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Net ozone photochemical production over the eastern and central North Pacific as inferred from GTE/CITE 1 observations during fall 1983

The role of photochemistry in the budget of tropospheric ozone is studied. Measurements of O3, NO, CO, H2O vapor, and temperature obtained during the fall of 1983 during the GTE/CITE project over the eastern and central North Pacific Ocean are analyzed. The effect of altitude on the measurements is discussed. The analysis reveals a correlation between ozone and NO levels; both increase in concentration and variability with altitude. It is observed that an additional source of secondary importance associated wih CO-rich air parcels exists. A photochemical model is utilized to calculate the net rate of ozone production by photochemical reactions. A net photochemical source of ozone in the free troposphere and a net sink in the boundary layer are detected. The relation between the ozone source in the free troposphere and NO is examined. It is estimated that photochemistry provides a net ozone source to the free troposphere overlying the eastern and central North Pacific Ocean of about 5 x 10 to the 10th molecules/sq cm sec and a net sink of ozone to the boundary layer overlying this region of about 3 x 10 to the 10th molecules/sq cm sec.

Chameides, W. L.↗

Ozone precursors and ozone photochemistry over eastern North Pacific during the spring of 1984 based on the NASA GTE/CITE 1 airborne observations

Simultaneous high-resolution measurements of O3, NO, CO, dew point temperature, and UV flux obtained during the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation (GTE/CITE 1) spring 1984 airborne field exercise over the eastern North Pacific Ocean are analyzed. Mid-tropospheric CO, O3, and NO mixing ratios averaged about 120 parts per billion by volume (ppbv), 50 ppbv, and 10 parts per trillion by volume (pptv), respectively. Statistical analysis of the high-resolution data indicates the existence of two ozone sources, one related to the downward transport of ozone-rich air from the upper troposphere and stratosphere, and the other to the transport of ozone-rich air from the continents. Modeling calculations based on these average levels imply that, from the surface to about 8 km, photochemical reactions probably supplied a net sink of ozone to the region overlying the eastern North Pacific Ocean during the sampling period. However, because the NO levels measured during the flights were frequently at or near the detection limit of the instruments and because the results are very sensitive to the absolute NO levels and their temporal variability, the conclusion must be considered provisional.

Chameides, W. L.↗

Eastern Ishtar Terra: Tectonic evolution derived from recognized features

Previous analyses have recognized several styles and orientations of compressional deformation, crustal convergence, and crustal thickening in Eastern Ishtar Terra. An east to west sense of crustal convergence through small scale folding, thrusting, and buckling is reflected in the high topography and ridge-and-valley morphology of Maxwell Montes and the adjacent portion of Fortuna Tessera. This east to west convergence was accompanied by up to 1000 km of lateral motion and large scale strike-slip faulting within two converging shear zones which has resulted in the present morphology of Maxwell Montes. A more northeast to southwest sense of convergence through large scale buckling and imbrication is reflected in large, northwest-trending scarps along the entire northern boundary of Ishtar Terra, with up to 2 km of relief present at many of the scarps. It was previously suggested that both styles of compression have occurred at the expense of pre-existing tessera regions which have then been overprinted by the latest convergence event. The difference in style is attributed mostly to differences in the properties of the crust converging with the tessera blocks. If one, presumably thick, tessera block converges with another tessera region, then the widespread, distributed style of deformation occurs, as observed in western Fortuna Tessera. However, if relatively thin crust (such as suggested for the North Polar Plains converges with thicker tessera regions, then localized deformation occurs, as reflected in the scarps along Northern Ishtar Terra. The purpose is to identify the types of features observed in Eastern Ishtar Terra. Their potential temporal and spatial relationships, is described, possible origins for them is suggested, and how the interpretation of some of these features has led to the multiple-style tectonic evolution model described is shown.

Vorderbruegge, R. W.↗

Airborne SAR determination of relative ages of Walker Valley moraines, eastern Sierra Nevada

A regional study of the distribution and elevations of Pleistocene moraines in the Andes requires a method of determining relative age from space. One of our primary objectives is to establish the relative chronology of major climatic events responsible for glaciation in the Andes and other regions that are difficult to access on the ground and where suitable material for absolute age determination is lacking. The sensitivity of radar to surface roughness makes it possible to develop a remotely-based relative dating technique for landforms for which surface age and roughness can be correlated. We are developing such a technique with Airborne Synthetic Aperture Radar (AIRSAR) imagery of the eastern Sierra Nevada where independent evidence is available for the ages and physical characteristics of moraines. The Sierra Nevada moraines are similar in form and environmental setting to Andean moraines that we have targeted for study during the pending Shuttle Imaging Radar-C (SIR-C) mission. SAR imagery is used to differentiate the ages of five moraine sequences of Walker Valley in the eastern Sierra Nevada. Other aspects of this investigation are briefly discussed.

Fox, A.↗

Tectonics and volcanism of Eastern Aphrodite Terra: No subduction, no spreading

Eastern Aphrodite Terra is approximately equal in size to the western North American Cordillera, from Mexico to Alaska. Its size and unique landforms make it an important area for understanding the tectonics of Venus, yet models for its formation are diametrically opposed. This region is part of the Equatorial Highlands, which was proposed as a region of lithospheric thinning, isostatic uplift, and attendant volcanism. Eastern Aphrodite Terra is dominated by circular structures within which deformation and volcanism are intimately related. These structures are marked by radial and concentric fractures, and volcanic flows that emanate from a central vent, as well as from concentric fracture sets. Cross-cutting relations between flows and concentric fracture sets indicate that outer concentric fracture sets are younger than inner fracture sets. The circular structures are joined by regional northeast- to east-trending fractures that dominantly postdate formation of the circular structures. We propose that the circular structures 'grow' outward with time. Although these structures probably represent addition of crust to the lithosphere, they do not represent significant lithospheric spreading or convergence, and the region does not mark the boundary between two distinct tectonic plates. This region is not easily explained by analogy with either terrestrial midocean rifts or subduction zones. It is perhaps best explained by upwelling of magma diapirs that blister the surface, but do not cause significant lithospheric spreading. Further study of the structural and volcanic evolution of this region using Magellan altimetry and SAR data should lead to better understanding of the tectonic evolution of this region.

Hansen, Vicki L.↗

Mariner 10 multispectral images of the eastern limb and farside of the moon

We present the first analysis of Mariner 10 multispectral image data for the eastern limb and farside of the moon. A new, rigorous calibration of these data is used that provides results that are consistent with independently derived data sets. From these newly calibrated data, a color ratio image (0.48/0.58 micron) is produced to show relative TiO2 abundances in mare units on the eastern limb and farside of the moon. Our results indicate that the farside lunar mare deposits examined have TiO2 contents that are intermediate to low (2.5 pct TiO2) relative to mare deposits on the nearside. We find no evidence for areally extensive deposits of either very low titanium or high to very high titanium basalts in these portions of the moon. Our findings support previous interpretations that the source regions for lunar mare basalts are laterally heterogeneous. Additionally, examination of highland units reveals a relatively blue region that corresponds with a previously proposed cryptomare, suggesting enhanced TiO2 for this unit. Finally, based on these Mariner 10 data, telescopic spectral data, Galileo multispectral image data, and lunar meteorite analyses we speculate that volcanism in farside mare deposits did not include high titanium basalts.

Robinson, Mark S.↗

Tectonics and volcanism of Eastern Aphrodite Terra, Venus - No subduction, no spreading

Eastern Aphrodite Terra, a deformed region with high topographic relief on Venus, has been interpreted as analogous to a terrestrial extensional or convergent plate boundary. However, analysis of geological and structural relations indicates that the tectonics of eastern Aphrodite Terra is dominated by blistering of the crust by magma diapirs. The findings imply that, within this region, vertical tectonism dominates over horizontal tectonism and, consequently, that this region is neither a divergent nor a convergent plate boundary.

Hansen, Vicki L.↗

Lunar impact basins: New data for the nearside northern high latitudes and eastern limb from the second Galileo flyby

During the December 1992 Galileo Earth/Moon encounter the northern half of the nearside, the eastern limb, and parts of the western farside of the Moon were illuminated and in view, a geometry that was complementary to the first lunar encounter in December, 1990, which obtained images of the western limb and eastern farside. The Galileo Solid State Imaging System (SSI) obtained multispectral images for these regions during the second encounter and color ratio composite images were compiled using combinations of band ratios chosen on the basis of telescopic spectra and laboratory spectra of lunar samples. Ratios of images taken at 0.41 and 0.76 micron are sensitive to changes in the slope in the visible portion of the spectrum, and ratios of 0.99 and 0.76 micron relate to the strength of near-infrared absorptions due to iron-rich mafic minerals (0.76/0.99 ratio) such as olivine and pyroxene. Results of the analyses of the compositional diversity of the crust, maria, and Copernican craters are presented elsewhere. Primary objectives for lunar basin analysis for the second encounter include analysis of: the north polar region and the Humboldtianum basin; the characteristics of the Imbrium basin along its northern border and the symmetry of associated deposits; the origin of light plains north of Mare Frigoris and associated with several other basins; the nature and significance of pre-basin substrate; the utilization of the stereo capability to assess subtle basis structure; the identification of previously unrecognized ancient basins; basin deposits and structure for limb and farside basins; and assessment of evidence for proposed ancient basins. These data and results will be applied to addressing general problems of evaluation of the nature and origin of basin deposits, investigation of mode of ejecta emplacement and ejecta mixing, analysis of the origin of light plains deposits, analysis of basin deposit symmetry/asymmetry, investigation of basin depth of excavation and crustal stratigraphy, and assessment of models for basin formation and evolution. Here we discuss some preliminary results concerning lunar impact basins, their deposits, and prebasin substrates, using the same approaches that we employed for the Orientale and South Pole-Aitken basins using the data from the first encounter.

Head, J. W.↗

Origin of tropospheric NO(x) over subarctic eastern Canada in summer

The original of NO(X) in the summertime troposphere over subarctic eastern Canada is investigated by photochemical modeling of aircraft and ground-based measurements from the Arctic Boundary Layer Expedition (ABLE 3B). It is found that decomposition of peroxyacetyl nitrate (PAN) can account for most of the NO(X) observed between the surface and 6.2 km altitude (aircraft ceiling). Forest fires represent the principal source of PAN in the region, implying the same origin for NO(X). There is, however, evidence for an unidentified source of NO(X) in occasional air masses subsiding from the upper troposphere. Isoprene emissions from boreal forests maintain high NO(X) concentrations in the continental boundary layer over eastern Canada by scavenging OH and NO3, thus slowing down conversion of NO(X) to HNO3, both in the daytime and at night. This effect is partly compensated by the production of CH3CO3 radicals during isoprene oxidation, which slows down the decomposition of PAN subsiding from the free troposphere. The peroxy radical concentrations estimated from concurrent measurements of NO and NO2 concentrations during ABLE 3B are consistent with values computed from our photochemical model below 4 km, but model values are low at higher altitudes. The discrepancy may reflect either a missing radical source in the model or interferences in the NO2 measurement.

Fan, S.-M↗

Geosat Data Assimilation with Application to the Eastern North Atlantic

An attempt is made to determine the three-dimensional ocean circulation from satellite altimeter measurements by assimilating Geosat sea surface height data into an eddy-resolving QuasiGeostrophic (QG) model of the eastern North Atlantic Ocean. Results are tested against independent information from hydrographic field observations and moored current meter data collected during the Geosat ERM. The comparison supports the concept of inferring aspects of the three-dimensional flow field from sea surface height observations by combining altimetric measurements with the dynamics of ocean circulation models. A Holland-type QG model with open boundaries is set up on a 2000 km X 2000 km domain of the eastern North Atlantic between 25 deg. and 45 deg. N, 32 deg. and 8 deg. W. By using a simple nudging technique, about two years of Geosat altimeter data are assimilated into the model every five days as space-time objective analyses on the model grid. The error information resulting from the analysis is used during the assimilation procedure to account for data uncertainties. Results show an intense eddy field, which in the surface layer interacts with a meandering Azores Front. Compared to Geosat, the model leads to smoothed fields that follow the observations. Model simulations are significantly correlated with hydrographic data from March 1988 and June 1989, both close to the surface and in the subsurface. Good agreement is also found between the model velocity fields and moored current meter data in the top two model layers. The agreement is visually weak in the bottom layer, although a coherence analysis reveals an agreement between the model simulation and current meter data over the full water column at periods exceeding 80 days.

Stammer, Detlef↗

Potential Mars Surveyor 2001 Landing Sites: Low-Elevation Cratered "Highlands" in Central and Eastern Sinus Meridiani and Near Amenthes Fossae

The main scientific goal for the Mars Surveyor Program 2001 (MSP 01) landed mission is to collect and characterize 91 rock and 13 soil core samples using an integrated instrument suite onboard the Athena Rover. If possible, these samples will be retrieved and returned to Earth via a MSP 05 or MSP 07 mission. Preliminary engineering constraints for the MSP 01 landing site call for a location that lies between 15 S and 30 N, and below about 2 km elevation (based on Viking-era topography). Desirable landing sites for MSP 01 are to be located "in the ancient highlands where the environmental conditions may have been favorable to the preservation of evidence of possible prebiotic or biotic processes including the emergence (and, potentially, the persistence) of life". We interpret this to mean that the desirable sites include those that have evidence of aqueous sediments that might have been deposited during the Noachian and/or Hesperian Epochs of Mars' history. In addition to the search for subaqueous sedimentary deposits, we took into consideration the fact that the rover, Athena, will need to be able to access these materials. Thus, a site where aeolian deflation has occurred might be desirable because it might expose, in situ, layered sedimentary deposits. Deflated areas, of course, might include potential landing hazards in the form of meterscale buttes and mesas (e.g., Christmas Lake Valley, OR), thus careful study of such sites with high resolution images will be required before a decision is made to land. We have been examining three regions that have potential to be considered for MSP 01 landing sites. This work is based on Viking (VIS, IRTM) and Phobos 2 (Termoskan) observations and should be regarded as preliminary because we believe that the final site selection should also be based upon analysis of Mars Global Surveyor observations that help constrain mineralogy (TES) and local geomorphology (MOC, MOLA). (1) Eastern Sinus Meridiani Region (proposed by K. S. Edgett) Sinus Meridiani is a persistent low-albedo (< 0. 16) region on the martian equator that has been recognized for about 400 years. All of Sinus Meridiani is below the 2 km elevation constraint for MSP 01. The region includes cratered highlands, valley networks, aeolian dunes, and possible aqueous sedimentary deposits. The landing site study region is located in the eastern portion of Sinus Meridiani. It is bounded by latitudes 10 S to 2 N, longitudes 355 W to 345 W, and the elevations are mostly 1-2 km. The center of this area contains a medium-albedo (0.19-0.21), relatively smooth-surfaced deposit that was suggested by Rice to be a lacustrine deposit. Several potential landing areas can be suggested within this region. Based on Viking and Phobos 2 data, the favored sites so far are centered at 7.6 S, 346.9 W and 0.8 S, 349 W. Thermal inertias are 3.2-7.0 x 10(exp -3) cal /sq cm s(exp -0.5)/K; and rock abundances are around 2-6%. The site at 7.6 S, 346.9 W is at the southern end of the smooth, medium-albedo unit that might have a lacustrine origin. At this location, numerous channels appear to have drained toward the smooth unit. Viking images from orbit 747A show this area at about 15 m/pixel ground resolution. The images reveal that aeolian deflation has occurred along the deposit's margins. Bright (i.e., albedo >= 0.21) aeolian dunes are present on the channel floors and in some of the depressions on the smooth unit. The bright, apparently active dunes might consist of material (perhaps lakedeposited sands) that has been eroded from the smooth unit. The site at approximately 0.8 S, 349 W is selected because it offers an opportunity to solve a long-standing puzzle about Mars remote sensing. There are three main "color" units on Mars: "dark red, dark gray, and bright red". This landing site would allow the Athena rover an opportunity to investigate all three materials within close proximity (the best place on Mars to do so). There are no high resolution (better than 100 m/pixel) Viking or Mariner images of this site. (2) Central Sinus Meridiani Region (proposed by K. S. Edgett and T. J. Parker) Central Sinus Meridiani is characterized by two types of surfaces [4]. One is like typical martian cratered highlands elsewhere- there are old valley networks and old impact craters. The other is relatively smooth and flat. These two units are in contact around 3.1 S between 5 W and 4 E longitudes. Valley networks- including one at 6'S, 358 W that rivals the Grand Canyon of Arizona- once drained toward the smooth unit. Edgett and Parker [4] proposed that the smooth unit might consist of sediments laid down in a large Noachian-aged sea/ocean that would have covered much of the northern hemisphere. Schultz and Lutz [I I I suggested that it is a paleopolar layered deposit. Regardless, the smooth unit where it contacts the cratered terrain would make an excellent site for Athena rover to investigate. The site is best seen in Viking high resolution images from orbits 408B (about 30 m/pixel) and 746A (about 12 m/pixel). These images suggest that aeolian deflation has occurred along the margin of the smooth unit, and this deflation has exposed horizontal larrs of material. The elevation is about 0.5 km; thermal inertias are 6.5-8.0 x 10(exp -3) cal /sq cm s(exp -0.5) / K; rock abundances are 2-4%; and the surface is probably sandy with dark drifts and ripples but almost no actual dunes. We suggest a landing around 3.2 S, 3.0 W would test the aqueous sediment hypothesis and provide a potentially smooth surface on which to land. (3) Amenthes Fossae Region (proposed by S. N. Huntwork and K. S. Edgett) The Amenthes Fossae are a series of graben/fissures that are circumferential to the southeast side of Isidis Planitia. These fissures cross a variety of ancient, heavily cratered Noachian terrain and younger, Hesperian and Amazonian terrain. We focused our search on a region 0-15 N, 250 - 270 W. Elevations are -0.5 to 2 km. Depending upon whether Isidis Planitia was ever a water-rich environment, this region might have been influenced by aqueous sedimentation. Valley networks are common, and they drained toward the north and northwest. We focused our work on a set of Viking orbiter high-resolution images, 719A 1-48. These have resolutions 16-24 rri/pixel. We examined images 20-23, centered at 2 N, 258 W. This site, on the plains just southwest of a 42 km-diameter crater, includes a valley network channel, a relatively young crater ejecta deposit, a few buttes composed of presumably ancient, Noachian bedrock, and a "plains" unit. The plains might make an ideal landing surface, except for the presence of some fine-scale ridges (oriented approximately N-S). The ridges are probably yardangs, thus this site offers a place where aeolian deflation has probably exposed some of the layered rock units that comprise the "plains". Thermal inertias are 7.9-8.3 x 10(exp -3) cal/sq cm s(exp -0.5) /K and rock abundances are 10-15%. A rover traverse might include the opportunity to go down to the floor (and sample along the walls) of the valley network channel at 2 N 258.1 W.

Edgett, K. S.↗

Tectonic Evolution of the Eastern Hemisphere of Mars

The magmatic-tectonic history of Mars is largely dominated by the Tharsis magmatic complex of the western hemisphere and the Elysium rise of the eastern hemisphere. In order to address the history of Mars, the tectonic history of the eastern hemisphere must also be unraveled. Additional information is contained in the original extended abstract.

Pounders, E.↗

Westerly Wind Events in the Eastern Indian Ocean as a Precursor to El Nino: A Case Study for the 2002-03 El Nino

This paper extends the work of our previous study, which showed the potential of using precipitation in the eastern Indian Ocean to predict when an El Nino would begin. The paper begins by showing the successful prediction of the 2002-03 El Nino. However, precipitation is really used as a substitute for wind (storms are usually accompanied by heavy wind), because a popular hypothesis is that winds (especially % winds out of the West) stir up the ocean surface in the western Pacific sending currents of warm waters to the east Pacific where El Ninos form. This paper shows that it is typical for storms that produce strong winds in the western Pacific to have traveled from the Indian Ocean. We begin in the Indian Ocean looking at strong bursts of wind over several days. The number of windy days seems to increase in the months prior to El Nino. We examined these relationships in detail for November 2001 to April 2002, before the recent El Nino, using NASA's TRMM and QuikSCAT data. We found in one case that a warming of the eastern Indian Ocean occurred about 25 days before heavy rainfall formed. As the stormed moved eastward it was followed (6 days later) by strong winds out of the West. The entire storm system (and warming of the sea) moved eastward through a small strip of water between Indonesia and Australia, before reaching the western Pacific. Thus, this paper increases our understanding of the physical processes leading to the formation of El Nino.

Curtis, Scott↗

Ocean Carbon Flux, Transport, and Burial Within the Western and Eastern US Coastal Zones

This project has been to develop and apply a regional. eddy-resolving circulation and biogeochemistry model of both the western and eastern U.S. coastal regions, capable of simulating the processes that control the carbon cycle. Validation has been by statistical comparison with analyses from various satellite measurements, including those from EOS sensors, as well as from in situ measurements. Sensitivity studies were carried out to investigate how the coastal ecosystem and biogeochemical cycles respond to changes in climate, large-scale eutrophication from indus- trial pollution, and other anthropogenic induced changes. The research has been conducted in collaboration with research groups at UCLA. NASA/GSFC (Wallops), Rutgers, and SIO. Overall. the project was focused on several key modeling issues, each of which tie back into completing the primary task of developing a coastal carbon model for both the eastern and western US. coasts. Individual groups within the entire program are still collaborating to address these specific tasks. These include: implementation of the coupled circulation/biogeochemical model within the U.S. West Coast. including high-resolution, embedded subdomains for the Southern California Bight and Monterey Bay region; development of a biogeochemical model with resolved carbon, nitrogen and oxygen cycles; development of data assimilation techniques for use of satellite data sets; reconfiguration of the model domain to U.S. East Coast; development of coastal forcing fields: development of methods to compare the model against remotely sensed data; and, the test of model sensitivity to environmental conditions. Below, we present a summary of the progress made toward achieving these soak. Because this has been a multi-institutional, collaborative effort, we note the groups involved with particular activities.

McWilliams, James C.↗

Modeling Forest Understory Fires in an Eastern Amazonian Landscape

Forest understory fires are an increasingly important cause of forest impoverishment in Ammonia, but little is known of the landscape characteristics and climatic phenomena that determine their occurrence. We developed empirical functions relating the occurrence of understory fires to landscape features near Paragominas, a 35- yr-old ranching and logging center in eastern Ammonia. An historical sequence of maps of forest understory fire was created based on field interviews With local farmers and Landsat TM images. Several landscape features that might explain spatial variations in the occurrence of understory fires were also mapped and co-registered for each of the sample dates, including: forest fragment size and shape, forest impoverishment through logging and understory fires, source of ignition (settlements and charcoal pits), roads, forest edges, and others. The spatial relationship between forest understory fire and each landscape characteristic was tested by regression analyses. Fire probability models were then developed for various combinations of landscape characteristics. The analyses were conducted separately for years of the El Nino Southern Oscillation (ENSO), which are associated with severe drought in eastern Amazonia, and non-ENS0 years. Most (91 %) of the forest area that burned during the 10-yr sequence caught fire during ENSO years, when severe drought may have increased both forest flammability and the escape of agricultural management fires. Forest understory fires were associated with forest edges, as reported in previous studies from Ammonia. But the strongest predictor of forest fire was the percentage of the forest fragment that had been previously logged or burned. Forest fragment size, distance to charcoal pits, distance to agricultural settlement, proximity to forest edge, and distance to roads were also correlated with forest understory fire. Logistic regression models using information on fragment degradation and distance to ignition sources accurately predicted the location of lss than 80% of the forest fires observed during the ENSO event of 1997- 1998. In this Amazon landscape, forest understory fire is a complex function of several variables that influence both the flammability and ignition exposure of the forest.

Alencar, A. A. C.↗

Simulation of the Genesis of Hurricane Javier (2004) in the Eastern Pacific

NASA is preparing for the Tropical Cloud Systems and Processes (TCSP) field experiment in July 2005, a joint effort with NOAA to study tropical cloud systems and tropical cyclone genesis in the Eastern Pacific. A major thrust of the TCSP program is the improvement of the understanding and prediction of tropical cyclone genesis, intensity, motion, rainfall potential, and landfall impacts using remote sensing and in-situ data, as well as numerical modeling, particularly as they relate to the three phases of water. The Eastern Pacific has the highest frequency of genesis events per unit area of any region worldwide. African easterly waves, mesoscale convective systems (MCSs), and orographic effects are thought to play roles in the genesis of tropical cyclones there. The general consensus is that tropical depressions form in association with one or more mid-level, mesoscale cyclonic vortices that are generated within the stratiform region of the MCS precursors. To create the warm core tropical depression vortex, however, the midlevel cyclonic circulation must somehow extend down to the surface and the tangential winds must attain sufficient strength (-10 m s- ) to enable the wind-induced surface heat exchange to increase the potential energy of the boundary layer air.

Braun, Scott↗

Towards Improved Forecasts of Atmospheric and Oceanic Circulations over the Complex Terrain of the Eastern Mediterranean

Forecasting atmospheric and oceanic circulations accurately over the Eastern Mediterranean has proved to be an exceptional challenge. The existence of fine-scale topographic variability (land/sea coverage) and seasonal dynamics variations can create strong spatial gradients in temperature, wind and other state variables, which numerical models may have difficulty capturing. The Hellenic Center for Marine Research (HCMR) is one of the main operational centers for wave forecasting in the eastern Mediterranean. Currently, HCMR's operational numerical weather/ocean prediction model is based on the coupled Eta/Princeton Ocean Model (POM). Since 1999, HCMR has also operated the POSEIDON floating buoys as a means of state-of-the-art, real-time observations of several oceanic and surface atmospheric variables. This study attempts a first assessment at improving both atmospheric and oceanic prediction by initializing a regional Numerical Weather Prediction (NWP) model with high-resolution sea surface temperatures (SST) from remotely sensed platforms in order to capture the small-scale characteristics.

Chronis, Themis↗

Influence of Ohio River Valley Emissions on Fine Particle Sulfate Measured from Aircraft over Large Regions of the Eastern United States and Canada during INTEX-NA

Aircraft measurements of fine inorganic aerosol composition were made with a particle-into-liquid sampler coupled to dual ion chromatographs (PILS-IC) as part of the NASA INTEX-NA study. The sampling campaign, which lasted from 1 July to 14 August 2004, centered over the eastern United States and Canada and showed that sulfate was the dominant inorganic species measured. The highest sulfate concentrations were observed at altitudes below 2 km, and back trajectory analyses showed a distinct difference between air masses that had or had not intercepted the Ohio River valley (ORV) region. Air masses encountered below 2 km with a history over the ORV had sulfate concentrations that were higher by a factor of 3.2 and total sulfur (S) concentrations higher by 2.5. The study's highest sulfate concentrations were found in these air masses. The sulfur of the ORV air masses was also more processed with a mean sulfate to total sulfur molar ratio of 0.5 compared to 0.3 in non-ORV measurements. Results from a second, independent trajectory model agreed well with those from the primary analysis. These ORV-influenced air masses were encountered on multiple days and were widely spread across the eastern United States and western Atlantic region.

Hennigan, Christopher J.↗