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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Comparative Techno-Economic and Life Cycle Analysis of Water Oxidation and Hydrogen Oxidation at the Anode in a CO 2 Electrolysis to Ethylene System

We compare the economic viability of employing hydrogen oxidation versus water oxidation at the anode of a commercial-scale electrolysis plant that converts CO 2 to ethylene. We vary the electrolyzer capital cost, membrane lifetime, and renewable electricity price to represent a current and future market scenario. We find that anodic hydrogen oxidation with membraneless reactor design can reduce the electrolyzer capital cost by up to 48% and reduce electricity demand by at least 50% with the current underdeveloped electrolyzer market. These capital and operating cost savings could further lead to a lower ethylene production cost from anodic hydrogen oxidation than the anodic water oxidation system with hydrogen supplied at less than $\$6$ kg. In the future scenario with a fully developed electrolyzer market and cheap renewable electricity, we find that the anodic hydrogen oxidation system requires hydrogen cheaper than $0.7/kg to compete with the anodic water oxidation system. Moreover, hydrogen oxidation at the anode enables extremely low cradle-to-gate emission ethylene by utilizing negative emission hydrogen such as biomass gasification with carbon capture and sequestration, ~240% lower than ethylene produced from the wind/solar electricity-driven water oxidation system. Furthermore, this low carbon footprint ethylene can further boost the economic competitiveness for anodic hydrogen oxidation with a future carbon credit market.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Technical Assessment of Novel Hydrogen Producing Solid Oxide Fuel Cell Power System

Solid oxide cell-based electrolysis (SOEC) systems are being considered for hydrogen production due to their potential for high efficiencies and for their integrability with base load power generation systems when operated in solid oxide fuel cell (SOFC) mode. However, a cost prohibitive combination of SOFC power systems and SOEC systems may be required to operate the plant flexibly to produce a combination of H 2 and power on-demand. A single (consequently less expensive) reversible SOFC/SOEC system, on the other hand, poses technological challenges related to the on demand switching between power and H 2 production. This report provides a high-level technical assessment of a novel SOFC based H 2 production concept that averts the potential drawbacks of the SOEC systems. The novel concept combines the advantages of steam-reforming of natural gas to produce H 2 with the high efficiency power generation capabilities of a SOFC in a single package.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2022

DETAIL Component Scaling and Methodology Comparison

The purpose of this study was to develop a process to convert input signals from one facility into another by reflecting geometric and environmental settings. The Dynamic Energy Transport and Integration Laboratory (DETAIL) is a research facility in development. Its aim is to emulate the daily interactions among power production industry systems and receive real-time data from those systems as inputs. To convert signals and ensure that the temporal sequences and magnitudes reflect laboratory settings, the ability to scale and project data is essential. To demonstrate this ability, Dynamical System Scaling (DSS) and Hierarchical Two-Tiered Scaling (H2TS) (methodologies that enable systems to scale and project or extrapolate data sets to desired environments while conserving the observed behavior based on first principles) were applied to DETAIL’s thermocline thermal storage system in the Thermal Energy Distribution System (TEDS) facility and solid-oxide electrolysis cell in the High Temperature Hydrogen Electrolysis (HTHE) facility. Both thermocline and electrolysis cell systems were successfully scaled, and test cases were conducted to generate a doubly accelerated energy charge and discharge in reference to past experimental data from the facilities. The research results represented a case for the thermocline system that required signals to be accelerated without altering the stored energy. To enhance the quality of the accelerated data, error propagation analyses were conducted on DSS post-processing terms to determine the consequences of raw-data-associated errors.

08 HYDROGEN↗
DOE OSTI2022

Preliminary Reversible Solid Oxide System Specification

This report presents the preliminary documentation of a 10 MWe DC reversible solid oxide cell (rSOC) system designed to use both electrical and thermal energy from a nuclear power plant (NPP). The system is designed to consume 10 MWe DC in electrolysis mode while producing hydrogen from demineralized feedwater. In fuel cell mode, the same stacks produce 2.37 MWe DC of electricity by reacting hydrogen and oxygen, while generating water as a byproduct which is recycled to be used later in the electrolysis mode. The system detailed in this specification is a high-temperature steam electrolysis (HTSE) system when operated in the electrolysis mode. HTSE systems have the benefit of producing hydrogen at a higher efficiency than conventional low-temperature electrolysis (LTE) systems. In this report it is assumed that some of the heat required for HTSE operation comes from an NPP. Heat extraction from an NPP for use in electrolysis mode of the rSOC system allows preheating and vaporization of feedwater before recuperators and trim heaters raise the feed temperature to the approximately 800 °C before entering the solid oxide stacks. The purpose of an rSOC system in a utility company setting is to employ energy arbitrage with a dispatchable demand load which can consume excess electricity generation during times of low grid demand / high generation and can produce electricity for the grid during times of high grid demand / low generation. There is a wide range of energy storage technologies that could be used for utility-scale energy arbitrage (utility-scale battery storage is considered the baseline technology), the object of this work is not to compare and contrast rSOC technology with any of these other technologies, but only to present this preliminary design for consideration and for use in future conceptual or front end engineering design (FEED) work. This document is not meant to be a final specification or definitive description of the rSOC system, but it is meant to showcase preliminary process modeling results, provide boundary conditions and interface requirements such as input feed and utility stream flowrates, temperatures, and pressures as well as thermal and electrical energy requirements, and output conditions in both electrolysis mode and fuel cell mode. These results are intended to inform the future development of a conceptual demonstration-scale study to assess the technical and economic feasibility of a future demonstration of an rSOC integrated project at an NPP.

08 HYDROGEN↗
DOE OSTI2024

High-Performance AEM LTE with Advanced Membranes, Ionomers and PGM-Free Electrodes

Alkaline low temperature electrolysis (LTE) systems enjoy several potential advantages over acid-based LTE systems including facile oxygen evolution reaction (OER) kinetics and electrodes that can use little to no platinum group metals (PGM). The polymer membranes and membrane electrode assembly (MEA) structures going into alkaline electrochemical systems have seen significant advances in recent years. The objective of this project is to combine state-of-the-art alkaline polymer electrolyzer components into one optimized membrane electrode assembly (MEA) system to achieve DOE low temperature electrolysis (LTE) goals. The benefit of individual component advances cannot be fully appreciated until all aspects and components of the MEA are working at an equally high level of performance. New electrode fabrication methods were developed where solvent cast catalyst/ionomer solutions were used in place of insoluble ionomers to significantly improve adhesion. The membranes were improved in terms of durability and mechanical properties. The OER and HER catalysts were improved and made more durable.

08 HYDROGEN↗
DOE OSTI2021

Development and Demonstration of a Reduced-Order PWR Power Dispatch Simulator

This report describes the development, modeling, and results of a reduced-order thermal power dispatch pressurized water reactor (RO-TPD-PWR) power plant simulator that incorporates coupled electrical and thermal power dispatch to an industrial process. The simulator is built on models that have been developed in previous work, including a Rancor Microworld model previously developed by INL and the University of Idaho [Ref] and reactor core and secondary system models that have been published previously [Ref]. The simulator also includes a scalable model of a high temperature electrolysis (HTE) system that has been developed at INL. A particular benefit of the Rancor Microworld model is that it is compatible with a human-system interface (HMI) that has already been developed by the Human System Simulation Laboratory (HSSL) at INL that can emulate the control room of a PWR for realistic human-in-the-loop studies with mock nuclear power plant operating procedures. The results of these human-in-the-loop tests will be compared with similar tests using a commercial full-scope generic PWR (GPWR) simulator that has been modified to include thermal power dispatch, referred to as the TPD-GPWR [ , ]. The simplicity of the RO-TPD-PWR helps to better understand and verify the results of the TPD-GPWR, which employs >1,000 variables and has much greater complexity. A second key purpose of the RO-TPD-PWR simulator is that its relative simplicity allows it scale between lab-size equipment (~100 kW) and full-scale nuclear power plants (~1 GW) by adjusting only a few parameters in the models, such as fluid masses and heat exchanger areas. The RO-TPD-PWR simulator will be used to guide the controls of lab tests, so that equipment in those tests, such as the Thermal Energy Distribution System (TEDS) and pilot-scale high temperature electrolysis (HTE) units at scales of 50-250 kW, may operate in a manner that is relevant to full-scale PWR operations.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2020

Roll-to-Roll Direct Coating of Catalyst Inks on Membrane Films: Progress and Challenges

Further development of low temperature electrolysis (LTE) systems is of importance to ensure the renewable hydrogen production for hydrogen-based energy systems. The membrane electrode assembly (MEA) is a key component of the LTE system and typically contains a catalyst coated membrane (CCM). To enable the U.S. Department of Energy's hydrogen production cost goal of $2/kg, high volume manufacturing processes will be required to lower manufacturing costs of the CCM. A promising way for high-throughput manufacturing of CCM is using roll-to-roll (R2R) methods that allow the direct coating of electrodes on membrane films. However, there are many challenges with this methodology, both in the coating process as well as with web handling. In this talk, we discuss the membrane-ink interaction by evaluating the solvent uptake of a Nafion membrane system and verify the coatability of various inks through lab-scale coatings onto this system. Furthermore, rheology and surface tension data of the ink will be discussed together with the resulting morphology of the coated electrodes. The R2R-processed CCMs will finally be analyzed using electrochemical performance data and the results put in context with the challenges that the mass production of CCMs for LTE system faces to date.

39 EE - Hydrogen and Fuel Cell Technologies (EE-3F↗
DOE OSTI2023

Life cycle analysis of a hydrogen production system based on solid oxide electrolysis cells integrated with different energy and wastewater sources

Hydrogen production via water electrolysis is a promising and evolving technology. The solid oxide electrolysis cell (SOEC) is one of the several technologies for this purpose. They are alternatives to the traditional hydrogen production from fossil fuels to enhance global energy decarbonization. However, in the bid for sustainability and a green economy, these technologies are not free from causing some environmental burdens. Using life cycle assessment (LCA), the greenhouse gas emission and degree of environmental impacts by these technologies can be identified and measured throughout their lifespan. This study addresses how to quantify these CO 2 emission impacts for an electrolytic system with different energy sources. The LCA of a novel integrated hydrogen production SOEC system with energy from solar photovoltaic and bituminous powerplant is performed using simaPro, the leading global LCA solution software. Measuring the environmental impact of the electrolytic operation in terms of weight, the bituminous powerplant poses damage which is, on average 700% more than solar PV. The thermal-to-hydrogen efficiency of the SOEC system is 56%, and a probable 28% reduction in carbon footprint with heat integration. The steam generation and the manufacturing of the SOEC have a very high environmental impact potential on the system. Here, we recommend LCA and net energy analysis is carried out for every new hydrogen technology and adequate comparison to enhance sustainable and green economy.

08 HYDROGEN↗
DOE OSTI2024

Optimal operations of a nuclear-based integrated energy system: A mixed integer program approach

A nuclear-based integrated energy system (IES), consisting of multiple carbon-free energy generation and conversion technologies to meet heterogeneous end-use demands, offers a promising approach to decarbonizing the U.S. economy. Operating such an IES is challenging due to its complexity and the diverse end-use demands, such as heating and electricity. This paper aims to address the optimal operation of an IES composed of a small modular reactor (SMR), a steam manifold, a balance of plant (BOP), a high-temperature steam electrolysis (HTSE) system, a district heating (DH) network, and electrical grids. We formulate the system’s operation as a mixed integer linear programming (MILP) problem to maximize net revenues from sales of electricity and hydrogen. To evaluate the efficacy of the proposed model, we conduct a 24-hour simulation considering day-ahead (DA) electricity prices from CAISO and a varying DH demand profile with hourly resolution. The simulation results show that our model effectively optimizes the operation by selling electricity during on-peak periods and purchasing electricity for hydrogen production during off-peak periods, while satisfying operating constraints within the IES.

08 HYDROGEN↗
DOE OSTI2025

Performance and Durability Investigation of Thin, Low Crossover Proton Exchange Membranes for Water Electrolyzers

The goal of this project was to fabricate and study the performance and durability implications of thin, mechanically reinforced membranes containing gas recombination catalysts (GRCs) for advanced proton exchange membrane water electrolysis (PEMWE) systems. The thinner membranes, optimized for a PEMWE environment, dramatically reduced the proton transport resistance across the membrane, improving the overall efficiency of the PEMWE system. At the same time, the GRC technology was deployed to recombine crossover hydrogen from the cathode with oxygen from the anode to form water within the membrane. This reaction mitigated the buildup of hydrogen in the oxygen stream, ensuring safe operation of the PEMWE system. Capabilities to measure the gas crossover in both an ex-situ screening cell and in operando application testing were developed over the course of the project to track membrane progress and quantify deliverables. State of the art roll to roll manufacturing technologies were leveraged to fabricate the membranes on a commercial scale, where the membrane structure was precisely tuned and GRC distributed within the membrane structure.

08 HYDROGEN↗
DOE OSTI2021

Methods for hydrogen gas production through water electrolysis

A method of producing hydrogen gas comprises introducing gaseous water to an electrolysis cell comprising a positive electrode, a negative electrode, and a proton conducting membrane between the positive electrode and the negative electrode. The proton conducting membrane comprises an electrolyte material having an ionic conductivity greater than or equal to about 10−2 S/cm at one or more temperatures within a range of from about 150° C. to about 650° C. The gaseous water is decomposed using the electrolysis cell. A hydrogen gas production system and an electrolysis cell are also described.

He, Ting↗
DOE OSTI2024

Warrick Conductivity Level Controllers Series 3H

This is my internship poster. In the poster I talk about the level controllers that I wired together and installed to support electrolysis testing systems in efforts to make the systems more efficient and run based on the communication between devices to ensure a closed loop system that can run on its own in a safe and controlled manner. I included pictures of some of the wiring as well as the level sensor devices and relays. I also included pictures of the tanks that will be filled at different heights with deionized water based on where the level sensors are.

08 HYDROGEN↗
DOE OSTI2023

Thermodynamic modeling of KCl-PrCl 3 and KCl-LiCl-PrCl 3 systems

Molten salt electrolysis can recover the actinides from spent nuclear fuels, and it involves a eutectic LiCl-KCl in molten form as an electrolyte. During reprocessing, the concentration of fission products such as La, Nd, Pr, etc., increases and affects the recovery efficiency of the electrolyte. In this work, thermodynamic modeling of KCl-PrCl 3 and KCl-LiCl-PrCl 3 systems was carried out using the CALPHAD (Calculation of Phase Diagrams) approach for the first time. The thermodynamic functions for the pure salts were taken from the SGTE (Scientific Group Thermodata Europe) Substances (SSUB) database. The experimental thermochemical and phase equilibria data available in the literature were used as input for the assessment of KCl-PrCl 3 and KCl-LiCl-PrCl 3 systems. The model parameters for the KCl-LiCl system were adjusted to include the new Gibbs energy descriptions for the pure salts. In addition, the sublattice model for the liquid phase in the LiCl-PrCl 3 system was modified and reassessed to ensure the model compatibility for higher-order extrapolation. There is a good agreement between the experimental and calculated thermochemical and phase diagram data for all the optimized constituent binaries and the ternary system. Furthermore, this work will be beneficial for determining the solubility limit of PrCl 3 in molten LiCl-KCl electrolytes and their thermodynamic properties for improving the efficiency of the pyrochemical process.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Cyber-Physical Simulation of an Innovative Solid Oxide Electrolysis Cell - Gas Turbine (SOEC-GT) Hybrid Energy System

To produce green hydrogen at scale and at low cost, the solid oxide electrolysis cell (SOEC) systems would be tied to renewable power sources (mainly solar and wind), leveraging zero-carbon electricity at low prices and even nearly free during overgeneration scenarios. However, due to the intermittency of renewable power generation, the SOEC system is subjected to rapid load transitions that occur not only in diurnal cycles but also in short timeframes (e.g., sub-minute). This can result in fast degradation and thus greatly reduce the SOEC’s lifetime. Our team at the National Energy Technology Laboratory has demonstrated that the anode air flow can have a crucial role in SOEC thermal management. Typically, a higher air flow rate can help to mitigate the local temperature gradient distortion during rapid load transitions. To move a large amount of air, the gas turbine (GT; i.e., compressor-turbine-generator set) has been regarded as the most mature and efficient technology. In this presentation, we show the configuration and preliminary results of an innovative SOEC-GT hybrid energy system in a cyber-physical simulation (CPS) approach.

Zhang, Biao↗
DOE OSTI2022

Concentrated Solar Power as a Pathway for Electrolytic Hydrogen Production

William Xi and Mark Ruth of the National Renewable Energy Laboratory (NREL), will present a new solar-electrolysis technoeconomic assessment capability: low-temperature and high-temperature electrolysis in the System Advisor Model (SAM) environment. They will also present analysis results including opportunities for solar-hydrogen systems to achieve the $2/kg hydrogen cost target.

concentrating solar power↗
DOE OSTI2024

Multi-Period Optimization of Multi-Timescale Energy Systems: Application to Solid-Oxide Electrolysis Cells

A presentation detailing the recent progress in the optimization of Solid-Oxide Cells under Chemical Degradation. The existing methods typically involve a quasi-steady state assumption to make this large-scale problem tractable. Here, we introduce an extension to this method that allows for adaptive coupling of degradation with the fast-timescale process based on a variety of error thresholds. This reduces the error accumulated during long-term optimization of the SOC under degradation and allows for decision making at multiple timescales. The results presented include long-term operating profiles of the SOC under degradation with both steady-state and fluctuating day to day operation.

Giridhar, Nishant↗
DOE OSTI2022

Integrated desiccant-based cooling and dehumidification

Integrated systems comprising both i) heat and mass exchange systems and ii) electrolysis stacks are disclosed, together with related methods of use. The disclosed systems cool and/or dehumidify air using two streams of salt solutions as liquid desiccants.

Woods, Jason David↗