedral molecular structure. Silicon dioxide crystal structures will always produce smaller sharp-edged replicas of the original crystal upon fracture. Larger, softer dry ice pellets do not share the same sharp-edged crystalline structures as their non-sublimable counterparts when broken. In fact, upon contact with the target surface, dry ice pellets will plastically deform and break apart. As such, dry ice cleaning is less harmful to sensitive substrates, workers and the environment than chemical or abrasive cleaning systems. Dry ice cleaning system components include: a dry ice pellet supply, a non-reactive propellant gas source, a pellet and propellant metering device, and a media transport and acceleration hose and nozzle arrangement. Dry ice cleaning system operating parameters include: choice of propellant gas, its pressure and temperature, dry ice mass flow rate, dry ice pellet size and shape, and acceleration nozzle configuration. These parameters may be modified to fit different applications. The growth of the dry ice cleaning industry will depend upon timely data acquisition of the effects that independent changes in these parameters have on cleaning rates, with respect to different surface coating and substrate combinations. With this data, optimization of cleaning rates for particular applications will be possible. The analysis of the applicable range of modulation of these parameters, within system component mechanical constraints, has just begun.

Barnett, Donald M.↗

Temperature cycling periods affect growth and tuberization in potatoes under continuous irradiation

Plants of the potato (Solanum tuberosum L.) cultivars Denali, Norland, Haig and Kennebec were grown for 42 days under three temperature cycling periods (thermoperiods) with continuous irradiation in two repeated experiments to help determine if temperature cycling might be varied to optimize tuber development of potatoes in controlled environments. Thermoperiods of 6/6 hours, 12/12 hours and 24/24 hours were established with the same temperature change of 22/14C and same controlled vapor pressure deficit of 0.60 kPa. The thermoperiod of 24/24 hours significantly promoted tuber initiation but slowed tuber enlargement in all four cultivars, compared to the thermoperiods of 6/6 hours and 12/12 hours. Denali' produced the highest tuber and total dry weights under the 6/6 hours thermoperiod. Kennebec' produced the highest tuber dry weight under the 12/12 hours thermoperiod. Thermoperiods had no significant effect on shoot and root dry weights of any cultivars. The major effect of thermoperiods was on initiation and enlargement of tubers.

NASA Program CELSS↗

Folic acid content in thermostabilized and freeze-dried space shuttle foods

This study was designed to determine whether freeze-dried and thermostabilized foods on a space shuttle contain adequate folate and to investigate any effects of freeze-drying on folacin. Frozen vegetables were analyzed after three states of processing: thawed; cooked; and rehydrated. Thermostabilized items were analyzed as supplied with no further processing. Measurable folate decreased in some freeze-dried vegetables and increased in others. Folacin content of thermostabilized food items was comparable with published values. We concluded that although the folacin content of some freeze-dried foods was low, adequate folate is available from the shuttle menu to meet RDA guidelines.

NASA Center JSC↗

Tropospheric range error parameters: Further studies

Improved parameters are presented for predicting the tropospheric effect on electromagnetic range measurements from surface meteorological data. More geographic locations have been added to the earlier list. Parameters are given for computing the dry component of the zenith radio range effect from surface pressure alone with an rms error of 1 to 2 mm, or the total range effect from the dry and wet components of the surface refractivity and a two-part quartic profile model. The new parameters are obtained, as before, from meteorological balloon data but with improved procedures, including the conversion of the geopotential heights of the balloon data to actual or geometric heights before using the data. The revised values of the parameter k (dry component of vertical radio range effect per unit pressure at the surface) show more latitude variation than is accounted for by the variation of g, the acceleration of gravity.

Hopfield, H. S.↗

Material for surface-enhanced Raman spectroscopy, and SER sensors and method for preparing same

Metal-doped sol-gel materials, suitable for use as sensors for surface-enhanced Raman spectroscopic analysis for trace chemical detection, are produced by effecting gelation and solvent removal of a doped sol-gel under mild temperature conditions. At least in certain instances reaction and drying will desirably be effected in an oxygen-starved environment. The metal of the sol-gel material functions, when irradiated, to produce a plasmon field for interaction with molecules of an analyte in contact therewith, increasing by orders of magnitude Raman photons that are generate by excitation radiation, and the method allows matching of the metal and metal particle size to a wavelength of light (or incident radiation, e.g., laser radiation) to generate surface plasmons. The porosity of the sol-gel material dramatically increases the surface area, and thereby the amount of metal exposed for analyte interaction. The sensors provided may be in the form of glass vials, fiber optics, multi-well micro-sample plates, etc., having surface coatings of the doped sol-gel material, to provide sampling systems for use in a Raman instrument.

Farquharson, Stuart↗

Tropospheric range error parameters: Further studies

Improved parameters are presented for predicting the tropospheric effect on electromagnetic range measurements from surface meteorological data. Parameters are given for computing the dry component of the zenith radio range effect from surface pressure alone with an rms error of 1 to 2 mm, or the total range effect from the dry and wet components of the surface refractivity, N, and a two-part quartic profile model. The parameters were obtained from meteorological balloon data with improved procedures, including the conversion of the geopotential heights of the balloon data to actual or geometric heights before using the data. The revised values of the parameter k show more latitude variation than is accounted for by the variation of g. This excess variation of k indicates a small latitude variation in the mean molecular weight of air and yields information about the latitude-varying water vapor content of air.

Hopfield, H. S.↗