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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Ultralow Thermal Conductivity, Multiband Electronic Structure and High Thermoelectric Figure of Merit in TlCuSe

The entanglement of lattice thermal conductivity, electrical conductivity, and Seebeck coefficient complicates the process of optimizing thermoelectric performance in most thermoelectric materials. Semiconductors with ultralow lattice thermal conductivities and high power factors at the same time are scarce but fundamentally interesting and practically important for energy conversion. In this work, an intrinsic p-type semiconductor TlCuSe that has an intrinsically ultralow thermal conductivity (0.25 W m -1 K -1 ), a high power factor (11.6 μ W cm -1 K -2 ), and a high figure of merit, ZT (1.9) at 643 K is described. The weak chemical bonds, originating from the filled antibonding orbitals p-d* within the edge-sharing CuSe 4 tetrahedra and long Tl-Se bonds in the PbClF-type structure, in conjunction with the large atomic mass of Tl lead to an ultralow sound velocity. Strong anharmonicity, coming from Tl + lone-pair electrons, boosts phonon-phonon scattering rates and further suppresses lattice thermal conductivity. The multiband character of the valence band structure contributing to power factor enhancement benefits from the lone-pair electrons of Tl + as well, which modify the orbital character of the valence bands, and pushes the valence band maximum off the Gamma-point, increasing the band degeneracy. The results provide new insight on the rational design of thermoelectric materials.

36 MATERIALS SCIENCE↗
NASA NTRS1991

Oxygen plant breadboard design, and techniques for improving mission figure-of-merit

A breadboard oxygen plant to process anaerobic carbon dioxide is designed and constructed; the objective is not only to produce a key propellant component extraterrestrially, but also to develop the important technologies that are necessary for a successful operation of in-situ materials utilization hardware. The solid electrolytic cells are supplied to specifications by an established vendor. The cell thermal control, electrical control, and flow control are installed after detailed designs. Extensive data are obtained that characterize the operation of the plant as the input parameters are varied. The initial mass, energy, and volume-needs provide the input to a figure-of-merit software program to calculate the impact of various candidate technologies upon the overall mission. The desirability of studies on storage and high-density propellants is shown. This task dovetails into other tasks that are evaluating alternative cell materials, catalysis for compactness, and smart sensors for effective control.

Ramohalli, Kumar↗
NASA NTRS2010

Figure of Merit Characteristics Compared to Engineering Parameters

A workshop held in 2005 defined a large number of parameters of interest for users of lunar simulants. The need for formal requirements and standards in the manufacture and use of simulants necessitates certain features of measurements. They must be definable, measureable, useful, and primary rather than derived. There are also certain features that must be avoided. Analysis of the total parameter list led to the realization that almost all of the parameters could be tightly constrained, though not predicted, if only four properties were measured: Particle composition, particle size distribution, particle shape distribution, and bulk density. These four are collectively referred to as figures of merit (FoMs). An evaluation of how each of the parameters identified in 2005 is controlled by the four FoMs is given.

Rickman, D.L.↗
NASA NTRS1989

Interdependent figure-of-merit software development

This program was undertaken in order to understand the complex nature of interdependent performance in space missions. At the first step in a planned sequence of progress, a spread sheet program was developed to evaluate different fuel/oxidizer combinations for a specific Martian mission. This program is to be linked with output attained using sophisticated software produced by Gordon and McBride. The programming to date makes use of 11 independent parameters. Optimization is essential when faced with the incredible magnitude of costs, risks, and benefits involved with space exploration. A system of weights needs to be devised on which to measure the options. It was the goal to devise a Figure of Merit (FoM) on which different choices can be presented and made. The plan was to model typical missions to Mars, identify the parameters, and vary them until the best one is found. Initially, most of the focus was placed on propellant selection.

Ramohalli, K.↗
DOE OSTI2023

High figure of merit extreme bandgap Al 0.87 Ga 0.13 N-Al 0.64 Ga 0.36 N heterostructures over bulk AlN substrates

We report on high-quality n -Al 0.87 Ga 0.13 N-A 0.64 Ga 0.36 N heterostructures over single crystal AlN. For these pseudomorphic heterostructures, high-resolution X-ray and X-ray Topographic analysis was used to establish a threading dislocation density of 7 × 10 3 cm -2 . Using reverse composition graded n + -Al x Ga 1- x N contact layers, we obtained linear ohmic contacts with 4.3 Ω mm specific resistance. A critical breakdown field >11 MV cm -1 was also measured. In combination with the channel resistance of 2400 Ω sq -1 , these translate to a Baliga’s Figure of Merit of 2.27 GW cm -2 . This, to the best of our knowledge is the highest reported value for extreme bandgap AlGaN heterostructures.

42 ENGINEERING↗
NASA NTRS2009

Lunar Regolith Characterization for Simulant Design and Evaluation using Figure of Merit Algorithms

NASA's Marshall Space Flight Center (MSFC), in conjunction with the United States Geological Survey (USGS) and aided by personnel from the Astromaterials Research and Exploration Science group at Johnson Space Center (ARES-JSC), is implementing a new data acquisition strategy to support the development and evaluation of lunar regolith simulants. The first analyses of lunar regolith samples by the simulant group were carried out in early 2008 on samples from Apollo 16 core 64001/64002. The results of these analyses are combined with data compiled from the literature to generate a reference composition and particle size distribution (PSD)) for lunar highlands regolith. In this paper we present the specifics of particle type composition and PSD for this reference composition. Furthermore. we use Figure-of-Merit (FoM) routines to measure the characteristics of a number of lunar regolith simulants against this reference composition. The lunar highlands regolith reference composition and the FoM results are presented to guide simulant producers and simulant users in their research and development processes.

Schrader, Christian M.↗
DOE OSTI2025

Nernst power factor and figure of merit in the compensated semimetal ScSb

Recently, topological semimetals have emerged as strong candidates for solid-state thermomagnetic refrigerators due to their enhanced Nernst effect. This enhancement arises from the combined contributions of the Berry-curvature-induced anomalous Nernst coefficient associated with topological bands and the normal Nernst effect resulting from synergistic electron-hole compensation. Generally, these two effects are intertwined in topological semimetals, making it challenging to evaluate them independently. Here, we report the observation of a high Nernst effect in the electron-hole compensated semimetal ScSb with topologically trivial electronic band structures. Remarkably, we find a high maximum Nernst power factor of 𝑃⁢𝐹 𝑁 ∼ 35 × 10 −4 W m −1 K −2 in ScSb. The Nernst thermopower (𝑆 𝑥⁢𝑦 ) exhibits a peak of ∼ 47 µ⁢V/K at 12 K and 14 T, yielding a Nernst figure of merit (𝑧 𝑁 ) of ∼ 28 × 10 −4 K −1 . Notably, despite its trivial electronic band structure, both the 𝑃⁢𝐹 𝑁 and 𝑧 𝑁 values of ScSb are comparable to those observed in topological semimetals with Dirac band dispersions. In conclusion, the origin of the large Nernst signal in ScSb is explained by compensated electron and hole carriers, through Hall resistivity measurements, angle-resolved photoemission spectroscopy, and density functional theory calculations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

All-atmospheric fabrication of Ag–Cu core–shell nanowire transparent electrodes with Haacke figure of merit >600 × 10–3 Ω−1

Abstract Transparent conducting electrodes (TCEs) are essential components in devices such as touch screens, smart windows, and photovoltaics. Metal nanowire networks are promising next-generation TCEs, but best-performing examples rely on expensive metal catalysts (palladium or platinum), vacuum processing, or transfer processes that cannot be scaled. This work demonstrates a metal nanowire TCE fabrication process that focuses on high performance and simple fabrication. Here we combined direct and plating metallization processes on electrospun nanowires. We first directly metallize silver nanowires using reactive silver ink. The silver catalyzes subsequent copper plating to produce Ag–Cu core–shell nanowires and eliminates nanowire junction resistances. The process allows for tunable transmission and sheet resistance properties by adjusting electrospinning and plating time. We demonstrate state-of-the-art, low-haze TCEs using an all-atmospheric process with sheet resistances of 0.33 Ω sq −1 and visible light transmittances of 86% (including the substrate), leading to a Haacke figure of merit of 652 × 10 –3 Ω −1 . The core–shell nanowire electrode also demonstrates high chemical and bending durability.

36 MATERIALS SCIENCE↗
NASA NTRS1990

A figure-of-merit approach to extraterrestrial resource utilization

A concept is developed for interrelated optimizations in space missions that utilize extraterrestrial resources. It is shown that isolated (component) optimizations may not result in the best mission. It is shown that substantial benefits can be had through less than the best propellants, propellant combinations, propulsion hardware, and actually, some waste in the traditional sense. One ready example is the possibility of discarding hydrogen produced extraterrestrially by water splitting and using only the oxygen to burn storable fuels. The gains in refrigeration and leak-proof equipment mass (elimination) outweigh the loss in specific impulse. After a brief discussion of this concept, the synthesis of the four major components of any future space mission is developed. The four components are: orbital mechanics of the transportation; performance of the rocket motor; support systems that include power; thermal and process controls, and instruments; and in situ resource utilization plant equipment. This paper's main aim is to develop the concept of a figure-of-merit for the mission. The Mars Sample Return Mission is used to illustrate the new concept. At this time, a popular spreadsheet is used to quantitatively indicate the interdependent nature of the mission optimization. Future prospects are outlined that promise great economy through extraterrestrial resource utilization and a technique for quickly evaluating the same.

Ramohalli, K.↗
DOE OSTI2024

Evaluating direct vessel injection accident-event progression of AP1000 and key figures of merit to support the design and development of water-cooled small modular reactors

The passive safety systems (PSSs) within water-cooled reactors are meticulously engineered to function autonomously, requiring no external power source or manual intervention. They depend exclusively on inherent natural forces and the fundamental principles of reactor physics, such as gravity, natural convection, and phase changes, to manage, alleviate, and avert the release of radioactive materials into the environment during accident scenarios like a loss-of-coolant accident (LOCA). PSSs are already integrated into such operating commercial reactors as the Advanced Pressurized Reactor-1000 MWe (AP1000) and the Water-Water Energetic Reactor-1200 MWe (WWER-1200) are adopted in most of the upcoming small modular reactor (SMR) designs. Examples of water-cooled SMR PSSs are the passive emergency core-cooling system (ECCS), passive containment cooling system (PCCS), and passive decay-heat removal system, the designs of which vary based on reactor system-design requirements. However, understanding the accident-event progression and phases of a LOCA is pivotal for adopting a specific PSS for a new SMR design. This study covers the accident-event progression for direct vessel injection (DVI) small-break loss-of-coolant accident (SB-LOCA), associated physics phenomena, knowledge gaps, and important figures of merit (FOMs) that may need to be evaluated and assessed to validate thermal-hydraulics models with an available experimental dataset to support new SMR design and development.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2020

ELM control optimization for various ITER scenarios based on linear and quasi-linear figures of merit

For the purpose of better understanding type-I edge localized mode (ELM) control in ITER with resonant magnetic perturbation (RMP) fields, the plasma response to RMP is computed by a resistive full magneto-hydrodynamic model in toroidal geometry. Five scenarios designed for ITER are considered, ranging from the pre-nuclear to nuclear phases. The plasma response to RMP is quantified by the plasma surface displacement near the X-point of the divertor plasma and at the outboard mid-plane. The optimal coil configurations between two high- Q deuterium-tritium (DT) scenarios (at the same plasma current of 15 MA and the same magnetic field of 5.3 T but different fusion gains, Q = 5 and 10) are predicted to be similar. For the other ITER scenarios with similar edge safety factor q 95 ~ 3 to that of the baseline scenario, the optimal coil phasing is also similar. The optimization results are different for a half-current full-field (7.5 MA/5.3 T) scenario, largely due to the difference in q 95 . The RMP coil currents are also optimized to tailor the core vs edge toroidal torques exerted by the 3D RMP fields on the plasma column. Torque optimization, with various objective functions proposed in the study, is useful for minimizing the side effects of RMP on the plasma core flow in ITER, while still maintaining the ELM control capability. Full utilization of three rows of ELM control coils in ITER is found to be essential to ensure both flexibility and robustness of ELM control, in terms of both linear and quasilinear plasma responses.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

High figure of merit spin polarized electron sources grown via MOCVD

Spin polarized photocathodes are key to the future operation of electron accelerators such as the ones at Thomas Jefferson National Accelerator Facility and Brookhaven National Laboratory. Currently, these photocathodes come in short supply due to limited production by molecular beam epitaxy. By developing a process to implement similar structures using metal organic chemical vapor deposition, the availability of these devices can be increased. Here, in this paper, we detail the implementation of recent photocathode advancements via metal organic chemical vapor deposition process and show an improvement in both polarization and quantum efficiency of our devices compared to those fabricated via molecular beam epitaxy, with devices reaching 82% polarization and 2.9% quantum efficiency.

43 PARTICLE ACCELERATORS↗
NASA NTRS1983

A figure of merit for competing communications satellite designs

Trends in launch schedules, weights, power, and space segment costs per transponder year for Intelsats and North American domsats (domestic communications satellites) are discussed. The Intelsat system currently services 25,000 point to point telephone links at any one moment, and a $3 billion order has been placed for Intelsat VIs, which feature 36,000 telephone circuits each. The Intelsat VI spacecraft will weigh 1670 kg in orbit, a continuance of the trend to heavier satellites, while the domsats will stay at 650 kg due to launch vehicle limitations. Direct television broadcast satellites are being designed for receive only (R/O) earth stations, with each satellite capable of servicing 50,000 individual ground stations. Competition is growing for C and Ku band satellite transponders for DBS, with costs $350,000 each. No standardized design has yet emerged.

Lovell, R. R.↗