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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

X-ray FEL linear accelerator design via start-to-end global optimization

An X-ray Free Electron Laser (FEL) prefers using an electron beam with low emittance, small energy spread, and a high core current to generate coherent radiation through an undulator. In order to attain such a high brightness beam, the linear accelerator beam dynamics design generally involves separate photoinjector optimization and linac optimization. In this paper, we propose a new beam dynamics design strategy based on global optimization with fast start-to-end simulations from the photocathode to the end of the accelerator. The new start-to-end model significantly reduces the simulation time and makes the global optimization practical. The global optimization method avoids the need to choose a single solution based on bunch length at the injector exit for the linac optimization and helps find the solution with unfavorable bunch length at the injector exit but better phase space distribution that can result in better final electron beam phase space distribution at the entrance of the undulator. Here, using the start-to-end global optimization, we showed in an application example, with a 100 pC beam that good transverse emittance and over kilo-Ampere final core current can be attained using a photoinjector that consists of a VHF gun and boosting RF cavities.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

A transmitted-beam diagnostic for the wavelength-tunable UV drive beam on OMEGA

A transmitted-beam diagnostic (P9TBD) was developed as part of a new experimental platform used to study laser–plasma interactions on OMEGA. Located in the opposing port to the wavelength-tunable (350 nm to 353 nm) UV drive beam, the P9TBD characterizes the beam after it propagates through an undersense plasma. The instrument consists of a large-aperture window that allows light to exit the target chamber and project onto a thin sheet of semi-transparent diffuser material. Light transmitted through the diffuser is recorded using a time-integrated camera and a fiber-optically coupled streaked spectrometer, providing measurements of the energy, power, fluence, polarization, and spectrum of the transmitted beam. Here, the diagnostic enables direct observation of a variety of cross-beam energy transfer phenomena, such as wavelength detuning, polarization effects, and gain saturation.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Respirator Cartridge Performance on Mixed Vapors from Hanford Tank Headspaces and Exhausters - 20427

Between 2016 and 2018, the Hanford Tank Operations Contractor - Washington River Protection Solutions (WRPS) - conducted a series of tests of air-purifying respirator (APR) chemical cartridges commonly used at Hanford tank farms to determine the period of time for which the cartridges would provide adequate performance when used in APRs and powered-air-purifying respirators (PAPRs) to protect workers when exposed to a mixture of vapors exiting tank headspaces. Although cartridge manufacturers provide service life estimating tools for individual chemical compounds, the projected performance of these cartridges on complex vapor mixtures is not available, and the adequacy of APRs for tank farm applications represents an important workforce concern. The Occupational Safety and Health Administration identifies cartridge testing as a valid approach for establishing cartridge service life. The primary function of the WRPS Cartridge Test Program was to obtain objective data to determine service lives for the APR and PAPR cartridges used at Hanford tank farms. WRPS contracted with Pacific Northwest National Laboratory to analyze the test data and offer an independent analysis of and recommendations based on respirator cartridge performance. A total of 28 APR and 10 PAPR cartridge tests were conducted between 2016 and 2018 on 12 different tank headspaces and tank farm exhauster slipstreams. Two APR cartridges from SCOTT (now 3M) and two PAPR cartridges from MSA Safety, Inc. and 3M were evaluated using a cartridge testing system specifically designed to measure and monitor test conditions and sample cartridge inlet and outlet vapor streams for important chemical compounds. Testing focused on analysis of approximately 61 tank vapor chemicals of potential concern (COPCs) that have been previously detected in tank vapors at levels above 10% of their occupational exposure limits (OELs). Each test was conducted over 16 hours of run time. Evidence of chemical breakthrough was assessed by comparing inlet and outlet COPC concentrations over the duration of each test. The breakthrough threshold was normally defined as exceeding 10% of the compounds OEL at the cartridge outlet. Ammonia breakthrough was observed in a majority of the cartridge tests and occurred earlier than breakthrough of any other chemical compound. Several other COPCs did exhibit breakthrough behavior, including mercury, 1,3-butadiene, furan, 2,5 dihydrofuran, and N-nitrosodimethylamine (NDMA), but only in a very limited number of cartridge tests and only after ammonia breakthrough had occurred. In addition, tests results suggest that breakthrough of some of these COPCs may have been affected by competition with and breakthrough of other non-COPC organics, such as ethanol and acetone, with substantially lower toxicological hazard. Comparison of cartridge manufacturers' service life estimates with the experimentally derived breakthrough times indicates that manufacturers' estimates are generally conservative, even in the presence of the complex mixed vapor streams experienced in these tests. With consideration of appropriate safety margins, these results provide valuable insights on cartridge performance to inform industrial hygiene professionals in establishing appropriate cartridge change-out schedules for APR and PAPR use in the Hanford tank farms. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Towards understanding the development and characteristics of under-expanded flash boiling jets

Here in this research, the n-hexane jets discharged from a straight channel were studied numerically to reveal the development and characteristics of under-expanded flashing jets. Firstly, the development of flash boiling jets was investigated and compared to that of two-phase jets without phase transition. It was shown that the two-phase jets without phase transition can be under-expanded only if the flow is choked. In contrast, flash boiling jets can be under-expanded whether or not the choked conditions are verified. Secondly, the factors affecting the flashing jet behaviors were discussed. The relaxation time in phase transition, the expansion ratio, and the injection pressure have been identified as three key factors determining the jet characteristics. With high enough expansion ratio and low enough relaxation time, the expansion was so strong that the flow became transonic and shock structures similar to those of under-expanded gaseous jets appeared near the orifice exit. Finally, two types of choking have been identified for flash boiling jets, i.e., vaporization-induced choking and expansion-induced choking. The former one is mainly ascribed to the vapor formation in the orifice which reduces the local speed of sound, while the latter one is due to the expansion of under-expanded two-phase flow and the resultant flow acceleration.

42 ENGINEERING↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) Cartridge Performance Testing on Hanford Tanks SX-101 and SX-104: Volume 2 - Raw Analytical Data

As the Tank Operations Contractor for U.S. Department of Energy operations at the Hanford site in Washington State, Washington River Protection Solutions (WRPS) is responsible for managing highly radioactive wastes stored in tanks at Hanford. To protect workers at Hanford Tank Farms, WRPS tests air-purifying respirator (APR) and powered air-purifying respirator (PAPR) chemical cartridges commonly used at the tank farms. The tests were conducted to determine the period of time the cartridges would provide adequate performance for APRs and PAPRs when workers are exposed to a mixture of Chemicals of Potential Concern (COPC) from any vapors exiting headspaces in the storage tanks. Occupational Safety and Health Administration (OSHA) Standard 29 Code of the Federal Regulations (CFR) 1910.134(d)(3)(iii)(b)(2) specifies that for protection against gases and vapors, employers shall implement a schedule for cartridges to ensure that change-outs occur before the end of service life. The change schedule can be based on objective information or data that ensures cartridge change-outs occur before the end of their service life. The primary function of the WRPS Cartridge Test Program is to obtain objective data to determine service lives for the APR and PAPR cartridges used at Hanford Tank Farms. WRPS contracted with Pacific Northwest National Laboratory to analyze the test data and offer an independent analysis and any recommendations. This report summarizes data analysis of APR cartridge testing on headspace vapors from Hanford SX-101 and SX-104 single-shell tanks. Volume 1 of this report documents the testing, data analysis, results, conclusions, and recommendations resulting from the APR testing on SX-101 and SX-104 headspace vapors. Volume 2 provides an introduction to the raw data, including analytical laboratory analysis results that supported the analysis and conclusions documented in Volume 1.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) and Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on a Hanford AX Tank Farm Exhauster Slipstream Volume 2: Raw Analytical Data

As the Tank Operations Contractor for U.S. Department of Energy operations at the Hanford site in Washington State, Washington River Protection Solutions (WRPS) is responsible for managing highly radioactive wastes stored in tanks at Hanford. To protect workers at Hanford Tank Farms, WRPS tests air-purifying respirator (APR) and powered air-purifying respirator (PAPR) chemical cartridges commonly used at the tank farms. The tests were conducted to determine the period of time the cartridges would provide adequate performance for APRs and PAPRs when workers are exposed to a mixture of Chemicals of Potential Concern (COPC) from any vapors exiting headspaces in the storage tanks. Occupational Safety and Health Administration (OSHA) Standard 29 Code of the Federal Regulations (CFR) 1910.134(d)(3)(iii)(b)(2) specifies that for protection against gases and vapors, employers shall implement a schedule for cartridges to ensure that change-outs occur before the end of service life. The change schedule can be based on objective information or data that ensures cartridge change-outs occur before the end of their service life. The primary function of the WRPS Cartridge Test Program is to obtain objective data to determine service lives for the APR and PAPR cartridges used at Hanford Tank Farms. WRPS contracted with Pacific Northwest National Laboratory to analyze the test data and offer an independent analysis and any recommendations. This report summarizes data analysis of APR and PAPR cartridge testing on a vapor slipstream from the Hanford AX tank farm exhauster. Volume 1 of this report documents the testing, data analysis, results, conclusions, and recommendations resulting from the cartridge testing on AX exhauster slipstream vapors. Volume 2 provides an introduction to the raw data, including analytical laboratory analysis results that supported the analysis and conclusions documented in Volume 1.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Analysis of Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on Hanford Tanks SX-101 and SX-104 Volume 1

Washington River Protection Solutions (WRPS) conducted tests using two types of chemical cartridges for use in powered air-purifying respirators (PAPR) to determine the period of time that the cartridges would provide adequate performance for PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPCs) from vapors exiting the headspaces of Hanford tanks SX-101 and SX-104. The Occupational Safety and Health Administration (OSHA) considers cartridge testing to be a valid approach for establishing cartridge change schedules. Testing is commonly applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate the cartridge service life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Testing was conducted from June 16-17, 2017, from headspace vapors from Hanford tank SX-101 and from June 23-24, 2017, from Hanford tank SX-104. Headspace vapors were fed to a respirator cartridge test stand developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Multipurpose high-efficiency PAPR cartridges, MSA-TL (TL1) (MSA Safety Inc., Pittsburgh, Pennsylvania) and 3M FR-57 (TL2) (3M Company, Maplewood, Minnesota) were assessed on separate days. Sample media (i.e., sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridge and were subsequently analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life. The key conclusions from the analysis are described below.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Analysis of Respirator Cartridge Performance Testing on a Hanford AP Tank Farm Primary Exhauster Slipstream

Washington River Protection Solutions (WRPS) conducted tests on two types of chemical cartridges for use in air purifying respirators (APR) to determine the period of time that the cartridges would provide adequate performance1 for APRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPCs) from vapors exiting the exhauster for the Hanford AP tank farm. The Occupational Safety and Health Administration (OSHA) identifies cartridge testing as a valid approach for establishing a cartridge change schedules. Testing is commonly applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate cartridge service life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Testing was conducted from June 24-26, 2016, on a slipstream from the AP exhauster fed to a respirator cartridge test stand developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Multipurpose respirator cartridges, SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina) were assessed on separate days. Sample media (sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridge and were subsequently analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Analysis of Respirator Cartridge Performance Testing on the 702-AZ Primary Exhauster for the Hanford AY/AZ Tank Farms during a Waste-Disturbing Event

Washington River Protection Solutions (WRPS) conducted tests using two types of chemical cartridges for use in air-purifying respirators (APR) to determine the period of time that the cartridges would provide adequate performance1 for APRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPC) from vapors exiting the 702-AZ Primary Exhauster for the Hanford AY-AZ tank farms. Unlike prior cartridge testing on the 702-AZ Primary Exhauster, the recent tests were performed during a waste-disturbing event. The Occupational Safety and Health Administration (OSHA) identifies cartridge testing as a valid approach for establishing a cartridge change schedules. Testing is commonly applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate the cartridge service life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Testing was conducted from February 10–11, 2017, on a slipstream from the 702-AZ exhauster fed to a respirator cartridge test stand developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Multipurpose respirator cartridges, SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina), were assessed on separate days. Sample media (sorbent tubes) and canisters (e.g., Summa) sampling were used to collect samples of the vapor stream entering and exiting the respirator cartridge and were subsequently analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Analysis of Respirator Cartridge Performance Testing on a Hanford AW Tank Farm Exhauster Slipstream

Washington River Protection Solutions (WRPS) conducted tests on two types of chemical cartridges for use in air-purifying respirators (APR) to determine the period of time that the cartridges would provide adequate performance for APRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPCs) from vapors exiting the exhauster for the Hanford AW tank farm. The Occupational Safety and Health Administration (OSHA) identifies cartridge testing as a valid approach for establishing a cartridge change schedules. Testing is commonly applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate cartridge service-life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Testing was conducted from September 23-25, 2016, on a slipstream from the AW exhauster, under static conditions fed to a respirator cartridge test stand developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Multipurpose respirator cartridges, SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina), were assessed on separate days. Sample media (sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridge, and were subsequently analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) and Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on a Hanford AX Tank Farm Exhauster Slipstream Volume 1

Washington River Protection Solutions (WRPS) conducted tests of four types of chemical cartridges for air-purifying respirators (APR) and powered air-purifying respirators (PAPR) to determine the period of time the cartridges would provide adequate performance1 for APRs and PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPCs) from vapors exiting the Hanford AX tank farm exhauster slipstream. The Occupational Safety and Health Administration (OSHA) considers cartridge testing to be a valid approach for establishing a cartridge service life. Testing is applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate the cartridge service life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Cartridge testing using vapors from a Hanford AX tank farm exhauster slipstream was conducted from August 25–27, 2017. Vapors from the exhauster slipstream were fed to two respirator cartridge test stands developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Four different cartridges were assessed. Multipurpose APR cartridges—SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina)—were assessed on separate days using an APR cartridge test stand. Multipurpose PAPR cartridges—MSA-TL (TL1) (MSA Safety Inc., Pittsburgh, Pennsylvania) and 3M FR57 (TL2) (3M Company, Maplewood, Minnesota)—also were tested over the same two days using a separate PAPR cartridge test stand. Sample media (i.e., sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridges and were subsequently analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life. The key conclusions from the analysis are described below.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) and Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on a Hanford AP Tank Farm Exhauster Slipstream (Volume 1)

Washington River Protection Solutions (WRPS) tested four types of chemical cartridges for use in air-purifying respirators (APR) and powered air-purifying respirators (PAPR). These tests were undertaken to determine the period of time that the cartridges would provide adequate performance1 for APRs and PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPC) from vapors exiting the Hanford AP tank farm exhauster slipstream. The Occupational Safety and Health Administration (OSHA) considers cartridge testing to be a valid approach for establishing cartridge change schedules. Testing commonly is applied in situations where mixtures of COPCs exist and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate the cartridge service life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Cartridge testing on a slipstream from the Hanford AP tank exhauster was conducted on March 23-24, 2018. This testing focused on both APR and PAPR cartridges. Previous testing of APR cartridges was conducted on the AP exhauster in June of 2016. However, an AP exhauster upgrade was completed in September 2016. In the most recent testing, slipstream vapors from the new AP exhauster were fed to two respirator cartridge test stands, one for the PAPR respirator cartridges and the other for the APR respirator cartridges. Both the APR and PAPR test stands were developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Multipurpose APR cartridges—SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina)—were assessed on separate days using the APR cartridge test stand. Multipurpose PAPR cartridges—MSA OptiFilter TL (MSA Safety Inc., Pittsburgh, Pennsylvania) and 3M FR-57 (3M Company, Maplewood, Minnesota)—were also tested consecutively over the same two days as the APR cartridge tests, using the PAPR cartridge test stand. Sample media (i.e., sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridges, and the samples then were analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life. The key conclusions from the analysis are described below.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) and Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on Hanford Tanks BY-108 and BY-110 Volume 1

Washington River Protection Solutions (WRPS) tested four types of chemical cartridges for use in air-purifying respirators (APR) and powered air-purifying respirators (PAPR). These tests were undertaken to determine the period of time that the cartridges would provide adequate performance for APRs and PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPC) from vapors exiting the headspaces of Hanford BY-108 and BY-110 waste storage tanks. The Occupational Safety and Health Administration (OSHA) considers cartridge testing to be a valid approach for establishing cartridge change schedules. Testing commonly is applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate the cartridge service life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Cartridge tests were conducted over two days from February 23-25, 2018, using headspace vapors from Hanford tanks BY-108 and BY-110. Headspace vapors from the BY-108 tank were fed to the PAPR respirator cartridge test stand, while vapors from the BY-110 headspace were fed to the APR respirator cartridge test stand. Both the APR and PAPR test stands were developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Two different cartridges were assessed on each tank. Multipurpose APR cartridges—SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina)—were assessed for vapors from BY-110 using the APR cartridge test stand. Multipurpose PAPR cartridges—MSA OptiFilter TL (MSA Safety Inc., Pittsburgh, Pennsylvania) and 3M FR-57 (3M Company, Maplewood, Minnesota)—also were assessed for vapors from BY-108 over the same two days using the PAPR cartridge test stand. Sample media (i.e., sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridges, and the samples then were analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life. The key conclusions from the analysis are described below.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Analysis of Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on Hanford Tanks SX-101 and SX-104: Volume 2 Raw Analytical Data

As the Tank Operations Contractor for U.S. Department of Energy operations at the Hanford site in Washington State, Washington River Protection Solutions (WRPS) is responsible for managing highly radioactive wastes stored in tanks at Hanford. WRPS tests of cartridges used in air-purifying respirators (APR) and powered air-purifying respirators (PAPR) commonly used at Hanford Tank Farms. The tests are conducted to determine the period of time the cartridges would provide adequate performance for APRs and PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPC) from any vapors exiting headspaces in the storage tanks. Occupational Safety and Health Administration (OSHA) Standard 29 Code of the Federal Regulations (CFR) 1910.134(d)(3)(iii)(b)(2) specifies that for protection against gases and vapors, employers shall implement a schedule for cartridges to ensure that change-outs occur before the end of service life. The change schedule can be based on objective information or data that ensures cartridge change-outs occur before the end of their service life. The primary function of the WRPS Cartridge Test Program is to obtain objective data to determine service lives for the APR and PAPR cartridges used at Hanford Tank Farms. WRPS contracted with Pacific Northwest National Laboratory to analyze the test data and offer an independent analysis and any recommendations. This report summarizes data analysis of PAPR cartridge testing on headspace vapors from Hanford SX-101 and SX-104 single-shell tanks. Two different PAPR cartridges—one from MSA Safety Inc. (Pittsburgh, Pennsylvania) and another from 3M (Maplewood, Minnesota)—were assessed on each tank headspace source on separate days. These data represent the first PAPR cartridge testing under the recent WRPS program, as testing to date had been focused on APR cartridges. Volume 1 of this report documents the testing, data analysis, results, conclusions, and recommendations resulting from the PAPR testing on SX-101 and SX-104 headspace vapors. Volume 2 provides an introduction to the raw data, including analytical laboratory analysis results that supported the analysis and conclusions documented in Volume 1.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Stream lamination and rapid mixing in a microfluidic jet for X-ray spectroscopy studies

Microfluidic mixers offer new possibilities for the study of fast reaction kinetics down to the microsecond time scale, and methods such as soft X-ray absorption spectroscopy are powerful analysis techniques. These systems impose challenging constraints on mixing time scales, sample volume, detection region size and component materials. The current work presents a novel micromixer and jet device which aims to address these limitations. The system uses a so-called ‘theta’ mixer consisting of two sintered and fused glass capillaries. Sample and carrier fluids are injected separately into the inlets of the adjacent capillaries. At the downstream end, the two streams exit two micron-scale adjoining nozzles and form a single free-standing jet. The flow-rate difference between the two streams results in the rapid acceleration and lamination of the sample stream. This creates a small transverse dimension and induces diffusive mixing of the sample and carrier stream solutions within a time scale of 0.9 microseconds. The reaction occurs at or very near a free surface so that reactants and products are more directly accessible to interrogation using soft X-ray. We use a simple diffusion model and quantitative measurements of fluorescence quenching (of fluorescein with potassium iodide) to characterize the mixing dynamics across flow-rate ratios.

Huyke, Diego A. (ORCID:0000000283356613)↗
DOE OSTI2024

Chaotic LLM billiards

Abstract We study null geodesics of the ten-dimensional LLM geometries. In particular, we show that there are a subset of these null geodesics that are confined to the LLM plane. The effective dynamics of these in-plane geodesics is that of a Hamiltonian system with two degrees of freedom (a phase space of dimension 4). We show that these are chaotic. In the two-coloring of the LLM plane, if they start in the empty region, they cannot penetrate the filled region and viceversa. The dynamical problem is therefore very similar to that of a billiards problem with fixed obstacles. We study to what extent LLM geometries with many droplets may be treated as an incipient black hole and draw analogies with the fuzzball proposal. We argue that for in-plane null geodesics deep in the interior of a region with a lot of droplets, in order to exit towards theAdSboundary they will need to undergo a process that resembles diffusion. This mechanism can account for signals getting lost in the putative black hole for a very long time.

Physics↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) and Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on a Hanford AP Tank Farm Exhauster Slipstream: Volume 2 Raw Analytical Data

As the Tank Operations Contractor for U.S. Department of Energy operations at the Hanford site in Washington State, Washington River Protection Solutions (WRPS) is responsible for managing highly radioactive wastes stored in tanks at Hanford. WRPS tests air-purifying respirator (APR) and powered air-purifying respirator (PAPR) chemical cartridges commonly used at Hanford Tank Farms to determine the period of time that the cartridges would provide adequate performance for APRs and PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPC) from any vapors exiting headspaces in the storage tanks. The Occupational Safety and Health Administration (OSHA) Standard promulgated in Title 29 of the Code of the Federal Regulations (CFR) 1910.134(d)(3)(iii)(b)(2) specifies that for protection against gases and vapors, employers shall implement a schedule for cartridges to ensure that change-outs occur before the end of service life. The change schedule can be based on objective information or data that ensures cartridge change-outs occur before the end of their service life.[2-5] The primary function of the WRPS Cartridge Test Program is to obtain objective data to determine service lives for the APR and PAPR cartridges used at Hanford Tank Farms. WRPS contracted with Pacific Northwest National Laboratory to analyze the test data and offer an independent analysis and any recommendations. Volume 1 of this report summarizes data analysis of APR and PAPR cartridge testing on vapors from the AP tank farm exhauster. Previous testing of APR cartridges was conducted on the AP exhauster in June 2016. However, an AP exhauster upgrade was completed in September 2016. Two different APR cartridges from SCOTT Safety (Monroe, North Carolina) were assessed for the new AP exhauster source, along with two different PAPR cartridges—one from MSA Safety Inc. (Pittsburgh, Pennsylvania) and another from 3M (Maplewood, Minnesota). Volume 2 provides an introduction to the raw data, including analytical laboratory analysis results that supported the analysis and conclusions documented in Volume 1.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) and Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on Hanford Tanks BY-108 and BY-110 Volume 2: Raw Analytical Data

As the Tank Operations Contractor for U.S. Department of Energy operations at the Hanford site in Washington State, Washington River Protection Solutions (WRPS) is responsible for managing highly radioactive wastes stored in tanks at Hanford. WRPS tests air-purifying respirator (APR) and powered air-purifying respirator (PAPR) chemical cartridges commonly used by workers at Hanford Tank Farms to determine the period of time that the cartridges would provide adequate performance for APRs and PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPC) from any vapors exiting headspaces in the storage tanks. The Occupational Safety and Health Administration (OSHA) Standard promulgated in Title 29 of the Code of the Federal Regulations (CFR) 1910.134(d)(3)(iii)(b)(2) specifies that for protection against gases and vapors, employers shall implement a schedule for cartridges to ensure that change-outs occur before the end of service life. The change schedule can be based on objective information or data that ensures cartridge change-outs occur before the end of their service life. The primary function of the WRPS Cartridge Test Program is to obtain objective data to determine service lives for the APR and PAPR cartridges used at Hanford Tank Farms. WRPS contracted with Pacific Northwest National Laboratory to analyze the test data and offer an independent analysis and any recommendations. This report summarizes data analysis of APR and PAPR cartridge testing on BY-110 and BY-108 headspace vapors, respectively. Two different APR cartridges from SCOTT Safety (Monroe, North Carolina) were assessed for the BY-110 headspace vapors, and two different PAPR cartridges—one from MSA Safety Inc. (Pittsburgh, Pennsylvania) and another from 3M (Maplewood, Minnesota)—were assessed for the BY-108 headspace vapors. Volume 1 of this report documents the testing, data analysis, results, conclusions, and recommendations resulting from the cartridge testing of vapors from the BY-110 and BY-108 headspaces. Volume 2 provides an introduction to the raw data, including analytical laboratory analysis results that supported the analysis and conclusions documented in Volume 1.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗